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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 703 records · Page 39
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Spatially Resolved Characterisation of Low Mass Fraction Uranium Glass Working Reference Materials

Here, we present the results of a study to generate reference glasses that reflect an environment analogous to historic nuclear fallout samples of interest for post-detonation nuclear forensics. The glasses were generated by melting and then quenching SiO 2 , Al 2 O 3 and CaCO 3 powders. Two suites of glasses with three distinct U isotopic ratios were successfully made with enrichments in the 235 U isotope (~ natural [0.72%], ~ 53% and 94%), but the bulk elemental data showed heterogeneity (~ 10% RSD) with U mass fractions ranging from 331.47 to 373.63 μg g -1 . Spatially resolved U isotopic measurements were performed using three mass spectrometry techniques (secondary ion mass spectrometry-single stage accelerator mass spectrometry [SIMS-SSAMS], large geometry [LG] - SIMS, and laser ablation-inductively coupled plasma-mass spectrometry [LA-ICP-MS]) across five National Laboratories. The results showed good agreement with the bulk U isotopic data for the low, medium, and high U mass fractions. We conclude that despite elemental heterogeneity, these samples can serve as useful working reference materials for spatially resolved nuclear fallout analyses, as well as for other related spatially resolved analyses.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Five draft genome assemblies from Bacillaceae isolated from a degraded wetland environment

Abstract We isolated 5 Bacillaceae from a degraded wetland environment and sequenced their genomes using Illumina NextSeq. Here, we report draft genome sequences of Bacillus velezensus-SC119, Priestia megaterium-SC120, Bacillus zhangzhouensis-SC123, Bacillus pumilis-SC124, and Bacillus idriensis-SC127. The genomes range between 3,657,353 and 5,772,725 base pairs with %GC between 37.62% and 46.38%. Introduction Wetland environments play critical roles in the terrestrial carbon and water cycles and microbial communities are key players in healthy ecosystem function. Endospore forming bacteria in the Bacillaceae family are metabolically and genomically diverse soil heterotrophs that influence plant health, carbon and nitrogen cycling, and often produce diverse natural products that influence other bacterial and non-bacterial species in their environment (1). We collected two soil samples on January 19, 2023 from 42°43'12.7"N 73°45'01.4"W. One was highly hydrated and within a patch of invasive common reeds (Phragmites sp.) and the other was near the base of an Eastern cottonwood tree (Populus deltoides). Bacillus pumilis strain SC124 was isolated from the soil from near the cottonwood tree, while Bacillus velezensis strain SC119, Priestia megaterium strain SC120, Bacillus zhangzhouensis strain SC123, Bacillus idriensis strain SC127 and were isolated from the marshy soil.

isolate, wetlands, genome announcement↗
DOE OSTI2022

Charge Compensation by Iodine Covalent Bonding in Lead Iodide Perovskite Materials

Metal halide perovskite materials (MHPs) are a family of next-generation semiconductors that are enabling low-cost, high-performance solar cells and optoelectronic devices. The most-used halogen in MHPs, iodine, can supplement its octet by covalent bonding resulting in atomic charges intermediate to I− and I0. Here, we examine theoretically stabilized defects of iodine using density functional theory (DFT); defect formation enthalpies and iodine Bader charges which illustrate how MHPs adapt to stoichiometry changes. Experimentally, X-ray photoelectron spectroscopy (XPS) is used to identify perovskite defects and their relative binding energies, and validate the predicted chemical environments of iodine defects. Examining MHP samples with excess iodine compared with near stoichiometric samples, we discern additional spectral intensity in the I 3d5/2 XPS data arising from defects, and support the presence of iodine trimers. I 3d5/2 defect peak areas reveal a ratio of 2:1, matching the number of atoms at the ends and middle of the trimer, whereas their binding energies agree with calculated Bader charges. Results suggest the iodine trimer is the preferred structural motif for incorporation of excess iodine into the perovskite lattice. Understanding these easily formed photoactive defects and how to identify their presence is essential for stabilizing MHPs against photodecomposition.

36 MATERIALS SCIENCE↗
DOE OSTI2023

The Demographics, Stellar Populations, and Star Formation Histories of Fast Radio Burst Host Galaxies: Implications for the Progenitors

We present a comprehensive catalog of observations and stellar population properties for 23 highly secure host galaxies of fast radio bursts (FRBs). Our sample comprises 6 repeating FRBs and 17 apparent nonrepeaters. We present 82 new photometric and 8 new spectroscopic observations of these hosts. Using stellar population synthesis modeling and employing nonparametric star formation histories (SFHs), we find that FRB hosts have a median stellar mass of ≈10 9.9 M ⊙ , mass-weighted age ≈5.1 Gyr, and ongoing star formation rate ≈1.3 M ⊙ yr -1 but span wide ranges in all properties. Classifying the hosts by degree of star formation, we find that 87% (20 of 23 hosts) are star-forming, two are transitioning, and one is quiescent. The majority trace the star-forming main sequence of galaxies, but at least three FRBs in our sample originate in less-active environments (two nonrepeaters and one repeater). Across all modeled properties, we find no statistically significant distinction between the hosts of repeaters and nonrepeaters. However, the hosts of repeating FRBs generally extend to lower stellar masses, and the hosts of nonrepeaters arise in more optically luminous galaxies. While four of the galaxies with the clearest and most prolonged rises in their SFHs all host repeating FRBs, demonstrating heightened star formation activity in the last ≲100 Myr, one nonrepeating host shows this SFH as well. Our results support progenitor models with short delay channels (i.e., magnetars formed via core-collapse supernova) for most FRBs, but the presence of some FRBs in less-active environments suggests a fraction form through more delayed channels.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1972

A computer program for Moessbauer data processing

A computer program to analyze Mossbauer data is presented in detail. The least-squares curve fitting techniques described apply to single line spectra, single hyperfine spectra, or when the constituent spectra are separated well enough to let the individual absorption peaks stand alone. The present program is not adapted for complex spectra resulting from the existence of several local environments in the absorber iron alloy. Sample problems are presented to aid the user in setting up and running the program. The program is written in FORTRAN 4 language for the Control Data 6000 series digital computer with the SCOPE 3.0 operating system and requires approximately 115,000 octal locations of core storage. A typical case with one absorption peak runs in 20 seconds, and a typical problem with six absorption peaks requires 50 seconds.

Howser, L. M.↗
NASA NTRS1972

Experiments with the Skylab fire detectors in zero gravity

The Skylab fire detector was evaluated in a zero gravity environment. To conduct the test, small samples of spacecraft materials were ignited in a 5 psi oxygen-rich atmosphere inside a combustion chamber. The chamber free-floated in the cabin of a C-135 aircraft, as the aircraft executed a Keplerian parabola. Up to 10 seconds of zero-gravity combustion were achieved. The Skylab fire-detector tubes viewed the flames from a simulated distance of 3m, and color movies were taken to record the nature of the fire. The experiments established the unique form of zero-gravity fires for a wide range of materials. From the tube-output data, the alarm threshold and detector time constant were verified for the Skylab Fire Detection System.

Linford, R. M. F.↗
NASA NTRS1981

Data-acquisition and control system for severe environments

Report evaluates control system by measuring accuracy and performance of system subcomponents, including interface wiring unit, power controller, and tape recorder. Test parameters establish variety of severe operation environments. Text features test program descriptions, sample readouts, and results. Summary of custom solar system simulator is included.

Source record↗
NASA NTRS1984

Balloon materials degradation (S1006)

The objective of this experiment is to assess the effects of long-term exposure of candidate balloon films, tapes, and lines to the hostile environment above the Earth's atmosphere. Degradation of mechanical and radiometric properties will be observed by a series of tests on exposed materials. The experiment is passive and will test candidate balloon films, tapes, and lines. The experiment will occupy one-third of a 3-in.-deep peripheral tray. Two additional identical sets of material will be prepared. The first set will be tested immediately and the second will be held in a controlled environment until the recovery of the samples placed on orbit. Tests will then be performed on this second set to determine any effects of aging. The specimens that are recovered from the Long Duration Exposure Facility will also be tested and the effects of long-duration exposure noted. In addition to these specimens, another set of specimens will be exposed at an accelerated exposure facility and the results will be compared with those of specimens exposed in situ.

Allen, D. H.↗
NASA NTRS1985

A theoretical basis for the analysis of redundant software subject to coincident errors

Fundamental to the development of redundant software techniques fault-tolerant software, is an understanding of the impact of multiple-joint occurrences of coincident errors. A theoretical basis for the study of redundant software is developed which provides a probabilistic framework for empirically evaluating the effectiveness of the general (N-Version) strategy when component versions are subject to coincident errors, and permits an analytical study of the effects of these errors. The basic assumptions of the model are: (1) independently designed software components are chosen in a random sample; and (2) in the user environment, the system is required to execute on a stationary input series. The intensity of coincident errors, has a central role in the model. This function describes the propensity to introduce design faults in such a way that software components fail together when executing in the user environment. The model is used to give conditions under which an N-Version system is a better strategy for reducing system failure probability than relying on a single version of software. A condition which limits the effectiveness of a fault-tolerant strategy is studied, and it is posted whether system failure probability varies monotonically with increasing N or whether an optimal choice of N exists.

Eckhardt, D. E., Jr.↗
NASA NTRS1984

Boundary layers of the earth's outer magnetosphere

The magnetospheric boundary layer and the plasma-sheet boundary layer are the primary boundary layers of the earth's outer magnetosphere. Recent satellite observations indicate that they provide for more than 50 percent of the plasma and energy transport in the outer magnetosphere although they constitute less than 5 percent by volume. Relative to the energy density in the source regions, plasma in the magnetospheric boundary layer is predominantly deenergized whereas plasma in the plasma-sheet boundary layer has been accelerated. The reconnection hypothesis continues to provide a useful framework for comparing data sampled in the highly dynamic magnetospheric environment. Observations of 'flux transfer events' and other detailed features near the boundaries have been recently interpreted in terms of nonsteady-state reconnection. Alternative hypotheses are also being investigated. More work needs to be done, both in theory and observation, to determine whether reconnection actually occurs in the magnetosphere and, if so, whether it is important for overall magnetospheric dynamics.

Eastman, T. E.↗
NASA NTRS1992

Constant-Frequency Pulsed Phase-Locked-Loop Measuring Device

Constant-frequency pulsed phase-locked-loop measuring device is sensitive to small changes in phase velocity and easily automated. Based on use of fixed-frequency oscillator in measuring small changes in ultrasonic phase velocity when sample exposed to such changes in environment as changes in pressure and temperature. Automatically balances electrical phase shifts against acoustical phase shifts to obtain accurate measurements of acoustical phase shifts.

Yost, William T.↗
NASA NTRS1992

Fiber pulling apparatus modification

A reduced gravity fiber pulling apparatus (FPA) was constructed in order to study the effects of gravity on glass fiber formation. The apparatus was specifically designed and built for use on NASA's KC-135 aircraft. Four flights have been completed to date during which E-glass fiber was successfully produced in simulated zero, high, and lunar gravity environments. In addition simulated lunar soil samples were tested for their fiber producing properties using the FPA.

Smith, Guy A.↗
NASA NTRS1993

Effects of atomic oxygen and ultraviolet radiation on candidate elastomeric materials for long duration missions. Test series no.1

Research was conducted at MSFC on the behavior of elastomeric materials after exposure to simulated space environment. Silicone S383 and Viton V747 samples were exposed to thermal vacuum, ultraviolet radiation, and atomic oxygen and then evaluated for changes in material properties. Characterization of the elastomeric materials included weight, hardness, optical inspection under normal and black light, spectrofluorescence, solar absorptance and emittance, Fourier transform infrared spectroscopy, and permeability. These results indicate a degree of sensitivity to exposure and provided some evidence of UV and atomic oxygen synergism.

Linton, R. C.↗
NASA NTRS1994

(Fe II) 1.53 and 1.64 micron emission from pre-main-sequence stars

We present flux-calibrated profiles of the (Fe II) 1.53 and 1.64 micron lines in five pre-main-sequence stars, PV Cep, V1331 Cyg, R Mon, and DG and HL Tau. The line centroids are blueshifted in all five sources, and four of the five have only blueshifted flux. In agreement with previous studies, we attribute the line asymmetries to local obscuration by dusty circumstellar disks. The absence of redshifted flux implies a minimum column density of obscuring material. The largest limit, N(sub H) greater than 3 x 10(exp 22)/sq cm, derived for V1331 Cyg, suggests disk surface densities greater than 0.05 g/sq cm and disk masses greater than 0.001 solar mass within a radius of approximately 200 AU. The narrow high-velocity lines in PV Cep, V1331 Cyg, and HL Tau require formation in well collimated winds. The maximum full opening angles of their winds range from less than 20 deg in V1331 Cyg to less than 40 deg in HL Tau. The (Fe II) data also yield estimates of the electron densities (n(sub e) approximately 10(exp 4)/cu cm), hydrogen ionization fractions (f(sub H(+)) approximately 1/3), mass-loss rates (approximately 10(exp -7) to 2 x 10(exp -6) solar mass/yr), and characteristic radii of the emitting regions (approximately 32 to approximately 155 AU). The true radial extents will be larger, and the mass-loss rates smaller, by factors of a few for the outflows with limited opening angles. In our small sample the higher mass stars have stronger lines, larger emitting regions, and greater mass-loss rates. These differences are probably limited to the scale and energetics of the envelopes, because the inferred geometries, kinematics and physical conditions are similar. The measured (Fe II) profiles samples both 'high'- and 'low'-velocity environments. Recent studies indicate that these regions have some distinct physical properties and may be spatially separate. The (Fe II) data show that similar sizes and densities can occur in both environments.

Hamann, Fred↗
NASA NTRS1993

Thermal infrared emission spectroscopy of natural surfaces: Application to desert varnish coatings on rocks

Thermal infrared spectroscopy has become an increasingly important tool for remote compositional analysis and geologic mapping. Most published laboratory measurements have been obtained in bidirectional reflection or transmission, whereas remotely sensed thermal infrared data are obtained by measuring the emitted energy. Section 2 of this paper describes a laboratory technique for determining calibrated emissivities of natural surfaces. Equations are developed to account for the energy reflected from the environment and to determine directly the sample temperature from measurements of hot and cold blackbody targets. Two methods for determining emissivity are developed: one in which only a hot sample measurement is made and the reflected background energy is removed by modeling, and a second in which the sample is cooled and the reflected energy is measured directly. Relative emissivity can be obtained to approximately 1% and absolute emissivities can be obtained to 2-15%, depending on the validity of the assumption that the emissivity of the sample is unity at some wavelength. The emission data agree well within the hemispherically integrated reflection data but point out probelms associated with bidirectional reflectance measurements. Section 3 applies emissivity measurements to the study of layered surfaces consisting of desert varnish coatings on granite and granodiorite rock suites. Two linear models are developed: the first assumes linear mixing of independent emission from the substrate and varnish (checkerboard model); the second models tansmission through an absorbing/emitting medium. Regardless of whether the varnish is or is not relatively transparant and strongly absorptive, the spectral effect of varnish increases linearly with varnish thickness, indicating that thick patches of varnish dominate the spectral properties. As a result, medium varnish thickness can be determined from spectral measurements. In addition, the composition of a substrate can be estimated through varnish layers up to 40-50 micrometers in median thickness, and the composition of the varnish material can be determined if the substrate material is known. The varnishes studied are composed primarily of clay materials, consistent with previous studies of varnish composition.

Christensen, Philip R.↗
NASA NTRS1995

The Fluid Processing Apparatus: from Flight Hardware to Electron Micrographs

Since the early years of space biology, a major drawback in spaceflight plant experiments has been the inability to fix specimens in microgravity, relying instead on fixation after return to Earth. As there, it is of a growing interest to look at the effect of microgravity on the structure and the developmental polarity of root graviperceptive cells, or columella cells, and so, it is important to use flight hardware which allows specimen fixation in space therefore avoiding the confounding effects of rapid readaptation to gravity after landing. As part of the Bioserve Space Technologies, a Center for the Commercial Development of Space (CCDS), we now have experiment flight opportunities through the Commercial Generic Bioprocessing Apparatus (CGBA) payload. In this study the Fluid Processing Apparatus (FPA) was used to grow seedlings for a limited period of time prior to fixation of the tissue in a microgravity environment. Upon return to Earth, the samples were processed for electron microscopy. This report describes the microscopic data obtained from the two space flights (STS-54 and STS-60). In both cases, the electron micrographs of the columella cells revealed well preserved cell structure, well defined microtubules, and the presence of calcium precipitates formed by a antimonate precipitation method.

Hilaire, Emmanuel↗
NASA NTRS1996

Electromechanical Materials for Cryogenic Use

Electromechanical materials can be used in smart sensor and actuator devices. Yet none performing at low temperatures are available. To meet this need, Pb((MgNi)(1/3)Ta(2/3))03 was synthesized as an electrostrictive ceramic for applications in cryogenic environments. Employing the columbite precursor route, samples with 0% to 100% Ni substitution for Mg were prepared, but only samples with Ni-substitutions less than or equal to 20% yielded primarily the desired perovskite phase. For these compositions the temperature of highest permittivity decreased linearly with increasing Ni content to yield a minimum value of -124 C for 20% Ni-substitution. This composition showed good relaxor dielectric behavior with a maximum relative permittivity of 5890 at 1 kHz. Additionally, in samples with excess MgO, the magnitude of permittivity doubled. In this effort, Pb((MgNi)(1/3)Ta(2/3))03 (PMNiTa) was fabricated to lower its transition temperature by substituting Ni for Mg successively.

Leidinger, Peter↗