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At least 703 records · Page 39

Oscillator strengths for Si II

New accurate results are presented for absorption oscillator strengths of Si II resonance lines. In these ab initio calculations, an extensive basis set of 67 electronic configuration are employed, including fine-structure states and relativistic effects in the Breit-Pauli approximation. For the strong Si II lines, good agreement is found with previous LS-coupling f-values of Dufton et al. (1983). Oscillator strengths of selected weaker lines disagree in some cases with empirically determined f-values by Shull, Snow, and York (1981) and by Van Buren (1986). The theoretical results are combined with curve-of-growth analyses of Copernicus and IUE data to yield a list of recommended Si II oscillator strengths consistent with the errors in both theoretical and observational analyses. These f-values have been used (Van Steenberg and Shull) for a Galactic survey of interstellar silicon abundances with the International Ultraviolet Explorer satellite.

Luo, Ding↗

Analysis of Microstrip Lines with Alternative Implementation of Conductors and Superconductors

An analysis of microstrip line structures in which either the strip or the ground plane or both are made of a high Tc superconductor is presented. The effect of implementation of a superconductor to the strip and the ground plane is explained with the calculation of a conductor loss of the structure by the Phenomenological Loss Equivalence Method (PEM). The theoretical values are compared with the experimental results from a ring resonator which is made of a gold ground plane and a high Tc superconductor, YBa2Cu3O(7-x), strip.

Kong, K.-S.↗

Modeling of THz Lasers Based on Intersubband Transitions in Semiconductor Quantum Wells

In semiconductor quantum well structures, the intersubband energy separation can be adjusted to the terahertz (THz) frequency range by changing the well width and material combinations. The electronic and optical properties of these nanostructures can also be controlled by an applied dc electric field. These unique features lead to a large frequency tunability of the quantum well devices. In the on-going project of modeling of the THz lasers, we investigate the possibility of using optical pumping to generate THz radiation based on intersubband transitions in semiconductor quantum wells. We choose the optical pumping because in the electric current injection it is difficult to realize population inversion in the THz frequency range due to the small intersubband separation (4-40 meV). We considered both small conduction band offset (GaAs/AlGaAs) and large band offset (InGaAs/AlAsSb) quantum well structures. For GaAs/AlGaAs quantum wells, mid-infrared C02 lasers are used as pumping sources. For InGaAs/AlAsSb quantum wells, the resonant intersubband transitions can be excited by the near-infrared diode lasers. For three- and four-subband quantum wells, we solve the pumpfield-induced nonequilibrium distribution function for each subband of the quantum well system from a set of rate equations that include both intrasubband and intersubband relaxation processes. Taking into account the coherent interactions between pump and THz (signal) waves, we calculate the optical gain for the THz field. The gain arising from population inversion and stimulated Raman processes is calculated in a unified manner. A graph shows the calculated THz gain spectra for three-subband GaAs/AlGaAs quantum wells. We see that the coherent pump and signal wave interactions contribute significantly to the gain. The pump intensity dependence of the THz gain is also studied. The calculated results are shown. Because of the optical Stark effect and pump-induced population redistribution, the maximum THz gain saturates at larger pump intensities.

Liu, Ansheng↗

A possible prebiotic synthesis of pantetheine, a precursor to coenzyme A

The involvement of coenzyme A in many enzyme reactions suggests that it acted in this capacity very early in the development of life on Earth. Particularly relevant in this regard is its role in the activation of amino acids and hydroxy acids in the biosynthesis of some peptide antibiotics--a mechanism of peptide synthesis that forms the basis for the proposal that a thioester world could have preceded the RNA world. The components of coenzyme A have been shown to be probable prebiotic compounds: beta-alanine, pantoyl lactone and cysteamine and possibly adenosine. We show here that the pantetheine moiety of coenzyme A (which also occurs in a number of enzymes) can be synthesized in yields of several per cent by heating pantoyl lactone, beta-alanine and cysteamine at temperatures as low as 40 degrees C. These components are extremely soluble and so would have been preferentially concentrated in evaporating bodies of water, for example on beaches and at lagoon margins. Our results show that amide bonds can be formed at temperatures as low as 40 degrees C, and provide circumstantial support for the suggestion that pantetheine and coenzyme A were important in the earliest metabolic systems.

NASA Discipline Number 52-20↗

Scanning Tunneling Optical Resonance Microscopy Developed

The ability to determine the in situ optoelectronic properties of semiconductor materials has become especially important as the size of device architectures has decreased and the development of complex microsystems has increased. Scanning Tunneling Optical Resonance Microscopy, or STORM, can interrogate the optical bandgap as a function of its position within a semiconductor micro-structure. This technique uses a tunable solidstate titanium-sapphire laser whose output is "chopped" using a spatial light modulator and is coupled by a fiber-optic connector to a scanning tunneling microscope in order to illuminate the tip-sample junction. The photoenhanced portion of the tunneling current is spectroscopically measured using a lock-in technique. The capabilities of this technique were verified using semiconductor microstructure calibration standards that were grown by organometallic vapor-phase epitaxy. Bandgaps characterized by STORM measurements were found to be in good agreement with the bulk values determined by transmission spectroscopy and photoluminescence and with the theoretical values that were based on x-ray diffraction results.

Bailey, Sheila G.↗

LC Circuits for Diagnosing Embedded Piezoelectric Devices

A recently invented method of nonintrusively detecting faults in piezoelectric devices involves measurement of the resonance frequencies of inductor capacitor (LC) resonant circuits. The method is intended especially to enable diagnosis of piezoelectric sensors, actuators, and sensor/actuators that are embedded in structures and/or are components of multilayer composite material structures.

Chattin, Richard L.↗

Surface Plasmon Tunable Filter and Spectrometer-on-a-Chip

Surface plasmon tunable filter (SPTF) is a new technology invented in Jet Propulsion Lab. When a white light is incident on a metal/air/metal structure, in certain condition, surface plasmon waves can be excited at one metal/air material interface; those photons in surface plasmon resonances wavelength range will be converted into the energy of free electrons in the metal than coupled into the other metal film, and re-radiate out the color light.

Surface↗

Heteronuclear transition metal diatomics - The bonding and electronic structure of ScNi, YNi, ScPd, and YPd

High quality ab initio calculations show that ScNi, YNi, ScPd, and YPd all have 2Sigma(+) ground states in agreement with electron spin resonance experiments. For ScNi and YNi, this is expected based on the lowest atomic asymptote. For ScPd and YPd, the lowest atomic asymptote would give the order of stability 2Delta greater than 2Pi equal to about 2Sigma(+), but the calculations show that mixing in of the excited asymptotes preferentially lowers the 2Sigma(+) state. The calculations show that the quartet states are about 20-30 kcal/mol above the ground state, and therefore probably do not contribute significantly to the unexpected g(vertical) values found in experiment. Calculations of excited states for YPd reveal some strong transitions that should be amenable to spectroscopic studies.

Faegri, Knut, Jr.↗

A Direct Comparison Between EUV Coronal Flux and Helium Resonance Line Photon Flux from SOHO/CDS Data

In the wealth of EUV spectroscopic and imaging data gathered by the SOHO and TRACE missions, a prominent role is played by the helium resonance emission. For example, He I lines are among the most intense features in CDS/NIS spectra, while the EIT 304 waveband (dominated by He II emission) is routinely employed to map the structure of the solar chromosphere and transition region. However, no 'standard' model has emerged so far that is able to interpret observed He spectra/images to a satisfactory degree of self-consistency. Recent research on the problem of the formation of the solar helium spectrum tends to rule out a dominant role of coronal radiation in exciting He resonance lines. However, while evidence for this result is strong, it is based on indirect tests. Here we present a preliminary assessment of this issue based on a more direct approach, which involves a measure with CDS/GIS of the photoionizing EUV radiation. This measure can be directly compared with the observed flux in the main He I and He II resonance lines observed with CDS/NIS2.

Andretta, V.↗

The gyroscopic vibration absorber.

Frequency response, equation of motion, elastic restraint and structural flexibility of gyroscopic vibration absorber, noting antiresonant frequency functions

ROTOR GYROSCOPE↗

Parametric instabilities of rotor-support systems with application to industrial ventilators

Rotor support systems interaction with parametric excitation is considered for both unequal principal shaft stiffness (generators) and offset disc rotors (ventilators). Instability regions and types of instability are computed in the first case, and parametric resonances in the second case. Computed and experimental results are compared for laboratory machine models. A field case study of parametric vibrations in industrial ventilators is reported. Computed parametric resonances are confirmed in field measurements, and some industrial failures are explained. Also the dynamic influence and gyroscopic effect of supporting structures are shown and computed.

Parszewski, Z.↗

The ultraviolet spectrum of the peculiar A star HD 51418

High-dispersion observations of the peculiar A star HD 51418 have been carried out in the ultraviolet by the IUE satellite. Atomic resonance lines observed in the regions 1800-2000 and 2500-3000 A include those of Mg II, Ti II, Cr I, Cr II, Mn II, Fe II and Zn II, and possibly Si II, S I, V II, Fe I, Co II, Y II, Ce II, Ce III, Eu II, Eu III and Tb III. The Mg II 2796 and 2803 A resonance lines exhibit definite variations in equivalent width with orbital phase, which can be attributed to changes in the local atmospheric structure due to the patchy distribution of other elements. In addition, the observations confirm the well known trend for a light-heavy asymmetry in iron peak spectra similar to that observed in the rare earths.

Adelman, S. J.↗

Measurement of atomic oxygen and related airglows in the lower thermosphere

Instruments on board a sounding rocket were used to make simultaneous observations of atomic oxygen density and airglow emissions between 80 and 120 km. Atomic oxygen was measured with a resonance lamp and was found to have a peak density of 6 x 10 to the 11th at 94 km. Similar structure is seen in the oxygen density profile on both uplegs and downlegs. The following airglow emissions were measured by using vertical-viewing photometers: Herzberg I bands near 300 nm; O(1S) green line at 557.7 nm; background at 566 nm; O2(1 Delta g) bands at 1.27 microns; and OH (X 2 pi) Meinel bands near 1.7 microns.

Thomas, R. J.↗

Vibration damping characteristics of graphite/epoxy composites for large space structures

Limited data on extensional and flexural damping of small specimens of graphite/epoxy and unreinforced epoxy resin were obtained. Flexural damping was measured using a forced vibration technique based on resonant flexural vibration of shaker excited double cantilever specimens. Extensional damping was measured by subjecting similar specimens to low frequency sinusoidal oscillation in a servohydraulic tensile testing machine while plotting load versus extensional strain. Damping was found to vary slowly and continuously over the frequency range 0.01 - 1000 Hz, and no drastic transitions were observed. Composite damping was found to be less than neat resin damping. Comparison of small specimen damping values with assembled column damping values seems to indicate that, for those materials, material damping is more important than joint damping. The data reported was limited not by the test apparatus, but by signal conditioning and data acquisition. It is believed that filtering of the strain gage signals and the use of digital storage with slow playback will make it possible to extend the frequency and amplitude ranges significantly.

Gibson, R. F.↗

R-matrix calculations for electron-impact excitation of C(+), N(2+), and O(3+) including fine structure

The new R-matrix package for comprehensive close-coupling calculations for electron scattering with the first three ions in the boron isoelectronic sequence, the astrophysically significant C(+), N(2+), and O(3+), is presented. The collision strengths are calculated in the LS coupling approximation, as well as in pair-coupling scheme, for the transitions among the fine-structure sublevels. Calculations are carried out at a large number of energies in order to study the detailed effects of autoionizing resonances.

Luo, D.↗

Potential approaches to the spectroscopic characterization of high performance polymers exposed to energetic protons and heavy ions

A potential limitation to human activity on the lunar surface or in deep space is the exposure of the crew to unacceptably high levels of penetrating space radiations. The radiations of most concerns for such missions are high-energy protons emitted during solar flares, and galactic cosmic rays which are high-energy ions ranging from protons to iron. The development of materials for effective shielding from energetic space radiations will clearly require a greater understanding of the underlying mechanisms of radiation-induced damage in bulk materials. This can be accomplished in part by the detailed spectroscopic characterization of bulk materials that were exposed to simulated space radiations. An experimental data base thus created can then be used in conjunction with existing radiation transport codes in the design and fabrication of effective radiation shielding materials. Electron Paramagnetic Resonance Spectroscopy was proven very useful in elucidating radiation effects in polymers (high performance polymers are often an important components of structural composites).

Suleman, Naushadalli K.↗