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At least 703 records · Page 39

Effect of Part Size, Displacement Rate, and Aging on Compressive Properties of Elastomeric Parts of Different Unit Cell Topologies Formed by Vat Photopolymerization Additive Manufacturing

Due to its ability to achieve geometric complexity at high resolution and low length scales, additive manufacturing (AM) has increasingly been used for fabricating cellular structures (e.g., foams and lattices) for a variety of applications. Specifically, elastomeric cellular structures offer tunability of compliance as well as energy absorption and dissipation characteristics. However, there are limited data available on compression properties for printed elastomeric cellular structures of different designs and testing parameters. In this work, the authors evaluate how unit cell topology, part size, the rate of compression, and aging affect the compressive response of polyurethane-based simple cubic, body-centered, and gyroid structures formed by vat photopolymerization AM. Finite element simulations incorporating hyperelastic and viscoelastic models were used to describe the data, and the simulated results compared well with the experimental data. Of the designs tested, only the parts with the body-centered unit cell exhibited differences in stress–strain responses at different part sizes. Of the compression rates tested, the highest displacement rate (1000 mm/min) often caused stiffer compressive behavior, indicating deviation from the quasi-static assumption and approaching the intermediate rate response. The cellular structures did not change in compression properties across five weeks of aging time, which is desirable for cushioning applications. This work advances knowledge on the structure–property relationships of printed elastomeric cellular materials, which will enable more predictable compressive properties that can be traced to specific unit cell designs.

36 MATERIALS SCIENCE↗

Compressive Response and Energy Absorption of Additively Manufactured Elastomers with Varied Simple Cubic Architectures

Additive manufacturing, and particularly the vat photopolymerization process, enables the fabrication of complex geometries at high resolution and small length scales, making it well-suited for fabricating cellular structures (e.g., foams and lattices). Among these, elastomeric cellular structures are of growing interest due to their tunable compliance and energy dissipation. However, comprehensive data on the compressive behavior of these structures remains limited, especially for investigating the structure-property effects from changing the density and distribution of material within the cellular structure. This study explores how the mechanical response of polyurethane-based simple cubic structures changes when varying volume fraction, unit cell length, and unit cell patterning, which have not been systematically investigated previously in additively manufactured elastomers. Increasing volume fraction from 10% to 50% yielded significant changes in compressive stress–strain performance (decreasing strain at 0.5 MPa by 41.6% and increasing energy absorption density by 3962.5%). Although changing the unit cell length between 2.5 and 7 mm in ~30 mm parts did not result in statistically different stress–strain responses, modifying the configuration of struts of different thicknesses across designs with 30% volume fraction altered the stress–strain behavior (differences of 12.5% in strain at 0.5 MPa and 109.4% for energy absorption density). Power law relationships were developed to understand the interactions between volume fraction, unit cell length, and elastic modulus, and experimental data showed strong fits (R 2 > 0.91). These findings enhance the understanding of how multiple structural design aspects influence the performance of elastomeric cellular materials, providing a foundation for informing strategic design of tailorable materials for diverse mechanical applications.

36 MATERIALS SCIENCE↗

Compatibility of Elastomers with Polyoxymethylene Dimethyl Ethers and Blends with Diesel

Polyoxymethylene dimethyl ethers (PODEs) have shown promise as candidates for diesel fuel blendstocks due to their low sooting tendency, high cetane number, and diesel-comparable boiling point range. However, there is a lack of literature regarding compatibility of PODEs with common automotive elastomers, which would be a prerequisite to their adoption into the marketplace. To address this need, an exposure study and complementary solubility analysis were undertaken. A commercially available blend of PODEs with polymerization degree ranging from 3 to 6 was blended with diesel certification fuel at 0, 33, 50, 67, at 100% by mass. Elastomer coupons were exposed to the various blends for a period of 4 weeks and evaluated for volume swell. The elastomer materials included multiple fluoroelastomers (Viton and fluorosilicone) and acrylonitrile butadiene rubbers (NBR), as well as neoprene, polyurethane, epichlorohydrin (ECO), PVC-nitrile blend (OZO), ethylene propylene diene monomer (EPDM), styrene-butadiene rubber (SBR), and silicone. The exposure results indicated overall poor compatibility for PODE, with every elastomer except for fluorosilicone exhibiting greater than 30% volume swell at the 33% blend level. The general trend across the elastomers was either a consistent increase in volume swell with PODE concentration, or maximum in volume swell at an intermediate blend fraction. One notable exception is EPDM, which is not generally compatible with diesel fuel and which exhibited a reduction in volume swell with increasing PODE concentration. The same elastomers and PODE/diesel blends were evaluated using Hansen solubility parameter analysis, which predicted similar trends to the exposure study with the exception of ECO. From these results, we conclude that adoption of PODEs as a diesel fuel blendstock will require either the development of specialized elastomers, or that the blend fraction be kept to a low level to maintain compatibility with existing elastomers.

42 ENGINEERING↗

ThermoPI—an Online Tool to Calculate Heat Transfer Through Foam Insulation

Thermal insulation materials with ultra-low effective thermal conductivity are crucial for a multitude of applications. Over the years, a significant amount of experimental work has been dedicated to creating new insulation materials with low thermal conductivity. Similarly, substantial efforts have been made to enhance the theoretical understanding of thermal transport mechanisms in thermal insulation materials and to push the boundaries of lower thermal conductivity. However, ample room remains for enhancing the thermal resistivity of closed-cell foam insulations. To aid in the development of ultra-low effective thermal conductivity foam insulations, Oak Ridge National Laboratory has introduced a unique online tool, ThermoPI. This tool calculates not only the effective thermal conductivity but also the thermal conductivity components for porous materials, including gases, solids, and radiative, based on the materials’ structural information (e.g., porosity, pore size, gas species, pressure, solid species, pore geometry, and temperature).This tool collected and improved the existing theoretical models for thermal insulation materials’ gas, solid, and radiative thermal conductivity. These improved models have been validated with experimental data. Effective medium theory and sound velocity softening effects are considered for solid thermal conductivity. The built-in solid materials include polystyrene, polyurethane, polyethylene, and silica. Users are allowed to input new solid materials that are not built inside the tool. For gas thermal conductivity, the subcontinuum Knudsen effect is considered. In addition to several built-in gases, users can input new gases. For solid and radiative thermal conductivity calculations, several models are available to select, and the tool can determine the best model to choose based on the materials that users input. Users are also allowed to change selections manually. In addition, the tool can also calculate the effect of interfacial resistance on the overall thermal conductivity of layered materials. This work will elaborate on the tool and discuss how it can guide the development of new insulation products.

Shrestha, Som [ORNL] (ORCID:0000000183993797)↗

Develop Renewable/Sustainable Material to Displace Petroleum-Derived Polymer Foams (CRADA Final Report)

NLR and EDEN will partner together to develop renewable, biodegradable alternatives to polyfoam (polyurethane) polymer foams. The initial focus will be on developing cellulose-based foam with tunable mechanical properties. NLR will produce and test the cellulose-based foam materials and characterize its microstructure and mechanical properties. Relationships between mechanical performance formulation and fabrication methods will be developed.

09 BIOMASS FUELS↗

Phonocardiograph microphone is rugged and moistureproof

Microphone used as a phonocardiograph transducer monitors small amplitude audio signals in the presence of large shock loads and high humidity. It contains a lead zirconate-lead titanate piezoelectric plate encapsulated in a flexible polyurethane resin. The resin is contained in a sealed nylon case having a diameter of less than one inch.

Young, W. J.↗

Special tool kit aids heavily garmented workers

Triangular aluminum tool kit, filled with polyurethane is constructed to receive various tools and hold them in a snug but quick-release fit as an aid to heavily gloved workers. The kit is designed to allow mounting within easily accessable reach and to provide protection of the tools during storage.

Holmes, A. E.↗

Grit blasting nozzle fabricated from mild tool steel proves satisfactory

Dry blasting with glass beads through a nozzle assembly descales both the outside and inside surfaces of tubes of Inconel 718 used for the distribution of gaseous oxygen. The inside of the nozzle is coated with polyurethane and the deflector with a commercially available liquid urethane rubber.

Mc Farland, J. E.↗

Process produces chlorinated aromatic isocyanate in high yield

Tetrachloreterephthaloyl chloride reacts with sodium azide in an atmosphere of nitrogen to form a high yield of tetrachloro-p-phenylene diisocyanate. The chlorinated diisocyanate should have application as an intermediate in the preparation of polyurethane foams. The high halogen content would impart added flame resistance to these foams.

Trischler, F.↗

Solvent permits solid curing agents to be used at room temperatures

Solvent system dissolves the solid curing agents used with polyurethane resins in adhesive systems. The system developed yields bond strengths comparable to 100 percent solid formulations. The optimum solvent chosen was a 55.5 percent solution in anhydrous tetrahydrofuran.

St. Cyr, M. C.↗

Locating and sealing air leaks in multiroomed buildings

Industrial, nontoxic smoke bombs are used in multiroomed buildings to locate and fill discovered leak areas with polyurethane foam. All obvious air escape routes are sealed and the room is then pressurized to a minimum of 0.1 inch water above the pressure of adjoining rooms.

Britton, J. M.↗