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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 703 records · Page 39

Biocompatible Bi(OH)3 nanoparticles with reduced photocatalytic activity as possible ultraviolet filter in sunscreens

Highlights: • Facilesynthesis of inorganic Bi(OH){sub 3} nanoparticles. • High biocompatibility in human skin and dog kidney cells in vitro. • Ultraviolet filter capable of reducing the photocatalytic activity of TiO{sub 2} and ZnO. • Preparation of TiO{sub 2}/Bi(OH){sub 3} and classical TiO{sub 2}/ZnO sunscreen formulations. • Significantly improved photoprotection and photostability compared to TiO{sub 2}/ZnO. - Abstract: In this study we investigate readily synthesised Bi(OH){sub 3} nanoparticles as a novel, multifunctional ultraviolet filter for sunscreen. The absorbance of Bi(OH){sub 3} NPs in the ultraviolet region is comparable to that of both ZnO and TiO{sub 2} NPs used in commercial sunscreens. In vitro photoprotection results show that the combination of TiO{sub 2}/Bi(OH){sub 3} is more efficient than TiO{sub 2}/ZnO over the whole UV range, with an increase in sun protection factor of 28%. The emulsions show rheological properties comparable to those of commercial sunscreens. The combination of TiO{sub 2}/Bi(OH){sub 3} led to insignificant damage on pre-painted steel panels after exterior exposure for twelve weeks. We also demonstrate that the addition of Bi(OH){sub 3} NPs reduces the degradation of crystal violet by photocatalytically active TiO{sub 2} or ZnO NPs under ultraviolet exposure. Finally, assessment of the biocompatibility of Bi(OH){sub 3} with HaCaT keratinocytes and Madin-Darby Canine Kidney (MDCK) cells in vitro is described.

60 APPLIED LIFE SCIENCES↗

Study on influence of PSP measurement system characteristics

The pressure-sensitive paint (PSP) technique as an optical method enables measurement of surface pressure distribution over a model and its measurement system plays an important role in this technique. In the present study, the fluorescent PSP is used and PSP measurement system is established by the authors. The influence of the measurement system characteristics on calibration curves is then explored through many PSP calibration experiments. With five camera apertures and two ultraviolet (UV) lamp powers, the original PSP calibration images and curves are presented in this paper. The experimental results demonstrated that: (1) the characteristics of the PSP measurement system have an important effect on the pressure measurement; (2) the 400-W UV lamp can provide adequate excitation photons to excite fluorescence molecules entering the energy transition and a larger charge-coupled device (CCD) aperture can be used to improve the signal-to-noise rate (SNR) of the CCD.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Assessment of the displacement field along a surface crack in a flat plate using optical techniques

Structural components may contain cracks, and for these components a crack tip represents a highly singular stress. The evaluation of the associated strain gradient is difficult to achieve with experimental discrete methods. An efficient alternative are the optical techniques which are non-contact, and so delivering continuous information of the displacement fields and associated derivatives for strain evaluation. This paper describes some experimental methods to fully characterize the displacement field near a crack tip existing in flat plates. Three optical field techniques based on image analysis were used in the present work; respectively, Electronic Speckle Pattern Interferometry, Moiré Interferometry, and Digital Image Correlation. These methods allow different resolutions which can be adjusted according to the expected strain gradient. While the first method depends on the laser wavelength and position of the illumination sources, the second depends on the grating pitch and the last on the surface texture or painted speckle. Algorithms to derivate and filtering the displacement field are developed to compute the strain field and will be used for further works.

36 MATERIALS SCIENCE↗

Ground Movement in SSRL Ring

Users of the Stanford Synchrotron Radiation Lightsource (SSRL) are being affected by diurnal motion of the synchrotron's storage ring, which undergoes structural changes due to outdoor temperature fluctuations. In order to minimize the effects of diurnal temperature fluctuations, especially on the vertical motion of the ring floor, scientists at SSRL tried three approaches: painting the storage ring white, covering the asphalt in the middle of the ring with highly reflective Mylar and installing Mylar on a portion of the ring roof and walls. Vertical motion in the storage ring is measured by a Hydrostatic Leveling System (HLS), which calculates the relative height of water in a pipe that extends around the ring. The 24-hr amplitude of the floor motion was determined using spectral analysis of HLS data, and the ratio of this amplitude before and after each experiment was used to quantitatively determine the efficacy of each approach. The results of this analysis showed that the Mylar did not have any significant effect on floor motion, although the whitewash project did yield a reduction in overall HLS variation of 15 percent. However, further analysis showed that the reduction can largely be attributed to a few local changes rather than an overall reduction in floor motion around the ring. Future work will consist of identifying and selectively insulating these local regions in order to find the driving force behind diurnal floor motion in the storage ring.

43 PARTICLE ACCELERATORS↗

High Power UV LED Industrial Curing Systems

UV curing is a green technology that is largely underutilized because UV radiation sources like Hg Lamps are unreliable and difficult to use. High Power UV LEDs are now efficient enough to replace Hg Lamps, and offer significantly improved performance relative to Hg Lamps. In this study, a modular, scalable high power UV LED curing system was designed and tested, performing well in industrial coating evaluations. In order to achieve mechanical form factors similar to commercial Hg Lamp systems, a new patent pending design was employed enabling high irradiance at long working distances. While high power UV LEDs are currently only available at longer UVA wavelengths, rapid progress on UVC LEDs and the development of new formulations designed specifically for use with UV LED sources will converge to drive more rapid adoption of UV curing technology. An assessment of the environmental impact of replacing Hg Lamp systems with UV LED systems was performed. Since UV curing is used in only a small portion of the industrial printing, painting and coating markets, the ease of use of UV LED systems should increase the use of UV curing technology. Even a small penetration of the significant number of industrial applications still using oven curing and drying will lead to significant reductions in energy consumption and reductions in the emission of green house gases and solvent emissions.

42 ENGINEERING↗

Surface Properties of Double-Fin Generated Shock-Wave/Boundary-Layer Interactions

Shock-Wave/Boundary-Layer Interaction (SBLI) is ubiquitous in high-speed air vehicles. SBLI surface flowfield properties of crossing shocks induced by symmetric Double-Fins (DFs) at fin angles of 8° and 10° at Mach 2 are experimentally investigated; a 10° Single-Fin (SF) is also explored as a comparison. Surface visualization is used to capture distinct flowfield structures such as separation and upstream influence. Steady and unsteady Pressure-Sensitive Paints (PSPs) are used to obtain global surface pressure fields. Characteristics of DF-SBLI surface topology are discussed by comparing the corresponding SF-SBLI. Here, the effect of fin angle on DF-SBLI is characterized, and unsteady dynamics of the pressure field are examined. Spectral Proper Orthogonal Decomposition (SPOD) is performed on unsteady PSP, and traveling surface pressure waves and their frequency-dependent behavior are discussed. Dispersion relation of surface pressure waves is revealed by performing two-dimensional space–time Fourier transform on unsteady PSP, and the results are compared with the phase velocity distributions obtained from SPOD. Accompanying group velocity behavior is examined for distinct SBLI regions wherein wave propagation is found dependent on its frequency. Steady surface pressures along the centerline are compared with previous experimental data. Fin-tip spacing is found to be an essential parameter for scaling of upstream influence length.

33 ADVANCED PROPULSION SYSTEMS↗

Solar simulation studies Summary

Solar simulation - paint testing, planning for high altitude tests of spectral irradiance, pressure arc and vortex stabilized radiation systems, and thermal control coating tests

SOLAR SIMULATION↗

Coatings degradation, section VIII

Vacuum chambers for particle irradiation of thermal control coatings, and testing of paint samples of alkali silicates and methyl silicones

SILICONE↗

Advanced Non-Intrusive Instrumentation for Propulsion Engines

Changes in engine technology such as higher temperatures, higher tip speeds, new metal/composite/ceramic materials together with radical changes in design philosophy will require amongst other prerequisites the ability to measure and to monitor key internal gas and structural characteristics. The symposium papers presented non-intrusive measurement and analysis technologies in the following categories: Laser Point Measurements (11); Absorption and Infrared Techniques (4); Paints - Surface Sensors (6); Laser Induced Fluorescence (6); Mechanical (7); Films (5); Laser Planar Measurement (9); and a Keynote Address.

Propulsion↗

Implementation of an Unsteady PSP System in the NASA Transonic Dynamics Tunnel

An unsteady pressure-sensitive paint (uPSP) system has been developed to provide time-resolved pressure measurements in the NASA Langley Transonic Dynamics Tunnel (TDT). Obtaining these measurements necessitated the development of environmental enclosures to protect the high-speed camera and ultraviolet lights required for uPSP from the harsh environment present during tunnel operation. Since the facility main drive was non-functioning during the testing window, performance of the uPSP system was demonstrated using an impinging jet with a passive oscillator attachment to provide unsteady flow with a known frequency independent of amplitude. Measurements were obtained for tunnel pressures ranging from 565 to 2116 psf, and model angles of attack between -4 degrees and 4 degrees. Results indicate that the system is capable of measuring surface pressure differentials on the order of 0.01 psi at full scale with a camera frame rate of at least 10 kHz. Spectral analysis shows that the fundamental frequency of the oscillating jet is captured by the uPSP system, as are the second and third harmonics. Dynamic mode decomposition highlights the dominant coherent spatial structures of the surface pressure, along with the associated frequency and growth rate of each mode, allowing for a de-noised reconstruction of the uPSP measurements. The experimental campaign outlined within this report also confirmed compatibility of the uPSP system with the TDT facility data acquisition system, and verified the successful integration with existing processing capabilities within the NASA advanced supercomputing environment.

unsteady pressure-sensitive paint↗

Implementation of an Unsteady PSP System in the NASA Transonic Dynamics Tunnel

An unsteady pressure-sensitive paint (uPSP) system has been developed to provide time-resolved pressure measurements in the NASA Langley Transonic Dynamics Tunnel (TDT). Obtaining these measurements necessitated the development of environmental enclosures to protect the high-speed camera and ultraviolet lights required for uPSP from the harsh environment present during tunnel operation. Since the facility main drive was non-functioning during the testing window, performance of the uPSP system was demonstrated using an impinging jet with a passive oscillator attachment to provide unsteady flow with a known frequency independent of amplitude. Measurements were obtained for tunnel pressures ranging from 565 to 2116 psf, and model angles of attack between -4 degrees and 4 degrees. Results indicate that the system is capable of measuring surface pressure differentials on the order of 0.01 psi at full scale with a camera frame rate of at least 10 kHz. Spectral analysis shows that the fundamental frequency of the oscillating jet is captured by the uPSP system, as are the second and third harmonics. Dynamic mode decomposition highlights the dominant coherent spatial structures of the surface pressure, along with the associated frequency and growth rate of each mode, allowing for a de-noised reconstruction of the uPSP measurements. The experimental campaign outlined within this report also confirmed compatibility of the uPSP system with the TDT facility data acquisition system, and verified the successful integration with existing processing capabilities within the NASA advanced supercomputing environment.

unsteady pressure-sensitive paint↗