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DOE OSTI2022

Transition of Large-Scale Environmental Conditions and Characteristics of Four Rainfall Types Observed by S-PolKa During the MJO-1 Active Phase of DYNAMO/CINDY/AMIE

Analyses of National Center for Atmospheric Research (NCAR) S-PolKa dual-polarization radar data and ERA5 reanalysis fields indicate gradual changes in convection characteristics and large-scale environmental conditions during a central Indian Ocean Madden-Julian Oscillation (MJO) event observed by the DYNAMO/CINDY/AMIE field campaigns in late October 2011 (MJO-1). Examination of four rainfall types (isolated convective cores, convective, mixed, and stratiform) reveals a transition of convection characteristics (i.e., areal coverage and depth) between distinct 5-day environmental periods at the beginning and end of this ~2-week MJO active phase. A shift toward less frequent rainfall covering less of the radar domain for all four rainfall types occurs when large-scale lower-tropospheric dry air advects into the region with the westerly wind burst (WWB). Drier and warmer lower-free-tropospheric conditions associated with the WWB contribute to increased large-scale surface-based convective inhibition (CIN), surface-based convective available potential energy (CAPE), and cloud base heights. A thermodynamic budget analysis indicates reduced surface heat fluxes contribute to the increased surface-based CAPE. Greater CAPE at the end of MJO-1 coincides with deeper 50-dBZ convective echoes, while decreased 10-dBZ depth for all rainfall types corresponds in time with WWB-related dry-air advection. Increased (decreased) reflectivity values in the lower-level vertical reflectivity distribution of convective (stratiform) precipitation indicate increased (decreased) convective (stratiform) intensities when the WWB is present. The opposite depth changes for convective echoes and opposite shifts in convective and stratiform precipitation intensities underscore how the WWB can have differing impacts at different reflectivity thresholds and stages of the deep convection lifecycle.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2001

The Evolution of Tropical and Extratropical Precipitation During ENSO Events

Many studies have tried to relate ENSO and global precipitation. This work examines changes in precipitation pattern, amount and intensity during ENSO events over the past 20+ years, using satellite-gauge merged data sets. ENSOs vary in duration and may peak at different times of the year. In this way, compositing events into seasons, such as onset, mature, and decay, is a challenge. This study will explore the sensitivity of using fixed versus variable month seasons to describe El Ninos and La Ninas. Global precipitation patterns will be shown. Both increases and decreases in rainfall are observed during ENSO, and there are more extreme and less 'normal' rain rates (i.e. a greater occurrence of drought and flood) in space and time. In the Southern Hemisphere during ENSO there is a spiral pattern of precipitation anomalies, centered at the pole, that agrees with previous studies looking at model-generated surface pressure. This study also examines the evolution of precipitation and SST in the tropical Pacific. The relation between the Maritime Continent convection center and the underlying surface temperatures of the islands will also be explored. An examination of the evolution of the 1997-98 El Nino and accompanying precipitation anomalies revealed that a dry area surrounding Indonesia, preceded the formation of positive SST anomalies in the eastern Pacific Ocean, 30-60 day oscillations in the winter of 1996/97 may have contributed to this lag relationship. A similar time line of onset was observed during the 1982-83 El Nino. These two events were comparable in strength and timing during the annual cycle. However, in the 1982-83 event the warming at the surface first appeared in the central Pacific, whereas in the 1997-98 event the warming first emerged off the coast of Peru. In both events the positive precipitation anomalies were first observed in the central Pacific, moving to the east Pacific within a month or two.

Curtis, W. R. Scott, III↗

NASA NTRS1986

Observations of vertical winds and the origin of thermospheric gravity waves launched by auroral substorms and westward travelling surges

Several sequences of observations of strong vertical winds in the upper thermosphere are discussed, in conjunction with models of the generation of such winds. In the auroral oval, the strongest upward winds are observed in or close to regions of intense auroral precipitation and strong ionospheric currents. The strongest winds, of the order of 100 to 200 m/sec are usually upward, and are both localized and of relatively short duration (10 to 20 min). In regions adjacent to those displaying strong upward winds, and following periods of upward winds, downward winds of rather lower magnitude (40 to about 80 m/sec) may be observed. Strong and rapid changes of horizontal winds are correlated with these rapid vertical wind variations. Considered from a large scale viewpoint, this class of strongly time dependent winds propagate globally, and may be considered to be gravity waves launched from an auroral source. During periods of very disturbed geomagnetic activity, there may be regions within and close to the auroral oval where systematic vertical winds of the order of 50 m/sec will occur for periods of several hours. Such persistent winds are part of a very strong large scale horizontal wind circulation set up in the polar regions during a major geomagnetic disturbance. This second class of strong horizontal and vertical winds corresponds more to a standing wave than to a gravity wave, and it is not as effective as the first class in generating large scale propagating gravity waves and correlated horizontal and vertical oscillations. A third class of significant (10 to 30 m/sec) vertical winds can be associated with systematic features of the average geomagnetic energy and momentum input to the polar thermosphere, and appear in statistical studies of the average vertical wind as a function of Universal Time at a given location.

Rees, D.↗

NASA NTRS2011

Drop Shapes Versus Fall Velocities in Rain: 2 Contrasting Examples

Rainfall retrievals from polarimetric radar measurements require the knowledge of four fundamental rain microstructure parameters, namely, drop size distribution, drop shape distribution, canting angles and drop fall velocities. Some recent measurements of all four parameters in natural rain are summarized in [1]. In this paper, we perform an in-depth analysis of two events, using two co-located 2D video disdrometers (2DVD; see [2]) both with high calibration accuracy, and a C-band polarimetric radar [3], located 15 km away. The two events, which occurred 7 days apart (on the 18th and the 25th of Dec 2009), had moderate-to-intense rainfall rates, but the second event had an embedded convection line within the storm. The line had passed over the 2DVD site, thus enabling the shapes and fall velocities to be determined as the line crossed the site. The first event was also captured in a similar manner by both the 2DVDs as well as the C-band radar. Drop fall velocity measurements for, say, the 3 mm drops show noticeable differences between the two events. Whereas for the first event, the velocity distribution showed a narrow and symmetric distribution, with a mode at the expected value (7.95 m/s, as given by the formula in [4]), the second event produced a wider distribution with a significant skewness towards lower velocities (although its mode too was close to the expected value). Moreover, the slower 3 mm drops in the second event occurred when the convection line was directly over the 2DVD site (03:35-03:45 utc), and not before nor after. A similar trend was observed in terms of the horizontal dimensions of the 3 mm drops, i.e. large fluctuations during the same time period, but not outside the period. Vertical dimensions of the drops also fluctuated but not to the same extent. Interestingly, the horizontal dimensions tended towards larger values during the 10-minute period, implying an increase in drop oblateness, which in turn indicates the possibility of the horizontal mode oscillation, one of the three fundamental modes of drop oscillations [5], albeit the most difficult one to excite.

Thurai, M.↗

DOE OSTI2020

In situ monitoring of the stopped muon flux at Mu2e

The specific object of Mu2e search is the neutrino-less coherent $\mu^-\rightarrow e^-$ conversion in the field of an aluminum nucleus and the signal is a monoenergetic electron of energy $ \approx 104.97$ MeV. This process is forbidden in the Standard Model but allowed in many of its extensions: with minimal changes to include neutrino masses and oscillation, the Branching Ratio of this process, or the similarly interesting $\mu\rightarrow e \gamma$ decay, is expected to be of the order of $\mathcal{O}(10^{-54})$. Values like these are below any currently achievable experimental sensitivity, and the observation of a signal would be unambiguous evidence of New Physics. The upper limit on the muon conversion was set by SINDRUM II at $7\times10^{-13}$ (90\% C.L.) and the goal of the Mu2e collaboration is an improvement of 4 order of magnitudes.\\ The Mu2e experiment can be conceptually divided into three stages: interaction of the primary proton pulse with the tungsten target a nd production of $\pi$ and $\mu$; collection and transport of the produced particles down to the aluminum stopping target; interaction with the stopping target and measurement of the output particles. The measurement of the stopped muon flux is of cardinal importance for the normalization of the Mu2e results. The baseline design includes two detectors developed to measure this flux, counting $\gamma$ emitted by the muonic atoms: HPGe and LaBr$_3$(Ce). The studies performed by the Mu2e Collaboration show that these two systems can be reliably used to determine the overall normalization.\\ The number of stopped muons is proportional to the number of protons on target, which itself depends on the extraction system for the proton beam. The Mu2e beam delivery system will use a resonant extraction to create the proton pulses and this method is characterized by intensity fluctuations on the time scale of milliseconds. These fluctuations, aside from the proportional fluctuation of t he number of muons, have a non-trivial impact on the overall! performance of the apparatus. For example, higher intensity proton bunches translate into higher veto rates by the Cosmic Rays Veto system, which is triggered by secondary particles generated by the proton interaction. Another example is the effect of the instantaneous luminosity on the reconstruction efficiency: higher intensity translates into higher detector occupancy, which in turn reduces the reconstruction efficiency.\\ The two cited detectors encounter limitations when trying to monitor the flux at the millisecond timescales: HPGe is by construction a slow detector while the rate of emission of the $\gamma (1809\textrm{ keV})$ the LaBr$_3$(Ce) will measure is too low. As of today, no system allows to monitor these fluctuations and the goal of this Thesis is to try filling this gap. The method we developed to monitor the fluctuations of the stopped muon flux, and by extension, the fluctuation in the proton pulses intensity is based on counting the number of muons capt ured in the stopping target by counting the number of protons produced in the process of the nuclear muon capture. This is one of the possible processes a stopped muon can undergo and it can lead to the ejection of charged particles.\\ The reconstruction algorithms were developed by the Mu2e collaboration with the explicit (and sometimes implicit) aim to reconstruct tracks of electrons in an energy range of a conversion electron. The protons we are interested in behave quite differently from these electrons and the cardinal task of this study has been to tailor the reconstruction routines to these particles. This has been done by analyzing simulated events consisting of a single proton to optimize the procedure and understand the features of these tracks. A major difference with respect to the electrons is the non-relativistic nature of $100\div300$ MeV$/c$ protons: accounting for the low velocity is both a challenge and a unique signature of the tracks.\\ The use of a pulse d beam and the need to allow produced $\pi$ to decay and $\m! u$ to int! eract in the stopping target forces the definition of a Mu2e \textit{event}: an event is comprised by everything which happens in a $1.7\ \mu$s window between the incidence two consecutive proton pulses. This means that the reconstruction will be performed in an environment crowded by many different particles. The next step of this study has been to estimate the performance of the method in a fully-fledged Mu2e simulated event and to study what kind of selections would improve it.\\ Our results are satisfactory since the number of reconstructed protons is significant (few per event), and show that a monitor on the timescale of milliseconds is indeed possible.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2025

Applicability of semiclassical theories in the strong-field plasma regime

For many purposes, classical plasma dynamics models can work surprisingly well, even for strong electromagnetic fields, approaching the Schwinger critical fields, and high frequencies, approaching the Compton frequency. However, the applicability of classical models tends to depend rather sensitively on the details of the problem. In the present paper, we study the specific case of plasma oscillations to draw a line between the classical and quantum relativistic regimes. Here, due to the field geometry of study, mechanisms like radiation reaction and Breit-Wheeler pair production, which tend to be important for electromagnetic fields, are rather effectively suppressed. Moreover, we find that the polarization current due to the electron spin is generally negligible for frequencies below the Compton frequency, compared with the free current, whose magnitude is well-approximated by the classical Vlasov theory. However, we show that pair creation due to the Schwinger mechanism can sometimes be important for surprisingly modest field strengths, of the order of 10% of the critical field or even smaller. A rough guideline for when the classical Vlasov theory can be applied is given.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2024

Inverse bremsstrahlung absorption rate for super-Gaussian electron distribution functions including plasma screening

Here we provide analytic expressions for the effective Coulomb logarithm for inverse bremsstrahlung absorption which predict significant corrections to the Langdon effect and overall absorption rate compared to previous estimates. The calculation of the collisional absorption rate of laser energy in a plasma by the inverse bremsstrahlung mechanism usually makes the approximation of a constant Coulomb logarithm. We dispense with this approximation and instead take into account the velocity dependence of the Coulomb logarithm, leading to a more accurate expression for the absorption rate valid in both classical and quantum conditions. In contrast to previous work, the laser intensity enters into the Coulomb logarithm. In most laser-plasma interactions the electron distribution function is super-Gaussian [Langdon, Phys. Rev. Lett. 44, 575 (1980)], and we find the absorption rate under these conditions is increased by as much as ≈ 30% compared to previous estimates at low density. In many cases of interest the correction to Langdon's predicted reduction in absorption is large; for example at Z = 6 and Te = 400 eV the Langdon prediction for the absorption is in error by a factor of ≈ 2. However, we also account for the additional effect of plasma screening, which predicts a reduction in absorption by a similar amount (up to ≈ 30%). These two effects compete to determine the overall absorption, which may be increased or decreased, depending on the conditions. The corrections can be incorporated into radiation-hydrodynamics simulation codes by replacing the familiar Coulomb logarithm with an analytic expression which depends on the super-Gaussian order “M” and the screening length.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2026

Entropy-mode-driven gas optics

We propose a class of gaseous diffractive optical elements created by imprinting an entropy mode in a gas. Previous approaches to gaseous diffractive optics have relied on the simultaneous excitation of a standing acoustic wave and an entropy mode to produce one-dimensional periodic structures. However, the presence of acoustic oscillations in the gas imposes stringent constraints on some of the operational parameters of these optical elements, such as their lifetime and diffraction angle. Here, in this work, we introduce an approach that eliminates the acoustic mode, relying solely on the entropy mode. This enables control of the lifetime and temporal profile of gaseous optical elements, and also allows the creation of arbitrary structures with greater contrast, including nonperiodic patterns such as chirped gratings or lenses. This approach should allow operation over a wider parameter space, including larger diffraction angles and compatibility with laser pulse durations ranging from femtoseconds to microseconds.

Optics and optical instruments↗

NASA NTRS2002

Transient Mixing Driven by Buoyancy Flows

Mixing driven by buoyancy-induced flows is of particular interest to microgravity processes, as the body force that governs the intensity of flow fields can be directly controlled. We consider a model experimental system to explore the dynamics of mixing which employs two miscible liquids inside a cavity separated initially by a divider. The two liquids are oriented vertically inside a rectangular cavity with constant width and height, and varying depths to span the range of a Hele-Shaw cell to a 3-[) configuration. The two miscible liquids can be sufficiently diluted and died, for example water and deuterium oxide, such that a distinct interface exists across the divider. The transient mixing characteristic of the two fluids is addressed by following the Lagrangian history of the interface for various aspect ratios in the z-plane (depth variation) as well as a range of pulling velocities of the divider. The mixing characteristics of the two fluids are quantified from measurement of the length stretch of the interface and its flow field using respectively image processing techniques and Particle Imaging Velocimetry. Scaling analysis shows that the length stretch depends on four governing parameters, namely the Grashof number (Gr), Schmidt number (Sc), aspect ratio (Ar), and Reynolds number (Re). Variation of the Schmidt number is taken into account through thermophysical property variation. Thus our problem reduces to a codimension three bifurcation in parametric space for Gr, Ar, and Re. Our experimental results show that for Gr on the order of 106 and a nominal cavity aspect ratio Ar = 0.2, the net effect of removal of the divider and the overwhelming buoyancy force causes an overturning motion which stretches and folds the interface to produce ml internal breakwave. The structure of the breakwave is similar to the ubiquitous Rayleigh-Taylor instability morphology. The breakwave is dissipated either through internal or wall collision depending on the impulsive velocity of the divider as prescribed by the Reynolds number. The decay of the collision event occurs through sloshing oscillations over a short time scale. The two fluids then become stably stratified with a diffusive band at the interface indicating local mass transport. The local bifurcation of the internal breakwave is investigated as a function of aspect ratio. Results show that for narrow cavities on the order of 2mm (Ar = 0.04) folding does not occur, the interface only stretches. As the cavity size increases folding occurs through a supercritical bifurcation. Insight into the mechanism of folding is obtained from measurement of the flow field which shows that in the neighborhood of the folding event, there exists hyperbolic points caused by multiple vortex interactions. The global length stretch of the interface as a function of time is nearly Gaussian; calculations of finite-time Liapunov exponents as well as construction of horseshoe maps indicate the likelihood of a chaotic transient.

W.M.B. Duval↗

NASA NTRS2000

Coupling, Q-Factor, and Integration Aspects of Microsphere Applications

With suggested applications varying from microlaser and cavity QED through optical locking of diode lasers to modulators and sensors, high-Q silica microspheres with whispering-gallery (WG) modes so far remain the subject of tabletop feasibility demonstrations. Despite the uniquely high quality-factor and submillimeter dimensions suitable for tight packaging, this novel type of high-finesse cavity still has to be adapted to fiber- and integrated-optic hardware. In the visible and near infrared-band experiments (633-850nm) measuring the ringdown time tau of free oscillations, Q = (0.6 to 0.8 ) x 10(exp 10) has been obtained in silica spheres of diameter -800 microns (corresponding tau = 3 to 4 microseconds). It was proved that under normal laboratory conditions, quality-factor is subject to deterioration within several-minute scale down to (2 ... 3 ) x 10(exp 9). The responsible mechanism was identified as adsorption of a monolayer of atmospheric water, so that preservation of the ultimate Q requires manipulation in dry environment, or fast packaging into sealed devices. Larger Q can be expected closer to minimum of attenuation in fused silica alpha = 0.2 dB/km; Q greater than or equal to 1 x 10(exp 11) at lambda=1.55 microns, with corresponding energy storage time tau approx. 0.1ms. Experiments are currently underway to determine whether this high Q can be realized experimentally. The evident difficulty is that OH-related optical absorption has its peaks located near the reported minimum of attenuation in silica. We can also mention here that some of proposed fiber materials, yet not ready for fiber drawing, have been predicted to have smaller attenuation than fused silica and may be suitable for microsphere fabrication (sodium-magnesium silicate glass, alpha = 0.06dB/km). WG modes possess very small radiative loss (it does not prevent Q-10(exp 20) and more) and therefore are electromagnetically isolated and cannot be excited by free-space beams. If no modification (such as grating) is made on the sphere surface, the coupling has to he provided by an appropriate near-field device. A systematic theoretical approach has been recently developed to quantify the performance of near-field couplers for WG modes. Efficient coupling can be obtained upon fulfillment of two main conditions: (1) mode matching and (2) sufficient coupling strength to provide the buildup of a WG mode with a given intrinsic loss. In other words, the wave in the coupler has to be phase-matched and sufficiently overlapped with the WG mode to provide enough buildup in the cavity. If the coupling efficiency is characterized by the fractional depth K(sup 2) of the resonance dip in intensity transmittance observed upon varying the frequency of the exciting wave in the coupler.

Ilchenko, V. S.↗

NASA NTRS2013

The Effect of Agricultural Growing Season Change on Market Prices in Africa

Local agricultural production is a key element of food security in many agricultural countries in Africa. Climate change and variability is likely to adversely affect these countries, particularly as they affect the ability of smallholder farmers to raise enough food to feed themselves. Seasonality influences farmers' decisions about when to sow and harvest, and ultimately the success or failure of their crops. At a 2009 conference in the United Kingdom hosted by the Institute of Development Studies, Jennings and Magrath (2009) described farmer reports from East Asia, South Asia, Southern Africa, East Africa and Latin America. Farmers indicate significant changes in the timing of rainy seasons and the pattern of rains within seasons, including: More erratic rainfall, coming at unexpected times in and out of season; Extreme storms and unusually intense rainfall are punctuated by longer dry spells within the rainy season; Increasing uncertainty as to the start of rainy seasons in many areas; Short or transitional second rainy seasons are becoming stronger than normal or are disappearing altogether. These farmer perceptions of change are striking in that they are geographically widespread and are remarkably consistent across diverse regions (Jennings and Magrath, 2009). The impact of these changes on farmers with small plots and few resources is large. Farming is becoming riskier because of heat stress, lack of water, pests and diseases that interact with ongoing pressures on natural resources. Lack of predictability in the start and length of the growing season affects the ability of farmers to invest in appropriate fertilizer levels or improved, high yielding varieties. These changes occur at the same time as the demand for food is rising and is projected to continue to rise for the next fifty years (IAASTD, 2008). Long-term data records derived from satellite remote sensing can be used to verify these reports, providing necessary analysis and documentation required to plan effective adaptation strategies. Remote sensing data can also provide some understanding of the spatial extent of these changes and whether they are likely to continue. Given the agricultural nature of most economies on the African continent, agricultural production continues to be a critical determinant of both food security and economic growth (Funk and Brown, 2009). Crop phenological parameters, such as the start and end of the growing season, the total length of the growing season, and the rate of greening and senescence are important for planning crop management, crop diversification, and intensification. The World Food Summit of 1996 defined food security as: "when all people at all times have access to sufficient, safe, nutritious food to maintain a healthy and active life". Food security roughly depends on three factors: 1) availability of food; 2) access to food and 3) appropriate use of food, as well as adequate water and sanitation. The first factor is dependent on growing conditions and weather and climate. In a previous paper we have investigated this factor by evaluating the effect of large scale climate oscillation on land surface phenology (Brown et al., 2010). We found that all areas in Africa are significantly affected by at least one type of large scale climate oscillations and concluded that these somewhat predictable oscillations could perhaps be used to forecast agricultural production. In addition, we have evaluated changes in agricultural land surface phenology over time (Brown et al., 2012). We found that land surface phenology models, which link large-scale vegetation indices with accumulated humidity, could successfully predict agricultural productivity in several countries around the world. In this chapter we are interested in the effect of variability in peak timing of the growing season, or phenology, on the second factor of food security, food access. In this chapter we want to determine if there is a link between market prices and land surface phenology and to determine which markets are vulnerable to land surface phenology changes and variability and which market prices are not correlated.

Prices↗

DOE OSTI2021

Legacy effects of drought on tree growth responses to hurricanes

Natural perturbations, including hurricanes and severe droughts, are becoming more frequent and intense in the tropics, yet our understanding of forest responses to these events is still limited. While the relationships between extreme climatic events and tree mortality are frequently studied, responses of trees that survived such perturbations have been rarely reported. Perturbations and their effects can be quite variable, and trees can respond both positively and negatively to them, depending on their sensitivity and opportunistic behavior. Understanding the potential variation in responses both within and among species is important for building predictions of forest responses. We studied tree growth responses (i.e., changes relative to standard conditions) to hurricanes and drought events in Puerto Rico across six common and broadly distributed species. We examined whether there is a congruence in responses to these contrasting extreme climatic events. We show that trees are particularly susceptible to droughts but display a wide range of responses to hurricanes. Despite the high stochasticity in the impacts of hurricanes, trees that showed reduced growth during previous droughts tend to show reduced growth during the hurricanes as well. Our results demonstrate that trees subjected to different and successive major climatic stresses have consistent declines in their performance. Projected increases in the severity of droughts and tropical storms could have an accumulated, and possibly compound, impact on tree growth. Long-term demographic studies are necessary to understand legacy effects of species responses to extreme climatic perturbations.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

Low Frequency Vibrational Modes of Two-Dimensional Lead-Free Metal Halide Double Perovskites

2D layered double perovskites of (S-MPA) 4 AgBiI 8 (MPA-AgBiI 8 ) and (S-MPA) 4 CuBiI 8 (MPA-CuBiI 8 ) (S-MPA, S-β-methylphenethylammonium) were synthesized with a hydrothermal method. The crystal structure of MPA-AgBiI 8 was determined using single-crystal X-ray diffraction (scXRD). Powder XRD (pXRD) data suggest that the crystal structure of MPA-CuBiI 8 is more complex than that of MPA-AgBiI 8 . UV-Vis electronic absorption spectra of these perovskites reveal a bandgap of 2.03 eV for both. Short exciton lifetime from time-resolved photoluminescence (TRPL) results and low PL intensity of the Cu-based perovskite suggest a high density of trap states within the bandgap. Low frequency Raman spectra of both materials show distinct peaks and a slightly higher frequency for the Cu-based perovskite than the Ag-based perovskite. Density functional theory (DFT) calculations were conducted to simulate the low frequency Raman spectra and help explain the different phonon modes, which are collective vibrations of metal halide bond bending and stretching within the Ag- and Cu-centered octahedra coupled with MPA libration and twisting within the inorganic layer. The DFT theory also quantified octahedral distortions in the two perovskites. Furthermore, this combined experimental and computational study provides new insights into the low frequency vibrations of 2D perovskites.

Halogens↗

DOE OSTI2021

Kinetic Measurements in Heterogeneous Catalysis

This contribution is about the experimental determination of the rate of a heterogeneous catalytic reaction and the analysis of kinetic data. In this case, the reaction rate can be defined as the frequency at which the closed sequence of elementary steps transforming reactants into products is occurring. However, the rate of chemical reaction is not directly observed; rather, one records the rate of substance change. The rate of chemical reaction is calculated based on the rate of substance change and assumed stoichiometry of the reaction. In order to make this an intensive quantity (i.e., independent of the volume in which the reaction is performed, this frequency is divided by the latter or by a quantity proportional to the latter). As the focus of what follows is on heterogeneously catalyzed reactions this can be the catalyst mass, the catalyst surface area or the total number of active sites present in the reaction volume confined by the walls of a chemical reactor. For example, the rate may be reported as one of the following: Net rate of consumption/production of component i mol m-3 s-1 Net specific rate of consumption/production of component i mol kg-1 s-1 Rate of substance change (per unit volume of catalyst) mol m-3 s-1 Specific reaction rate (per unit mass of catalyst) mol kg-1 s-1 Net rate of consumption/production of component i mol m-2 s-1 The turnover frequency (TOF) is a characteristic originally introduced by Boudart [1] is expressed as TOF=R/G_tot , where R is the steady-state rate of reactant consumption or product generation and G_totis the total areal density of active sites [mol m-2]. The latter is typically taken from experimental chemisorption data obtained at low temperature. The advancement of a chemical reaction leads to changes in the amounts of reactants and products which, for a stoichiometric single reaction, are connected by the stoichiometric coefficients. In many cases, for the sake of simplicity, we will assume that the investigated reaction proceeds according to a single reaction pathway, so that the net production rate of a reaction component is directly proportional to the reaction rate and that the latter equals the net production rate of any of the involved components when divided by the appropriate stoichiometric coefficient. For complex stoichiometric reactions the net production rates of the involved components are linear combinations of the reaction rates. Different goals for kinetic measurements can be formulated: Catalyst testing, i.e., obtaining the kinetic dependences for the development and discrimination of efficient catalytic materials. Precise kinetic characterization of active materials via high-throughput screening is a part of such activity. Detailed kinetics, i.e., revealing the detailed mechanism of complex catalytic reaction via systematic kinetic studies, both steady-state and non-steady-state Industrial kinetics, i.e., obtaining data and relationships for describing and predicting the behaviour of catalytic reactors and processes at industrial scale Finally, mathematical modeling and analysis where kinetic measurements provide data for understanding complex kinetic phenomena, e.g., oscillations, non-linear self-organization, etc.

36 MATERIALS SCIENCE↗

DOE OSTI2025

The HIBEAM instrument at the European spallation source

The European spallation source (ESS) will be the world’s brightest neutron source and will open a new intensity frontier in particle physics. The HIBEAM collaboration aims to exploit the unique potential of the ESS with a dedicated ESS instrument for particle physics which offers world-leading capability in a number of areas. The HIBEAM program includes the first search in thirty years for free neutrons converting to antineutrons and searches for sterile neutrons, ultralight axion dark matter and nonzero neutron electric charge. This paper outlines the capabilities, design, infrastructure, and scientific potential of the HIBEAM program, including its dedicated beamline, neutron optical system, magnetic shielding and control, and detectors for neutrons and antineutrons. Additionally, we discuss the long-term scientific exploitation of HIBEAM, which may include measurements of the neutron electric dipole moment and precision studies of neutron decays.

47 OTHER INSTRUMENTATION↗

NASA NTRS2013

Toward Global Drought Early Warning Capability - Expanding International Cooperation for the Development of a Framework for Monitoring and Forecasting

Drought has had a significant impact on civilization throughout history in terms of reductions in agricultural productivity, potable water supply, and economic activity, and in extreme cases this has led to famine. Every continent has semiarid areas, which are especially vulnerable to drought. The Intergovernmental Panel on Climate Change has noted that average annual river runoff and water availability are projected to decrease by 10 percent-13 percent over some dry and semiarid regions in mid and low latitudes, increasing the frequency, intensity, and duration of drought, along with its associated impacts. The sheer magnitude of the problem demands efforts to reduce vulnerability to drought by moving away from the reactive, crisis management approach of the past toward a more proactive, risk management approach that is centered on reducing vulnerability to drought as much as possible while providing early warning of evolving drought conditions and possible impacts. Many countries, unfortunately, do not have adequate resources to provide early warning, but require outside support to provide the necessary early warning information for risk management. Furthermore, in an interconnected world, the need for information on a global scale is crucial for understanding the prospect of declines in agricultural productivity and associated impacts on food prices, food security, and potential for civil conflict. This paper highlights the recent progress made toward a Global Drought Early Warning Monitoring Framework (GDEWF), an underlying partnership and framework, along with its Global Drought Early Warning System (GDEWS), which is its interoperable information system, and the organizations that have begun working together to make it a reality. The GDEWF aims to improve existing regional and national drought monitoring and forecasting capabilities by adding a global component, facilitating continental monitoring and forecasting (where lacking), and improving these tools at various scales, thereby increasing the capacity of national and regional institutions that lack drought early warning systems or complementing existing ones. A further goal is to improve coordination of information delivery for drought-related activities and relief efforts across the world. This is especially relevant for regions and nations with low capacity for drought early warning. To do this requires a global partnership that leverages the resources necessary and develops capabilities at the global level, such as global drought forecasting combined with early warning tools, global real-time monitoring, and harmonized methods to identify critical areas vulnerable to drought. Although the path to a fully functional GDEWS is challenging, multiple partners and organizations within the drought, forecasting, agricultural, and water-cycle communities are committed to working toward its success.

GDEWS↗