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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 703 records · Page 39
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Microscopic Observation of Solid Electrolyte Interphase Bilayer Inversion on Silicon Oxide

Silicon has been investigated in recent years as an alloying anode material to enhance gravimetric energy density in lithium-ion batteries. Although recent developments have suggested that silicon oxides exhibit improved cycling stability over pure Si, the origin of the improved cycling performance is still poorly understood. The initial solid electrolyte interphase (SEI) formation mechanisms on Si wafers with both native oxide and chemically etched thermal oxide coatings are investigated structurally, chemically, and morphologically in the nanoscale. After one electrochemical cycle, microscopy reveals that SEI formed on native SiO x features the typical SEI bilayer structure with a carbon-rich outer SEI layer and an inorganic-rich inner SEI layer. In contrast, the SEI formed on chemically etched thermal oxide shows an inversion in the structure. This work observes distinct initial SEI formation mechanisms on the HF-etched SiO 2 surface, which may be partially responsible for improved cycle life observed in SiO x -based anode materials.

25 ENERGY STORAGE↗
DOE OSTI2026

Compositional Phase Control in High-Entropy Alloy Electrocatalysts

High-entropy alloys (HEAs) provide uniquely tunable structural and electronic properties that enable robust electrocatalysis. While compositional manipulation of HEAs is well-known, systematically controlling the crystalline phase and morphology remains a challenge that could provide new avenues for controlling reactive sites and physical properties. Here, we show the preferential stabilization of mixed fcc/bcc to fcc phases by controlling the Au content in quinary AuPdFeCoNi HEA nanoparticles. This systematic structural and compositional control, when investigated with an ensemble of electronic, X-ray synchrotron, and surface techniques, allows us to identify the critical short- (few-Å) and medium- (6–10 Å) range structural motifs that deliver exceptional hydrogen evolution reaction (HER) catalysis. Specifically, these HEAs exhibit both outstanding durability (240 h) and high mass activity (50 A/mg PGM ) normalized to noble metal content, outperforming commercial Pt/C (3.18 A/mg PGM ). This structural control over HEA morphology, and its direct association with changes in specific metallic oxidation states and pair–pair atomic structural features, provides new means and strategies for finely designing robust and sustainable electrocatalysts with a majority nonprecious metal composition.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Decoding NGC 7252 as a blue elliptical galaxy

Elliptical galaxies with blue optical colours and significant star formation are hypothesised to be major merger remnants of gas-rich spiral galaxies or normal elliptical galaxies with a sudden burst of star formation. We present here a scenario in which blue elliptical galaxies identified in shallow imaging surveys may fail to recover faint features that are indicative of past merger activity using a nearby major merger remnant. Based on deep optical imaging data of the post-merger galaxy, NGC 7252, we demonstrate that the galaxy can appear as an elliptical galaxy if it is observed at higher redshifts. The main body and the low surface brightness merger features found at the outskirts of the galaxy are blue in the optical g – r colour map. We argue that the higher-redshift blue elliptical galaxies discovered in surveys as shallow as the SDSS or DECaLS may be advanced mergers whose defining tidal features fall below the detection limits of the surveys. This should be taken into consideration during the morphological classification of these systems in future and ongoing surveys.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1972

Cosmic influences on the early history of the lunar surface.

The testimony which the main features of the lunar surface bear on the cosmic environment in which the satellite acquired its principal morphological characteristics is examined. It is assumed as a working hypothesis that, in the earliest stages of the moon's history, the lunar sculpture in the continental areas was predominantly shaped by external impacts. It is considered that the argument against heliocentric orbits of particles whose collisions with the moon disfigured most of its continental areas continues to hold good. The distribution of craters due to oblique impacts appears to be essentially at random all over the lunar surface.

Kopal, Z.↗
NASA NTRS1974

Geologic guide to the island of Hawaii: A field guide for comparative planetary geology

With geological data available for all inner planets except Venus, we are entering an era of true comparative planetary geology, when knowledge of the differences and similarities for classes of structures (e.g., shield volcanoes) will lead to a better understanding of general geological processes, regardless of planet. Thus, it is imperative that planetologists, particularly those involved in geological mapping and surface feature analysis for terrestrial planets, be familiar with volcanic terrain in terms of its origin, structure, and morphology. One means of gaining this experience is through field trips in volcanic terrains - hence, the Planetology Conference in Hawaii. In addition, discussions with volcanologists at the conference provide an important basis for establishing communications between the two fields that will facilitate comparative studies as more data become available.

Greeley, R.↗
NASA NTRS1991

Earth observations during Space Shuttle flight STS-41 - Discovery's mission to planet earth

An overview of space flight STS-41 is presented, including personal observations and comments by the mission astronauts. The crew deployed the Ulysses spacecraft to study the polar regions of the sun and the interplanetary space above the poles. Environmental observations, including those of Lake Turkana, Lake Chad, biomass burning in Madagascar and Argentina, and circular features in Yucatan are described. Observations that include landforms and geology, continental sedimentation, desert landscapes, and river morphology are discussed.

Lulla, Kamlesh P.↗
NASA NTRS2011

Concretions in Exhumed Channels Near Hanksville Utah: Implications for Mars

The landscape near Hanksville, Utah, contains a diversity of Mars analogue features. These included segmented and inverted anatasomosing palaeochannels exhumed from the Late Jurassic Brushy Basin Member of the Morrison Formation that hosts abundant small carbonate concretions. The exhumed and inverted channels closely resemble many seen on the surface of Mars in satellite imagery and which may be visited by surface missions in the near future. The channels contain a wealth of palaeo-environmental information, but intrinsically difficult terrain would make their study challenging on Mars. We show that an unexhumed channel feature can be detected geophysically, this may allow their study in more easily accessed terrain. The concretions morphologically and in their surface expression parallel the haematite blue berries that are strewn across the surface of Meridiani Planum on Mars. They are best developed in poorly cemented medium to coarse channel sandstones and appear to have formed early in the diagenetic history.

Clarke, Jonathan↗
NASA NTRS2022

Global GNSS-RO Electron Density in the Lower Ionosphere

Lack of instrument sensitivity to low electron density (Ne) concentration makes it difficult to measure sharp Ne vertical gradients (four orders of magnitude over 30 km) in the D/E-region. A robust algorithm is developed to retrieve global D/E-region Ne from the high-rate GNSS radio occultation (RO) data, to improve spatio-temporal coverage using recent SmallSat/CubeSat constellations.The new algorithm removes F-region contributions in the RO excess phase profile by fitting a linear function to the data below the D-region.The new GNSS-RO observations reveal many interesting features in the diurnal, seasonal, solar-cycle, and magnetic-field-dependent variations in the Ne morphology. While the D/E-region Ne is a function of solar zenith angle (c), it exhibits strong latitudinal variations for the same c with a distribution asymmetric about noon. In addition, large longitudinal variations are observed along the same magnetic field pitch angle. The summer-midlatitude Ne and sporadic-E(Es) show a distribution similar to each other. The distribution of auroral electron precipitation correlates better with the pitch angle from the magnetosphere than from one at100 km. Finally, anew TEC retrieval technique is developed for the high-rate RO data with a top reaching at least 120 km. For better characterization of the E-to-F transition in Ne and more accurate TEC retrievals, it is recommended to have all GNSS-RO acquisition routinely up to 220 km.

GNSS radio occultation↗
NASA NTRSDate not supplied

Building and Breaking Carbon Composites with REACTER

Carbon composites have become indispensable for aerospace and other high-performance applications, and a detailed picture of their morphology and failure mechanisms remains difficult to obtain through experiment. REACTER is a versatile computational modeling tool for atomistic molecular dynamics designed to model chemical reactions at the speed and length scales of classical force fields.1 In this work, several recent features of REACTER were applied to the creation and subsequent mechanical testing of two classes of carbon composites, carbon-fiber reinforced polymers (CFRP) and carbon nanotube (CNT) composites. Carbon fiber core morphologies were created by the method of Desai et al.,2 but using the advanced reaction constraints framework of REACTER, their proposed multistep procedure was reduced to a single uninterrupted molecular dynamics simulation. The carbon fiber filler was embedded into a polymer matrix by simulated in situ polymerization of several thermosetting resins, including bismaleimide and polyarylacetylene, to obtain the final CFRP model. To generate the second class of carbon composite, CNT networks were grown dynamically using the new ‘create atoms’ feature of REACTER, and similarly infiltrated with resin to obtain CNT composites. The resulting models were compared directly to experiment using simulated high resolution transmission electron microscopy and x-ray diffraction. Failure mechanisms were elucidated by simulating mechanically induced bond breaking, as characterized by third-order DFT-based tight-binding (DFTB3) simulations, via a reaction constraint on the total potential energy of the involved atoms.

Molecular Dynamics↗
NASA NTRS1986

Microstructure-property relationships in directionally solidified single crystal nickel-base superalloys

Some of the microstructural features which influence the creep properties of directionally solidified and single crystal nickel-base superalloys are discussed. Gamma precipitate size and morphology, gamma-gamma lattice mismatch, phase instability, alloy composition, and processing variations are among the factors considered. Recent experimental results are reviewed and related to the operative deformation mechanisms and to the corresponding mechanical properties. Special emphasis is placed on the creep behavior of single crystal superalloys at high temperatures, where directional gamma coarsening is prominent, and at lower temperatures, where gamma coarsening rates are significantly reduced. It can be seen that very subtle changes in microstructural features can have profound effects on the subsequent properties of these materials.

Mackay, R. A.↗
NASA NTRS2017

Lava Eruption and Emplacement: Using Clues from Hawaii and Iceland to Probe the Lunar Past

Investigating recent eruptions on Earth is crucial to improving understanding of relationships between eruption dynamics and final lava flow morphologies. In this study, we investigated eruptions in Holuhraun, Iceland, and Kilauea, Hawaii to gain insight into the lava dynamics near the source vent, the initiation of lava channels, and the origin of down-channel features. Insights are applied to Rima Bode on the lunar nearside to deduce the sequence of events that formed this lunar sinuous rille system.These insights are crucial to correctly interpreting whether the volcanic features associated with Rima Bode directly relate to eruption conditions at the vent and, thus, can help us understand those eruption dynamics, or, alternatively, whether the features formed as a result of more localized influences on lava flow dynamics. For example, if the lava channel developed early in the eruption and was linked to pulses in vent activity, its morphology can be analyzed to interpret the flux and duration of the eruption. Conversely, if the lava channel initiated late in the eruption as the result of a catastrophic breaching of lava that had previously pooled within the vent [e.g., 1], then the final channel morphology will not indicate eruption dynamics but rather local dynamics associated with that breach event. Distinguishing between these two scenarios is crucial for correctly interpreting the intensity and duration of volcanic history on the Moon.

sinuous rille↗
NASA NTRS2017

Lava Eruption and Emplacement: Using Clues from Hawaii and Iceland to Probe the Lunar Past

Investigating recent eruptions on Earth is crucial to improving understanding of relationships between eruption dynamics and final lava flow morphologies. In this study, we investigated eruptions in Holuhraun, Iceland, and Kilauea, Hawaii to gain insight into the lava dynamics near the source vent, the initiation of lava channels, and the origin of down-channel features. Insights are applied to Rima Bode on the lunar nearside to deduce the sequence of events that formed this lunar sinuous rille system. These insights are crucial to correctly interpreting whether the volcanic features associated with Rima Bode directly relate to eruption conditions at the vent and, thus, can help us understand those eruption dynamics, or, alternatively, whether the features formed as a result of more localized influences on lava flow dynamics. For example, if the lava channel developed early in the eruption and was linked to pulses in vent activity, its morphology can be analyzed to interpret the flux and duration of the eruption. Conversely, if the lava channel initiated late in the eruption as the result of a catastrophic breaching of lava that had previously pooled within the vent [e.g., 1], then the final channel morphology will not indicate eruption dynamics but rather local dynamics associated with that breach event. Distinguishing between these two scenarios is crucial for correctly interpreting the intensity and duration of volcanic history on the Moon.

Needham, Debra Hurwitz↗
NASA NTRS2002

Plasmaspheric Density Troughs: Global IMAGE EUV Observations and Analysis via Global Core Plasma Modeling

To date, the IMAGE EUV camera has observed several plasmaspheric density trough features inside the plasmapause under a wide range of geomagnetic activity. From the perspective of EUV, a density trough feature appears as a channel of diminished pixel counts which spans a width of L-shell (DELTA L) and magnetic local time (MLT) inside the plasmapause. Plasmaspheric density troughs are found to be morphologically complex possessing considerable spatial and temporal variability. We present an analysis of the evolution of trough DELTA L and MLT extent as functions of associated D (sub ST) and K (sub p) history. Trough features range in size from 0.16 less than or equal to DELTA L less than or equal to 1.2 with azimuthal extent from 1500 less than or equal to MLT less than or equal to 1200. All cases of plasmaspheric density troughs studied to date appear to have evolved as a result of the inner edge of the afternoon/evening plasma drainage plume being wrapped around through the nightside plasmasphere. The structure of plasmaspheric density trough features is further probed by analyzing simulated EUV images produced by forward modeling artificially introduced regions of depleted density into both static and dynamic global core plasmaspheric models. Forward modeling suggests that (1) L-shell refilling of density troughs during storm recovery can be modeled as filling from the ionosphere toward the equator (i.e., bottom-up refilling), and (2) that an erosion process is operating within flux tubes beyond the outer L-shell wall of the observed density troughs.

Adrian, M. L.↗
NASA NTRS1988

Microstructure-property relationships in directionally solidified single-crystal nickel-base superalloys

This paper discusses some of the microstructural features which influence the creep properties of directionally solidified and single-crystal nickel-base superalloys. Gamma prime precipitate size and morphology, gamma-gamma (prime) lattice mismatch, phase instability, alloy composition, and processing variations are among the factors considered. Recent experimental results are reviewed and related to the operative deformation mechanisms and to the corresponding mechanical properties. Special emphasis is placed on the creep behavior of single-crystal superalloys at high temperatures, where directional gamma (prime) coarsening is prominent, and at lower temperatures, where gamma (prime) coarsening rates are significantly reduced. It can be seen that very subtle changes in microstructural features can have profound effects on the subsequent properties of these materials.

Mackay, Rebecca A.↗
DOE OSTI2023

Disturbed, diffuse, or just missing? A global study of the H I content of Hickson compact groups

Hickson compact groups (HCGs) are dense configurations of four to ten galaxies, whose H I morphology appears to follow an evolutionary sequence of three phases, with gas initially confined to galaxies, then significant amounts spread throughout the intra-group medium, and finally with almost no gas remaining in the galaxies themselves. It has also been suggested that several groups may harbour a diffuse H I component that is resolved out by interferometric observations. The H I deficiency of HCGs is expected to increase as the H I morphological phase progresses along the evolutionary sequence. If this is the case, H I deficiency would be a rough proxy for the age and evolutionary state of a HCG. We aim to test this hypothesis for the first time using a large sample of HCGs and to investigate the evidence for diffuse H I in HCGs. We performed a uniform reduction of all publicly available VLA H I observations (38 HCGs) with a purpose-built pipeline that also maximises the reproducibility of this study. The resulting H I data cubes were then analysed with the latest software tools to perform a manual separation of emission features into those belonging to galaxies and those extending into the intra-group medium. We thereby classified the H I morphological phase of each group as well as quantified their H I deficiency compared to galaxies in isolation. We find little evidence that H I deficiency can be used as a proxy for the evolutionary phase of a compact group in either of the first two phases, with the distribution of H I deficiency being consistent in both. However, for the final phase, the distribution clearly shifts to high H I deficiencies, with more than 90% of the expected H I content typically missing. Across all HCGs studied, we identify a few cases where there is strong evidence for a diffuse gas component in the intra-group medium, which might be detectable with improved observations. We also classify a new sub-phase where groups contain a lone H I -bearing galaxy, but are otherwise devoid of gas. The new morphological phase we have identified is likely the result of an evolved, gas-poor group acquiring a new, gas-rich member. The large spread of H I deficiencies in the first two morphological phases suggests that there is a broad range of initial H I content in HCGs, which is perhaps influenced by large-scale environment, and that the timescale for morphological changes is, in general, considerably shorter than the timescale for the destruction or consumption of neutral gas in these systems.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Facet-Dependent Ni Segregation in a Micron-Sized Single-Crystal Li 1.2 Ni 0.2 Mn 0.6 O 2 Cathode

Elemental surface segregation in cathode materials is critical for determining the phase and interfacial reaction between electrode and electrolyte, which consequently affects the electrochemical properties. Single-crystal cathode of Li 1.2 Ni 0.2 Mn 0.6 O 2 and Li 1.2 Ni 0.2 Mn 0.6 O 1.95 F 0.05 with an octahedral morphology of (102) and (003) dominated facets have been manifested to show enhanced electrochemical properties. However, the surface structural features of such single crystals have not been investigated. Herein, using scanning transmission electron microscopy, energy dispersive X-ray spectroscopy, and electron energy loss spectroscopy, we probe the elemental surface segregation characteristics in these single-crystal cathode. We reveal that Ni surface segregation shows dependence on the crystal facet such that it occurs on crystal facets with a mix of cations and anions, but not on the facets with only cations or anions. Furthermore, facet-dependent surface reconstructions are observed, featuring a spinel-like structure at the Ni-rich facet but rock-salt structure at the facet without Ni segregation. The commonly known Mn reduction appears at the single crystal surfaces, more pronounced at the facet without Ni segregation. We further reveal that fluorination leads to the stabilization of surface oxygens. In conclusion, this study provides detailed structural and chemical information about the facet-dependent Ni surface segregation and the resulted phase formation in the rather less explored micron-sized octahedral Li 1.2 Ni 0.2 Mn 0.6 O 2 and Li 1.2 Ni 0.2 Mn 0.6 O 1.95 F 0.05 single crystals, which is key to further exploration of electrochemical properties of cathode in the form of micro-sized single crystal.

25 ENERGY STORAGE↗
DOE OSTI2023

A robust approach to 3D neuron shape representation for quantification and classification

We consider the problem of finding an accurate representation of neuron shapes, extracting sub-cellular features, and classifying neurons based on neuron shapes. In neuroscience research, the skeleton representation is often used as a compact and abstract representation of neuron shapes. However, existing methods are limited to getting and analyzing “curve” skeletons which can only be applied for tubular shapes. This paper presents a 3D neuron morphology analysis method for more general and complex neuron shapes. First, we introduce the concept of skeleton mesh to represent general neuron shapes and propose a novel method for computing mesh representations from 3D surface point clouds. A skeleton graph is then obtained from skeleton mesh and is used to extract sub-cellular features. Finally, an unsupervised learning method is used to embed the skeleton graph for neuron classification. Extensive experiment results are provided and demonstrate the robustness of our method to analyze neuron morphology.

3D neuron morphology↗
DOE OSTI2026

Modeling Single-Crystal Battery Materials: From Fundamental Understanding to Performance Evaluation

The performance of rechargeable batteries is fundamentally influenced by the physicochemical properties and microstructural features of their key material components. Recent experimental advancements have highlighted the potential of single-crystal (SC) morphologies to address inherent limitations of polycrystalline (PC) electrodes and solid-state electrolytes, offering tunable charge transport kinetics and improved cell cycling performance. Here, this review examines how state-of-the-art computational modeling, from atomistic and mesoscale to continuum-level approaches, including machine learning methodologies, has been utilized to investigate the critical factors governing the electrochemical behavior of SC battery materials. We explore how predictive modeling can elucidate the processing–structure–property–performance relationships of SC cathodes, anodes, and solid-state electrolytes, with a focus on unique SC characteristics such as crystallographic anisotropy, size effects, and facet-dependent properties. Additionally, we identify limitations in commonly used modeling techniques and discuss strategies to address these challenges. By integrating high-fidelity simulations with experimental insights, this review aims to outline a clear path for the rational design and optimization of SC battery components, paving the way for accelerated advancements in energy storage technologies.

Materials science↗