Thermodynamic properties of extended chain polymethylene single crystals.
Density, morphology and melting data on extended chain linear polyethylene and high molecular weight polymethylene crystallized from melt under high pressure
POLYETHYLENE↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Post-threshold energy dependence of the cross section for endoergic processes - Vibrational excitation and reactive scattering.
The essential features of the translational energy dependence or excitation function for two types of endoergic collisional processes are deduced on the basis of information on the inverse, exoergic processes. Microreversibility is conveniently exploited via the symmetric field function, Y(E), which is uniquely determined at a given total energy, E. In the case of the vibrational excitation of diatomic molecules by atomic or molecular impact, use is made of the abundant data on the temperature dependence of the relaxation time.
Levine, R. D.↗
Diurnal and semidiurnal nitrogen density and temperature variations from thermosphere probe measurements.
Amplitudes and phases for the diurnal and semidiurnal variations of thermospheric molecular nitrogen density and temperature are determined from data obtained by six rocket-launched thermosphere probes. The semidiurnal tide is significant for the lower thermosphere variations, where it could dominate in the N2 density at 140 km and in the temperature for altitudes between 170 and 200 km. At exospheric heights, the magnitudes of the semidiurnal modes in density and temperature are significantly smaller than those of the diurnal mode. The temperature phase is height-dependent in both diurnal and semidiurnal components below 200 km, thus contributing to phase differences between N2 density and temperature in both modes. No significant phase differences are apparent between N2 density and thermospheric temperature above 250 km.
Newton, G. P.↗
Preliminary results Skylab experiment TO27 optical contamination in space
Current results from the TO27 experiment which was performed on the first two Skylab missions are presented. The purpose of the experiment was to determine the change in optical properties of various transmissive windows, mirrors, and diffraction gratings caused by the deposition of contaminants found about the orbital assembly and to measure the sky brightness background caused by solar illumination of particulate contaminants. The sample array system containing 248 optical surfaces and exposed outside the orbital workshop did not collect any significant contaminants. Only trace amounts of surface deposited contaminants have been seen, in all cases the measurement was near the limiting sensitivity of the instrument. Unfortunate performance compromises and the relative cleanliness of the assembly on the anti-solar side appeared to place the amount of available surface contaminants near the limiting sensitivity of the sample array. Mass spectroscopy on the trace contaminants show the presence of high molecular weight species, up to 773 amu. The data suggests the presence of condensed aromatics.
Muscari, J. A.↗
Infrared observations of the surface and atmosphere of Titan
Infrared photometry of Titan, Saturn, and Saturn's Rings at 3.5, 4.9, 17.8, and 18.4 microns is reported. Comparison of the albedo of Titan in the 4.9 micron 'window' with the albedo of the rings and with laboratory spectra suggests that frost, possibly water ice, could be a major constituent. If thick clouds are present they must be very dark at 4.9 microns. The 17.8 and 18.4 micron data are not consistent with a clear, dense molecular hydrogen atmosphere.
Knacke, R. F.↗
Tables of thermospheric temperature, density and composition derived from satellite and ground based measurements. Volume 2: Ap=20
A mass spectrometer and incoherent scatter empirical thermosphere model is used to measure the neutral temperature and neutral densities for N2, O2, O, Ar, He and H, the mean molecular weight, and the total mass density. The data is presented in tabular form.
Hedin, A. E.↗
Nighttime temperatures and ion chemistry from OGO 6 plasma measurements
Results are presented of a statical investigation of temperature and molecular ion chemistry in the nighttime thermosphere, with data from plasma measurements between 400 and 450 km from the retarding potential analyzer on the OGO 6 satellite. Temperatures and ion concentrations from the equatorial region are discussed. Emphasis is placed on statistical analyses of all data acquired within small cells of finite width in latitude and day of observation. Attention is given to a significant fraction of the nighttime hemisphere between low summer and middle winter latitudes.
Sanatani, S.↗
The Jovian ammonia abundance from interferometric observations of limb darkening at 3.4 mm
The relative abundances of the various atomic and molecular constituents in the Jovian atmosphere are important data for studies of the origin of the solar system. The determination of the ammonia abundance presents a number of difficulties. However, difficulties related to a use of the microwave sensing technique can be largely overcome by measuring the brightness distribution across the disk. In particular, information about the atmosphere can be obtained from the degree of limb darkening, which requires only a relative brightness measurement as opposed to an absolute measurement. Valdes and Welch (1978) have used the considered approach in a study of Jupiter at 1.3 cm. In the present investigation a more general relation between the amount of limb darkening in the broad 1.25-cm inversion band of ammonia and the ammonia abundance is derived. The model is applied to new measurements of Jupiter's limb darkening at 3.4 mm.
Valdes, F.↗
A multifrequency study of star formation in the blue compact dwarf galaxy IZw 36
Radio, near IR, optical, and UV observations of I Zw 36 = Mrk 209 = Haro 29 are reported. The H I distribution shows a core-halo structure, the core containing half of the mass and showing systematic motions; the halo is diffuse and contains several H I clumps. The visible star formation region is associated with the core but is shifted slightly with respect to the H I peak column density; and the virial mass is 5 to 7 times the H I mass. Star formation models with an initial mass function of slope 1.5 (the Salpeter value being 1.35) and a burst age or duration of a few million years fit well the optical spectrophotometric measurements. The data also suggest that the column density of molecular hydrogen in I Zw 36 is 6 + or - 3 times that of the neutral hydrogen, about the right amount to account for the virial mass.
Viallefond, F.↗
The HD/H2 ratio in the atmosphere of Uranus
High resolution spectra of HD and H2 were brought together to derive the D/H ratio for Uranus. The deuterium concentration in the dominant molecular hydrogen phase is least susceptible to the effects of isotope fractionation in the planetary atmosphere, and the determination of relative abundances of HD and H2 is unambiguous due to nearness and relative weakness of the chosen spectral lines. The HD 5-0 R(0) and R(1) dipole lines and the H2 4-0 S(0), S(1), and S(2) quadrupole lines were obtained with a PEPSIOS instrument at the Palomar 5-meter telescope. The H2 spectra, which resolve the asymmetric line profiles resulting from pressure shifts in the deep stratified Uranus atmosphere, unambiguously define the line-of-sight hydrogen abundance for comparison with the HD spectra. The 5-0 band of HD was chosen to minimize interference from blended CH4 lines. However, weak interfering lines were found in the 5-0 bands from Uranus as well, and some uncertainties remain regarding the intrinsic line strengths in molecular hydrogen, complicating the analysis of the HD/H2 data. Nevertheless, it is established that the D/H ratio in the atmosphere of Uranus is smaller than the Jovian value, and is significantly smaller than recent theoretical predictions for Uranus based on estimates of isotope fractionation in the pre-planetary solar nebulae.
Trauger, J. T.↗
Microgravity nucleation and particle coagulation experiments support
A hollow sphere model is developed to predict the range of supersaturation ratio values for refractory metal vapors in a proposed experimental nucleation apparatus. Since the experiments are to be carried out in a microgravity environment, the model neglects the effects of convection and assumes that the only transfer of vapors through an inert gas atmosphere is by conduction and molecular diffusion. A consistent set of physical properties data is assembled for the various candidate metals and inert ambient gases expected to be used in the nucleation experiments. Transient partial pressure profiles are computed for the diffusing refractory species for two possible temperature distributions. The supersaturation ratio values from both candidate temperature profiles are compared with previously obtained experimetnal data on a silver-hydrogen system. The model is used to simulate the diffusion of magnesium vapor through argon and other inert gas atmospheres over ranges of initial and boundary conditions. These results identify different combinations of design and operating parameters which are liekly to produce supersaturation ratio values high enough to induce homogeneous nucleation in the apparatus being designed for the microgravity nucleation experiments.
Lilleleht, L. U.↗
High spatial resolution far-infrared scans of W3(OH)
The strong far-infrared continuum source associated with the OH maser-ultracompact H II region W3(OH) was observed from the Kuiper Airborne Observatory in order to determine its size at 50 and 100 microns. Maximum entropy deconvolutions of the slit scans made in orthogonal directions across the source show it to be approximately circular with FWHM sizes of 8 arcsec and 13 arcsec at 50 and 100 microns, respectively. For these sizes, W3(OH) is optically thick in the far-infrared. A spherically symmetric, dusty molecular cloud model is developed to fit the data.
Campbell, M. F.↗
LinkFinder: An expert system that constructs phylogenic trees
An expert system has been developed using the C Language Integrated Production System (CLIPS) that automates the process of constructing DNA sequence based phylogenies (trees or lineages) that indicate evolutionary relationships. LinkFinder takes as input homologous DNA sequences from distinct individual organisms. It measures variations between the sequences, selects appropriate proportionality constants, and estimates the time that has passed since each pair of organisms diverged from a common ancestor. It then designs and outputs a phylogenic map summarizing these results. LinkFinder can find genetic relationships between different species, and between individuals of the same species, including humans. It was designed to take advantage of the vast amount of sequence data being produced by the Genome Project, and should be of value to evolution theorists who wish to utilize this data, but who have no formal training in molecular genetics. Evolutionary theory holds that distinct organisms carrying a common gene inherited that gene from a common ancestor. Homologous genes vary from individual to individual and species to species, and the amount of variation is now believed to be directly proportional to the time that has passed since divergence from a common ancestor. The proportionality constant must be determined experimentally; it varies considerably with the types of organisms and DNA molecules under study. Given an appropriate constant, and the variation between two DNA sequences, a simple linear equation gives the divergence time.
Inglehart, James↗
Extraction of Aerosol and Rayleigh Components from Doppler Lidar Return Signal
One of the most significant problems which limits the applicability of lidar systems for pressure and density profile measurements below 30 km altitude is the presence of atmospheric aerosols which contaminate the molecular or Rayleigh return signal. A new technique is described which allows for the separation of the return signal into aerosol and molecular scattered components. The technique was applied to data from the University of Michigan's High Resolution Doppler Lidar (HRDL).
Barnes, John E.↗
Constellation-X Observatory
Women in Science Conferences are designed to allow young women in grades 7 through 12 to learn first-hand about careers in science, mathematics, and technology from accomplished professional women. Results of an international science and mathematics study conducted in 2000 indicated that "children in the United States were among the leaders in the 4th grade assessment, but by high school graduation, they were almost last." Part of the problem is that many girls and young women in junior and senior high school lose interest in science and technological careers. The goal of the WIS-Conferences held at the University of Wyoming in Laramie, and at Central Wyoming College in Riverton, are to directly address this problem. The conferences will be a cooperative effort supported by local agencies, schools, and businesses, in addition to several state agencies. By presenting positive role models in the science, mathematics, and technological fields, we hope to encourage all students (especially young women and minorities) to pursue higher education and careers in mathematics and science. The workshop topics include: 1) Engineering; 2) Robotics; 3) Physics/Astronomy; 4) Geology; 5) Paleontology; 6) Remote Sensing (GPS/GIS); 7) Molecular Biology; 8) Veterinary Medicine; 9) Optometry; 10) Data Encryption; and 11) Wildlife Biology.
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HST/WFC3 Observations of Giant Hot Exoplanets
Low resolution thermal emission spectra of roger two dozen extrasolar planets have been measured using Spitzer, and HST observations of a few key exoplanets have defined molecular abundances via transmission spectroscopy. However, current models for the atmospheric structure of these worlds exhibit degeneracies wherein different combinations of temperature and molecular abundance profiles can fit the same Spitzer data. The advent of the IR capability on HST/WFC3 allows us to address this problem. We are currently obtaining transmission spectroscopy of the 1.4-micron water band in a sample of 13 planets, using the G141 grism on WFC3, Among the abundant molecules, only water absorbs at this wavelength, and our measurement of water abundance will enable us to break the degeneracies in the Spitzer results with minimal model assumptions. We will also use the G141 grism to observe secondary eclipses for 7 very hot giant exoplanets at 1.5-microns, including several bright systems in the Kepler and CoRoT fields. The strong temperature sensitivity of the thermal continuum at 1.5-microns provides high leverage on atmospheric temperature for these worlds, again helping to break degeneracies in interpreting the Spitzer data. We here describe preliminary results for several exoplanets observed in this program,
Deming, D.↗
HST/WFC3 Observations of Giant Hot Exoplanets
Low resolution thermal emission spectra of several dozen extrasolar planets have been measured using Spitzer, and HST observations of a few key exoplanets have reported molecular abundances via transmission spectroscopy. However, current models for the atmospheric structure of these worlds exhibit degeneracies wherein different combinations of temperature and molecular abundance profiles can fit the same Spitzer data. The advent of the IR capability on HST/WFC3 allows us to address this problem. We are currently obtaining transmission spectroscopy of the 1.4-micron water band in a sample of 13 planets, using the G141 grism on WFC3. This is the largest pure-exoplanet program ever executed on HST (115 orbits). Among the abundant molecules, only water absorbs significantly at 1.4-microns, and our measurement of water abundance will enable us to break the degeneracies in the Spitzer results with minimal model assumptions. We are also using the G141 grism to observe secondary eclipses for 7 very hot giant exoplanets at 1.S-microns, including several bright systems in the Kepler and CoRoT fields. The strong temperature sensitivity of the thermal continuum at 1.S-microns provides high leverage on atmospheric temperature for these worlds, again helping to break degeneracies in interpreting the Spitzer data. We here describe preliminary results for several exoplanets observed in this program.
Deming, D.↗
Observing Planets and Small Bodies in Sputtered High Energy Atom (SHEA) Fluxes
The evolution of the surfaces of bodies unprotected by either strong magnetic fields or thick atmospheres in the Solar System is caused by various processes, induced by photons, energetic ions and micrometeoroids. Among these processes, the continuous bombardment of the solar wind or energetic magnetospheric ions onto the bodies may significantly affect their surfaces, with implications for their evolution. Ion precipitation produces neutral atom releases into the exosphere through ion sputtering, with velocity distribution extending well above the particle escape limits. We refer to this component of the surface ejecta as sputtered high-energy atoms (SHEA). The use of ion sputtering emission for studying the interaction of exposed bodies (EB) with ion environments is described here. Remote sensing in SHEA in the vicinity of EB can provide mapping of the bodies exposed to ion sputtering action with temporal and mass resolution. This paper speculates on the possibility of performing remote sensing of exposed bodies using SHEA The evolution of the surfaces of bodies unprotected by either strong magnetic fields or thick atmospheres in the Solar System is caused by various processes, induced by photons, energetic ions and micrometeoroids. Among these processes, the continuous bombardment of the solar wind or energetic magnetospheric ions onto the bodies may significantly affect their surfaces, with implications for their evolution. Ion precipitation produces neutral atom releases into the exosphere through ion sputtering, with velocity distribution extending well above the particle escape limits. We refer to this component of the surface ejecta as sputtered high-energy atoms (SHEA). The use of ion sputtering emission for studying the interaction of exposed bodies (EB) with ion environments is described here. Remote sensing in SHEA in the vicinity of EB can provide mapping of the bodies exposed to ion sputtering action with temporal and mass resolution. This paper speculates on the possibility of performing remote sensing of exposed bodies using SHEA and suggests the need for quantitative results from laboratory simulations and molecular physic modeling in order to understand SHEA data from planetary missions. In the Appendix, referenced computer simulations using existing sputtering data are reviewed.
Milillo, A.↗