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At least 703 records · Page 39
All sourcesNASA NTRSDOE OSTI
NASA NTRS2022

Non-Protein Amino Acids Identified in Carbon-Rich Hayabusa Particles

Amino acid abundances in acid-hydrolyzed hot water extracts of gold foils containing five Category 3 (carbon-rich) Hayabusa particles were studied using liquid chromatography with tandem fluorescence and accurate mass detection. Initial particle analyses using field emission scanning electron microscopy with energy-dispersive X-ray spectrometry indicated that the particles were composed mainly of carbon. Prior to amino acid analysis, infrared and Raman microspectroscopy showed some grains possessed primitive organic carbon. Although trace terrestrial contamination, namely L-protein amino acids, was observed in all Hayabusa extracts, several terrestrially uncommon non-protein amino acids were also identified. Some Hayabusa particles contained racemic (D≈L) mixtures of the non-protein amino acids β-aminoisobutyric acid (β-AIB) and β-amino-n-butyric acid (β-ABA) at low abundances ranging from 0.09 to 0.31 nmol g −1 . Larger abundances of the non-protein amino acid β-alanine (9.2 nmol g −1 , ≈4.5 times greater than background levels) were measured in an extract of three Hayabusa particles. This β-alanine abundance was ≈6 times higher than that measured in an extract of a CM2 Murchison grain processed in parallel. The comparatively high β-alanine abundance is surprising as asteroid Itokawa is similar to amino acid-poor LL ordinary chondrites. Elevated β-alanine abundances and racemic β-AIB and β-ABA in Hayabusa grains suggested these compounds have non-biological and plausibly non-terrestrial origins. These results are the first evidence of plausibly extraterrestrial amino acids in asteroid material from a sample-return mission and demonstrate the capabilities of the analytical protocols used to study asteroid Ryugu and Bennu samples returned by the JAXA Hayabusa2 and NASA OSIRIS-REx missions, respectively.

Eric T. Parker↗
NASA NTRS2015

Failure Analysis Results and Corrective Actions Implemented for the EMU 3011 Water in the Helmet Mishap

During EVA (Extravehicular Activity) No. 23 aboard the ISS (International Space Station) on 07/16/2013 water entered the EMU (Extravehicular Mobility Unit) helmet resulting in the termination of the EVA (Extravehicular Activity) approximately 1-hour after it began. It was estimated that 1.5-L of water had migrated up the ventilation loop into the helmet, adversely impacting the astronauts hearing, vision and verbal communication. Subsequent on-board testing and ground-based TT and E (Test, Tear-down and Evaluation) of the affected EMU hardware components led to the determination that the proximate cause of the mishap was blockage of all water separator drum holes with a mixture of silica and silicates. The blockages caused a failure of the water separator function which resulted in EMU cooling water spilling into the ventilation loop, around the circulating fan, and ultimately pushing into the helmet. The root cause of the failure was determined to be ground-processing short-comings of the ALCLR (Airlock Cooling Loop Recovery) Ion Filter Beds which led to various levels of contaminants being introduced into the Filters before they left the ground. Those contaminants were thereafter introduced into the EMU hardware on-orbit during ALCLR scrubbing operations. This paper summarizes the failure analysis results along with identified process, hardware and operational corrective actions that were implemented as a result of findings from this investigation.

Steele, John↗
NASA NTRS1951

Analysis of thrust augmentation of turbojet engines by water injection at compressor inlet including charts for calculating compression processes with water injection

A psychrometric chart having total pressure (sum of partial pressures of air and water vapor) as a variable, a Mollier diagram for air saturated with water vapor, and charts showing the thermodynamic properties of various air-water vapor and exhaust gas-water vapor mixtures are presented as aids in calculating the thrust augmentation of a turbojet engine resulting from the injection of water at the compressor inlet. Curves are presented that show the theoretical performance of the augmentation method for various amounts of water injected and the effects of varying flight Mach number, altitude, ambient-air temperature, ambient relative humidity, compressor pressure ratio, and inlet-diffuser efficiency. Numerical examples, illustrating the use of the psychrometric chart and the Mollier diagram in calculating both compressor-inlet and compressor-outlet conditions when water is injected at the compressor inlet, are presented.

Wilcox, E Clinton↗
NASA NTRS2012

Simulation of Complex Cracking in Plain Weave C/SiC Composite under Biaxial Loading

Finite element analysis is performed on a mesh, based on computed geometry of a plain weave C/SiC composite with assumed internal stacking, to reveal the pattern of internal damage due to biaxial normal cyclic loading. The simulation encompasses intertow matrix cracking, matrix cracking inside the tows, and separation at the tow-intertow matrix and tow-tow interfaces. All these dissipative behaviors are represented by traction-separation cohesive laws. Not aimed at quantitatively predicting the overall stress-strain relation, the simulation, however, does not take the actual process of fiber debonding into account. The fiber tows are represented by a simple rule-of-mixture model where the reinforcing phase is a hypothetical one-dimensional material. Numerical results indicate that for the plain weave C/SiC composite, 1) matrix-crack initiation sites are primarily determined by large intertow matrix voids and interlayer tow-tow contacts, 2) the pattern of internal damage strongly depends on the loading path and initial stress, 3) compressive loading inflicts virtually no damage evolution. KEY WORDS: ceramic matrix composite, plain weave, cohesive model, brittle failure, smeared crack model, progressive damage, meso-mechanical analysis, finite element.

Cheng, Ron-Bin↗
NASA NTRS1971

Experiments in Jovian atmosphere.

A 1000 ml reaction vessel, fitted with a stopcock, two joints for the electrodes, and a connecting joint, was used in the investigation. The flask, which has a cold finger at the bottom, was filled with an equimolar mixture of anhydrous methane and ammonia. The electrodes were adjusted to provide a gap of about 0.8 cm between them so that the current flowing through the electrodes was about 0.5 mA and a continuous spark could be observed. The operation was continued for 20 hr. The analysis of the reaction products showed the formation of amino nitriles under the conditions of the investigation.

Chadha, M. S.↗
NASA NTRS1976

Measurement techniques for analysis of fission fragment excited gases

Spectroscopic analysis of fission fragment excited He, Ar, Xe, N2, Ne, Ar-N2, and Ne-N2 have been conducted. Boltzmann plot analysis of He, Ar and Xe have indicated a nonequilibrium, recombining plasma, and population inversions have been found in these gases. The observed radiating species in helium have been adequately described by a simple kinetic model. A more extensive model for argon, nitrogen and Ar-N2 mixtures was developed which adequately describes the energy flow in the system and compares favorably with experimental measurements. The kinetic processes involved in these systems are discussed.

Schneider, R. T.↗
NASA NTRS1986

Ignition delay times of cyclopentene oxygen argon mixtures

The oxidation of cyclopentene was studied experimentally to expand the database on pyrolysis and the reaction products of five carbon unsaturated ring compounds. Pyrolysis was carried out in a single-pulse shock tube. Data were gathered on the shock speed, wall pressure, and reflected shock temperatures. Four different mixtures of C5H8, O2 and Ar, ranging from 0.25-1 percent cyclopentene and 1.75-7 percent O2, were examined in 76 different trials. The data showed a shock temperature range of 1323-1816 K and a pressure range of 1.67-7.36 atmospheres. A student-t test analysis of the results led to definition of an ignition delay equation accurate to the 2-sigma level.

Burcat, A.↗
NASA NTRS1990

Optimization of the propulsion cycles for advanced shuttles. II - Performance model methodology

In 1988 computer codes from NASA and DLR were combined to analyze and optimize rocket engines for advance launch vehicles. Further effort has addressed performance propulsion parameters such as chamber pressure, cycle selection (including mixed and tripropellant cycles), nozzle extension, and new technologies. Results of the study indicate that lower dry masses can be reached with the staged combustion cycle than with the gas-generator cycle, using oxygen/hydrogen at relatively high mixture ratio (7:1) and modest chamber pressure (220 bar). For low dry masses the staged combustion cycle is only excelled by the dual-expander cycle using hydrogen and propane as fuels. The emphasis here is to explain the procedure and boundary conditions used for the analysis and the variety of configurations treated, as well as to demonstrate the methods used by presenting some of the major results.

Manski, Detlef↗
NASA NTRS1992

A Volatile Organic Analyzer for Space Station - Description and evaluation of a gas chromatography/ion mobility spectrometer

An on-board Volatile Organic Analyzer (VOA), an essential component of the Environmental Health System (EHS) air-quality monitoring strategy, is described. The strategy is aimed at warning the crew and ground personnel if volatile compounds exceed safe exposure limits. The VOA uses a combination of gas chromatography (GC) and ion-mobility spectrometry (IMS) for environmental monitoring and analysis. It is concluded that the VOA dual-mode detection capability and the ion mobilities in the drift region are unique features that can assist in the resolution of coeluting GC peaks. The VOA is capable of accurately identifying and quantifying target compounds in a complex mixture.

Limero, Thomas↗
NASA NTRS2000

Preliminary Results from an Assimilation of Saharan Dust Using TOMS Radiances and the GOCART Model

At NASA Goddard we are developing a global aerosol data assimilation system that combines advances in remote sensing and modeling of atmospheric aerosols. The goal is to provide high resolution, 3-D aerosol distributions to the research community. Our first step is to develop a simple assimilation system for Saharan mineral aerosol. The Goddard Chemistry and Aerosol Radiation model (GOCART) provides accurate 3-D mineral aerosol size distributions. Surface mobilization, wet and dry deposition, convective and long-range transport are all driven by assimilated fields from the Goddard Earth Observing System Data Assimilation System, GEOS-DAS. Our version of GOCART transports sizes from .08-10 microns and only simulates Saharan dust. We draw the assimilation to two observables in this study: the TOMS aerosol index (Al) which is directly related to the ratio of the 340 and 380 radiances and the 380 radiance alone. The forward model that simulates the observables requires the aerosol optical thickness, the single scattering albedo and the height of the aerosol layer from the GOCART fields. The forward model also requires a refractive index for the dust. We test three index values to see which best fits the TOMS observables. These are 1) for Saharan dust reported by Patterson, 2) for a mixture of Saharan dust and a highly reflective material (sea salt or sulfate) and 3) for pure illite. The assimilation works best assuming either pure illite or the dust mixture. Our assimilation cycle first determines values of the aerosol index (Al) and the radiance at 380 nm based on the GOCART aerosol fields. Differences between the observed and GOCART model calculated Al and 380 nm radiance are first analyzed horizontally using the Physical-space Statistical Analysis System (PSAS). A quasi-Newton iteration is then performed to produce analyzed 3D aerosol fields according to parameterized background and observation error covariances. We only assimilate observations into the the GOCART model over regions of Africa and the Atlantic where mineral aerosols are dominant and carbonaceous aerosols are minimal.

Weaver, C. J.↗
NASA NTRS2008

Combustion Devices CFD Team Analyses Review

A variety of CFD simulations performed by the Combustion Devices CFD Team at Marshall Space Flight Center will be presented. These analyses were performed to support Space Shuttle operations and Ares-1 Crew Launch Vehicle design. Results from the analyses will be shown along with pertinent information on the CFD codes and computational resources used to obtain the results. Six analyses will be presented - two related to the Space Shuttle and four related to the Ares I-1 launch vehicle now under development at NASA. First, a CFD analysis of the flow fields around the Space Shuttle during the first six seconds of flight and potential debris trajectories within those flow fields will be discussed. Second, the combusting flows within the Space Shuttle Main Engine's main combustion chamber will be shown. For the Ares I-1, an analysis of the performance of the roll control thrusters during flight will be described. Several studies are discussed related to the J2-X engine to be used on the upper stage of the Ares I-1 vehicle. A parametric study of the propellant flow sequences and mixture ratios within the GOX/GH2 spark igniters on the J2-X is discussed. Transient simulations will be described that predict the asymmetric pressure loads that occur on the rocket nozzle during the engine start as the nozzle fills with combusting gases. Simulations of issues that affect temperature uniformity within the gas generator used to drive the J-2X turbines will described as well, both upstream of the chamber in the injector manifolds and within the combustion chamber itself.

Rocker, Marvin↗
NASA NTRS2017

Quantitative EPMA Compositional Mapping of NWA 2995: Characterization, and Petrologic Interpretation of Mafic Clasts

We present the first fully quantitative compositional maps of lunar meteorite NWA 2995 using electron microprobe stage mapping, and compare selected clast mineralogy and chemistry. NWA 2995 is a feldspathic fragmental breccia containing numerous highland fine grained lithologies, including anorthosite, norite, olivine basalt, subophitic basalt, gabbro, KREEP-like basalt, granulitic and glassy impact melts, coarse-grained mineral fragments, Fe-Ni metal, and glassy matrix [1]. Chips of NWA 2995, representing these diverse materials, were analyzed by INAA and fused-bead electron-probe microanalysis (EPMA); comparison of analytical data suggests grouping of lunar meteorites NWA 2995, 2996, 3190, 4503, 5151, and 5152. The mean composition of NWA 2995 corresponds to a 2:1 mixture of feldspathic and mare material, with approximately 5% KREEP component [2]. Clast mineral chemistry and petrologic interpretation of paired stone NWA 2996 has been reported by Mercer et al. [3], and Gross et al. [4]. This study combines advances in quantitative EPMA compositional mapping and data analysis, as applied to selected mafic clasts in a polished section of NWA 2995, to investigate the origin of mafic lithic components and to demonstrate a procedural framework for petrologic analysis.

Carpenter, P. K.↗
NASA NTRS2015

Survival of Organic Materials in Ancient Cryovolcanically-Produced Halite Crystals

Spectroscopic evidence supports the presence of Mg-Na-K salts derived from cryovolcanism on the surface of Europa. Halite (NaCl) is effective at very long-term preservation of organic phases and structures. Collection of salt crystals from Europan plumes would provide solid inclusions of organics, potentially also biomaterials, all suitable for analysis. Two thermally-metamorphosed ordinary chondrite regolith breccias (Monahans 1998 (H5) and Zag (H3-6)) contain fluid and solid inclusion-bearing halite crystals, dated to approximately 4.5 billion years, and thus the trapped aqueous fluids and solids are at least as old. Heating/freezing studies of the aqueous fluid inclusions in these halites demonstrated that they were trapped near 25 degrees Centigrade, and their continued presence in the halite grains requires that their incorporation into the H chondrite asteroid occurred after that body's metamorphism ended, since heating would have dessicated the halite. O and H isotopes of the trapped fluids are consistent with mixing of asteroidal and cometary water. Cryovolcanic Origin of the Halite: We hypothesize that these meteoritic halites derive from ancient cryovolcanism based on the following points. (1) Salts crystals are observed as products of current cryovolcanism on Enceladus. (2) In-situ spacecraft analysis of some of the icy grains associated with the Enceladus salt found minor organic or siliceous components, including methane, also found in the Monahans halite. (3) Cryovolcanic fluids are observed to be in chemical disequilibrium, reflecting incomplete reactions between interior volatiles and rocky materials. The coexistence of N2 and HCN in Enceladus' cryovolcanic fluids requires that the plume consists of a mixture of materials whose sources experienced different degrees of aqueous processing, including primordial material trapped in ice that has not been in contact with liquid water. The observed mineral assemblage within the Monahans and Zag halites is also far from equilibrium. Cryovolcanoes on Ceres are a potential source of our halite, however the processes that form halite should also be operating within Europa. Dissolution of Monahans halite grains has revealed a remarkable variety of organics, which dominate the population of solid inclusions. Thermal alteration of this macromolecular carbon (measured by Raman spectroscopy) shows remarkable diversity. We have identified highly-condensed aromatics, diamond, carbonates and chloromethane. Light organic compounds like methane tend to be water soluble and require cold formation temperatures at high hydrogen fugacity - i.e. require water ice. Another indication that these halites have not been heated is that light organics readily volatilize or aromaticize into PAHs. We are currently analyzing the organics by Raman and C-XANES, and measuring the content and exploring the potential chirality of amino acids in the halite. Implications for Europa Plumes: Organic materials and structures erupted by a Europa cryovolcano should be similarly preserved within halite, and other salts, which will be a convenient form for capture and analysis, since halite will serve to encapsulate and protect the organics from spacecraft contamination. Also, being transparent at many wavelengths halite will permit analysis by spacecraft-mounted spectroscopic techniques. In addition, halite is readily dissolved, permitting further analysis of entrained organics.

Zolensky, M.↗
NASA NTRS1981

Heat Capacity Mapping Mission (HCMM): Interpretation of imagery over Canada

Visual analysis of HCMM images acquired over two sites in Canada and supporting aircraft and ground data obtained at a smaller subsite in Alberta show that nightime surface temperature distribution is primarily related to the near-surface air temperature; the effects of topography, wind, and land cover were low or indirect through air temperature. Surface cover and large altitudinal differences were important parameters influencing daytime apparent temperature values. A quantitative analysis of the relationship between the antecedent precipitation index and the satellite thermal IR measurements did not yield statistically significant correlation coefficients, but the correlations had a definite temporal trend which could be related to the increasing uniformity of vegetation cover. The large pixel size (resulting in a mixture of cover types and soil/canopy temperatures measured by the satellite) and high cloud cover frequency found in images covering both Canadian sites and northern U.S. were considered the main deficiencies of the thermal satellite data.

Cihlar, J.↗
NASA NTRS1985

Chemical components of the Apollo 15 regolith

The lunar regolith is a complex mixture of many components. Compositional data is used to identify and estimate the relative importance of the various chemical components of the regolith. The results and conclusions of four methods that were applied to Apollo 15 regolith data were reviewed to determine the important chemical components: graphical techniques, analysis of individual soil particles, factor analysis, and multicomponent mixing models. This synthesis relies heavily on data and conclusions from the literature as well as new analyses on 28 regolith breccia samples, 28 soil samples, and 50 individual 1 to 2 mm particles from soil 15272.

Korotev, R. L.↗
NASA NTRS1990

An analysis of the threshold method for measuring area-average rainfall

Experimental evidence shows that the area-average rain rate and the fractional area covered by rain rate exceeding a fixed threshold are highly correlated; that is, are highly linearly related. A precise theoretical explanation of this fact is given. The explanation is based on the observation that rain rate has a mixed distribution, one that is a mixture of a discrete distribution and a continuous distribution. Under a homogeneity assumption, the slope of the linear relationship depends only on the continuous part of the distribution and as such is found to be markedly immune to parameter changes. This is illustrated by certain slope surfaces obtained from three specific distributions. The threshold level can be chosen in an optimal way by minimizing a certain distance function defined over the threshold range. In general, the threshold level should be not too far from the mean rain rate conditional on rain. The so-called threshold method advocates measuring rainfall from fractional area exploiting the observed linear relationship of the later with the area average rain rate. The method is potentially useful for the estimation of rainfall from space via satellites.

Kedem, Benjamin↗
NASA NTRS2011

XANES Analysis of Organic Residues Produced from the UV Irradiation of Astrophysical Ice Analogs

Organic residues formed in the laboratory from the ultraviolet (UV) photo-irradiation or ion bombardment of astrophysical ice analogs have been extensively studied for the last 15 years with a broad suite of techniques, including infrared (IR) and UV spectroscopies, as well as mass spectrometry. Analyses of these materials show that they consist of complex mixtures of organic compounds stable at room temperature, mostly soluble, that have not been fully characterized. However, the hydrolysis products of these residues have been partly identified using chromatography techniques, which indicate that they contain molecular precursors of prebiotic interest such as amino acids, nitrile-bearing compounds, and amphiphilic compounds. In this study, we present the first X-ray absorption near-edge structure (XANES) spectroscopy measurements of three organic residues made from the UV irradiation of ices having different starting compositions. XANES spectra confirm the presence of different chemical functions in these residues, and indicate that they are rich in nitrogenand oxygen-bearing species. These data can be compared with XANES measurements of extraterrestrial materials. Finally, this study also shows how soft X rays can alter the chemical composition of samples.

XANES(X-RAY ABSORPTION NEAR-EDGE STRUCTURE)↗
NASA NTRS1978

Computational fluid dynamics applied to flows in an internal combustion engine

The reported investigation is a continuation of studies conducted by Diwakar et al. (1976) and Griffin et al. (1976), who reported the first computational fluid dynamic results for the two-dimensional flowfield for all four strokes of a reciprocating internal combustion (IC) engine cycle. An analysis of rectangular and cylindrical three-dimensional engine models is performed. The working fluid is assumed to be inviscid air of constant specific heats. Calculations are carried out of a four-stroke IC engine flowfield wherein detailed finite-rate chemical combustion of a gasoline-air mixture is included. The calculations remain basically inviscid, except that in some instances thermal conduction is included to allow a more realistic model of the localized sparking of the mixture. All the results of the investigation are obtained by means of an explicity time-dependent finite-difference technique, using a high-speed digital computer.

Griffin, M. D.↗