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At least 703 records · Page 39

Prediction of nonlinear optical properties of organic materials. General theoretical considerations

The prediction of nonlinear optical properties of organic materials is geared to assist materials scientists in the selection of good candidate molecules. A brief summary of the quantum mechanical methods used for estimating hyperpolarizabilities will be presented. The advantages and limitations of each technique will be discussed. Particular attention will be given to the finite-field method for calculating first and second order hyperpolarizabilities, since this method is better suited for large molecules. Corrections for dynamic fields and bulk effects will be discussed in detail, focusing on solvent effects, conformational isomerization, core effects, dispersion, and hydrogen bonding. Several results will be compared with data obtained from third-harmonic-generation (THG) and dc-induced second harmonic generation (EFISH) measurements. These comparisons will demonstrate the qualitative ability of the method to predict the relative strengths of hyperpolarizabilities of a class of compounds. The future application of molecular mechanics, as well as other techniques, in the study of bulk properties and solid state defects will be addressed. The relationship between large values for nonlinear optical properties and large conjugation lengths is well known, and is particularly important for third-order processes. For this reason, the materials with the largest observed nonresonant third-order properties are conjugated polymers. An example of this type of polymer is polydiacetylene. One of the problems in dealing with polydiacetylene is that substituents which may enhance its nonlinear properties may ultimately prevent it from polymerizing. A model which attempts to predict the likelihood of solid-state polymerization is considered, along with the implications of the assumptions that are used. Calculations of the third-order optical properties and their relationship to first-order properties and energy gaps will be discussed. The relationship between monomeric and polymeric third-order optical properties will also be considered.

Cardelino, B.↗

Effect of angleplying and matrix enhancement on impact-resistant boron/aluminum composites

Efforts to improve the impact resistance of B/Al are reviewed and analyzed. Tensile and dynamic modulus tests, thin sheet Charpy and Izod impact tests, and standard full size Charpy impact tests were conducted on 0.20 mm (8 mil) diameter-B/1100 Al matrix composites. Angleplies ranged from unidirectional to + or - 30 deg. The best compromise between reduced longitudinal properties and increased transverse properties was obtained with + or - 15 deg angleply. The pendulum impact strengths of improved B/Al were higher than that of notched titanium and appear to be enough to warrant consideration of B/Cl for application to fan blades in aircraft gas turbine engines.

Mcdanels, D. L.↗

Initial Pioneer Venus magnetometer observations

Initial Pioneer Venus magnetometer observations reveal a highly dynamic interaction between the solar wind and the ionosphere and a very weak and possibly absent intrinsic magnetic field. The bow shock position and the altitude of the ionopause vary markedly from day to day. The magnetic pressure in the magnetosheath just outside the ionopause is in near balance with the thermal ionospheric pressure inside. Although the ionospheric magnetic field strength is generally low, occasional enhancements are observed with field strengths exceeding that in the magnetosheath. These bundles of magnetic flux, or flux ropes, may be convected to the night side ionosphere in which large field strengths (compared to the dayside) are common. The magnetic field magnitude and direction in this region are quite variable, suggesting that the field is not due to an intrinsic planetary source, but rather due to induced ionospheric currents. The magnetic moment is probably much less than 10 to the 22nd Gauss-cu cm.

Russell, C. T.↗

Multifunctional Low-Pressure Turbine for Core Noise Reduction, Improved Efficiency, and Nitrogen Oxide (NOx) Reduction

This work studied the feasibility of using Helmholtz resonator cavities embedded in low-pressure-turbine (LPT) airfoils to (1) reduce core noise by damping acoustic modes; (2) use the synthetic jets produced by the liner hole acoustic oscillations to improve engine efficiency by maintaining turbulent attached flow in the LPT at low-Reynolds-number cruise conditions; and (3) reduce engine nitrogen oxide emissions by lining the internal cavities with materials capable of catalytic conversion. Flat plates with embedded Helmholtz resonators, designed to resonate at either 3000 or at 400 Hz, were simulated using computational fluid dynamics. The simulations were conducted for two inlet Mach numbers, 0.25 and 0.5, corresponding to Reynolds numbers of 90 000 and 164 000 based on the effective chordwise distance to the resonator orifice. The results of this study are (1) the region of acoustic treatment may be large enough to have a benefit; (2) the jets may not possess sufficient strength to reduce flow separation (based on prior work by researchers in the flow control area); and (3) the additional catalytic surface area is not exposed to a high velocity, so it probably does not have any benefit.

Miller, Christopher J.↗

A Large-Eddy Simulation Of Turbulent Flow Over A Backward Facing Step

Large-eddy simulation (LES) was used to study the turbulent flow over a backward facing step. The simulations examine the details of the turbulent flow's separated and reattaching regions created by the step geometry. An explicit high-order of accuracy/high resolution finite-difference computational fluid dynamics solver was used for both LES and Reynolds-averaged Navier-Stokes (RANS) simulations. The experimental data from the backward facing step experiment of Driver and Seegmiller was used for comparison. Data presented are derived from a RANS simulation using the Spalart-Allmaras turbulence model and LES simulations using the implict LES assumption on three different grids of varying resolution. The RANS solution agrees with past work. It does an adequate job of predicting the flowfield and reattachment point, but misses details such as the strength of the recirculating region and magnitudes of the Reynolds stresses. The synthetic eddy method was used to provide a turbulent inflow to the quasi-2D LES domains. For the LES, the coarse grid was of insufficient resolution and under-predicted the skin friction coefficient and over-predicted the normal stresses. The finer grid LES results accurately predict the skin friction coefficient and provide more accurate Reynolds stresses. Triple product velocity correlations are also computed from the LES and the finer grid results did a good job predicting the magnitudes of the curves and the shapes were reasonably represented. It is recommended that future work include investigating the turbulent inflow domain length, width of the quasi-2D domain, and additional grid refinement.

turbulence↗

Electron dynamics and energy conversion in O-type linear-beam devices.

A general nonlinear interaction theory is used to investigate the effects of transverse fields (i.e., radial circuit fields and radial space-charge fields) in traveling-wave amplifiers for a variety of beam-focusing conditions. Magnetic focusing fields which are periodic or tapered (increased) with distance along the device are considered in addition to uniform magnetic fields. Results are presented for Brillouin flow and near-Brillouin flow, and the minimum magnetic field strength required to effectively constrain the electron beam is determined as a function of the operating parameters for the various focusing systems. Confined flow is also examined for the uniform-field case in order to have a basis of comparison from which the effects of radial motion of the beam electrons can be determined. The results indicate the importance of transverse effects and further yield information on the stability of strongly modulated cylindrical electron beams.-

Detweiler, H. K.↗

A Large-Eddy Simulation Of Turbulent Flow Over A Backward Facing Step

Large-eddy simulation (LES) was used to study the turbulent flow over a backward facing step. The simulations examine the details of the turbulent flow’s separated and reattaching regions created by the step geometry. An explicit high-order of accuracy/high resolution finite-difference computational fluid dynamics solver was used for both LES and Reynolds-averaged Navier-Stokes (RANS) simulations. The experimental data from the backward facing step experiment of Driver and Seegmiller was used for comparison. Data presented are derived from a RANS simulation using the Spalart-Allmaras turbulence model and LES simulations using the implicit LES assumption on three different grids of varying resolution. The RANS solution agrees with past work. It does an adequate job of predicting the flowfield and reattachment point, but misses details such as the strength of the recirculating region and magnitudes of the Reynolds stresses. The synthetic eddy method was used to provide a turbulent inflow to the quasi-2D LES domains. For the LES, the coarse grid was of insufficient resolution and under-predicted the skin friction coefficient and over-predicted the normal stresses. The finer grid LES results accurately predict the skin friction coefficient and provide more accurate Reynolds stresses. Triple product velocity correlations are also computed from the LES and the finer grid results did a good job predicting the magnitudes of the curves and the shapes were reasonably represented. It is recommended that future work include investigating the turbulent inflow domain length, width of the quasi-2D domain, and additional grid refinement

turbulence↗

The structural response of a rail accelerator

The transient response of a 0.4 by 0.6 cm rectangular bore rail accelerator was analyzed by a three dimensional finite element code. The copper rail deflected to a peak value of 0.08 mm in compression and then oscillated at an amplitude of 0.02 mm. Simultaneously the insulating side wall of glass fabric base, epoxy resin laminate (G-1o) was compressed to a peak value of 0.13 mm and rebounded to a steady state in extension. Projectile pinch or blowby due to the rail extension or compression, respectively, can be identified by examining the time history of the rail displacement. The effect of blowby was most significant at the side wall characterized by mm size displacement in compression. Dynamic stress calculations indicate that the G-10 supporting material behind the rail is subjected to over 21 MPa at which the G-10 could fail if the laminate was not carefully oriented. Results for a polycarbonate resin (Lexan) side wall show much larger displacements and stresses than for G-10. The tradeoff between the transparency of Lexan and the mechanical strength of G-10 for sidewall material is obvious. Displacement calculations from the modal method are smaller than the results from the direct integration method by almost an order of magnitude, because the high frequency effect is neglected.

Wang, S. Y.↗

The structural response of a rail acceleration

The transient response of a 0.4 by 0.6 cm rectangular bore rail accelerator was analyzed by a three dimensional finite element code. The copper rail deflected to a peak value of 0.08 mm in compression and then oscillated at an amplitude of 0.02 mm. Simultaneously the insulating side wall of glass fabric base, epoxy resin laminate (G-10) was compressed to a peak value of 0.13 mm and rebounded to a steady state in extension. Projectile pinch or blowby due to the rail extension or compression, respectively, can be identified by examining the time history of the rail displacement. The effect of blowby was most significant at the side wall characterized by mm size displacement in compression. Dynamic stress calculations indicate that the G-10 supporting material behind the rail is subjected to over 21 MPa at which the G-10 could fail if the laminate was not carefully oriented. Results for a polycarbonate resin (Lexan) side wall show much larger displacements and stresses than for G-10. The tradeoff between the transparency of Lexan and the mechanical strength of G-10 for sidewall material is obvious. Displacement calculations from the modal method are smaller than the results from the direct integration method by almost an order of magnitude, because the high frequency effect is neglected. Previously announced in STAR as N83-35412

Wang, S. Y.↗

One-dimensional multispecies magnetohydrodynamic models of the ramside ionosphere of Titan

The interaction of the Saturnian magnetosphere with the ionosphere of Titan has much in common with the solar wind interaction with nonmagnetic bodies in general. A one-dimensional magnetohydrodynamic model was developed, for radial distances of 1.3 to 2 Titan radii (R(sub T)), to study the dynamics of H2CN(+), C(sub n) H(sub m) (+) (n, m greater than z), C2H5(+), and CH5(+), in the ramside ionosphere of Titan. For the case of a dayside ramside ionosphere (solar zenith angle of 60 degs) we found that the external magnetospheric plasma interacting with Titan's ionosphere produced a very broad region of ionospheric magnetic field whose peak field strength was approximately 26 nT. The ionosphere was magnetized well below the ionospheric peak, allowing ionizing Saturnian magnetospheric electrons access to this region. The sources of ionization and the electron temperature profiles incorporated into the model depend on the relative locations of Titan, Saturn, and the Sun. The calculated electron and ion density profiles as well as the magnetic field profile also depend on the relative positions of Titan, Saturn, and the Sun.

Keller, C. N.↗

Characteristics of Quasi-Terminator Orbits Near Primitive Bodies

Quasi-terminator orbits are introduced as a class of quasi-periodic trajectories in the solar radiation pressure (SRP) perturbed Hill dynamics. These orbits offer significant displacements along the Sun-direction without the need for station-keeping maneuvers. Thus, quasi-terminator orbits have application to primitive-body missions, where a variety of observation geometries relative to the Sun (or other directions) can be achieved. This paper describes the characteristics of these orbits as a function of normalized SRP strength and invariant torus frequency ratio and presents a discussion of mission design considerations for a global surface mapping orbit design.

orbital motions↗

Evolution and interaction of large interplanetary streams

A computer simulation for the evolution and interaction of large interplanetary streams based on multi-spacecraft observations and an unsteady, one-dimensional MHD model is presented. Two events, each observed by two or more spacecraft separated by a distance of the order of 10 AU, were studied. The first simulation is based on the plasma and magnetic field observations made by two radially-aligned spacecraft. The second simulation is based on an event observed first by Helios-1 in May 1980 near 0.6 AU and later by Voyager-1 in June 1980 at 8.1 AU. These examples show that the dynamical evolution of large-scale solar wind structures is dominated by the shock process, including the formation, collision, and merging of shocks. The interaction of shocks with stream structures also causes a drastic decrease in the amplitude of the solar wind speed variation with increasing heliocentric distance, and as a result of interactions there is a large variation of shock-strengths and shock-speeds. The simulation results shed light on the interpretation for the interaction and evolution of large interplanetary streams. Observations were made along a few limited trajectories, but simulation results can supplement these by providing the detailed evolution process for large-scale solar wind structures in the vast region not directly observed. The use of a quantitative nonlinear simulation model including shock merging process is crucial in the interpretation of data obtained in the outer heliosphere.

Whang, Y. C.↗

Structural Design and Analysis of a Light-Weight Laminated Composite Heat Sink for Spaceflight PWBs

In order to reduce the overall weight in spaceborne electronic systems, a conventional metallic heat sink typically used for double-sided printed wiring boards was suggested to be replaced by light-weight and high-strength laminated composite materials. Through technology validation assurance (TVA) approach, it has been successfully demonstrated that using laminated composite heat sink can not only reduce the weight of the heat sink by nearly 50%, but also significantly lower the internal thermally-induced stresses that are largely responsible for potential delamination under cyclic temperature variations. With composite heat sink, both thermal and dynamic performance of the double-sided printed wiring board (PWB) exceeds that of its counterpart with metallic heat sink. Also included in this work is the original contribution to the understanding of creep behavior of the worst-case leadless chip carrier (LCC) surface mount solder joint. This was identified as the interconnection most susceptible to thermal fatigue damage in the PWB assembly.

Fan, Mark S.↗

High-Strain-Rate Compression Testing of Ice

In the present study a modified split Hopkinson pressure bar (SHPB) was employed to study the effect of strain rate on the dynamic material response of ice. Disk-shaped ice specimens with flat, parallel end faces were either provided by Dartmouth College (Hanover, NH) or grown at Case Western Reserve University (Cleveland, OH). The SHPB was adapted to perform tests at high strain rates in the range 60 to 1400/s at test temperatures of -10 and -30 C. Experimental results showed that the strength of ice increases with increasing strain rates and this occurs over a change in strain rate of five orders of magnitude. Under these strain rate conditions the ice microstructure has a slight influence on the strength, but it is much less than the influence it has under quasi-static loading conditions. End constraint and frictional effects do not influence the compression tests like they do at slower strain rates, and therefore the diameter/thickness ratio of the samples is not as critical. The strength of ice at high strain rates was found to increase with decreasing test temperatures. Ice has been identified as a potential source of debris to impact the shuttle; data presented in this report can be used to validate and/or develop material models for ice impact analyses for shuttle Return to Flight efforts.

Shazly, Mostafa↗

Managing Flap Vortices via Separation Control

A pilot study was conducted on a flapped semi-span model to investigate the concept and viability of near-wake vortex management by means of boundary layer separation control. Passive control was achieved using a simple fairing and active control was achieved via zero mass-flux blowing slots. Vortex sheet strength, estimated by integrating surface pressures, was used to predict vortex characteristics based on inviscid rollup relations and vortices trailing the flaps were mapped using a seven-hole probe. Separation control was found to have a marked effect on vortex location, strength, tangential velocity, axial velocity and size over a wide range of angles of attack and control conditions. In general, the vortex trends were well predicted by the inviscid rollup relations. Manipulation of the separated flow near the flap edges exerted significant control over either outboard or inboard edge vortices while producing small lift and moment excursions. Unsteady surface pressures indicated that dynamic separation and attachment control can be exploited to perturb vortices at wavelengths shorter than a typical wingspan. In summary, separation control has the potential for application to time-independent or time-dependent wake alleviation schemes, where the latter can be deployed to minimize adverse effects on ride-quality and dynamic structural loading.

Greenblatt, David↗

Dynamics of Unusual Debris Flows on Martian Sand Dunes

Gullies that dissect sand dunes in Russell impact crater often display debris flow-like deposits in their distal reaches. The possible range of both the rheological properties and the flow rates are estimated using a numerical simulation code of a Bingham plastic flow to help explain the formation of these features. Our simulated results are best explained by a rapid debris flow. For example, a debris flow with the viscosity of 10(exp 2) Pa s and the yield strength of 10(exp 2) Pa can form the observed deposits with a flow rate of 0.5 cu m/s sustained over several minutes and total discharged water volume on the order of hundreds of cubic meters, which may be produced by melting a surface layer of interstitial ice within the dune deposits to several centimeters depth.

Miyamoto, Hideaki↗

Diffuse and dark clouds in the interstellar medium

Observations of clouds in the ISM of the Galaxy and the Magellanic Clouds, obtained with the IUE satellite since its launch in 1978, are reviewed. Consideration is given to the techniques used to analyze IUE Maxwellian growth curves and oscillator strengths, the general structure of the Galactic ISM, the high-velocity clouds, heavy-element depletion, and observations toward strongly reddened stars in the outer portions of dark clouds. Theoretical models of interstellar dust formation and selective and nonselective removal of elements from dust grains are discussed; observations of reflection nebulae and their implications for light scattering by dust are examined; the dynamics and ionization structure of the Galactic halo ISM are described; and the Magellanic Cloud observations are briefly characterized. Diagrams, graphs, and tables of numerical data are provided.

De Boer, Klaas S.↗

Range profiling of the rain rate by an airborne weather radar

A class of methods based on a measure of path attenuation that is used to constrain the Hitschfeld-Bordan solution is investigated. Such methods are investigated for lidar, radar, and combined radar-radiometer applications. Their function is to allocate the attenuation in proportion to the strength of the measured reflectivity. A description is provided of four estimates of rain rate that have been tested using data from a dual-wavelength airborne radar at 10 GHz and 35 GHz. It is concluded, that when attenuation is significant, the estimates are generally more accurate than those without attenuation correction. Thus, such methodologies can be utilized to extend the effective dynamic range of the radar to higher rain rates.

Meneghini, Robert↗