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At least 703 records · Page 39
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Peptide formation in the prebiotic era - Thermal condensation of glycine in fluctuating clay environments

As geologically relevant models of prebiotic environments, systems consisting of clay, water, and amino acids were subjected to cyclic variations in temperature and water content. Fluctuations of both variables produced longer oligopeptides in higher yields than were produced by temperature fluctuations alone. The results suggest that fluctuating environments provided a favorable geological setting in which the rate and extent of chemical evolution would have been determined by the number and frequency of cycles.

Lahav, N.↗
NASA NTRS1979

A review of at rest droplet growth equations for condensing nitrogen in transonic cryogenic wind tunnels

Droplet growth equations are reviewed in the free-molecular, transition, and continuum flow regimes with the assumption that the droplets are at rest with respect to the vapor. As comparison calculations showed, it was important to use a growth equation designed for the flow regime of interest. Otherwise, a serious over-prediction of droplet growth may result. The growth equation by Gyarmathy appeared to be applicable throughout the flow regimes and involved no iteration. His expression also avoided the uncertainty associated with selecting a mass accommodation coefficient and consequently involved less uncertainty in specifying adjustable parameters than many of the other growth equations.

Hall, R. M.↗
NASA NTRS1978

Photoacoustic spectroscopy of condensed matter

Photoacoustic spectroscopy is a new analytical tool that provides a simple nondestructive technique for obtaining information about the electronic absorption spectrum of samples such as powders, semisolids, gels, and liquids. It can also be applied to samples which cannot be examined by conventional optical methods. Numerous applications of this technique in the field of inorganic and organic semiconductors, biology, and catalysis have been described. Among the advantages of photoacoustic spectroscopy, the signal is almost insensitive to light scattering by the sample and information can be obtained about nonradiative deactivation processes. Signal saturation, which can modify the intensity of individual absorption bands in special cases, is a drawback of the method.

Somoano, R. B.↗
NASA NTRS1979

Emission and extinction of ground and vapor-condensed silicates from 4 to 14 microns and the 10 micron silicate feature

Emission and absorption spectra from 4 to 14 microns of ground and laser-vaporized olivine and enstatite silicates are compared with the 10-micron emission feature of the Orion Trapezium. The agreement in band center and shape between the amorphous laser-vaporized olivine sample and the Trapezium feature suggests that amorphous silicate grains of approximately olivine composition may be a major constituent of interstellar dust. Differences between the emission and absorption spectral profiles (absorption plus scattering) show characteristics that could be used as a sensitive probe of the morphology of interstellar grain systems when high signal-to-noise ratio (30-100) observational spectra become available.

Stephens, J. R.↗
NASA NTRS1979

Comets, carbonaceous chondrites, and interstellar clouds: Condensation of carbon

Comets, carbonaceous chondrites, and interstellar clouds are discussed in relation to information on interstellar dust. The formation and presence of carbon in stars, comets, and meteorites is investigated. The existence of graphite in the interstellar medium, though it is predicted from thermodynamic calculations, is questioned and the form of carbon contained in comets is considered.

Field, G. B.↗
NASA NTRS1979

Theory of deposition of condensible impurities on surfaces immersed in combustion gases

The components resulting from the deposition of inorganic salts (e.g., Na2S04) and oxides present in the combustion products from gas turbine engines were investigated. Emphasis was placed on the effects of multicomponent vapor transport, thermophoretic transport of vapor and small particles to actively cooled surfaces, variable fluid properties within mass transfer boundary layers, and free stream turbulence.

Rosner, D. E.↗
NASA NTRS1979

Mars - CO2 adsorption and capillary condensation on clays: Significance for volatile storage and atmospheric history

Results on the adsorbate-adsorbent system CO2-nontronite are reported at 230, 196, and 158 deg K, covering the range of subsurface regolith temperature on Mars. A three-part regolith-atmosphere-cap model reveals that cold nontronite, and expanding clays in general, are far better but far more complex CO2 adsorbers than cold pulverized basalt. In addition, the layered terrain, and possibly the adjacent debris mantle, contains about 2% or more by mass of atmosphere-exchangeable CO2 and the total regolith inventory of available adsorbed CO2 is estimated to be 400 g/ sq cm.

Fanale, F. P.↗
NASA NTRS1980

Visible and ultraviolet /800-130 nm/ extinction of vapor-condensed silicate, carbon, and silicon carbide smokes and the interstellar extinction curve

The extinction curves from 800 to 130 nm (1.25-7.7/micron) of amorphous silicate smokes nominally of olivine and pyroxene composition, carbon smokes, and crystalline SiC smokes are presented. The SiC smoke occurred in the low-temperature (beta) cubic structural form. The SiC smoke showed an absorption edge which occurred at significantly longer wavelengths than the calculated extinction profile of the hexagonal SiC form previously used to calculate the interstellar extinction profile. Neither SiC nor amorphous silicates show an extinction band similar to the observed 6.6/micron astronomical extinction band. The infrared absorption peaks for the silicate and SiC samples near 10 microns and 11-13 microns, respectively, were also measured. The ultraviolet to infrared extinction ratio for the amorphous silicate samples is similar to the observed astronomical extinction ratio. The measured extinction ratios for SiC smokes are significantly below the interstellar extinction ratio. The extinction peak of the carbon smokes occurred at 4.0 and 4.25/micron, for samples of mean radii 13 and 6 nm, respectively. The extinction profile is distinctly different from that predicted for graphite grains of the same size, and is similar to that predicted for glassy carbon grains.

Stephens, J. R.↗
NASA NTRS1980

Theory of bubble dynamics in condensed explosive during start-up transient

Test firings with experimental liquid propellant gun systems indicate that the main concern standing in the way of practical application of LPG's is the possibility of unexpected explosions during start up when pressure is rapidly applied to the liquid monopropellant in the chamber. The phenomenon of many collapse-rebound cycles of imploding bubbles is theorized as the probable cause of explosions in LP systems. It may be concluded that LPG safety would be enhanced by choosing an LP with low bulk modulus, as well as low decomposition reaction rate, and that a benign looking DTA trace is not a sufficient quarantee of insensitivity to a pressure induced explosion. It is also shown that pre-pressurizing an LP charge, thus pre-compressing the bubbles near-isothermally, makes the system relatively insensitive to such pressure induced explosions. The applicability of this analysis to the question of acceleration induced explosion of explosive filled warheads is indicated.

Benreuven, M.↗
NASA NTRS1981

Homogeneous condensation - Freezing nucleation rate measurements for small water droplets in an expansion cloud chamber

Experimental data on ice nucleation, presented in an earlier paper, are analyzed to yield information about the homogeneous nucleation rate of ice from supercooled liquid and the heights of energy barriers to that nucleation. The experiment consisted of using an expansion cloud chamber to nucleate from the vapor a cloud of supercooled pure water drops and the observation of the fraction of drops which subsequently froze. The analysis employed standard classical homogeneous nucleation theory. The data are used to extract the first experimental measurement (albeit indirect) of the activation energy for the transfer of a water molecule across the liquid-ice interface at temperatures near -40 C. The results provide further evidence that the local liquid structure becomes more icelike as the temperature is lowered.

Hagen, D. E.↗
NASA NTRS1981

Condensation of activated diguanylates on a Poly/C/ template

The metal-ion catalysis of the oligomerization of activated diguanylate isomers on a polycytidylic acid template is studied in an investigation of possible early prebiotic polynucleotide replication mechanisms. The 5'-imidazolides of diguanylates linked 2' to 5' or 3' to 5' were reacted with polyC in a 1-methylimidazole or a 2,6-lutidine buffer in the presence of a Zn(+2) or a Pb(+2) catalyst, and reaction products were determined by paper chromatography, paper electrophoresis and liquid chromatography. In the lutidine buffer, the presence of both the Zn(+2) catalyst and the polyC template is found to result in the production of 3'-5' linked oligomers with up to 10 diguanylate units, and from diguanylates in the presence of the monomer. In the reactions conducted in the 1-methylimidazole buffer, the addition of Pb(+2) is found to lead to less marked increases in oligomerization in the presence of template, with approximately equal proportions of 2'-5' and 3'-5' oligomers formed from the 2'-5' substrate and mainly 3'-5' bonds from the 3'-5' linked dimer.

Lohrmann, R.↗
NASA NTRS1981

The infrared emission from supernova condensates

The possibility of detecting grains formed in supernovae by observations of their emission in the infrared is examined. The basic processes determining the temperature and infrared radiation of grains in supernova environments are analyzed, and the results are used to estimate the infrared emission from the highly metal enriched fast moving knots in Cas A. The predicted fluxes lie within the reach of current ground-based facilities at 10 microns, and their emission should be detectable throughout the infrared band with cryogenic space telescopes.

Dwek, E.↗
NASA NTRS1981

A cloud condensation nucleus spectrometer designed for airborne measurements

The spectrometer is a simple extension of the continuous flow diffusion chamber (CFDC) operated in the vertical mode. The principal new design features of the instrument are its rapid time response and ability to rapidly measure the CCN activity spectrum. The activity spectrum of CCN in an air sample is measured by simultaneously operating the spectrometer at four supersaturations. The CCN spectrometer consists of four essentially indepenent CFDC's in a parallel array. Each CFDC is 61 cm long, 10 cm wide, and consists of two vertical parallel plates 1 cm apart, maintained at different temperatures. Each CFDC has a single particle optical counter located at the center of its base.

Radke, L. F.↗
NASA NTRS1981

Aerosol generation and distribution system for the Third International Cloud Condensation Nuclei Workshop

In order to obtain identical samples participating CCN instruments and aerosol characterizing equipment were located along and connected to a 8.2 cm diameter aluminum tube through which the test aerosols were pumped directly from the source at very slight overpressure. Of the total of 29 experiments, 18 were carried out with artificial NaCl or (NH4)2SO4 aerosols. These were generated from salt solutions by pneumatic atomizers of special design to ensure high constancy of the aerosol output concentration. In three experiments with insoluble CCN (AgI, paraffin wax) the aerosols were generated thermally. In some of the tests, an electrostatic classifier was used for narrowing the particle size distributions.

Katz, U.↗
NASA NTRS1981

Elemental composition of aerosols in fourteen experiments of the Cloud Condensation Nuclei Workshop

Aeosols were collected with two Ci impactors and analyzed with proton induced X-ray emission (PIXE) for chemical composition and to detect if contamination was present. One of the impactors sampled the generated aerosols; the other impactor sampled droplets from a diffusion cloud chamber. The purpose of the experiments was to test the feasibility of a study of the transfer of chemical elements from the fine particle sizes to the coarse particle sizes, after CCN are activated and cloud droplets are formed. The data indicated that sulfur-containing aerosols did exhibit the expected transfer.

Mach, W. H.↗
NASA NTRS1981

Comparison between two Aitken counters and with cloud condensation nuclei counters at the 1980 International CCN Workshop

The Pollak and the TSI 3020 counters agreed to within about 10% at concentrations below 1000 cu cm, whereas above that concentration, substantial systematic differences were observed. When the test aerosol was monodisperse and the CCN counters were operated at supersaturations that should nucleate all the aerosol, the Pollak counter read about 6% to 20% lower than the CCN counter in the concentration range from 250/cu cm to 1800/cu cm. The TSI 3020 read about 20% lower than the CCN counter at concentrations less than 1000/cu cm, and a factor of about two higher at concentrations above 1000/cu cm.

Rogers, C. F.↗