Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “capture”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 703 records · Page 39
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Carbon Capture in Novel Porous Liquids

Direct air capture (DAC) of CO 2 is one of the negative emission technologies under development to limit the impacts of climate change. The dilute concentration of CO 2 in the atmosphere (~400 ppm) requires new materials for carbon capture with increased CO 2 selectivity that is not met with current materials. Porous liquids (PLs) are an emerging material that consist of a combination of solvents and porous hosts creating a liquid with permanent porosity. PLs have demonstrated excellent CO 2 selectivity, but the features that control how and why PLs selectively capture CO 2 is unknown. To elucidate these mechanisms, density functional theory (DFT) simulations were used to investigate two different PLs. The first is a ZIF-8 porous host in a water/glycol/2-methylimidazole solvent. The second is the CC13 porous organic cage with multiple bulky solvents. DFT simulations identified that in both systems, CO 2 preferentially bound in the pore window rather than in the internal pore space, identifying that the solvent-porous host interface controls the CO 2 selectivity. Additionally, SNL synthesized ZIF-8 based PL compositions. Evaluation of the long-term stability of the PL identified no change in the ZIF-8 crystallinity after multiple agitation cycles, identifying its potential for use in carbon capture systems. Through this project, SNL has developed a fundamental understanding of solvent-host interactions, as well as how and where CO 2 binds in PLs. Through these results, future efforts will focus not on how CO 2 behaves inside the pore, but on the porous host-solvent interface as the driving force for PL stability and CO 2 selectivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Models to Incorporate Reaction Mechanisms into DG-OSPREY: Fixed-Bed Simulations for Organic Iodides Capture Using Ag 0 Z

As one of the most potent radioisotopes released during spent nuclear fuel reprocessing, 129 I is strictly regulated and must be removed before discharge. Organic iodides (primarily alkyl iodides with different chain lengths, i.e., CH 3 I, C 4 H 9 I, and C 12 H 25 I) comprise ~2% of the total iodine in the reprocessing off-gases and are primarily present in vessel off-gas (VOG). Reduced silver mordenite (Ag 0 Z) is predominantly considered for the removal of radioiodine; however, its capture performance and underlying interaction processes with long-chain organic iodides are not fully understood. Two major tasks were accomplished in this study. First, to improve upon the previous experimental studies where Ag 0 Z was used to capture CH 3 I, C 4 H 9 I, and C 12 H 25 I at different concentrations, we comprehensively investigated the corresponding capture mechanisms by characterizing fully loaded Ag 0 Z samples. Second, computational codes were implemented to perform fixed-bed simulations that account for transport and reaction mechanisms. Scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX), powder X-ray diffraction (PXRD), UV-visible diffuse reflectance spectroscopy (UV-vis DRS), and thermogravimetric analysis (TGA) were conducted on Ag 0 Z samples that are saturated with I 2 , CH 3 I, C 4 H 9 I, and C 12 H 25 I), respectively. Results indicate that AgI is the predominant adsorption product regardless of the adsorbed iodine species, yet alkyl iodides with different carbon chain lengths may have different compositions of α- and γ-AgI. Synchrotron pair distribution function (PDF) measurements and TGA coupled with a Fourier transformed infrared detector (TGA FTIR) have been performed, and experimental data are currently analyzed. Results are expected to provide further insights into the adsorption mechanisms. The fixed-bed capture performance for CH 3 I was successfully simulated by solving mathematical equations that describe the underlying transport processes and adsorption reactions. The computational framework, Catalytic After Treatment System (CATS), that was originated in our research group, was used to solve the governing equations. Kinetic parameters, including the pore diffusivity and reaction rate constant were obtained by optimization techniques using data from thin-bed experiments performed at Oak Ridge National Laboratory. The performance of a deep bed predicted using the optimized parameters showed promising agreement with the experimental data.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Eliminating the Derate of Carbon Capture Retrofits (Rev. 2)

This study presents updated cost and performance information on retrofitting pulverized coal (PC) power plants with post-combustion carbon capture based on an advanced solvent process, based on NETL's Fossil Energy Baseline, Revision 4A. Cases considered include those using a fully integrated capture system, a case that provides capture system steam via a natural gas boiler, and a case that provides combined heat and power via a natural gas simple cycle system. Comparison cases include both new build and retrofit analysis at 90% and 95% carbon capture.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2023

Selective Electrochemical Capture and Release of Uranyl in Solution (Final Report)

The goal of this project is to investigate the selective, electrochemical capture and release of uranyl ((UO 2 ) 2 +) from biphasic or heterogeneous mixtures using a class of cluster molecules, ortho-carboranes (Cb), containing selective binding groups. Possible applications in PUREX, seawater uranyl extraction, or in actinide/lanthanide (An/Ln) or Ln/Ln separations are envisioned. With this funding, we sought to achieve these goals by harnessing the redox-switchable chelating properties of the “closo” Cb to the reduced “nido” Cb enabling the electrochemical control of the ligand bite angle. Using this premise, specific goals include: 1) integrating new selective coordinating groups (L) onto the carbon positions of Cb for the selective capture and release of uranyl, and; 2) anchoring these selective carboranes onto electrode and/or heterogeneous surfaces for the selective, heterogeneous capture and release of uranyl from aqueous solutions under flow conditions. Overall, this work focuses on advancing our understanding and controlling the properties of this new platform for metal capture and release chemistry which, we believe, has the potential for broader applicability in the separation sciences.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2023

Measurement of the Neutron-Induced Capture-to-Fission Cross Section Ratio in 233 U at LANSCE [Slides]

This presentation finds that new measurement at LANSCE combining DANCE and NEUANCE at the end of 2020 and 2021. Additionally, two samples of 10 mg and 20 mg of 233 U have been prepared at LANL by Evelyn M. Bond (December 2020). Data analysis has been finished and results of the capture-to-fission ratio on 233 U in the neutron energy region from 0.7 eV to 250 keV have been provided. The focus was to provide data from 1-300 keV. We are providing data from 0.7 eV to 1 keV in addition. The result has been normalized to the ENDF/B-VIII.0 broadened capture-to-fission cross section ratio in the neutron energy region recommended by the Luiz Leal and Marco Pigni, between 8.1 and 14.7 eV. This is the first measurement of the capture-to-fission ratio between 2 - 30 keV. The data show some small differences in the RRR with the evaluation though the general trend is consistent. In the URR this data shows a smaller capture-to-fission ratio than the evaluation from 10 to 150 keV

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2024

Innovations in Direct Air Capture: Unveiling a Simple and Robust Synthesized Fibrous Amine-functionalized Matrix (FAM) Sorbent for Commercial Scale-up

The escalating challenge of climate change necessitates innovative solutions in the realm of carbon management, particularly in mitigating the impact of fossil fuel emissions. Direct Air Capture (DAC) technology emerged as a critical component within the spectrum of Carbon Capture and Sequestration (CCS) solutions, offering the distinct advantage of directly removing CO2 from the atmosphere irrespective of the source. This attribute grants DAC systems unparalleled flexibility in deployment locations and the potential to make substantial contributions to lowing atmospheric CO2 levels. The success of DAC technologies significantly depends on the development of an efficient, economical sorbent capable of selective and durable CO2 capture from ambient air. Recent advancements in material science have led to the exploration of amine-functionalized sorbents, hollow fiber sorbents and membranes, and other novel materials designed to meet these criteria. This study explores a novel Fibrous Amine-functionalized Matrix (FAM) sorbent. The FAM sorbent distinguished itself through its mechanical robustness, a streamlined synthesis process, and the capability for low-temperature regeneration (is 90 oC really low temperature?). FAM’s exceptional adsorption-desorption kinetics enable swift CO2 capture and release, crucial for the viability of DAC on a commercial scale. The synthesis process involves a simple dip-coating technique, allowing crosslinked amines to coat glass substrates.

Wang, Qiuming↗
DOE OSTI2024

Optimization of Membrane-based Carbon Capture using Dimensional Analysis, CFD and Process System Engineering

Carbon capture is a promising option to mitigate CO2 emissions from existing coal-fired power plants, cement and steel industries, and petrochemical complexes. Among the available technologies, membrane-based carbon capture presents the lowest energy consumption, operating costs, and carbon footprint. In addition, membrane processes have important operational flexibil-ity and response times. On the other hand, the major challenges to widespread application of this technology are related to reducing capital costs and improving membrane stability and durability.To upscale the technology into stacked flat sheet configurations, high fidelity computational fluid dynamics (CFD) that describes the separation process accurately are required. High fidelity simulations have been shown to be effective in studying the complex transport phenomena in membrane systems. In addition, obtaining high CO2 recovery percentages and product purity requires a multi-stage membrane process, where the optimal network configuration of the membrane modules must be studied in a systematic way. In order to address the design problem at process scale, we formulate a superstructure for the membrane-based carbon capture, including up to three separation stages. In the formulation of the optimization problem, we include reduced models, based on rigorous CFD simulations of the membrane modules. Numerical results indicate that the optimal design includes three membrane stages, and the capture cost is 45.4 $/t-CO2.

Pedrozo, Hector A.↗
DOE OSTI2024

Advancements in Direct Air Capture: Unveiling a Simple and Robust Synthesized Fibrous Amine-functionalized Matrix (FAM) Sorbent for Commercial Scale-up

The escalating challenge of climate change necessitates innovative solutions in the realm of carbon management, particularly in mitigating the impact of fossil fuel emissions. Direct Air Capture (DAC) technology emerges as a critical component within the spectrum of Carbon Capture and Sequestration (CCS) solutions, offering the distinct advantage of directly removing CO2 from the atmosphere irrespective of the source. This attribute grants DAC systems unparalleled flexibility in deployment location sand the potential to make substantial contributions to lowing atmospheric CO2 levels. The success of DAC technologies significantly depends on the development of efficient, economical sorbent capable of selective and durable CO2 capture from ambient air. Recent advancements in material science have led to the exploration of amine-functionalized sorbents, hollow fiber sorbents and membranes, and other novel materials designed to meet these criteria. This study introduces a significant advancement in DAC technology with the development of a Fibrous Amine-functionalized Matrix (FAM) sorbent. The FAM sorbent distinguished itself through its mechanical robustness, a streamlined synthesis process, and the capability for low-temperature regeneration. Its exceptional adsorption-desorption kinetics enable swift CO2 capture and release, crucial for the viability of DAC on a commercial scale.

Wang, Qiuming↗
DOE OSTI2024

CFD Model Development of a Small-Scale Fixed-Bed Reactor for Direct Air Capture of CO2

Direct air capture (DAC) is a promising approach to significantly reduce the CO2 concentration in the ambient air. This approach requires the extraction of CO2 from air with ultra dilute CO2 concentration which makes this approach more expensive than point source CO2 capture. Several efforts are being made in academics and industry to develop cost-efficient sorbents and solvents suitable for DAC. One of them is polymer with intrinsic microporosity (PIM) which is often used for CO2 capture because of its higher porosity and rigidity. A novel, cost-efficient aminated PIM sorbent, PF-15-TAEA, was developed at the National Energy Technology Laboratory for DAC applications. The current work is focused on the computational investigation of the CO2 capture by this novel sorbent from a gas mixture with ultra dilute concentration of CO2 in dry and humid conditions in a laboratory-scale fixed-bed reactor.

Aziz, Hossain↗
DOE OSTI2024

Computational Modeling of CO2 Capture By Novel PIM-RU in a Fluidized Bed Riser

The interest in carbon capture, storage, and utilization (CCUS) has increased significantly in the past few decades as it can help mitigate the threat of global warming caused by substantial increase in CO2 emissions due to anthropogenic activities. Although several CO2 capture technologies have been developed, porous solid sorbents, which adsorb CO2 by physisorption, are considered promising candidates for post-combustion CO2 capture because of the easier recovery of adsorbed CO2 and high material stability. Some prominent types of porous solid sorbents are metal-organic frameworks (MOFs), Zeolite, mesoporous silica, and polymer-based sorbents (e.g., polymers with intrinsic microporosity or PIM). Oak Ridge National Laboratory (ORNL) recently developed a novel PIM-based sorbent, referred to here as PIM-RU. The main objective of this work is to investigate the CO2 capture performance of this sorbent using computational fluid dynamics (CFD). While process configuration and reactor design are open questions, a fluidized bed riser was selected as the contactor type for this study.

Aziz, Hossain↗
DOE OSTI2024

Direct Air Capture Recovery of Energy for CCUS Partnership (DAC RECO 2 UP) Final Technical Report

The “Direct Air Capture Recovery of Energy for CCUS Partnership (DAC RECO 2 UP)” project employs a team approach and supports the U.S. Department of Energy Office of Fossil Energy and Carbon Management’s (DOE-FECM) goal to decrease the cost of capture through the testing of existing direct air capture (DAC) materials in integrated field units that produce a concentrated carbon dioxide (CO 2 ) stream of at least 95% purity. Solid-amine CO 2 adsorption-desorption contactor technology, proven in the laboratory, is undergoing high-fidelity design/validation. Recoverable energy is readily available from a large number of commercial locations where DAC can be deployed; therefore, advancing the fidelity of energy recovery to directly reduce the cost of DAC is a key project objective. In addition, many commercial facilities have low-concentration CO 2 vents that are uneconomical to treat alone but could provide more efficient mass and thermal transport to DAC systems with integrated energy recovery and flexible CO 2 treatment capabilities. Technology scale-up leverages past research and occurs in a commercially relevant environment at the National Carbon Capture Center. Prescreening techno-economic analysis, risk assessments, and life cycle analysis are being performed by experienced team members. Results of the project will address critical technical barriers that, when solved, will improve the capital and operating costs of DAC while validating commercial relevance of cost and product quality/need.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Critical Component/Technology Gap in 21 st Century Power Plant Gasification Based Polygeneration: Advanced Ceramic Membranes/Modules for Ultra Efficient Hydrogen (H 2 ) Production/Carbon Dioxide (CO 2 ) Capture for Coal-Based Polygeneration

The 21 st Century Power Plant Gasification Based Polygeneration power plant layout is a relatively straightforward retrofit of well-established ammonia synthesis technology to the baseline IGCC process and envisions co-production of power and chemicals from coal in the context of carbon capture. A Dual Stage Membrane Process (DSMP) for pre-combustion CO 2 capture in a coal fired IGCC power plant has been demonstrated by Media and Process Technology Inc (MPT) (DE-FE0013064) in bench-scale live gas testing at the NCCC. This work, however, highlighted the importance of permeate purge capability to deliver deep H 2 recovery at moderate pressures and high carbon capture performance. Further, in the area of warm gas processing, a permeate purgeable membrane support for a wide range of inorganic high-performance membrane materials (CMS, Pd-alloy, zeolite, ZIF, graphene, etc.) was not available and hence had been a common and significant barrier to their commercialization. Hence, the Critical Technology Gap to implementing the DSMP in the Polygeneration power plant and more broadly in advanced warm gas separation applications was the inability to permeate purge the membranes coupled with the lack of the availability of a high packing density scalable package design. To overcome this Critical Technology Gap, in this project, the primary objective was the development of a permeate purgeable full ceramic support for these high-performance inorganic membranes and the complementary high packing density housing. Our goal and approach were to extend our “candle filter” design to a “dual end open” package to enable permeate purge and scalability. Microporous ceramic membranes have been proven to be a low cost, stable material for high temperature applications under harsh environment. They are the leading support choice of researchers in advanced inorganic membrane development in applications such as pre-combustion CO 2 capture. The new 2nd Generation “dual end open” bundle developed in this project is a universal support for these existing and emerging inorganic membrane technologies that up to now have lacked a pathway out of the laboratory. The full ceramic permeate purgeable support represents a transformational technology and opens the door to commercialization of these advanced membrane materials in a wide array of mega scale commercial applications in gas (and liquid) processing under aggressive conditions not suited to conventional polymeric membranes.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2023

Direct Air Capture of Carbon Dioxide Using Nickel Hydroxide Batteries in a Membrane Electrode Assembly

Direct air capture (DAC) is a growing field responding to the need to remove carbon dioxide from the atmosphere. Several technologies are being developed today attempting to meet this need. The technology furthest in development are temperature swing adsorption technologies which have recently moved out of the pilot plant scale.1 This presentation looks to present an electrochemical device as alternative to these technologies. The electrochemical device proposed is a pair of nickel hydroxide (Ni(OH)2) battery electrodes which produce hydroxide (OH-). The hydroxide reacts with carbon dioxide (CO2) to create carbonate (CO32-) and bicarbonate (HCO3-). These carbonates can be transported from the cathode across an anion exchange membrane to the anode where they are evolved back into CO2 due to a pH reduction at the anode. This builds on work that optimized a Hydroxide Exchange Membrane Fuel Cell (HEMFC) for CO2 capture, showing the efficacy of an electrochemically mediated pH swing carbon capture device.2,3 The benefit of the nickel hydroxide battery approach is the low energy cost associated with separation. Because a pair of nickel hydroxide batteries undergo the same electrochemical reaction, low potentials, and thus low energy cost is required. Experiments have shown device level energy requirements of less than 1 MWh ton-1CO2. Most of the energy required by the device produces the pH gradient used to capture and release CO2. The biggest hurdle for this electrochemical approach is increasing the flux of CO2 to allow for more compact devices. Strategies for managing the transient charge and discharge behavior of the battery system will be discussed. Focus will be on improving flux to reduce the overall cost of the device.

Buchen, James↗
DOE OSTI2025

Project-specific considerations for retrofitting carbon capture technology to power generating and industrial facilities

The National Energy Technology Laboratory (NETL) has previously reported on learnings from 7 FEED studies examining retrofitting power plants with capture. This presentation builds on this effort by highlighting learnings from 3 additional FEED studies examining retrofitting power plants with capture and 7 FEED and pre-FEED studies examining retrofitting industrial plants with capture. This includes a discussion of the design, performance, and cost implications associated with (1) site-specific considerations such as water availability, land availability, and site accessibility, and (2) host-plant-specific factors such as flue gas specifications, operational mode, and allowable degree of integration between the capture system and host plant.

FEED Studies↗
DOE OSTI2024

Enzymes Under Confinement: Materials Interactions and Functionality for CO2 Capture and Conversion

CO2 capture membranes are of interest in industries where large amounts of CO2 waste is produced. Captured CO2 can be electrochemically reduced to CO and recycled for other uses. These capture membranes consist of an alumina substrate with a silicon layer. Enzymes have been used to lower reaction energies on nanoporous silica enabling better CO2 capture, however eliminating the silicon layer would improve manufacturability. We have proposed the use of nanoporous alumina alone, as an alternative.

Peretti, Amanda Sheree↗
DOE OSTI2025

Enhanced Outcrop Methane Capture (Final Project Report)

This report provides the final status of the “Enhanced Outcrop Methane Capture (EOMC) Project” which was focused on drilling two new methane capture wells along the Fruitland Formation Outcrop for capture of methane and carbon dioxide which are naturally seeping from the Outcrop. The EOMC Project was focused on evaluating whether novel horizontal drilling technology will result in improved capture of methane and carbon dioxide which are naturally seeping from the Fruitland Formation Outcrop on Southern Ute tribal trust lands within the Southern Ute Indian Reservation (the “Reservation”).

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2024

Life Cycle Greenhouse Gas Emissions of Coal-Biomass Co-Firing Power Plants with Carbon Capture and Storage

The United States has set a target to achieve the net-zero economy by 2050. Bioenergy with Carbon Capture and Sequestration (BECCS) is one of the promising negative-emission routes in the mitigation portfolio to help meet this goal. Coal-biomass co-firing with carbon capture and storage (CCS) is a key BECCS technology to realize the carbon mitigation at fossil-fuel power plants. The mitigation potential of co-firing option is affected by numerous critical factors, such as biomass properties, co-firing level, and carbon capture rate. The objectives of the study are to characterize and estimate the life cycle greenhouse gas (GHG) emissions and performance of coal-biomass co-firing power plants with CCS, determine the breakeven co-firing level at power plants necessary to achieve net-zero life cycle emissions, and quantify the variabilities and uncertainties in life cycle emissions. The scope of the life cycle assessment includes the fuel supply, combustion-based power generation, and CO2 transport and storage. A fuel-based life cycle module is developed and embedded in the Integrated Environmental Control Model (IECM), a fossil-fuel power plant modeling tool. This study then applies the enhanced IECM to conduct the process-based life cycle assessment for an array of biomass co-firing scenarios. Deterministic analysis indicates that reaching net-zero life cycle emissions in a biomass co-firing plant without CCS deployment is challenging. Combining biomass co-firing and CCS deployment can significantly lower the overall life cycle emissions of power plants. Net-zero life cycle emissions can be achieved with a 20 wt.% co-firing level and 90% CCS when the Powder River Basin coal is co-fired with energy crops or forestry residues. However, the breakeven co-firing level for net-zero emissions depend on the selected fuel properties. Fuel supply and plant operation are the critical stages influencing the life cycle emissions of power plants with 90% CCS. Deployment of deep CCS beyond 90% CO2 capture can remarkably reduce operational emissions and the breakeven co-firing level. With 99% CCS, the breakeven co-firing rate can be reduced to 12% on average. These findings highlight the trade-offs between technical performance and environmental impact of biomass co-firing at coal-fired power plants and emphasize the role of deep CCS in achieving a net-zero emissions future.

Wu, Wanying↗
DOE OSTI2016

DYNAMICS OF TIDALLY CAPTURED PLANETS IN THE GALACTIC CENTER

Recent observations suggest ongoing planet formation in the innermost parsec of the Galactic center. The supermassive black hole (SMBH) might strip planets or planetary embryos from their parent star, bringing them close enough to be tidally disrupted. Photoevaporation by the ultraviolet field of young stars, combined with ongoing tidal disruption, could enhance the near-infrared luminosity of such starless planets, making their detection possible even with current facilities. In this paper, we investigate the chance of planet tidal captures by means of high-accuracy N -body simulations exploiting Mikkola's algorithmic regularization. We consider both planets lying in the clockwise (CW) disk and planets initially bound to the S-stars. We show that tidally captured planets remain on orbits close to those of their parent star. Moreover, the semimajor axis of the planetary orbit can be predicted by simple analytic assumptions in the case of prograde orbits. We find that starless planets that were initially bound to CW disk stars have mild eccentricities and tend to remain in the CW disk. However, we speculate that angular momentum diffusion and scattering by other young stars in the CW disk might bring starless planets into orbits with low angular momentum. In contrast, planets initially bound to S-stars are captured by the SMBH on highly eccentric orbits, matching the orbital properties of the clouds G1 and G2. Our predictions apply not only to planets but also to low-mass stars initially bound to the S-stars and tidally captured by the SMBH.

79 ASTRONOMY AND ASTROPHYSICS↗