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At least 703 records · Page 39

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NASA NTRS2001

Whole Blood Activation Results in Altered T Cell and Monocyte Cytokine Production Profiles by Flow Cytometry

An excellent monitor of the immune balance of peripheral circulating cells is to determine their cytokine production patterns in response to stimuli. Using flow cytometry, a positive identification of cytokine producing cells in a mixed culture may be achieved. Recently, the ability to assess cytokine production following a whole-blood activation culture has been described. In this study, whole blood activation was compared to traditional PBMC activation and the individual cytokine secretion patterns for both T cells, T cell subsets and monocytes was determined by flow cytometry. RESULTS: For T cell cytokine assessment (IFNg/IL-10 and IL-21/L-4) following PMA +ionomycin activation: (1) a Significantly greater percentages of T cells producing IFNgamma and IL-2 were observed following whole-blood culture and (2) altered T cell cytokine production kinetics were observed by varying whole blood culture times. Four-color analysiS was used to allow assessment of cytokine production by specific T cell subsets. It was found that IFNgamma production was significantly elevated in the CD3+/CD8+ T cell population as compared to the CD3+/CD8- population following five hours of whole blood activation. Conversely, IL-2 and IL-10 production were Significantly elevated in the CD3+/CD8- T cell population as compared to the CD3+/CD8+ population. Monocyte cytokine production was assessed in both culture systems following LPS activation for 24 hours. A three-color flow cytometric was used to assess two cytokines (IL-1a/IL-12 and TNFa/IL-10) in conjunction with CD14. Nearly all monocytes were stimulated to produce IL-1a, IL-12 and TNFa. equally well in both culture systems, however monocyte production of IL-10 was significantly elevated in whole blood culture as compared to PBMC culture. IL-12 producing monocytes appeared to be a distinct subpopulation of the IL-1a producing set, whereas IL-10 and TNFa producing monocytes were largely mutually exclusive. IL-10 and TNFa producing monocytes may represent distinct monocyte subsets with unique functions. CONCLUSIONS: Whole blood culture eliminates the need to purify cell populations prior to culture and may have Significant utility for the routine monitoring of the cytokine balances of the peripheral blood T cell and monocyte populations. In addition, there are distinct advantages to performing whole-blood (WB) activation as compared to PBMC activation. These advantages would include retaining all various cell-cell interactions as well as any soluble factors present in serum that influence cell activation. In this study, alterations in cytokine production are demonstrated between whole blood and PBMC activation. It is likely that whole blood activation more accurately represents the in-vivo immune balance than PBMC activation.

Crucian, Brian E.↗

NASA NTRS1995

A far-wing line shape theory which satisfies the detailed balance principle

A far-wing theory in which the validity of the detailed balance principle is maintained in each step of the derivation is presented. The role of the total density matrix including the initial correlations is analyzed rigorously. By factoring out the rapidly varying terms in the complex-time development operator in the interaction representation, better approximate expressions can be obtained. As a result, the spectral density can be expressed in terms of the line-coupling functions in which two coupled lines are arranged symmetrically and whose frequency detunings are omega - 1/2(omega(sub ji) + omega (sub j'i'). Using the approximate values omega - omega(sub ji) results in expressions that do not satisfy the detailed balance principle. However, this principle remains satisfied for the symmetrized spectral density in which not only the coupled lines are arranged symmetrically, but also the initial and final states belonging to the same lines are arranged symmetrically as well.

Ma, Q.↗

DOE OSTI2021

Device Performance of Emerging Photovoltaic Materials (Version 2)

Following the 1st release of the "Emerging photovoltaic (PV) reports", the best achievements in the performance of emerging photovoltaic devices in diverse emerging photovoltaic research subjects are summarized, as reported in peer-reviewed articles in academic journals since August 2020. Updated graphs, tables, and analyses are provided with several performance parameters, e.g., power conversion efficiency, open-circuit voltage, short-circuit current density, fill factor, light utilization efficiency, and stability test energy yield. These parameters are presented as a function of the photovoltaic bandgap energy and the average visible transmittance for each technology and application and are put into perspective using, e.g., the detailed balance efficiency limit. The 2nd installment of the "Emerging PV reports" extends the scope toward tandem solar cells and presents the current state-of-the-art in tandem solar cell performance for various material combinations.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Device Performance of Emerging Photovoltaic Materials (Version 3)

Abstract Following the 2nd release of the “Emerging PV reports,” the best achievements in the performance of emerging photovoltaic devices in diverse emerging photovoltaic research subjects are summarized, as reported in peer‐reviewed articles in academic journals since August 2021. Updated graphs, tables, and analyses are provided with several performance parameters, e.g., power conversion efficiency, open‐circuit voltage, short‐circuit current density, fill factor, light utilization efficiency, and stability test energy yield. These parameters are presented as a function of the photovoltaic bandgap energy and the average visible transmittance for each technology and application, and are put into perspective using, e.g., the detailed balance efficiency limit. The 3rd installment of the “Emerging PV reports” extends the scope toward triple junction solar cells.

14 SOLAR ENERGY↗

DOE OSTI2026

Adaptive Sampling-Based Bi-Fidelity Stochastic Trust Region Method for Stochastic Derivative-Free Optimization

Bi-fidelity stochastic optimization has gained increasing attention as an efficient approach to reduce computational costs by leveraging a low-fidelity (LF) model to optimize an expensive high-fidelity (HF) objective. In this paper, we propose ASTRO-BFDF, an adaptive sampling trust-region method specifically designed for unconstrained bi-fidelity stochastic derivative-free optimization problems. In ASTRO-BFDF, the LF function serves two purposes: (i) to identify better iterates for the HF function when the optimization process indicates a high correlation between them and (ii) to reduce the variance of the HF function estimates using bi-fidelity Monte Carlo (BFMC). The algorithm dynamically determines sample sizes while adaptively choosing between crude Monte Carlo and BFMC to balance the trade-off between optimization and sampling errors. We prove that the iterates generated by ASTRO-BFDF converge to a first-order stationary point almost surely. Additionally, we demonstrate the effectiveness of the proposed algorithm through numerical experiments on synthetic benchmarks and simulation optimization problems involving discrete event systems.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2023

Impacts of a Prescribed Fire on Air Quality in Central New Mexico

A short-duration but high-impact air quality event occurred on 28 November 2018 along the Rio Grande Valley of New Mexico. This fire occurred outside the typical wildfire season, and greatly impacted the air quality in Socorro, NM, and the surroundings. Measurements were taken during the event using an aerosol light scattering technique (integrating nephelometer) and a particulate mass concentration monitor (DustTrak PM optical monitor). The instruments sampled the ambient air during the event on the campus of the New Mexico Institute of Mining and Technology in Socorro, New Mexico. The peak values on a 5-min basis of light scattering and the PM mass concentration reached 470 Mm -1 and 270 µg/m 3 , respectively. We examined the meteorological context of the event using local meteorological data and back trajectories using the NOAA HYSPLIT model to determine atmospheric transport and possible sources. Several fires, both prescribed and wildfires, occurred in the region including a prescribed burn at Bosque del Apache National Wildlife Refuge (17 km south-southeast of the receptor site). The data suggest that the prescribed burn at Bosque del Apache was the dominant contributor due to transport evidence and the event’s narrow spatiotemporal extent. The increasing importance of restoring ecosystem function using prescribed fire in wildland fire management will likely lead to more frequent air quality impacts and sets up policy tradeoffs that require a balance between these public goals. This study examines the evidence of the effects of a prescribed fire in a protected wildland area impacting the air quality in a nearby populated area.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1972

Effects of electrostatic rocket material deposited on solar cells.

If solar arrays on solar-electric spacecraft protrude into the exhaust hemisphere of the electric thrusters, they will receive fluxes (usually small) of both propellant and accelerator grid atoms. Unlike propellants, grid materials have low vapor pressures and will not reevaporate. An analysis is presented of degradation in the optical, thermal, and electrical performance of solar cells resulting from thin deposits of grid material (aluminum and molybdenum) on various array surfaces. The classical optical theory of thin films, heat balance equations, and a typical relationship for solar cell efficiency vs temperature are used to compute curves showing optical properties, temperature, and power output as functions of film thickness. The results compare favorably with available experimental data. It is shown that a few monolayers of metal deposition on the illuminated surface will seriously degrade cell performance. A means of estimating the arrival rate of these materials is provided.

Kemp, R. F.↗

NASA NTRS1981

Numerical studies of the energy balance in coronal loops

A numerical method is applied to treat the energy balance of quasi-static solar coronal loops, which have been observed to persist for periods much greater than the radiative cooling time. The quasi-static loop model employed takes into account gravity, density-, temperature- or position-dependent energy input, an accurate form of the radiative losses and variable loop cross-sectional area, under assumptions of energy input by coronal heating balanced by radiative and conductive losses, an optically thin plasma, energy conduction along the field lines only and hydrostatic equilibrium. Computations of an emission measure function for various distributions of the energy input and loop geometries are then presented which show that little information on the location of the energy input may be gained from spectral line intensity measurements integrated over a single loop.

Underwood, J. H.↗

NASA NTRS1983

Derivation of the fundamental equation of sound generated by moving aerodynamic surfaces

Ffowcs Williams and Hawkings (1969) based their derivation of the fundamental equation of the sound generated by arbitrarily moving aerodynamic surfaces on the study of mass and momentum balance of a control volume imbedding a mathematical surface(s) exactly corresponding to real surface(s). These investigators also sketched an alternative method, employing generalized functions, for its derivation. This latter method, which was later developed by Farassat (1975), is purely mathematical and formal. Goldstein (1976) used the free-space Green function to produce an implicit derivation of the Ffowcs Williams and Hawkings equation. In the study presented here, Lowson's (1965) concept of moving point singularities is generalized to moving surface singularities, and a new derivation is given of the fundamental equation. The derivation is based on topological considerations of the underlying space, the fluid medium, and the integral properties of the Dirac delta function.

Aggarwal, H. R.↗

NASA NTRS1986

Basic studies on delta wing flow modifications by means of apex fences

The effectiveness of apex fences on a 60-deg delta wing at low speeds was experimentally investigated. Resembling highly swept spoilers in appearance, the fences are designed to fold out of the wing apex region upper surface near the leading edges, where they generate a powerful vortex pair. The intense suction of the fence vortices augments lift in the apex region, the resulting positive pitching moment being utilized to trim trailing edge flaps for lift augmentation during approach and landing at relatively low angles of attack. The fences reduce the apex lift at high angles of attack, leading to a desirable nose-down moment. The above projected functions of the apex fence device were validated and quantified through low speed tunnel tests, comprising upper surface pressure surveys on a semispan model and balance measurements on a geometrically similar fully span wing/body configuration. Fence parameters such as area, shape, hinge position and deflection angle were investigated. Typical results are presented indicating the apex fence potential in controlling the longitudinal characteristics of a tail-less delta.

Hoffler, K. D.↗

NASA NTRS1987

Experiments with a three-dimensional statistical objective analysis scheme using FGGE data

A three-dimensional (3D), multivariate, statistical objective analysis scheme (referred to as optimum interpolation or OI) has been developed for use in numerical weather prediction studies with the FGGE data. Some novel aspects of the present scheme include: (1) a multivariate surface analysis over the oceans, which employs an Ekman balance instead of the usual geostrophic relationship, to model the pressure-wind error cross correlations, and (2) the capability to use an error correlation function which is geographically dependent. A series of 4-day data assimilation experiments are conducted to examine the importance of some of the key features of the OI in terms of their effects on forecast skill, as well as to compare the forecast skill using the OI with that utilizing a successive correction method (SCM) of analysis developed earlier. For the three cases examined, the forecast skill is found to be rather insensitive to varying the error correlation function geographically. However, significant differences are noted between forecasts from a two-dimensional (2D) version of the OI and those from the 3D OI, with the 3D OI forecasts exhibiting better forecast skill. The 3D OI forecasts are also more accurate than those from the SCM initial conditions. The 3D OI with the multivariate oceanic surface analysis was found to produce forecasts which were slightly more accurate, on the average, than a univariate version.

Baker, Wayman E.↗

NASA NTRS1994

The effect of inlet swirl on the dynamics of long annular seals in centrifugal pumps

This paper describes additional results from a continuing research program which aims to identify the dynamics of long annular seals in centrifugal pumps. A seal test rig designed at Heriot-Watt University and commissioned at Weir Pumps Research Laboratory in Alloa permits the identification of mass, stiffness, and damping coefficients using a least-squares technique based on the singular value decomposition method. The analysis is carried out in the time domain using a multi-fiequency forcing function. The experimental method relies on the forced excitation of a flexibly supported stator by two hydraulic shakers. Running through the stator embodying two symmetrical balance drum seals is a rigid rotor supported in rolling element bearings. The only physical connection between shaft and stator is the pair of annular gaps filled with pressurized water discharged axially. The experimental coefficients obtained from the tests are compared with theoretical values.

Ismail, M.↗

NASA NTRS1995

Stellar coronal abundances. 3: The solar first ionization potential effect determined from full-disk observation

In this paper we reanalayze the full-disk quiet-sun spectrum of Mallinovsky & Heroux (1973) with modern atomic data. The purposes of this are to check our atomic data and methods in other investigations using data from nearby stars obtained with the NASA Extreme Ultraviolet Explorer (EUVE) satellite, and to confirm that the solar first ionization potential (FIP) effect investigated by previous authors studying discrete solar regions is the same as that found in full-disk spectra. We recover the usual solar FIP effect of a coronal abundance enhancement of elements with a low FIP of a factor approximately 3-4 for lines formed at temperatures greater than approximately 10(exp 6) K. For lower temperatures, the FIP effect seems to be substantially smaller, in qualitative agreement with other data. Comparing our full-disk result with those from discrete solar structures suggest that the FIP effect is a function of altitude, with the lower temperature full-disk emission being dominated by the super-granulation network. We also compare the recent ionization balance of Arnaud & Raymond (1992) with that of Arnaud & Rothenflug (1985).

Laming, J. Martin↗

NASA NTRS1994

A measurement system for large, complex software programs

This paper describes measurement systems required to forecast, measure, and control activities for large, complex software development and support programs. Initial software cost and quality analysis provides the foundation for meaningful management decisions as a project evolves. In modeling the cost and quality of software systems, the relationship between the functionality, quality, cost, and schedule of the product must be considered. This explicit relationship is dictated by the criticality of the software being developed. This balance between cost and quality is a viable software engineering trade-off throughout the life cycle. Therefore, the ability to accurately estimate the cost and quality of software systems is essential to providing reliable software on time and within budget. Software cost models relate the product error rate to the percent of the project labor that is required for independent verification and validation. The criticality of the software determines which cost model is used to estimate the labor required to develop the software. Software quality models yield an expected error discovery rate based on the software size, criticality, software development environment, and the level of competence of the project and developers with respect to the processes being employed.

Rone, Kyle Y.↗

NASA NTRS1999

Aeroacoustic Data for a High Reynolds Number Axisymmetric Subsonic Jet

The near field fluctuating pressure and aerodynamic mean flow characteristics of a cold subsonic jet issuing from a contoured convergent nozzle are presented. The data are presented for nozzle exit Mach numbers of 0.30, 0.60, and 0.85 at a constant jet stagnation temperature of 104 F. The fluctuating pressure measurements were acquired via linear and semi-circular microphone arrays and the presented results include plots of narrowband spectra, contour maps, streamwise/azimuthal spatial correlations for zero time delay, and cross-spectra of the azimuthal correlations. A pitot probe was used to characterize the mean flow velocity by assuming the subsonic flow to be pressure-balanced with the ambient field into which it exhausts. Presented are mean flow profiles and the momentum thickness of the free shear layer as a function of streamwise position.

Ponton, Michael K.↗

NASA NTRSDate not supplied

Extending ISS Life Beyond 2030

The United States On-orbit Segment (USOS) of the International Space Station (ISS) was designed to meet a 15-year on-orbit life. Since the first hardware was launched in late 1998, the ISS would have reached its end of life in 2013. With the realization that the ISS would be needed well into the next decade, and beyond, a multi-disciplinary effort was undertaken to extend the ISS’ life through 2028 and to show that further extension to 2040 and beyond is not only feasible but achievable. Currently, NASA and the ISS international partners have agreed to extend its operations through 2030. This collaborative effort ensures that the ISS will continue to serve as a hub for scientific research, international cooperation, and educational endeavors for the next decade. Maintaining a continuous human presence in Low Earth Orbit (LEO) is desirable for testing new LEO, lunar, and deep-space technologies; conducting scientific research in micro-gravity for the benefit of life on Earth; and enabling a seamless transition of capabilities to one or more commercially owned and operated destinations. This paper provides an overview of the ISS life extension project with a particular focus on the analytical approach used to assess the primary structure. This analytical approach includes future operations planning, critical location screening, on-orbit dynamic load simulation, on-orbit optical property degradation studies, on-orbit thermal analyses, spectra generation, crack model idealization, fracture analyses, and post processing. Structural life results and identification of the most critical on-orbit events are presented. Also addressed are life extension approaches for other affected sub-systems, including: 1. Secondary Structure. 2. Materials. Evaluations consider environmental exposure to atomic oxygen, ionizing and gamma radiation, fluids, etc. Life limited materials, wear, and usage effects are also considered. 3. Environmental Control and Life Support Systems, including oxygen supply and generation, water recovery and management, and regenerative hardware. Evaluations are performed to determine which hardware can be run to failure and which are assessed for life extension. 4. Electrical power system. ISS is powered by eight channels of solar arrays and an electrical energy storage system providing 357 kWh power. Power generation and balance analyses are performed considering hardware degradation and increasing power demand. 5. Logistics and maintenance. Analyses are performed to determine critical spares required to maintain functionality. Consideration is given to supply chain health, obsolescence issues, onboard stowage availability, and up-mass capability. The successful life extension results have built confidence to safely operate, maintain and enhance the ISS well beyond the current decade. Extending the operational life of the ISS maintains an international presence in LEO and serves to avoid a gap in capability necessary to fulfill the exploration and research needs of NASA, international partners, and industry without interruption until a commercial space station is operational.

design life↗

DOE OSTI2026

Computational prediction of ferromagnetic 𝐴⁢𝑇 6 ⁢𝑋 6 kagome compounds

We present a systematic high-throughput density-functional-theory investigation of the structural and magnetic stability of 312 substitutional compounds in the magnetic kagome 𝐴⁢𝑇 6⁢ 𝑋 6 family. Our screening confirms the stability of many previously reported structures and predicts several additional stable candidates. Within collinear spin configurations, we find that Fe-based systems predominantly adopt antiferromagnetic ground states, whereas Mn-based analogs exhibit a more balanced distribution between ferromagnetic and antiferromagnetic order. For compounds exhibiting several nearly degenerate collinear configurations, we analyze the nature of their magnetic ground states, assess the possible emergence of noncollinear order, and discuss the limitations and uncertainties inherent to standard density-functional approaches. Our electronic structure analysis further reveals that predicted ferromagnetic kagome systems display characteristic features of topological metals, with rich magnetic configurations that can be tuned by chemical substitution. Altogether, these ferromagnetic kagome compounds constitute a broad and still largely unexplored materials platform for the emergence of exciting magnetotransport phenomena.

Density functional calculations↗

DOE OSTI2022

237 Np Mössbauer Isomer Shifts: A Lesson About the Balance of Static and Dynamic Electron Correlation in Heavy Element Complexes

A large set of neptunium compounds with different oxidation states (III to VII) was assembled to study the Mössbauer isomer shift by wave function calculations and better understand covalency in f-elements complexes. The contact density approach was used to calculate the isomer shift using complete active space self-consistent field (CASSCF) multiconfiguration wave functions, as well as matrix product states [from Density Matrix Renormalization Group (DMRG) algorithms] for large active spaces. Dynamic correlation effects for the isomer shifts were treated via CASPT2 energy derivatives with respect to the nuclear radius. The CASSCF calculations appear to produce different orbital overlocalization errors for low and high Np oxidation states. For compounds with low Np oxidation numbers, the errors can be attributed to the overlocalization of the 5f orbitals. For the compounds with high Np oxidation numbers, the main errors arise from an overlocalization of ligand orbitals and concomitant to weak donation bonding. Attempts to mitigate the overlocalization errors with large active spaces using DMRG were only partially successful, showing that explicit treatment of dynamic correlation is necessary for accurate predictions of Mössbauer isomer shifts. The CASPT2 calculations perform very satisfactorily. For a subset of Np compounds, both static and dynamic correlation effects were substantial. Furthermore, a rational active space selection based on orbital entanglement diagrams proved beneficial for determining the optimal reference wave function.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗