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At least 703 records · Page 39

Two Catalysts for Selective Oxidation of Contaminant Gases

Two catalysts for the selective oxidation of trace amounts of contaminant gases in air have been developed for use aboard the International Space Station. These catalysts might also be useful for reducing concentrations of fumes in terrestrial industrial facilities especially facilities that use halocarbons as solvents, refrigerant liquids, and foaming agents, as well as facilities that generate or utilize ammonia. The first catalyst is of the supported-precious-metal type. This catalyst is highly active for the oxidation of halocarbons, hydrocarbons, and oxygenates at low concentrations in air. This catalyst is more active for the oxidation of hydrocarbons and halocarbons than are competing catalysts developed in recent years. This catalyst completely converts these airborne contaminant gases to carbon dioxide, water, and mineral acids that can be easily removed from the air, and does not make any chlorine gas in the process. The catalyst is thermally stable and is not poisoned by chlorine or fluorine atoms produced on its surface during the destruction of a halocarbon. In addition, the catalyst can selectively oxidize ammonia to nitrogen at a temperature between 200 and 260 C, without making nitrogen oxides, which are toxic. The temperature of 260 C is higher than the operational temperature of any other precious-metal catalyst that can selectively oxidize ammonia. The purpose of the platinum in this catalyst is to oxidize hydrocarbons and to ensure that the oxidation of halocarbons goes to completion. However, the platinum exhibits little or no activity for initiating the destruction of halocarbons. Instead, the attack on the halocarbons is initiated by the support. The support also provides a high surface area for exposure of the platinum. Moreover, the support resists deactivation or destruction by halogens released during the destruction of halocarbons. The second catalyst is of the supported- metal-oxide type. This catalyst can selectively oxidize ammonia to nitrogen at temperatures up to 400 C, without producing nitrogen oxides. This catalyst converts ammonia completely to nitrogen, even when the concentration of ammonia is very low. No other catalyst is known to oxidize ammonia selectively at such a high temperature and low concentration. Both the metal oxide and the support contribute to the activity and selectivity of this catalyst.

Wright, John D.↗

Flow Visualization Study of the F-14 Fighter Aircraft Configuration

Water tunnel studies were performed to qualitatively define the flow field of the F-14. Particular emphasis was placed on defining the vortex flows generated at high angles of attack. The flow visualization tests were conducted in the Northrop water tunnel using a 1/72 scale model of the F-14 with a wing leading-edge sweep of 20 deg. Flow visualization photographs were obtained for angles of attack up to 55 deg and sideslip angles up to 10 deg. The F-14 model was investigated to determine the vortex flow field development, vortex path, and vortex breakdown characteristics as a function of angle of attack and sideslip. Vortex flows were found to develop on the highly swept glove and on the upper surface of the forebody. At 10 deg of sideslip, the windward glove vortex shifted inboard and broke down farther forward than the leeward glove vortex. This asymmetric breakdown of the vortices in sideslip contributes to a reduction in the lateral stability above 20 deg angle of attack. The initial loss of directional stability is a consequence of the adverse sidewash from the windward vortex and the reduced dynamic pressure at the vertical tails.

Lorincz, D. J.↗

Analysis of Black Bearing Balls from a Space Shuttle Body Flap Actuator

A significantly deteriorated ball bearing mechanism from a body flap actuator on Space Shuttle OV-103 was disassembled and the balls submitted for analysis in conjunction with Return to Flight activities. The OV-103 balls, referred to as the "black balls", were subjected to X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FT-IR) and Raman micro spectroscopy, surface profilometry, and optical and electron microscopy. The spectroscopic results in combination with microscopy analysis allowed a determination of the lubricant degradation pathway. The chemical attack mechanism does not adequately explain the unique visual appearance of the black balls. Numerous efforts have unsuccessfully focused on duplication of the phenomena causing this unique surface structure and appearance of the black balls. Further detail will be presented supporting these conclusions along with plausible explanations of the unique black appearance to the balls.

Sovinski, Marjorie F.↗

Influence of native oxide film on corrosion behavior of additively manufactured stainless steel 316L

The influence of the native oxide film on passive film properties and localized corrosion of additively manufactured SS 316L was studied in 1 wt% HCl by XPS characterization, electrochemical polarization curves, and post-test morphology analysis by SEM. Increased Cr oxidation kinetics was observed in the as-polished sample with the native oxide film resulting in formation of an overall more protective and compact film compared to the cathodically-activated sample. Electrochemical analysis showed that corrosive attack varied between dislocation cell boundaries to cell interiors depending on the initial surface state and polarization conditions. In conclusion, a corrosion mechanism is proposed to explain this variation.

36 MATERIALS SCIENCE↗

A co-opted steroid synthesis gene, maintained in sorghum but not maize, is associated with a divergence in leaf wax chemistry

Significance Virtually all above-ground plant surfaces, such as leaf and stem exteriors, are covered in a cuticle: a wax-infused polyester. This waxy biocomposite is the largest interface between Earth’s biosphere and atmosphere. Its chemical composition is not only highly tuned to mediate nonstomatal water loss, but it also self-assembles to produce superhydrophobic surfaces, protects against UV radiation, and contains bioactive compounds that help resist microbial attack. Developing fundamental knowledge of waxy biocomposites, particularly those on crop species, is a prerequisite for an understanding of their structure–function relationships. Here, we uncover a likely genetic basis for the presence and absence, respectively, of triterpenoids in the leaf waxes of sorghum and maize—compounds previously associated with creating heat-tolerant cuticular water barriers.

09 BIOMASS FUELS↗

Investigation of Control Effectiveness and Stability Characteristics of a Model of a Low-Wing Missile with Interdigitated Tail Surfaces at Mach Numbers of 2.29, 2.97, and 3.51

A brief investigation of the longitudinal stability and control effectiveness at supersonic speeds of a model of a low-wing missile with interdigitated tail surfaces was made in the Langley Unitary Plan wind tunnel. The data were obtained at Mach numbers M of 2.29, 2.97, and 3.51 for Reynolds number (based on the mean geometric chord of the wing) of 1.15 x 10(exp 6), 1.14 x 10(exp 6), and 1.11 x 10(exp 6), respectively. Data were obtained for three settings of the longitudinal control surfaces: with deflection of all surfaces, with deflection of the lower surfaces only, and with all surfaces undeflected. Directional stability data were obtained at M=3.51 for angles of attack of approximately 0 deg and 10 deg. These data, with summary data and typical schlieren photographs, are presented with only a brief analysis. The data indicate that the controls are effective throughout the Mach number range and lift-coefficient range (CL = -0.15 to 0.7, approximately) of the tests. There is a severe break in the pitching-moment curve at M=2.29 which might result in a pitch-up condition in flight, and also a large forward movement of the aerodynamic center with increasing Mach number that produces neutral longitudinal stability at M=3.51 for the moment center used in this investigation. The model was directionally unstable at M=3.51; however, the level of directional stability was about the same for 0 deg and 10 deg angles of attack.

STABILITY AND CONTROL↗

A method for predicting shock shapes and pressure distributions on two dimensional airfoils at large angles of attack

A method is presented for determining shock envelopes and pressure distributions for two-dimensional airfoils at angles of attack sufficiently large to cause shock detachment and subsonic flow over the windward surface of the airfoil. Correlation functions obtained from exact solutions are used to relate the shock standoff distance at the stagnation and sonic points of the body through a suitable choice for the shock shape. The necessary correlation functions were obtained from perfect gas solutions but may be extended to any gas flow for which the normal shock-density ratio can be specified.

Kaattari, G. E.↗

Aerodynamic heating on the corrugated surface of a 10.2 deg half-angle blunted cone at Mach 6.7

A 10.2 deg half-angle blunted cone with corrugated surfaces was tested in the Langley 8-foot high-temperature structures tunnel to measure the aerodynamic heating of its surfaces. The tests were made in a turbulent boundary layer at angles of attack of 0 deg, 5 deg, and 10 deg. Heating of the windward side was in reasonable agreement with theoretical turbulent predictions for a smooth cone, while heating on the leeward side was between laminar and turbulent predictions as a result of local transitional flow or flow separation produced by high lee-side pressures. Localized heating measurements indicated a significant increase in heating at large cross-flow angles, with the maximum heating rates occurring where the flow reattaches on the upstream side of the corrugation crest and the minimum occurring on the downstream side where the flow is separated.

Weinstein, I.↗

An experimental study of airfoil-spoiler aerodynamics

The steady/unsteady flow field generated by a typical two dimensional airfoil with a statically deflected flap type spoiler was investigated. Subsonic wind tunnel tests were made over a range of parameters: spoiler deflection, angle of attack, and two Reynolds numbers; and comprehensive measurements of the mean and fluctuating surface pressures, velocities in the boundary layer, and velocities in the wake. Schlieren flow visualization of the near wake structure was performed. The mean lift, moment, and surface pressure characteristics are in agreement with previous investigations of spoiler aerodynamics. At large spoiler deflections, boundary layer character affects the static pressure distribution in the spoiler hingeline region; and, the wake mean velocity fields reveals a closed region of reversed flow aft of the spoiler. It is shown that the unsteady flow field characteristics are as follows: (1) the unsteady nature of the wake is characterized by vortex shedding; (2) the character of the vortex shedding changes with spoiler deflection; (3) the vortex shedding characteristics are in agreement with other bluff body investigations; and (4) the vortex shedding frequency component of the fluctuating surface pressure field is of appreciable magnitude at large spoiler deflections. The flow past an airfoil with deflected spoiler is a particular problem in bluff body aerodynamics is considered.

Mclachlan, B. G.↗

Low-speed stability and control wind-tunnel investigations of effects of spanwise blowing on fighter flight characteristics at high angles of attack

The effects of spanwise blowing on two configurations representative of current fighter airplanes were investigated. The two configurations differed only in wing planform, with one incorporating a trapezoidal wing and the other a 60 delta wing. Emphasis was on determining the lateral-directional characteristics, particularly in the stall/departure angle-of-attack range; however, the effects of spanwise blowing on the longitudinal aerodynamics were also determined. The-tunnel tests included measurement of static force and forced-oscillation aerodynamic data, visualization of the airflow changes created by the spanwise blowing, and free-flight model tests. The effects of blowing rate, chordwise location of the blowing ports, asymmetric blowing, and blowing on the conventional aerodynamic control characteristics were investigated. In the angle-of-attack regions in which the spanwise blowing substantially improved the wing upper-surface flow field (i.e., provided reattachment of the flow aft of the leading-edge vortex), improvements in both static and dynamic lateral-directional stability were observed. Blowing effects on stability could be proverse or adverse depending on blowing rate, blowing port loaction, and wing planform. Free-flight model tests of the trapezoidal wing confirmed the beneficial effects of spanwise blowing measured in the static and dynamic force tests.

Satran, D. R.↗

Experimental measurements in a large separation bubble due to a simulated glaze ice shape

The effect of a simulated glaze ice accretion on the aerodynamic performance of a NACA 0012 airfoil was studied experimentally. Two ice shapes were tested, one from an experimentally measured accretion and one from an accretion predicted using a computer model given the same icing conditions. Lift, drag and moment coefficients were measured for the airfoil with both ice shapes, smooth and rough. The aerodynamic performance of the two shapes compared well at positive, but not negative, angles of attack. Split hot-film probe velocity data were presented in the upper surface boundary layer and in the wake. Boundary layer parameters were presented for the separation bubble and in the reattached turbulent boundary layer.

Bragg, M. B.↗

A concurrent hybrid Navier-Stokes/Euler approach to fluid dynamic computations

We present a methodology for the numerical simulation of flow fields by the simultaneous application of two distinct approaches to computational aerodynamics. We compute the three dimensional flow field of a missile at moderate angle of attack by dividing the flow field into two regions: a region near the surface where we use a structured grid and a Navier Stokes solver, and a region farther away from the surface where we utilize an unstructured grid and an Euler solver. The two solvers execute as independent UNIX processes either on the same machine or on two machines. The solvers communicate data across their common interfaces within the same machine or over the network. The computations indicate that extensively separated flow fields can be computed without significant distortion by combining viscous and inviscid solvers.

Tavella, Domingo A.↗

Supersonic flow visualization of a nacelle in close proximity to a simulated wing

A flow visualization study was made in the 9 x 9 inch supersonic wind tunnel at Wichita State University to examine shock and boundary layer flow interaction for a nacelle in close proximity to the lower surface of a simulated wing. The test matrix included variations of angle of attack from -2 degrees to +4 degrees, nacelle-wing gap from 0.5 to 3-nacelle inlet diameter (0.12 inch), and Reynolds number based on nacelle length (1.164 inch) from 1.16 x 10(exp 6) to 1.45 x 10(exp 6) at a nominal Mach number of 2. Schlieren pictures of wing and nacelle flowfield were recorded by a video camera during each tunnel run. Results show that the nacelle inlet shock wave remains attached to the inlet lip and its impingement does not significantly affect the wing boundary layer. At the nacelle trailing edge location, the wing boundary layer thickness is approximately one nacelle inlet diameter at alpha = 0 degrees and it decreases with increase of angle of attack.

Biber, Kasim↗

A Structured Grid Based Solution-Adaptive Technique for Complex Separated Flows

The objective of this work was to enhance the predictive capability of widely used computational fluid dynamic (CFD) codes through the use of solution adaptive gridding. Most problems of engineering interest involve multi-block grids and widely disparate length scales. Hence, it is desirable that the adaptive grid feature detection algorithm be developed to recognize flow structures of different type as well as differing intensity, and adequately address scaling and normalization across blocks. In order to study the accuracy and efficiency improvements due to the grid adaptation, it is necessary to quantify grid size and distribution requirements as well as computational times of non-adapted solutions. Flow fields about launch vehicles of practical interest often involve supersonic freestream conditions at angle of attack exhibiting large scale separate vortical flow, vortex-vortex and vortex-surface interactions, separated shear layers and multiple shocks of different intensity. In this work, a weight function and an associated mesh redistribution procedure is presented which detects and resolves these features without user intervention. Particular emphasis has been placed upon accurate resolution of expansion regions and boundary layers. Flow past a wedge at Mach=2.0 is used to illustrate the enhanced detection capabilities of this newly developed weight function.

Thornburg, Hugh↗

Sweep and Compressibility Effects on Active Separation Control at High Reynolds Numbers

This paper explores the effects of compressibility, sweep and excitation location on active separation control at high Reynolds numbers. The model, which was tested in a cryogenic pressurized wind tunnel, simulates the upper surface of a 20% thick Glauert Goldschmied type airfoil at zero angle of attack. The flow is fully turbulent since the tunnel sidewall boundary layer flows over the model. Without control, the flow separates at the highly convex area and a large turbulent separation bubble is formed. Periodic excitation is applied to gradually eliminate the separation bubble. Two alternative blowing slot locations as well as the effect of compressibility, sweep and steady suction or blowing were studied. During the test the Reynolds numbers ranged from 2 to 40 million and Mach numbers ranged from 0.2 to 0.7. Sweep angles were 0 and 30 deg. It was found that excitation must be introduced slightly upstream of the separation region regardless of the sweep angle at low Mach number. Introduction of excitation upstream of the shock wave is more effective than at its foot. Compressibility reduces the ability of steady mass transfer and periodic excitation to control the separation bubble but excitation has an effect on the integral parameters, which is similar to that observed in low Mach numbers. The conventional swept flow scaling is valid for fully and even partially attached flow, but different scaling is required for the separated 3D flow. The effectiveness of the active control is not reduced by sweep. Detailed flow field dynamics are described in the accompanying paper.

Seifert, Avi↗

Evaluation of Scaling Methods for Rotorcraft Icing

This paper reports result of an experimental study in the NASA Glenn Icing Research Tunnel (IRT) to evaluate how well the current recommended scaling methods developed for fixed-wing unprotected surface icing applications might apply to representative rotor blades at finite angle of attack. Unlike the fixed-wing case, there is no single scaling method that has been systematically developed and evaluated for rotorcraft icing applications. In the present study, scaling was based on the modified Ruff method with scale velocity determined by maintaining constant Weber number. Models were unswept NACA 0012 wing sections. The reference model had a chord of 91.4 cm and scale model had a chord of 35.6 cm. Reference tests were conducted with velocities of 76 and 100 kt (39 and 52 m/s), droplet MVDs of 150 and 195 fun, and with stagnation-point freezing fractions of 0.3 and 0.5 at angle of attack of 0deg and 5deg. It was shown that good ice shape scaling was achieved for NACA 0012 airfoils with angle of attack lip to 5deg.

Tsao, Jen-Ching↗

An Experimental Investigation of the 30P30N Multi-Element High-Lift Airfoil

High-lift devices often generate an unsteady flow field producing both broadband and tonal noise which radiates from the aircraft. In particular, the leading edge slat is often a dominant contributor to the noise signature. An experimental study of a simplified unswept high-lift configuration, the 30P30N, has been conducted to understand and identify the various flow-induced noise sources around the slat. Closed-wall wind tunnel tests are performed in the Florida State Aeroacoustic Tunnel (FSAT) to characterize the slat cove flow field using a combination of surface and off-body measurements. Mean surface pressures compare well with numerical predictions for the free-air configuration. Consistent with previous measurements and computations for 2D high-lift configurations, the frequency spectra of unsteady surface pressures on the slat surface display several narrowband peaks that decrease in strength as the angle of attack is increased. At positive angles of attack, there are four prominent peaks. The three higher frequency peaks correspond, approximately, to a harmonic sequence related to a feedback resonance involving unstable disturbances in the slat cove shear layer. The Strouhal numbers associated with these three peaks are nearly insensitive to the range of flow speeds (41-58 m/s) and the angles of attack tested (3-8.5 degrees). The first narrow-band peak has an order of magnitude lower frequency than the remaining peaks and displays noticeable sensitivity to the angle of attack. Stereoscopic particle image velocimetry (SPIV) measurements provide supplementary information about the shear layer characteristics and turbulence statistics that may be used for validating numerical simulations.

Pascioni, Kyle A.↗