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At least 703 records · Page 39

Assessment of Active Metal Removal from Pyroprocessing Salt by Electrodeposition

Active metals present in used nuclear fuel dissolve into the salt during pyroprocessing, but are not recovered during electrorefining or drawdown operations due to their chemical stability in the salt. The accumulation of 137 Cs and 90 Sr in process salt over time increases the heat load and ionizing radiation level of the salt such that it must be replaced frequently, resulting in a significant amount of salt waste. An effective means of removing active metals from the molten salt to enable recycle of the electrolyte (e.g., LiCl/KCl) would increase the efficiency of pyroprocessing and decrease the volume of salt waste requiring disposal.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Recycled Paper as a Source of Renewable Jet Fuel in the United States

Converting biomass into jet fuel involves more than the core chemical process. The overall process includes the logistics of harvesting and transporting the biomass, handling and preparing the material for processing, and processing and disposal of waste. All of these activities contribute to cost. Controlling cost involves more than developing efficient process chemistry. Choice of feedstock also has a significant impact on process economics. We consider chemical conversion of paper from municipal solid waste as a feedstock for the production of jet fuel and diesel. Paper has a significantly higher cellulose content than raw lignocellulosic biomass such as corn stover, so it requires less pretreatment to convert it into hydrocarbons than lignocellulosic biomass. Our techno-economic analysis showed that the cost of converting paper waste into jet fuel is about $1.00/gal less than jet fuel produced from corn stover. Although the cost of recycling paper into jet fuel is less than producing it from corn stover, the process is not competitive with petroleum. We estimated a minimum selling price of $3.97/gal for paper-derived jet fuel. Our sensitivity studies indicated that the biggest economic obstacle is the cost of cellulose hydrolysis. Direct hydrogenation of paper to sugar alcohols combined with increased economy of scale could make recycling paper jet fuel competitive.

09 BIOMASS FUELS↗

Prediction of Long-Term Geochemical Change in Bentonite Based on the Interpretative THMC Model of the FEBEX In Situ Test

Since nuclear energy is crucial in the decarbonization of the energy supply, one hurdle to remove is the handling of high-level radioactive waste (HLW). Disposal of HLW in a deep geological repository has long been deemed a viable permanent option. In the design of a deep geological repository, compacted bentonite is the most commonly proposed buffer material. Predicting the long-term chemical evolution in bentonite, which is important for the safety assessment of a repository, has been challenging because of the complex coupled processes. Models for large-scale tests and predictions based on such models have been some of the best practices for such purposes. An 18-year-long in situ test with two dismantling events provided a unique set of chemical data that allowed for studying chemical changes in bentonite. In this paper, we first developed coupled thermal, hydrological, mechanical, and chemical (THMC) models to interpret the geochemical data collected in the in situ test and then extended the THMC model to 200 years to make long-term prediction of the geochemical evolution of bentonite. The interpretive coupled THMC model shows that the geochemical profiles were strongly affected by THM processes such as evaporation/condensation, porosity change caused by swelling, permeability change, and the shape of concentration profiles for major cations were largely controlled by transport processes, but concentration levels were regulated by chemical reactions, and the profiles of some species such as pH, bicarbonate, and sulfate were dominated by these reactions. The long-term THMC model showed that heating prolongs the time that bentonite becomes fully saturated in the area close to the heater/canister; however, once the bentonite becomes fully saturated, high concentrations of ions in bentonite near the heater, which was observed in the field test, will disappear; illitization continues for 50 years but will not proceed further.

Zheng, Liange↗

Life-support systems.

Life support systems in manned spacecraft, detailing environment control and water and waste management

ENVIRONMENTAL CONTROL↗

Space industrialization

Space industrialization is defined as the use of space flight and the space environment for commercial or utilitarian purposes in contrast to other uses such as gains in basic scientific knowledge, national defense, or exploration. Some unique attributes of space that make it amenable to industrial use include overview of the earth, the 'zero gravity' effect, potential for near perfect vacuum, unlimited reservoir for disposal of waste products, availability of essentially uninterrupted flow of solar energy, and the 'perpetual motion' characteristic of orbital mechanics. The role of human participation in assembling and maintaining the large sophisticated systems that will be required for future space industrialization needs is considered.

Disher, J. H.↗

Integrated waste and water management system

The performance requirements of the NASA Space Station have prompted a reexamination of a previously developed integrated waste and water management system that used distillation and catalytic oxydation to purify waste water, and microbial digestion and incineration for waste solids disposal. This system successfully operated continuously for 206 days, for a 4-man equivalent load of urine, feces, wash water, condensate, and trash. Attention is given to synergisms that could be established with other life support systems, in the cases of thermal integration, design commonality, and novel technologies.

Murray, R. W.↗

Spacecraft Fire-Safety Experiments for Space Station: Technology Development Mission

Definitions, overall descriptions, and preliminary apparatus and instrumentation requirements are presented for three spacecraft fire-safety experiments appropriate for inclusion in a growth-version of the Space Station. The experiments are as follows: 1. Combustion and Flame Spread of Typical Spacecraft Materials in a Low­ Velocity Convective Flow in Low Gravity 2. Fire and Fire-Extinguishant Interactions with Various Fire Scenarios in Low Gravity 3. Smoldering and Deep-Seated Combustion in Low Gravity. The experiments were selected from an assessment of recommendations for advanced technologies for prevention, detection, and control of fires in spacecraft. The experiments and their facilities are intended to constitute a portion of a Spacecraft Fire Safety Technology Development Mission (TDM). Basic requirements for the mission study are that the Space Station is essential for the accomplishment of the experimental objectives and that the technology being developed is appropriate for the growth version of the Space Station. The advantages of these three experiments are that, not only do they explore problems relevant to the Space Station operation and utilization, but also they constitute tests adaptable to two multiuse facilities installed in the Space Station laboratory module, the Combustion Tunnel Facility and the Combustion Facility. Three additional spacecraft fire-safety experiments, essential precursors to the TD M for near-term performance, are also described as follows: 1. Near-Term Testing of Materials for Combustion and Flame Spread 2. Near-Term Extinguishment of Fires in a Low-Gravity Test Bed 3. Post-Fire Recovery of Sensitive Electrical and Electronic Equipment. For all the experiments, the study defines accommodations in terms of first-order space, mass, power, consumables, and crew-time estimates. The study also reviews the key problems to be addressed, namely experiment safety hazards, non-intrusive diagnostics development and waste-products disposal. A preliminary task and time schedule for design, development, and experiment fabrication is proposed.

Youngblood, Wallace W.↗

Two-Phase Accumulator

Two-phase accumulator maintains pressure and temperature in thermal-bus system within predetermined range during variations in heat load on system. Stores liquid and vapor ammonia. Exchanges liquid ammonia with condenser to adjust level of liquid in condenser. Prototype has capacity of 13 gallons (49 liters). Simple and highly reliable. Responds quickly, restoring pressure and temperature to proper values within minutes. Low in cost and requires little further development. Used to dispose of waste heat, such as that from electronic equipment or power-plant.

Kalb, Charles E.↗

Closed-loop Habitation Air Revitalization Model for Regenerative Life Support Systems

The primary function of any life support system is to keep the crew alive by providing breathable air, potable water, edible food, and for disposal of waste. In a well-balanced or regenerative life support system, the various components are each using what is available and producing what is needed by other components so that there will always be enough chemicals in the form in which they are needed. Humans are not just users, but also one of the participating parts of the system. If a system could continuously recycle the original chemicals, this would make it virtually a Closed-loop Habitation (CH). Some difficulties in trying to create a miniature version of a CH are briefly discussed. In a miniature CH, a minimal structure must be provided and the difference must be made up by artificial parts such as physicochemical systems that perform the conversions that the Earth can achieve naturally. To study the interactions of these parts, a computer model was designed that simulates a miniature CH with emphasis on the air revitalization part. It is called the Closed-loop Habitation Air Revitalization Model (CHARM).

Hart, Maxwell M.↗

Space Station propulsion system

Viewgraphs on space station propulsion systems are presented. Topics covered include: space station propulsion system requirements; space station propulsion system design; space station propulsion system drivers; hydrazine technology development; waste fluid disposal system; space station propulsion system evolution; propellant selection trade study; technology needs to water electrolysis/oxygen-hydrogen propulsion system; and technology needs for bipropellant systems.

Henderson, J.↗