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At least 703 records · Page 39

Covalent adaptable polymer networks with CO 2 -facilitated recyclability

Cross-linked polymers with covalent adaptable networks (CANs) can be reprocessed under external stimuli owing to the exchangeability of dynamic covalent bonds. Optimization of reprocessing conditions is critical since increasing the reprocessing temperature costs more energy and even deteriorates the materials, while reducing the reprocessing temperature via molecular design usually narrows the service temperature range. Exploiting CO 2 gas as an external trigger for lowering the reprocessing barrier shows great promise in low sample contamination and environmental friendliness. Herein, we develop a type of CANs incorporated with ionic clusters that achieve CO 2 -facilitated recyclability without sacrificing performance. The presence of CO 2 can facilitate the rearrangement of ionic clusters, thus promoting the exchange of dynamic bonds. The effective stress relaxation and network rearrangement enable the system with rapid recycling under CO 2 while retaining excellent mechanical performance in working conditions. This work opens avenues to design recyclable polymer materials with tunable dynamics and responsive recyclability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Design of Particle-Based Thermal Energy Storage for a Concentrating Solar Power System

Solid particles can operate at higher temperature than current molten salt or oil, and they can be a heat-transfer and storage medium in a concentrating solar power (CSP) system. By using inexpensive solid particles and containment material for thermal energy storage (TES), the particle-TES cost can be significantly lower than other TES methods such as a nitrate-salt system. The particle-TES system can hold hot particles at more than 800 degrees C with high thermal performance. The high particle temperatures increase the temperature difference between the hot and cold particles, and they improve the TES capacity. The particle-based CSP system is able to support high-efficiency power generation, such as the supercritical carbon-dioxide Brayton power cycle, to achieve >50% thermal-electric conversion efficiency. This paper describes a solid particle-TES system that integrates into a CSP plant. The hot particles discharge to a heat exchanger to drive the power cycle. The returning cold particles circulate through a particle receiver to absorb solar heat and charge the TES. This paper shows the design of a particle-TES system including containment silos, foundation, silo insulation, and particle materials. The analysis provides results for four TES capacities and two silo configurations. The design analysis indicates that the system can achieve high thermal efficiency, storage effectiveness (i.e., percentage usage of the hot particles), and exergetic efficiency. An insulation method for the hot silo was considered. The particle-TES system can achieve high performance and low cost, and it holds potential for next-generation CSP technology.

14 SOLAR ENERGY↗

NASA/University JOint VEnture (JOVE) Program. VIXEN(tm): Object-Oriented, Technology-Adaptive, Virtual Information Exchange Environment

Vixen is a collection of enabling technologies for uninhibited distributed object computing. In the Spring of 1995 when Vixen was proposed, it was an innovative idea very much ahead of its time. But today the technologies proposed in Vixen have become standard technologies for Enterprise Computing. Sun Microsystems J2EE/EJB specifications, among others, are independently proposed technologies of the Vixen type. I have brought Vixen completely under the J2EE standard in order to maximize interoperability and compatibility with other computing industry efforts. Vixen and the Enterprise JavaBean (EJB) Server technologies are now practically identical; OIL, another Vixen technology, and the Java Messaging System (JMS) are practically identical; and so on. There is no longer anything novel or patentable in the Vixen work performed under this grant. The above discussion, notwithstanding, my independent development of Vixen has significantly helped me, my university, my students and the local community. The undergraduate students who worked with me in developing Vixen have enhanced their expertise in what has become the cutting edge technology of their industry and are therefore well positioned for lucrative employment opportunities in the industry. My academic department has gained a new course: "Multi-media System Development", which provides a highly desirable expertise to our students for employment in any enterprise today. The many Outreach Programs that I conducted during this grant period have exposed local Middle School students to the contributions that NASA is making in our society as well as awakened desires in many such students for careers in Science and Technology. I have applied Vixen to the development of two software packages: (a) JAS: Joshua Application Server - which allows a user to configure an EJB Server to serve a J2EE compliant application over the world wide web; (b) PCM: Professor Course Manager: a J2EE compliant application for configuring a course for distance learning. These types of applications are, however, generally available in the industry today.

Anyiwo, Joshua C.↗

SIRIUS: Science-Driven Data Management for Multi-Tiered Storage

The data sets being generated by large applications on very large-scale systems are increasing in both size and complexity. At the same time, there are new ways available to store and access these data sets. The goal in this project is to develop software that applications can use to make use of new and existing storage technologies in more sophisticated ways. One challenge in scientific data management is handling ‘hot’ vs ‘cold’ data. Data that is hot is data that is needed (or will be needed soon) in order for the program to continue progressing, while cold data is either output (and so will not be need further during the life of the program) or will not be needed until significantly later in the program’s run. Hot data should be stored in a way that allows fast access. On most systems, economic factors lead to an inverse relationship between storage performance and storage capacity and so fast access storage is limited. This makes it important to correctly place hot and cold data and avoid cold data unnecessarily consuming precious resources. In this reporting period, we addressed this challenge in various ways and at various levels. Data management frameworks offer only limited control to applications in how data is stored. We have added software capabilities for seamlessly moving data between layers of the storage technology using promote and demote functions to existing software frameworks. This gives direct control to applications in deciding what priority data receives. Additionally, we integrated different storage layer management frameworks in order to allow data to be exchanged and moved between storage layers in a consistent way across the application. Further, applications are not always able to directly decide what storage level makes sense for a given piece of data without an understanding of the underlying storage technologies. Data storage frameworks are often positioned to make these sorts of decisions in service of the application. We have added machine-learning based capabilities to data staging frameworks in order to make intelligent decisions about where data should be stored given learning about patterns in previous usage of similar data.

97 MATHEMATICS AND COMPUTING↗

1987 overview of free-piston Stirling technology for space power application

The Lewis Research Center program concerned with the development of a free-piston Stirling engine for space-power applications is examined. The system mass of a Stirling system is compared to that of a Brayton system for the same peak temperature and output power; the advantages of the Stirling system are discussed. The predicted and experimental performances of the 25 kWe opposed-piston space power demonstrator engine are evaluated. It is determined that in order to enhance performance the regenerator needs to be modified, and the gas bearing flow between the displacer and power piston needs to be isolated in order to increase the operating stroke. Identification and correction of the energy losses, the design and operation of the linear alternator, and heat exchange concepts are considered. The design parameters and conceptual design characteristics for a 25 kWe single-cylinder free-piston Stirling space-power converter are described.

Slaby, Jack G.↗

Interaction between water and carbon nanostructures: How good are current density functional approximations?

Due to their current and future technological applications, including realization of water filters and desalination membranes, water adsorption on graphitic sp2-bonded carbon is of overwhelming interest. However, these systems are notoriously challenging to model, even for electronic structure methods such as density functional theory (DFT), because of the crucial role played by London dispersion forces and noncovalent interactions, in general. Recent efforts have established reference quality interactions of several carbon nanostructures interacting with water. Here, we compile a new benchmark set (dubbed WaC18), which includes a single water molecule interacting with a broad range of carbon structures and various bulk (3D) and two-dimensional (2D) ice polymorphs. The performance of 28 approaches, including semilocal exchange-correlation functionals, nonlocal (Fock) exchange contributions, and long-range van der Waals (vdW) treatments, is tested by computing the deviations from the reference interaction energies. The calculated mean absolute deviations on the WaC18 set depend crucially on the DFT approach, ranging from 135 meV for local density approximation (LDA) to 12 meV for PBE0-D4. We find that modern vdW corrections to DFT significantly improve over their precursors. Within the 28 tested approaches, we identify the best performing within the functional classes of generalized gradient approximated (GGA), meta-GGA, vdW-DF, and hybrid DF, which are BLYP-D4, TPSS-D4, rev-vdW-DF2, and PBE0-D4, respectively.

Brandenburg, Jan Gerit (ORCID:0000000292192948)↗

Pressure dependence of the oxygen reduction reaction at the platinum microelectrode/nafion interface - Electrode kinetics and mass transport

The investigation of oxygen reduction kinetics at the platinum/Nafion interface is of great importance in the advancement of proton-exchange-membrane (PEM) fuel-cell technology. This study focuses on the dependence of the oxygen reduction kinetics on oxygen pressure. Conventional Tafel analysis of the data shows that the reaction order with respect to oxygen is unity at both high and low current densities. Chronoamperometric measurements of the transport parameters for oxygen in Nafion show that oxygen dissolution follows Henry's isotherm. The diffusion coefficient of oxygen is invariant with pressure; however, the diffusion coefficient for oxygen is lower when air is used as the equilibrating gas as compared to when oxygen is used for equilibration. These results are of value in understanding the influence of O2 partial pressure on the performance of PEM fuel cells and also in elucidating the mechanism of oxygen reduction at the platinum/Nafion interface.

Parthasarathy, Arvind↗

Flux Synthesis of Lattice‐Engineered Rutile Solid Solutions for Acidic Oxygen Evolution

Developing efficient and stable electrocatalysts for the acidic oxygen evolution reaction (OER) is vital for advancing proton exchange membrane water electrolysis (PEMWE) technologies. Here, in this study, we report a flux synthesis of nitrogen-doped Ti–Ru rutile-type solid-solution oxides (M-TiRu 4 ) using molten NaNO 3 as the flux medium. The flux medium promotes the low-temperature conversion of TiN to rutile TiO 2 , while in situ-formed RuO 2 nanoparticles facilitate lattice templating and couple with interfacial ion migration, enabling the formation of homogeneous solid solutions with abundant lattice heterogeneity. Simultaneously, nitrogen atoms are stably incorporated into the lattice of solid solutions, inducing bandgap narrowing, which enhances electronic conductivity. The developed M-TiRu 4 catalyst exhibits exceptional acidic OER performance, delivering a low overpotential of 194 mV at 10 mA cm −2 , superior durability over 600 h, and a Ru mass activity 7.8 times that of commercial RuO 2 . At the device level, M-TiRu 4 enables PEMWE operation at 1.64 V @ 2 A cm −2 and maintains stable performance at 500 mA cm −2 for 200 h with a minimal degradation rate of 20 µV h −1 . This work demonstrates a robust approach for designing high-performance, durable acidic OER catalysts via synergistic lattice and electronic structure engineering, paving the way for next-generation water-splitting technologies.

Wang, Fan [Univ. of Tennessee, Knoxville, TN (Unit↗

SERIIUS-MAGEEP Visiting Scholars Program

Recent studies have assessed closed-loop supercritical carbon dioxide (s-CO 2 ) Brayton cycles to be a higher energy-density system in comparison to equivalent superheated steam Rankine systems. At turbine inlet conditions of 700°C and 20 MPa, a cycle thermal efficiency of ~50% can be achieved. Achieving these high efficiencies will help concentrating solar power (CSP) technologies to become a competitive alternative to current power generation methods. To incorporate an s-CO 2 Brayton power cycle in a solar power tower system, the development of a solar receiver capable of providing an outlet temperature of 700°C (at 20 MPa) is necessary. To satisfy the temperature requirements of an s-CO 2 Brayton cycle with recuperation and recompression, the s-CO 2 must undergo a temperature rise of ~200°C as it flows through the solar receiver. The main objective is to develop an optical-thermal-fluid and structural model to validate a tubular receiver that will receive a heat input ~0.33 MWth from the heliostat field at the National Solar Thermal Test Facility (NSTTF), Albuquerque, NM, USA. We also commenced the development of computational models and testing of air receivers being developed by the Indian Institute of Science (IISc) and the Indian Institute of Technology in Bombay (IIT-B). The helical tubular receiver is expected to counteract the effect of thermal expansion while using a cavity to reduce the radiative and convective losses. Initially, this receiver will be tested for a temperature range of 100-300°C under 1 MPa of pressurized air. The helical air receiver will be exposed to 10kWth to achieve a temperature rise of ~200°C. Preliminary tests to validate the modeling will be performed before the design and construction of a larger scale receiver. Lastly, I focused on the development of a new computational tool that would allow us to perform a nodal creep-fatigue analysis on the receivers and heat exchangers being developed. This tool was developed using MATLAB and is capable of processing the results obtained from ANSYS Fluent and Structural combined, which was limited when using commercial software. The main advantage of this code is that it can be modified to run in parallel making it more affordable and faster compared to commercial codes available. The code is in the process of validation and is currently being compared to nCode Design Life.

25 ENERGY STORAGE↗

Assessment of Laser-Driven Pulsed Neutron Sources for Poolside Neutron-based Advanced NDE – A Pathway to LANSCE-like Characterization at INL

A variety of opportunities for characterization of fresh nuclear fuels using thermal (~25meV) and epithermal (~10eV) neutrons have been documented at Los Alamos National Laboratory. They include spatially resolved non-destructive characterization of features, isotopic enrichment, chemical heterogeneity and stoichiometry. The LANSCE spallation neutron source is well suited in neutron fluence and temporal characteristics for studies of fuels. However, recent advances in high power short pulse lasers suggest that compact neutron sources might, over the next decade, become viable at a price point that would permit their consideration for poolside characterization on site at irradiation facilities. In a laser-driven neutron source the laser is used to accelerate deuterium ions into a beryllium target where neutrons are produced. At this time, the technology is new and their total neutron production is approximately four orders of magnitude less than a facility like LANSCE. However, recent measurements on a sub-optimized system demonstrated >10 10 neutrons in sub-nanosecond pulses in predominantly forward direction. The compactness of the target system compared to a spallation target may allow exchanging the target during a measurement to e.g. characterize a highly radioactive sample with thermal, epithermal, and fast neutrons as well as hard X-rays, thus avoiding sample handling. At this time several groups are working on laser-driven neutron production and are advancing concepts for lasers, laser targets, and optimized neutron target/moderator systems. Advances in performance sufficient to enable poolside fuels characterization with LANSCE-like fluence on sample within a decade may be possible. This report describes the underlying physics and state-of-the-art of the laser-driven neutron production process from the perspective of the DOE/NE mission. It also discusses the development and understanding that will be necessary to provide customized capability for characterization of irradiated fuels. Potential operational advantages compared to a spallation neutron source include reduced shielding complexity, reduced energy requirements, and a production target free of fission products. Contributors to this report include experts in laser-driven neutron production (Roth, Fernandez), laser design (Haefner, Siders, Leemans), laser target design (Glenzer), spallation target/moderator design (Mocko), neutron instrumentation and characterization applications (Vogel, Bourke).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Development of a Framework for Data Integration, Assimilation, and Learning for Geological Carbon Sequestration (DIAL-GCS) (Final Report)

This project aimed to develop and demonstrate a Data Integration, Assimilation, and Learning framework for geologic carbon sequestration projects (DIAL-GCS). DIAL-GCS is an intelligence monitoring system (IMS) for automating GCS closed-loop management by leveraging recent developments in machine learning technologies, complex event processing (CEP), and reduced-order modeling. The safe and efficient operation of GCS repositories requires integrated monitoring to track the injected CO¬2 as it moves within a storage reservoir. GCS projects are data intensive, as a result of proliferation of digital instrumentation and smart-sensing technologies. GCS projects are also resource intensive, often requiring multidisciplinary teams performing different monitoring, verification, accounting (MVA) tasks throughout the lifecycle of a project to ensure secure containment of injected CO2. The success of GCS thus depends in a large part on our ability to access, assimilate, and analyze heterogeneous data and information sources in a timely manner. This project included a number of meaningful and necessary tasks to transform the human domain knowledge into machine-interpretable rules for automating knowledge extraction and discovery in GCS. The specific technical objectives of the proposed DIAL-GCS project were to develop an ontology-driven GCS data management module for storing, querying, and exchanging GCS data (both historic and live sensor data) from multiple sources and in heterogeneous formats. Incorporate a CEP engine for detecting abnormal situations by seamlessly combining expert knowledge, rule-based reasoning, and machine learning. Enable uncertainty quantification and predictive analytics using a combination of coupled-process modeling, AI/ML methods, and reduced-order modeling, and integrate and demonstrate the system’s capabilities with both real and simulated data. As far as we know, this is one of the first projects aimed to develop intelligent monitoring systems (IMS) targeting the GCS. Under this project, the team had developed a large number of web applications and scientific algorithms that contribute the main theme of intelligent monitoring. The team has published more than a dozen peer reviewed papers and disseminated the research results at multiple technical meetings.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Test results on re-use of reclaimed shower water: Summary

A microgravity whole body shower (WBS) and waste water recovery systems (WWRS) were evaluated in three separate closed loop tests. Following a protocol similar to that anticipated for the U.S. Space Station, test subjects showered in a prototype whole body shower. The WWRS processes evaluated during the test series were phase change and reverse osmosis (RO). A preprototype Thermoelectric Integrated Hollow Fiber Membrane Evaporation Subsystem phase change process was used for the initial test with chemical pretreatment of the shower water waste input. The second and third tests concentrated on RO technologies. The second test evaluated a dynamic RO membrane consisting of zirconium oxide polyacrylic acid (ZOPA) membranes deposited on the interior diameter of 316L porous stainless steel tubes while the final test employed a thin semipermeable RO membrane deposited on the interior surface of polysulfone hollow fibers. All reclaimed water was post-treated for purity using ion exchange and granular activated carbon beds immediately followed by microbial control treatment using both heat and iodine. The test hardware, controls exercised for whole body showering, types of soaps evaluated, shower subject response to reclaimed water showering, and shower water collection and chemical pretreatment (if required) for microbial control are described. The WWRS recovered water performance and the effectiveness of the reclaimed water post-treatment techniques used for maintaining water purity and microorganism control are compared. Results on chemical and microbial impurity content of the water samples obtained from various locations in the shower water reuse system are summarized.

Verostko, C. E.↗

Scalable, Dual-Mode Occupancy Sensing for Commercial Venues

The ability to establish accurate occupancy is a key enabler for improved energy efficiency in human-occupied indoor spaces. The accurate counts can be used to adjust, in real-time, air exchange, heating, and cooling, to closely match the environmental needs of the occupants rather than to use a single setting based on maximum room occupancy. This project focuses on the use of overhead fisheye cameras and artificial intelligence (AI) algorithms as the technology to realize accurate people counting in large commercial spaces. We developed Computational Occupancy Sensing SYstem ("COSSY''), which supports large-scale deployment (thousands of square feet) and straightforward installation (using conventional power over ethernet), while providing high accuracy and low cost. COSSY has been validated at Boston University and by a third party, demonstrating people-counting accuracy of at least 89.5% in large spaces (2,000 sqft). A cost/benefit analysis performed for Boston commercial market indicates that a full payback of COSSY deployment costs due to energy savings would occur within 3-6 months from installation. Applications of COSSY reach far beyond saving energy. The precise people counting in real time could also be useful for emergency response (e.g., fire), in spatial analytics (e.g., office space management) and in some health applications (e.g., social distance assessment during pandemics).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Multifunctional Carbon Foams for Aerospace Applications

Carbon foams produced by the controlled thermal decomposition of inexpensive coal extracts exhibit a combination of structural and thermal properties that make them attractive for aerospace applications. Their thermal conductivity can be tailored between 0.5 and 100 W/mK through precursor selection/modification and heat treatment conditions; thus, they can serve in either thermal protection or heat transfer systems such as heat exchangers. Because their structure is essentially a 3D random network of graphite-like members, they also can be considered low-cost, easily fabricated replacements for multi-directional structural carbon fiber preforms. Strengths of over 4000 psi in compression are common. Their density can be designed between 0.1 and 0.8 g/cc, and they can be impregnated with a variety of matrices or used, unfilled, in sandwich structures. These foams also exhibit intriguing electrochemical properties that offer potential in high-efficiency fuel cell and battery applications, mandrels and tooling for composite manufacture, ablative performance, and fire resistance. This paper presents the results of research conducted under NASA SBIR Topic 99.04.01, General Aviation Technology, supported from Langley Research Center. The potential of foam design through precursor selection, cell size and density control, density grading, and heat treatment is demonstrated.

Rogers, D. K.↗

Initial Results From the Newly Upgraded LTX- β

LTX-β, the upgraded Lithium Tokamak Experiment, recently began its first campaign with a goal to study the transport properties of gradient-free electron temperature profile equilibria with increased toroidal field and neutral beam injection. The temperature-gradient-free equilibria in LTX were enabled by the lithium plasma-facing surface. To make the lithium surface conditions more consistent for LTX-β, a new, faster lithium evaporator system has been developed. The toroidal magnetic field has been nearly doubled to ≥0.3 T. Auxiliary heating and fueling with a high flux (35 A, 20 kV) neutral beam has begun. The beam provides core fueling without cold edge neutrals, to test whether flat temperature profiles can be sustained, and makes possible core ion temperature measurements via charge exchange recombination spectroscopy. Neutral beam fueling has been demonstrated with increases in line-integrated density. The coupling of the beam matches well with NUBEAM predictions for shine through. Improved performance has been observed following lithium evaporative coatings and an increase in field strength.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

An Evaluation of OpenSHMEM Interfaces for the Variable-Length Alltoallv() Collective Operation, In: OpenSHMEM and Related Technologies. Experiences, Implementations, and Technologies

Alltoallv() is a collective operation which allows all processes to exchange variable amounts of data with all other processes in the communication group. This means that Alltoallv() requires not only O(N2) communications, but typically also additional exchanges of the data lengths that will be transmitted in the eventual Alltoallv() call. This pre-exchange is used to calculate the proper offsets for the receiving buffers on the target processes. However, we propose two new candidate interfaces for Alltoallv() that would mitigate the need for the user to set up this extra exchange of information at the possible cost of memory efficiency. We explain the new interface variants and show how a single call can be used in place of the traditional Alltoall()/ Alltoallv() pair. We then discuss the performance tradeoffs for overall communication and memory costs, as well as both software and hardware-based optimizations and their applicability to the various proposed interfaces.

Computer Science↗

Corrosion of alloys in a chloride molten salt (NaCl-LiCl) for solar thermal technologies

Next-generation solar power conversion systems in concentrating solar power (CSP) applications require high-temperature advanced fluids in the range of 600–800 °C. Current commercial CSP plants use molten nitrate salt mixtures as the heat transfer fluid and the thermal energy storage (TES) media while operating with multiple hours of energy capacity and at temperatures lower than 565 °C. At higher temperatures, the nitrates cannot be used because they decompose. Molten chloride salts are candidates for CSP applications because of their high decomposition temperatures and good thermal properties; but they can be corrosive to common alloys used in vessels, heat exchangers, and piping at these elevated temperatures. In this article, we present the results of the corrosion evaluations of several alloys in eutectic 34.42 wt% NaCl – 65.58 wt% LiCl at 650–700 °C in nitrogen atmosphere. Electrochemical evaluations were performed using open-circuit potential followed by a potentiodynamic polarization sweep. Corrosion rates were determined using Tafel slopes and Faraday's law. A temperature increase of as little as 50 °C more than doubled the corrosion rate of AISI stainless steel 310 and Incoloy 800H compared to the initial 650 °C test. These alloys exhibited localized corrosion. Inconel 625 was the most corrosion-resistant alloy with a corrosion rate of 2.80±0.38 mm/year. For TES applications, corrosion rates with magnitudes of a few millimeters per year are not acceptable because of economic considerations. Additionally, localized corrosion (intergranular or pitting) can be catastrophic. Furthermore, corrosion-mitigation approaches are required for advanced CSP plants to be commercially viable.

47 OTHER INSTRUMENTATION↗

Field Validation of Electrochemical Water Filtration System on Open Loop Cooling Towers at Automotive Plants

Open loop cooling towers play a pivotal role in rejecting heat for chilled water systems serving industrial processes, heating, ventilation, and air conditioning loads. Exposure to outside conditions can present certain operating challenges to system performance including scaling, corrosion, and biological growth. These issues are mitigated through the use of effective cooling tower water filtration and treatment systems to reduce contaminants—along with other total suspended solids (TSS) and total dissolved solids (TDS)—in the system. The U.S. Department of Energy’s Industrial Efficiency and Decarbonization Office is interested in an electrochemical-based filtration system with the ability to remove TSS particulate down to 1 micron. The removal of finer particulates reduces the need for blowdown and, in turn, makeup water use and chemical treatment in the cooling tower. Additionally, the removal process can reduce fouling at the condensers, resulting in better heat exchange and energy savings. Two Industrial Technology Validation program projects validated the electrochemical water filtration system at the Toyota Motor Manufacturing, Mississippi plant in Blue Springs, Mississippi, and the Nissan Canton Vehicle Assembly Plant in Canton, Mississippi. Researchers found that installation of both systems resulted in water and chemical treatment savings with minimal impact on energy use.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗