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At least 703 records · Page 39

Chemicals from biomass - The U.S. prospects for the turn of the century

Historically, chemicals from biomass have been and are expected to be economical in three major areas: byproducts, specialty items and polymers. Assessments of producing major chemicals from biomass in a processing plant based on the available conversion techniques indicate that they are not economically attractive, with the possible exception of conversion to ammonia and ethanol. The deterrents are the heavy capital investments, dependability of raw material supply and transportation costs for large plants, lack of operation experience, inadaptability of market variations, and competition from petroleum and coal. More importantly, it is also shown that even if chemicals from biomass were economical today, the resultant savings in petroleum would be far less than those achieved through other options available for the utilization of biomass as fuel and structural material. Thus, it is concluded that near-term research and development must be toward improved conversion processes, recovery of valuable products from waste streams at existing plants, more efficient use of biomass of energy and more efficient production of superior material products.

Sarbolouki, M. N.↗

The Integrated Technology and Flight Research Rotor Technology demonstrators for the 1985-1995 timeframe

The purposes and progress in the Integrated Technology Rotor/Flight Research Rotor (ITR/FRR) Project, a joint effort by the U.S. Army and NASA, are outlined. The project goal is to integrate the disciplines of rotor design, aerodynamics, structures, materials, dynamics, and acoustics, to remove the risks in applying the technology, and to develop an advanced flight research rotor which permits significant variation in the rotor properties. Composite rotors are believed to be capable of displaying infinite fatigue lifetimes with fail-safe characteristics, and bearingless hubs simplify hub designs. The programs will also consider the flight control, propulsion, and structures. Concept definition contracts are presently distributed among five companies, and preliminary designs will lead to model tests in 1984.

Bousman, W.↗

Multiscale Computer Simulation of Failure in Aerogels

Aerogels have been of interest to the aerospace community primarily for their thermal properties, notably their low thermal conductivities. While such gels are typically fragile, recent advances in the application of conformal polymer layers to these gels has made them potentially useful as lightweight structural materials as well. We have previously performed computer simulations of aerogel thermal conductivity and tensile and compressive failure, with results that are in qualitative, and sometimes quantitative, agreement with experiment. However, recent experiments in our laboratory suggest that gels having similar densities may exhibit substantially different properties. In this work, we extend our original diffusion limited cluster aggregation (DLCA) model for gel structure to incorporate additional variation in DLCA simulation parameters, with the aim of producing DLCA clusters of similar densities that nevertheless have different fractal dimension and secondary particle coordination. We perform particle statics simulations of gel strain on these clusters, and consider the effects of differing DLCA simulation conditions, and the resultant differences in fractal dimension and coordination, on gel strain properties.

Good, Brian S.↗

Hyperthermal Environments Simulator for Nuclear Rocket Engine Development

An arc-heater driven hyperthermal convective environments simulator was recently developed and commissioned for long duration hot hydrogen exposure of nuclear thermal rocket materials. This newly established non-nuclear testing capability uses a high-power, multi-gas, wall-stabilized constricted arc-heater to produce hightemperature pressurized hydrogen flows representative of nuclear reactor core environments, excepting radiation effects, and is intended to serve as a low-cost facility for supporting non-nuclear developmental testing of hightemperature fissile fuels and structural materials. The resulting reactor environments simulator represents a valuable addition to the available inventory of non-nuclear test facilities and is uniquely capable of investigating and characterizing candidate fuel/structural materials, improving associated processing/fabrication techniques, and simulating reactor thermal hydraulics. This paper summarizes facility design and engineering development efforts and reports baseline operational characteristics as determined from a series of performance mapping and long duration capability demonstration tests. Potential follow-on developmental strategies are also suggested in view of the technical and policy challenges ahead. Keywords: Nuclear Rocket Engine, Reactor Environments, Non-Nuclear Testing, Fissile Fuel Development.

Litchford, Ron J.↗

Overview of high-temperature materials for high-energy space power systems

The current state of technology and some of the more pressing research needs and challenges associated with the possible use of high temperature materials in future high energy space power systems are discussed. Particularly, emphasis is on the need to improve and quantify the fundamental understanding of the effects of the following: (1) fast neutron radiation on the properties and behavior of nuclear reactor fuels and claddings; and (2) long term, high temperature, space (vacuum) exposure on the properties of refractory metals considered for use as structural materials in various power conversion systems.

Saunders, N. T.↗

Double-Vacuum-Bag Process for Making Resin-Matrix Composites

A double-vacuum-bag process has been devised as a superior alternative to a single-vacuum-bag process used heretofore in making laminated fiber-reinforced resin-matrix composite-material structural components. This process is applicable to broad classes of high-performance matrix resins including polyimides and phenolics that emit volatile compounds (solvents and volatile by-products of resin-curing chemical reactions) during processing. The superiority of the double-vacuum-bag process lies in enhanced management of the volatile compounds. Proper management of volatiles is necessary for making composite-material components of high quality: if not removed and otherwise properly managed, volatiles can accumulate in interior pockets as resins cure, thereby forming undesired voids in the finished products. The curing cycle for manufacturing a composite laminate containing a reactive resin matrix usually consists of a two-step ramp-and-hold temperature profile and an associated single-step pressure profile as shown in Figure 1. The lower-temperature ramp-and-hold step is known in the art as the B stage. During the B stage, prepregs are heated and volatiles are generated. Because pressure is not applied at this stage, volatiles are free to escape. Pressure is applied during the higher-temperature ramp-and-hold step to consolidate the laminate and impart desired physical properties to the resin matrix. The residual volatile content and fluidity of the resin at the beginning of application of consolidation pressure are determined by the temperature and time parameters of the B stage. Once the consolidation pressure is applied, residual volatiles are locked in. In order to produce a void-free, high-quality laminate, it is necessary to design the curing cycle to obtain the required residual fluidity and the required temperature at the time of application of the consolidation pressure.

Bradford, Larry J.↗

Effects of target fragmentation on evaluation of LET spectra from space radiation in low-earth orbit (LEO) environment: impact on SEU predictions

Recent improvements in the radiation transport code HZETRN/BRYNTRN and galactic cosmic ray environmental model have provided an opportunity to investigate the effects of target fragmentation on estimates of single event upset (SEU) rates for spacecraft memory devices. Since target fragments are mostly of very low energy, an SEU prediction model has been derived in terms of particle energy rather than linear energy transfer (LET) to account for nonlinear relationship between range and energy. Predictions are made for SEU rates observed on two Shuttle flights, each at low and high inclination orbit. Corrections due to track structure effects are made for both high energy ions with track structure larger than device sensitive volume and for low energy ions with dense track where charge recombination is important. Results indicate contributions from target fragments are relatively important at large shield depths (or any thick structure material) and at low inclination orbit. Consequently, a more consistent set of predictions for upset rates observed in these two flights is reached when compared to an earlier analysis with CREME model. It is also observed that the errors produced by assuming linear relationship in range and energy in the earlier analysis have fortuitously canceled out the errors for not considering target fragmentation and track structure effects.

STS-51 Shuttle Project↗

Effects of Target Fragmentation on Evaluation of LET Spectra From Space Radiation in Low-Earth Orbit (LEO) Environment: Impact on SEU Predictions

Recent improvements in the radiation transport code HZETRN/BRYNTRN and galactic cosmic ray environmental model have provided an opportunity to investigate the effects of target fragmentation on estimates of single event upset (SEU) rates for spacecraft memory devices. Since target fragments are mostly of very low energy, an SEU prediction model has been derived in terms of particle energy rather than linear energy transfer (LET) to account for nonlinear relationship between range and energy. Predictions are made for SEU rates observed on two Shuttle flights, each at low and high inclination orbit. Corrections due to track structure effects are made for both high energy ions with track structure larger than device sensitive volume and for low energy ions with dense track where charge recombination is important. Results indicate contributions from target fragments are relatively important at large shield depths (or any thick structure material) and at low inclination orbit. Consequently, a more consistent set of predictions for upset rates observed in these two flights is reached when compared to an earlier analysis with CREME model. It is also observed that the errors produced by assuming linear relationship in range and energy in the earlier analysis have fortuitously canceled out the errors for not considering target fragmentation and track structure effects.

Shinn, J. L.↗

Register of experts for information on mechanics of structural failure

This register is comprised of a list of approximately 300 experts from approximately 90 organizations who have published results of theoretical and/or experimental research related to six problem areas in the mechanics of structural failure: (1) life prediction for structural materials, (2) fracture toughness testing, (3) fracture mechanics analysis; (4) hydrogen embrittlement; (5) protective coatings; and (6) composite materials. The criteria for the selection of names for the register are recent contributions to the literature, participation in or support of relevant research programs, and referral by peers. Each author included is listed by organizational affiliation, address, and principal field of expertise. The purpose of the register is to present, in easy reference form, sources for dependable information regarding failure modes and mechanisms of aerospace structures. The register includes two indexes; an alphabetical listing of the experts and an alphabetical listing of the organizations with whom they are affiliated.

Carpenter, J. L., Jr.↗

Application of PoF Based Virtual Qualification Methods for Reliability Assessment of Mission Critical PCBs

Reliability is the ability of a product to perform the function for which it was intended for a specified period of time (or cycles) for a given set of life cycle conditions. In today's compressed mission development cycles where designing, building and testing the physical models has to occur in a matter of months not years, Projects don't have the luxury of iteratively building and testing those models. Physics of failure (PoF) is an engineering-based approach to reliability that begins with an understanding of materials, processes, physical interactions, degradation and failure mechanisms, as well as identifying failure models. The PoF approach uses modeling and simulation to qualify a design and manufacturing process, with the ultimate intent of eliminating failures early in the design process by addressing the root cause. The physics-of-failure analysis proactively incorporates reliability into the design process by establishing a scientific basis for evaluating new materials, structures and technologies. Virtual physics-of-failure modeling allows engineers to determine if new technological node can be added to an existing system. This presentation will illustrate an application of a PoF based tool during the initial phases of a printed circuit board assembly development and how the NASA GSFC team was able to dynamically study the effects of electronics parts and printed circuit board material configuration changes under simulated thermal and vibrational stresses

Electronics packaging↗

Application of PoF Based Virtual Qualification Methods for Reliability Assessment of Mission Critical PCBs

Reliability is the ability of a product to perform the function for which it was intended for a specified period of time (or cycles) for a given set of life cycle conditions. In today's compressed mission development cycles where designing, building and testing the physical models has to occur in a matter of months not years, Projects don't have the luxury of iteratively building and testing those models. Physics of failure (PoF) is an engineering-based approach to reliability that begins with an understanding of materials, processes, physical interactions, degradation and failure mechanisms, as well as identifying failure models. The PoF approach uses modeling and simulation to qualify a design and manufacturing process, with the ultimate intent of eliminating failures early in the design process by addressing the root cause. The physics-of-failure analysis proactively incorporates reliability into the design process by establishing a scientific basis for evaluating new materials, structures and technologies. Virtual physics-of-failure modeling allows engineers to determine if new technological node can be added to an existing system. This presentation will illustrate an application of a PoF based tool during the initial phases of a printed circuit board assembly development and how the NASA GSFC team was able to dynamically study the effects of electronics parts and printed circuit board material configuration changes under simulated thermal and vibrational stresses.

Physics of Failure↗

Overview of High Temperature Material Needs for Space Nuclear Propulsion Reactors

Space nuclear propulsion systems are capable of enabling future crewed missions to Mars. Two primary options of these systems exist: nuclear thermal propulsion (NTP) and nuclear electric propulsion (NEP). NTP systems use a reactor as a heat exchanger to heat a hydrogen propellant to produce high specific impulse (≥ 900 s) and thrust (10 - 100 klbf). A NTP materials challenge is development of nuclear fuel capable of operating for short durations (hours) under high power densities (≥ 5 MW/L) and temperatures (> 2700 K) in a corrosive hydrogen environment. In NEP systems, the reactor heats a working fluid which transfers heat to a power conversion system to power electric thrusters. NEP is capable of higher specific impulse (≥ 2000 s) but limited to low thrust (10s lbf). Light weight vessel and in-core structural materials that are radiation-resistant, creep-resistant, and dimensionally stable while operating at ~1500 K over mission times up to several years are needed for NEP. Both systems can benefit from high temperature neutron moderators. Through the Space Nuclear Propulsion project, NASA, supported by the DOE, is developing NTP and NEP systems. Technology maturation planning and risk reduction activities related to fabrication and testing of reactor material candidates is ongoing. This presentation overviews NTP and NEP materials needs and current ceramic and composite development activities.

nuclear thermal propulsion↗

Technology benefits and ground test facilities for high-speed civil transport development

The advanced technology base necessary for successful twenty-first century High-Speed Civil Transport (HSCT) aircraft will require extensive ground testing in aerodynamics, propulsion, acoustics, structures, materials, and other disciplines. This paper analyzes the benefits of advanced technology application to HSCT concepts, addresses the adequacy of existing groundbased test facilities, and explores the need for new facilities required to support HSCT development. A substantial amount of HSCT-related ground testing can be accomplished in existing facilities. The HSCT development effort could also benefit significantly from some new facilities initially conceived for testing in other aeronautical research areas. A new structures testing facility is identified as critically needed to insure timely technology maturation.

Winston, Matthew M.↗

Conceptual design of a self-deployable, high performance parabolic concentrator for advanced solar-dynamic power systems

NASA has initiated technology development programs to develop advanced solar dynamic power systems and components for space applications beyond 2000. Conceptual design work that was performed is described. The main efforts were the: (1) conceptual design of self-deploying, high-performance parabolic concentrator; and (2) materials selection for a lightweight, shape-stable concentrator. The deployment concept utilizes rigid gore-shaped reflective panels. The assembled concentrator takes an annular shape with a void in the center. This deployable concentrator concept is applicable to a range of solar dynamic power systems of 25 kW sub e to in excess of 75 kW sub e. The concept allows for a family of power system sizes all using the same packaging and deployment technique. The primary structural material selected for the concentrator is a polyethyl ethylketone/carbon fiber composite also referred to as APC-2 or Vitrex. This composite has a nearly neutral coefficient of thermal expansion which leads to shape stable characteristics under thermal gradient conditions. Substantial efforts were undertaken to produce a highly specular surface on the composite. The overall coefficient of thermal expansion of the composite laminate is near zero, but thermally induced stresses due to micro-movement of the fibers and matrix in relation to each other cause the surface to become nonspecular.

Dehne, Hans J.↗

Energy absorption in composite materials for crashworthy structures

Crash energy-absorption processes in composite materials have been studied as part of a research program aimed at the development of energy absorbing subfloor beams for crashworthy military helicopters. Based on extensive tests on glass/epoxy, graphite/epoxy, and Kevlar/epoxy composites, it is shown that the energy-absorption characteristics and crushing modes of composite beams are similar to those exhibited by tubular specimens of similar material and architecture. The crushing mechanisms have been determined and related to the mechanical properties of the constituent materials and specimen architecture. A simple and accurate method for predicting the energy-absorption capability of composite beams has been developed.

Farley, Gary L.↗

Environmental Barrier Coatings for Ceramic Matrix Composites - An Overview

Ceramic Matrix Composites (CMCs) are increasingly being considered as structural materials for advanced power generation equipment. Broadly speaking the two classes of materials are oxide-based CMCs and non-oxide based CMCs. The non-oxide CMCs are primarily silicon-based. Under conditions prevalent in the gas turbine hot section the water vapor formed in the combustion of gaseous or liquid hydrocarbons reacts with the surface-SiO2 to form volatile products. Progressive surface recession of the SiC-SiC CMC component, strength loss as a result of wall thinning and chemical changes in the component occur, which leads to the loss of structural integrity and mechanical strength and becomes life limiting to the equipment in service. The solutions pursued to improve the life of SiC-SiC CMCs include the incorporation of an external barrier coating to provide surface protection to the CMC substrate. The coating system has become known as an Environmental Barrier Coating (EBC). The relevant early coatings work was focused on coatings for corrosion protection of silicon-based monolithic ceramics operating under severely corrosive conditions. The development of EBCs for gas turbine hot section components was built on the early work for silicon-based monolithics. The first generation EBC is a three-layer coating, which in its simplest configuration consists of a silicon (Si) base coat applied on top of the CMC, a barium-strontium-aluminosilicate (BSAS) surface coat resistant to water vapor attack, and a mullite-based intermediate coating layer between the Si base coat and BSAS top coat. This system can be represented as Si-Mullite-BSAS. While this baseline EBC presented a significant improvement over the uncoated SiC-SiC CMC, for the very long durations of 3-4 years or more expected for industrial operation further improvements in coating durability are desirable. Also, for very demanding applications with higher component temperatures but shorter service lives more rugged EBCs will be necessary. A second generation of EBCs incorporates rare earth silicates which have extremely favorable resistance against environmental attack and a higher temperature capability. Performance data for this class of EBCs is more limited and especially field data are not as extensive as for the first generation EBCs. Extensive laboratory, rig and engine testing, including testing of EBC coated SiC-SiC CMCs in actual field applications is in progress. The development of next generation EBCs with even higher temperature capability than the second generation EBC is also underway. This paper will discuss the current status of EBC technology and future direction based on literature survey.

Laboratory↗

Research and development activities in unified control-structure modeling and design

Results of work sponsored by JPL and other organizations to develop a unified control/structures modeling and design capability for large space structures is presented. Recent analytical results are presented to demonstrate the significant interdependence between structural and control properties. A new design methodology is suggested in which the structure, material properties, dynamic model and control design are all optimized simultaneously. The development of a methodology for global design optimization is recommended as a long term goal. It is suggested that this methodology should be incorporated into computer aided engineering programs, which eventually will be supplemented by an expert system to aid design optimization. Recommendations are also presented for near term research activities at JPL. The key recommendation is to continue the development of integrated dynamic modeling/control design techniques, with special attention given to the development of structural models specially tailored to support design.

Nayak, A. P.↗