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NASA NTRS1995

A Hubble Space Telescope study of the underlying white dwarf in the dwarf nova VW Hydri during quiescence

We have analyzed a far-ultraviolet spectrum of the dwarf nova VW Hyi obtained during quiescence with the Hubble Space Telescope Faint Object Spectrograph (HST FOS). The observation occurred 10 days after the return to optical quiescence from a superoutburst of VW Hyi. The spectrum reveals a very strong Stark-broadened Ly-alpha absorption with narrow geocoronal emission, and a very rich metallic absorption-line spectrum dominated by strong resonance absorption features of singly and doubly ionized silicon and carbon, the first solid identification of metallic absorption features arising in the accreted atmosphere of the white dwarf. We confirm the reported low-resolution IUE detection of the underlying white dwarf photosphere by Mateo & Szkody. A synthetic spectral analysis with hot, high-gravity LTE model atmospheres yields a best-fit model with the following parameters: T(sub eff) = 22,000 +/- 1000 K, log g = 8.0 +/- 0.3, with chemical abundances for oxygen of 0.3 times solar, for nitrogen of 5 times solar, and for all other heavy elements of 0.15 times solar. Based upon our absorption-line measurements of the observations at different orbital phases, we find no conclusive evidence of equivalent width variations with orbital phase. In the absence of any significant reduction of the white dwarf's core mass by past nova explosions, its lower limit cooling age is approximately 50 million years.

Sion, Edward M.↗

NASA NTRS1994

The resonance lines of MG2 as diagnostics of the upper solar chromosphere

The resonance lines of singly ionized magnesium, the MgII h&k lines at about 280 nm, are two of the small number of lines in the solar spectrum that are optically thick in the chromospheric part of the solar atmosphere. Potentially these lines contain information on the initial temperature rise that occurs at the top of the photosphere. Unfortunately, few good observations of the lines exist due to their wavelength near 280 nm the ultraviolet. However, a fair number of observations (on the order of 200) are available from the data base of the UltraViolet Polarimeter and Spectrometer (UVSP) instrument that flew on board of NASA's Solar Maximum Mission (SMM) satellite. In addition, this data base contains a number of spectra that include the Mg I resonance line at (lambda)285.2nm, just longward of the h&k lines. The neutral magnesium line is not as strong as its ionic counterparts and samples slightly lower parts of the atmosphere. Its width is a sensitive diagnostic of the ionization balance between neutral and singly ionized magnesium, which determines the opacity scale (and formation height) of other diagnostically important MgI lines like the 457.1 nm intercombination line, the magnesium b lines and the infrared MgI emission lines near 12 microns. Analysis of the observed line profiles shows that it is necessary to include the effects of partial frequency redistribution (PRD) in the formation of the line as in the case of the h&k lines. This implies that the core of the line is very sensitive to the way scattering is treated in the modeling of the line, and in turn this allows us to separate the uncertain effects in the atomic data (viz. the Van der Waals broadening) from the uncertainties in the underlying atmospheric model. The main objective of this research was to compare observed spectra of the magnesium resonance lines against theoretical line profiles calculated from recent models of the solar atmosphere by Fontenla et al., hereafter called FAL. These models extend earlier solar models by Avrett et al. and provide yet a better match between observed and calculated spectra, in particular of the hydrogen Lyman line, by including the effects of ambipolar diffusion of hydrogen and helium in the mass and energy transport equations for the chromosphere-corona transition region. Although the transition region models can be built self-consistently (without additional observational input) once the proper boundary conditions are given at the top of the chromosphere, there are uncertainties in the models precisely because these boundary conditions are not well known. With the analysis of UVSP magnesium observations we strive to constrain these uncertainties.

Avrett, Eugene H.↗

NASA NTRS1999

Carbon chain abundance in the diffuse interstellar medium

Thanks to the mid-IR sensitivities of the ISO and IRTS orbiting spectrometers it is now possible to search the diffuse interstellar medium for heretofore inaccessible molecular emission. In view of the recent strong case for the presence of C(7-) (Kirkwood et al. 1998, Tulej et al. 1998),and the fact that carbon chains possess prominent infrared active modes in a very clean portion of the interstellar spectrum, we have analyzed the IRTS spectrum of the diffuse interstellar medium for the infrared signatures of these species. Theoretical and experimental infrared band frequencies and absolute intensities of many different carbon chain species are presented. These include cyanopolyynes, neutral and anionic linear carbon molecules, and neutral and ionized, even-numbered, hydrogenated carbon chains. We show that--as a family--these species have abundances in the diffuse ISM on the order of 10(-10) with respect to hydrogen, values consistent with their abundances in dense molecular clouds. Assuming an average length of 10 C atoms per C-chain implies that roughly a millionth of the cosmically available carbon is in the form of carbon chains and that carbon chains can account for a few percent of the visible to near-IR diffuse interstellar band (DIB) total equivalent width (not DIB number).

Carbon/analysis/chemistry↗

DOE OSTI2021

Evaluation of gamma-ray transmission through rectangular collimator slits for application in nuclear fuel spectrometry

Gamma-ray spectrometry is widely applied in several science fields, and in particular in non-destructive gamma scanning and gamma emission tomography of irradiated nuclear fuel. Usually, a collimator is used in the experimental setup, to selectively interrogate a region of interest in the fuel. For the optimization of instrument design, as well as for planning measurement campaigns, predictive models for the transmitted gamma-ray intensity through the collimator are needed. Commonly, Monte Carlo Radiation Transport tools are used for accurate prediction of gamma-ray transport, however, the long computation time requirements when used in low-efficiency experimental setups present challenges. Here, the full-energy peak intensity transmitted through a rectangular collimator slit was examined. A uniform planar surface source emitting isotropically was considered, and the rate of photons reaching an ideal counter plane on the opposite side of the collimator was evaluated by analytical integration. To find a closed-form primitive function, some idealizations were required, and thereby parametric models were obtained for the optical field of view, dependent on slit dimensions (length, height and width) and source-to-collimator distance. For contributions from outside the optical field of view, where a closed-form expression cannot be found, fast numerical integral methods were instead used. The results were validated using the Monte Carlo code MCNP6 and show an agreement within three percent for the numerical method. For the analytical method, deviations up to tens of percent were obtained, which is deemed to still be sufficient for instrument design and measurement planning, where often the order of magnitude of the count rate is not a priori known. The method is planned for use in iterative optimization routines in the design of Gamma Emission Tomography devices, as well as for the prediction of gamma spectra obtained in the planning of fuel inspections. An application of the proposed method was demonstrated in spectrum prediction for a short cooling-time fuel rod test from the Halden reactor.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

DOE OSTI2020

High-resolution infrared spectroscopy of jet cooled CH 2 Br radicals: The symmetric CH stretch manifold and absence of nuclear spin cooling

Direct laser absorption of a slit supersonic discharge expansion provides the first high-resolution spectroscopic results on the symmetric CH stretch excitation (ν 1 ) of the bromomethyl (CH 2 Br) radical in the ground electronic state. Narrowband (<1 MHz) mid-infrared radiation is produced by difference-frequency generation of two visible laser beams, with the open shell halohydrocarbon radical generated by electron dissociative attachment of CH 2 Br 2 in a discharge and rapidly cooled to T rot = 18 ± 1 K in the subsequent slit-jet supersonic expansion. A rovibrational structure in the radical spectrum is fully resolved, as well as additional splittings due to spin-rotation effects and 79 Br/ 81 Br isotopologues in natural abundance. Spectroscopic constants and band origins are determined by fitting the transition frequencies to a non-rigid Watson Hamiltonian, yielding results consistent with a vibrationally averaged planar radical and an unpaired electron in the out-of-plane p π orbital. Additionally, extensive satellite band structure from a vibrational hot band is observed and analyzed. The hot band data is compared to CFOUR/VPT2 (CCSD(T)cc-pVQZ) ab initio anharmonic predictions of the vibration rotation alpha matrix, which permits unambiguous assignment to CH 2 symmetric-stretch excitation built on the singly excited CH 2 out-of-plane bending mode (ν 1 + ν 4 ← ν 4 ). Longitudinal cooling of the Doppler width in the slit-jet expansion geometry also reveals partially resolved hyperfine structure on transitions out of the lowest angular momentum states in excellent agreement with predictions based on microwave studies. High level ab initio MOLPRO calculations [CCSD(T)-f12b/VnZ-f12 (n = 3, 4, CBS)] are also performed with explicitly correlated f12 electron methods for the out-of-plane CH 2 bending mode over the halogen series CH 2 X (X = F, Cl, Br, I), which clearly reveals a non-planar geometry for X = F (with a ΔE ≈ 0.3 kcal/mol barrier) and yet planar equilibrium geometries for X = Cl, Br, and I. Finally, a detailed Boltzmann analysis of the transition intensities provides support for negligible collisional equilibration of the entangled H atom nuclear spin states on the few hundred microsecond time scale and high collision densities of a slit supersonic expansion.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2007

The Suzaku Observation of the Nucleus of the Radio Loud Active Galaxy Centaurus A: Constraints on Abundances in the Accreting Material

A Suzaku observation of the nucleus of the radio-loud AGN Centaurus A in 2005 has yielded a broadband spectrum spanning 0.3 to 250 keV. The hard X-rays are fit by two power laws, absorbed by columns of 1.5 and 7 x 10(exp 23) per square centimeter. The dual power-laws are consistent with previous suggestions that the powerlaw components are X-ray emission from the sub-pc VLBI jet and from Bondi accretion at the core, or are consistent with a partial covering interpretation. The soft band is dominated by thermal emission from the diffuse plasma and is fit well by a two-temperature VAPEC model, plus a third power-law component to account for scattered nuclear emission, kpc-scale jet emission, and emission from X-ray Binaries and other point sources. Narrow fluorescent emission lines from Fe, Si, S, Ar, Ca and Ni are detected. The width of the Fe Ka line yields a 200 light-day lower limit on the distance from the black hole to the line-emitting gas. K-shell absorption edges due to Fe, Ca, and S are detected. Elemental abundances are constrained via the fluorescent lines strengths, absorption edge depths and the diffuse plasma emission lines. The high metallicity ([Fe/H]=+0.l) of the circumnuclear material compared to that in the metal-poor outer halo suggests that the accreting material could not have originated in the outer halo unless enrichment by local star formation has occurred. Relative abundances are consistent with enrichment from Type II and Ia supernovae.

Markowitz, A.↗

NASA NTRSDate not supplied

SURFACE EXOSURE TIMESCALES OF APOLLO CORE SAMPLE 73002 SPACE WEATHERED GRAINS

Introduction: Space weathering causes the surface regolith on airless bodies like the Moon to be morphologically, microstructurally, and chemically altered due to micrometeoroid bombardment and solar wind irradiation[1]. These processes produce a multitude of microstructural and chemical changes in individual soil grains that accumulate as grains are exposed on the surface over time. One microstructural feature produced by exposure to the solar wind is the development of ion-damaged rims on regolith grains via H+ and He+ ion irradiation. Also present are solar energetic particle (SEP) tracks, which are nanoscale lineations of ionization damage within grain interiors formed by high energy solar flare ions(primarily Fe group nuclei) which penetrate millimeters below the surface [2]. Recent work has confirmed that the thickness of solar wind-damaged amorphous rims on anorthite grains, nanocrystalline rims on olivine grains, and their respective SEP track densities are correlated with their surface exposure ages [3].Core sample 73002, recently released under the Apollo Next Generation Sample Analysis (ANGSA) Program, has provided an opportunity to study material collected from the light mantle formation during Apollo 17. The light mantle is thought to have been deposited via a landslide originating from the neighboring South Massif [4]. Spectral profiles and ferromagnetic resonance measurements of bulk soils sampled at cm-intervals from 73002 indicate the existence of mature regolith extending ~8 cm below the surface, suggesting the presence of an in-situ reworking zone in the core[5,6].Here we present the distribution of SEP track densities, solar wind damaged rim widths, and the corresponding surface exposure ages of grains residing in the proposed in-situ reworking zone of core 73002. Methods: Bulk samples of regolith from the first eight intervals and every following fourth interval down the core (dissection Pass 2) were delivered to Purdue University as <45 μm size fractions. The first eight0.5 cm intervals, representing the top 4cmof regolith, were individually dry sieved to a<20 μm size fraction, and grains were prepared by ultramicrotomy for analysis in the scanning transmission electron microscope (STEM). Bright field (BF) and dark field (DF) STEM images of solar flare tracks and solar wind damaged rims were acquired on a JEOL 2500SE TEM, equipped with a 60 mm2ultra-thin window silicon drift energy dispersive X-ray (EDX) spectrometer at NASA John-son Space Center. Grain compositions were determined by EDX compositional spectrum imaging. SEP track densities and amorphous rim thicknesses were measured on BF and DF images. Results: The fraction of grains with discernable space weathering features decreased with depth, with 100% in the first interval exhibiting space weathering features as opposed to ~60% in Interval 8.BF and DF STEM images show splash-melt and vapor deposited rims on outermost grain margins with embedded Fe-bearing nanoparticles ranging in size up to ~10 nm in diameter. Images also show solar-wind damaged rims below the vapor deposits, and SEP tracks present in grain interiors. The rim thicknesses and SEP track densities were determined using the methods of [3] for 54grains spanning the top 4 cm. ~80% of the grains analyzed were anorthite and ~20% were olivine. The track production rate from[3] was used to estimate the surface exposure times of the grains in this study. The majority of exposure times are in the 1 -5 MY range for all intervals. The lowest value was 3.8x 10¬5years in Interval 8and the highest value was1.1x 107years in Interval 6. Grains with the highest solar wind damage rim thicknesses and SEP track densities are found in Interval 6.The highest rim thickness and track density observed for anorthiteis126.5 nm and4.7 x 1011tracks/cm2, while for olivine they are 98.6 nm and 1.83 x 1011tracks/cm2, respectively. Discussion: Intervals from the top 4 cm of 73002 show similar SEP track density and solar wind damaged rim thickness distributions. Spectral and ferromagnetic resonance measurements of 73002 indicate an in-situ reworking zone up to~8 cm below the surface[5,6].The depth analyzed in this work is within the core’s uppermost in-situ reworking zone and may serve as an explanation to the homogenous distribution of exposure ages. The decreasing abundance of space weathered features with depth is consistent with regolith mixing models showing an exponential decay in regolith maturity with depth over time[7].A maximum surface exposure age determined via SEP track density is approximately 10million years. This timescale is consistent with the lower estimate of surface exposure ages of the light mantle determined in previous studies, which can range from 10s to over 100 Ma [4].It also falls within the core regolith reworking development timescale of ~17 Ma [5,6]. Additional analysis will be performed for a further seven intervals in 73002.

J A McFadden↗

NASA NTRS1975

Interstellar absorption lines toward gamma Arae

The available data on interstellar absorption lines in the spectrum of gamma Ara observed from the ground and with the Copernicus telescope have been analyzed to give column densities of various ion stages of H, C, N, O, Na, Mg, Si, P, S, Ar, Ca, Mn, and Fe. The element abundances with respect to H nuclei in H I regions are similar to the values for zeta Oph, with depletions relative to the sun tending to increase with increasing condensation temperature. For example, toward gamma Ara, Fe is depleted by a factor of 50; Mg, Si, and Mn by about 10; and S, P, and N little or none. Interstellar Si IV and probably S IV appear stronger than in most other stars, but still their low ratios to Si III and S III suggest that soft X-rays and low-energy cosmic rays are not important sources of ionization. The width of the O VI lines and the absence of N V have been interpreted as evidence for a collisionally ionized region with a temperature between 300,000 and 700,000 K containing at least 0.0004 of the total interstellar column density.

Morton, D. C.↗

NASA NTRS1995

Mass loss in the interacting semi-detached binary delta librae

The interacting Algol-type binary Delta Librae (AOV + G: V) has been observed with the International Ultraviolet Explorer (IUE) satellite. More than fifty high resolution spectra in the far-ultraviolet and mid-ultraviolet spectrum have been analyzed in order to model the mass flow in the Delta Librae system. The resonance lines of Si IV and C IV are present in absorption and vary in strength both secularly and with phase. The radial velocities of the Si IV and C IV absorption lines generally follow the orbital motion of the primary star but deviate by typically a few tens of kilometers per second in the direction of the observer. The presence of Si IV and C IV features indicates the existence of a region considerably hotter than the normal AOV photosphere and, since these lines are present at all phases, this region must be fairly extensive. These results are interpreted in terms of a 'pseudo-photosphere' around the equatorial region of the AOV star, created by matter being accreted from the G-type companion. The widths of the Si IV and C IV absorption features imply that some of the matter lost by the G-star leaves the system entirely.

Mccluskey, George E., Jr.↗

NASA NTRS2006

Comprehensive Analysis of RXTE Data from Cyg X-1. Spectral Index-Quasi-Periodic Oscillation Frequency-Luminosity Correlations

We present timing and spectral analysis of approx. 2.2 Ms of Rossi X-ray Time Explorer (RXTE) archival data from Cyg X-1. Using the generic Comptonization model we reveal that the spectrum of Cyg X-1 consists of three components: a thermal seed photon spectrum, a Comptonized part of the seed photon spectrum and the iron line. We find a strong correlation between 0.1-20 Hz frequencies of quasiperiodic oscillations (QPOs) and the spectral power-law index. Presence of two spectral phases (states) are clearly seen in the data when the spectral indices saturate at low and high values of QPO frequencies. This saturation effect was discovered earlier in a number of black hole candidate (BHC) sources and now we strongly confirm this phenomenon in Cyg X-1. In the soft state this index- QPO frequency correlation shows a saturation of the photon index Gamma approx. 2.1 at high values of the low frequency upsilon(sub L). The saturation level of Gamma approx. 2.1 is the lowest value found yet in BHCs. The bolometric luminosity does not show clear correlation with the index. We also show that Fe K(sub alpha) emission line strength (equivalent width, EW) correlates with the QPO frequency. EW increases from 200 eV in the low/hard state to 1.5 keV in the high/soft state. The revealed observational correlations allow us to propose a scenario for the spectral transition and iron line formation which occur in BHC sources. We also present the spectral state (the power-law index) evolution for eight years of Cyg X-1 observations by RXTE.

Shaposhnikov, Nickolai↗

NASA NTRS1987

The measurement of precipitation with synthetic aperture radar

The radar equation for the measurement of precipitation by SAR is identical to that for a conventional radar. The achievable synthetic beamwidth, beta(s), is proportional to sigma(v)/U, the ratio of the spread of the precipitation Doppler spectrum to the platform velocity. Thus, a small beta(s) can be achieved only with small sigma(v) or from a fast-moving vehicle such as a spacecraft. Also, the along-track resolution is variable with sigma(v) and is not known. Nevertheless, the reflectivity is measured correctly. A possible approach to the measurement of sigma(v) is noted. The C-band SAR proposed for the SIR-C mission is capable of detecting a rain rate as small as 0.5 mm/h at nadir when the beam is filled. Because the cross-track beam dimension is about 20 km wide, the use of a high-resolution microwave radiometer to correct for the unfilled beam and the variation of gain across it is suggested. Alternatively, the cross-track dimension should be decreased to no more than about 5 km by increasing the antenna width and/or decreasing the wavelength.

Atlas, David↗

DOE OSTI2020

Onset of interfacial waves in the terahertz spectrum of a nanoparticle suspension

We used inelastic x-ray scattering to gain insight into the complex terahertz dynamics of a diluted Au-nanoparticle suspension in glycerol. Here, we observe that, albeit sparse, Au nanoparticles leave clear signatures on the dynamic response of the system, the main one being an additional mode propagating at the nanoparticle-glycerol interface. A Bayesian inferential analysis of the line shape reveals that such a mode, at variance with conventional acoustic modes, keeps a hydrodynamiclike behavior well beyond the continuous limit and down to subnanometer distances.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS2008

Single-Mode WGM Resonators Fabricated by Diamond Turning

A diamond turning process has made possible a significant advance in the art of whispering-gallery-mode (WGM) optical resonators. By use of this process, it is possible to fashion crystalline materials into WGM resonators that have ultrahigh resonance quality factors (high Q values), are compact (ranging in size from millimeters down to tens of microns), and support single electromagnetic modes. This development combines and extends the developments reported in "Few- Mode Whispering-Gallery-Mode Resonators" (NPO-41256), NASA Tech Briefs, Vol. 30, No. 1 (January 2006), page 16a and "Fabrication of Submillimeter Axisymmetric Optical Components" (NPO-42056), NASA Tech Briefs, Vol. 31, No. 5 (May 2007), page 10a. To recapitulate from the first cited prior article: A WGM resonator of this special type consists of a rod, made of a suitable transparent material, from which protrudes a thin circumferential belt of the same material. The belt is integral with the rest of the rod and acts as a circumferential waveguide. If the depth and width of the belt are made appropriately small, then the belt acts as though it were the core of a single-mode optical fiber: the belt and the rod material adjacent to it support a single, circumferentially propagating mode or family of modes. To recapitulate from the second cited prior article: A major step in the fabrication of a WGM resonator of this special type is diamond turning or computer numerically controlled machining of a rod of a suitable transparent crystalline material on an ultrahigh-precision lathe. During the rotation of a spindle in which the rod is mounted, a diamond tool is used to cut the rod. A computer program is used to control stepping motors that move the diamond tool, thereby controlling the shape cut by the tool. Because the shape can be controlled via software, it is possible to choose a shape designed to optimize a resonator spectrum, including, if desired, to limit the resonator to supporting a single mode. After diamond turning, a resonator can be polished to increase its Q. By virtue of its largely automated, computer-controlled nature, the process is suitable for mass production of nominally identical single-mode WGM resonators. In a demonstration of the capabilities afforded by this development, a number of WGM resonators of various designs were fabricated side by side on the surface of a single CaF2 rod (see figure).

Grudinin, Ivan↗

NASA NTRS2004

Discovery of the Neutron Star Spin Frequency in EXO 0748-676

We report the results of a search for burst oscillations during thermonuclear X-ray bursts from the low mass X-ray binary (LMXB) EXO 0748-676. With the proportional counter array (PCA) onboard the Rossi X-ray Timing Explorer (RXTE) we have detected a 45 Hz oscillation in the average power spectrum of 38 thermonuclear X-ray bursts from this source. We computed power spectra with 1 Hz frequency resolution for both the rising and decaying portions of 38 X-ray bursts from the public RXTE archive. We averaged the 1 Hz power spectra and detected a significant signal at 45 Hz in the decaying phases of the bursts. The signal is detected at a significance level of 4 x 10 (exp -8) similar signal was detected in the rising intervals. The oscillation peak is unresolved at 1 Hz frequency resolution, indicating an oscillation quality factor, Q = nu (sub 0)/Delta nu (sub fwhm) greater than 45, and the average signal amplitude is approximately equal to 3% (rms) The detection of 45 Hz burst oscillations from EXO 0748-676 provides compelling evidence that this is the neutron star spin frequency in this system. We use the inferred spin frequency to model the widths of absorption lines from the neutron star surface and show that the widths of the absorption lines from EXO 0748-676 recently reported by Cottam et al. are consistent with a 45 Hz spin frequency as long as the neutron star radius is in the range from about 9.5 - 15 km. With a known spin frequency, precise modelling of the line profiles from EXO 0748-676 holds great promise for constraining the dense matter equation of state.

Villarreal, Adam R.↗

NASA NTRS2008

Spectral Analysis of the Accretion Flow in NGC 1052 with Suzaku

We present an analysis of the 101 ks, 2007 Suzaku spectrum of the LINER galaxy NGC 1052. The 0:3..10 keV continuum is well-modeled by a power-law continuum modified by Galactic and intrinsic absorption, and exhibits a soft, thermal emission component below 1 keV. Both a narrow core and a broader component of Fe-Ka emission are robustly detected at 6:4 keV. While the narrow line is consistent with an origin in material distant from the black hole, the broad line is best fit empirically by a model that describes fluorescent emission from the inner accretion disk around a rapidly rotating black hole. We find no direct evidence for Comptonized reflection of the hard X-ray source by the disk above 10 keV, however, which casts doubt on the hypothesis that the broad iron line is produced in a standard accretion disk. We explore other possible scenarios for producing this spectral feature and conclude that the high equivalent width and full width half maximum velocity of the broad iron line (v greater than or equals 0:37c) necessitate an origin within d approx. 8r(sub g) of the hard X-ray source. Based on the confirmed presence of a strong radio jet in this source, the broad iron line may be produced in dense plasma at the base of the jet, implying that emission mechanisms in the central-most portions of active galactic nuclei are more complex than previously thought.

Brenneman, L. W.↗

NASA NTRSDate not supplied

Classifying Agnostic Biosignatures using Raman, VNIR, and Elemental Data

How can we use our current wealth of terrestrial data, encompassing biogenic and abiogenic systems, to determine the distinguishing properties of life? SCOBI (Statistical Classification of Biosignature Information) uses machine learning techniques to algorithmically identify combinations of measurements that are “indicative of life”. A set of ~1000 observations, comprising elemental abundance, isotopic fractionation, VNIR reflectance, and (in progress) Raman spectra, have been assembled from existing literature and databases. The observations cover systems classified as “indicative alive” (e.g., cells, vegetation), “indicative non-alive” (e.g., fossils, teeth), “mixed indicative” (e.g., soil, pond water), or “non-indicative” (e.g., rocks, meteorites). VNIR data was preprocessed by linear interpolation from 400-2100 nm and smoothed with a Savitzky-Golay filter. To limit the amount of Earth-biochemistry-specific (non-agnostic) information included, the first five spectral features extracted were number of peaks, number of troughs, mean reflectance, mean peak width, and broadest peak width. To help further emphasize agnostic biosignatures, Earth-specific features such as chlorophylls have been manually flagged so that feature importance with and without them can be compared. Classifiers including k-nearest neighbors (KNN), Gaussian Naïve Bayes (GNB), logistic regression (LR), random forest (RF), and support vector machine (SVM) were implemented, as was a combination voting classifier. Performance metrics included false positive rates, false negative rates, and AUC with 50-50 test/train splits (Monte Carlo simulations). Key takeaways from this stage, prior to the inclusion of Raman spectra, are (1) the overall success rate of 0.933 AUC was most heavily influenced by the elemental abundance data; and (2) VNIR reflectance had the lowest classification performance with 0.52 AUC (58% of objects correctly classified). The next steps are to complete integration of Raman spectral data and to improve the approach to pre-processing and feature extraction for both types of spectral data, such as automated baseline removal, whole spectrum matching, and dimensionality reduction.

Biosignatures↗

DOE OSTI2022

A method to predict texture effect on ion beam channeling analysis of polycrystals and the application to study the mosaic spreading effect in highly oriented pyrolytic graphite

We propose a method to convert the channeling Rutherford backscattering spectrum yield map of a single crystal to a polycrystal through a matrix rotation technique. The rotation matrix is determined by the deviation of the crystal axial direction from the original z axis. The final yield map is created after averaging the rotated yields using the texture function as the weight factor. For highly oriented pyrolytic graphite (HOPG) exhibiting mosaic spread, the method leads to a Gaussian kernel averaging of the map obtained from a single crystal. The yield map of a single crystal is obtained by a simulation of ion trajectories in a potential field described by Moliere screened Coulomb potentials. Yield maps are calculated under various σ values (standard deviations of mosaic spread). The simulated results are compared with experimental results obtained using 1.2 MeV alpha particle. σ is extracted through the best fitting, demonstrating that the method can be used to obtain texture details. The effects of mosaic spread on minimum yield χ min and the half-width at half maximum of angular scans ψ ½ are systematically modeled and compared with previous theoretical equations. The study also shows that previous theoretical equations are valid only at small σ values. The proposed method can be applied to any type of polycrystal and is not limited to HOPG. It provides near-surface mosaic spread and crystallography information with a longitudinal depth resolution of tens of nanometers and is not influenced by grain shapes.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

NASA NTRS1993

The effects of flaring in H1 on the observed velocity field of spirals

This work is part of a larger project in which we want to determine the shapes of dark halos around spiral galaxies. Rotation curves 'probe' the halos in the radial direction. The derived halo mass distributions are badly constrained. The local halo densities fully determine the width of the gas distribution once the gaseous velocity dispersion is known. There where the dark halo dominates, the Full Width at Half Maximum (FWHM) of the gas layer is proportional to (rho(sub halo))(exp -0.5). Therefore, measuring the width of the gas layer probes the halo density directly. In a dark halo dominated potential, the FWHM of the gas layer increases linearly with radius. This increase of the thickness of the gas layer is known as 'flaring'. Flaring has been found inside the stellar disk. Beyond the edge of the stellar disk, the analysis is hampered by the onset of the warp. Since the galaxy we are studying, NGC 4244, has no significant warp we hope to extend Rupen's analysis into the halo dominated regime. The usual method to derive a rotation curve from an observed 2-dimensional velocity field is to assume that the hydrogen is distributed in infinitely thin rings. For a flaring disk, any line of sight samples many different parts of the galaxy, all having different densities and projected velocities. In order to fully exploit the information contained in the gas distribution, we have to understand the effects of flaring on the observables (the spectrum for each point of the galaxy). We have investigated the effects of a flaring disk on the observed velocity field. It is obvious that the largest (kinematical) effects are to be expected for low density dark halos at large inclinations. For low mass galaxies we expect that the flaring of the H1 layer will have a major effect on the observed kinematics. For galaxy with intermediate V(sub max,halo) seen at intermediate inclinations, one overestimates Vsin(i) typically by a few percent. For more massive galaxies, any effects arising from the flaring H1 layer are minuscule unless the inclination is not too far from 90 deg.

Olling, Rob↗