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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 703 records · Page 39

All sources NASA NTRS DOE OSTI

NASA NTRS1980

The low energy plasma in the Jovian magnetosphere

Measurements below 6 keV from the plasma science experiment on the Voyager spacecraft show that positive ions with temperatures as low as 30 eV to several keV are observed to distances at least as great as 40 Jupiter radii in the dayside Jovian magnetosphere. When velocity determinations are possible between 10 and 40 Jupiter radii, the plasma velocity component along the rigid corotation direction is found to be consistently less than the full corotation speed. Positive ion measurements above 28 keV from the low energy charged particle experiment on Voyager demonstrate the existence of positive ions with temperatures of 20-30 keV at all distances greater than 30 Jupiter radii. Taken together, these observations suggest that the low energy plasma population from 30 to at least 40 Jupiter radii frequently contains both a cold and a hot component. A two-component plasma of this nature may indicate different sources, acceleration mechanisms, or time histories for the disparate components. It may also be indicative of a single acceleration mechanism which is highly energy dependent.

Belcher, J. W.↗

NASA NTRS1975

Micrometeoroid composition analyzer

Technique has been developed to detect moving charged particles and to determine their positions and/or their velocity vectors, relative to three mutually orthogonal axes, without particle impact or any elements of detector and without changing particle charge or motion.

Auer, S. O.↗

DOE OSTI2022

Acid-Base Equilibrium and Dielectric Environment Regulate Charge in Supramolecular Nanofibers

Peptide amphiphiles are a class of molecules that can self-assemble into a variety of supramolecular structures, including high-aspect-ratio nanofibers. It is challenging to model and predict the charges in these supramolecular nanofibers because the ionization state of the peptides are not fixed but liable to change due to the acid-base equilibrium that is coupled to the structural organization of the peptide amphiphile molecules. Here, we have developed a theoretical model to describe and predict the amount of charge found on self-assembled peptide amphiphiles as a function of pH and ion concentration. In particular, we computed the amount of charge of peptide amphiphiles nanofibers with the sequence C 16 − V 2 A 2 E 2 . In our theoretical formulation, we consider charge regulation of the carboxylic acid groups, which involves the acid-base chemical equilibrium of the glutamic acid residues and the possibility of ion condensation. The charge regulation is coupled with the local dielectric environment by allowing for a varying dielectric constant that also includes a position-dependent electrostatic solvation energy for the charged species. We find that the charges on the glutamic acid residues of the peptide amphiphile nanofiber are much lower than the same functional group in aqueous solution. There is a strong coupling between the charging via the acid-base equilibrium and the local dielectric environment. Our model predicts a much lower degree of deprotonation for a position-dependent relative dielectric constant compared to a constant dielectric background. Furthermore, the shape and size of the electrostatic potential as well as the counterion distribution are quantitatively and qualitatively different. These results indicate that an accurate model of peptide amphiphile self-assembly must take into account charge regulation of acidic groups through acid–base equilibria and ion condensation, as well as coupling to the local dielectric environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1987

Optical tracking using charge-coupled devices

The extraction of precise positional information from CCD images of point-source and extended optical targets is considered, and three examples of CCD optical trackers for space-based operation are described. For ideal point sources, a centerfinding accuracy of 1/100 pixel and a measuremet jitter of less than 1/250 pixel have been obtained using thinned, backside-illuminated devices. Tracker accuracy is shown to be limited by small variation in the optical image shape. Techniques for tracking, and methods for searching the entire field for the desired targets, are also discussed.

Stanton, Richard H.↗

NASA NTRS2005

Technical Consultation of the Hubble Space Telescope (HST) Nickel Hydrogen (NiH2) Battery Charge Capacity Prediction

The purpose of the GSFC position paper is to identify critical HST milestone dates for continued science studies followed by the attachment of a re-entry module or a robotic servicing mission. The paper examines the viability of the HST with respect to the NiH2 continued battery charge capacity. In the course of the assessment, it was recognized that the HST battery thermal control system has an average heat dissipation limitation of 30 W per bay per orbit cycle. This thermal constraint will continue to govern options for battery capacity maintenance. In addition, the HST usage represents the longest exposure ofNiH2 batteries to Low Earth Orbit (LEO) at the current level of Depth of Discharge (DOD). Finally, the current battery life is at the limit predicted by the manufacturer, Eaglepicher. Therefore, given these factors, the potential exists that the HST battery capacities could radically degrade at any point. Given this caveat on any life extrapolations, the conservative model proposed in the GSFC position paper was viewed by the NESC as having several technical assumptions such as limited utilization of flight battery capacity data, the susceptibility of the proposed prediction method to large variations when supplemented with additional information, and the failure to qualitatively or quantitatively assess life prediction sensitivities. The NESC conducted an independent evaluation of the supporting information and assumptions to generate the predictions for battery capacity loss and practicality of on-orbit battery conditioning.

Gentz, Steven J.↗

DOE OSTI2023

Pre-equilibrium evolution of conserved charges with initial conditions in the ICCING Monte Carlo event generator

Heavy-ion collisions can be well described through relativistic viscous hydrodynamics, but questions still remain when hydrodynamics is applicable because the initial state may begin very far from equilibrium. Thus, a pre-equilibrium evolution phase is used to bridge the gap between the initial state and hydrodynamics. KøMPøST is one such pre-equilibrium model that propagates the energy-momentum tensor by decomposing it into the background and fluctuations around that background, whose evolution is captured by Green's functions. We extend this formalism to include conserved charges and calculate the corresponding nonequilibrium Green's functions in the relaxation-time approximation. The ICCING algorithm initializes conserved charges in the initial state by sampling $g$ → $q$$\overline{q}$ splitting probabilities and is, thus, perfectly positioned to implement Green's functions for charge propagation. As a result, we show that this method alters the initial-state charge geometries and is applicable in central to mid-central collisions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2024

Molecular-scale insights into the electrical double layer at oxide-electrolyte interfaces

The electrical double layer (EDL) at metal oxide-electrolyte interfaces critically affects fundamental processes in water splitting, batteries, and corrosion. However, limitations in the microscopic-level understanding of the EDL have been a major bottleneck in controlling these interfacial processes. Herein, we use ab initio-based machine learning potential simulations incorporating long-range electrostatics to unravel the molecular-scale picture of the EDL at the prototypical anatase TiO 2 -electrolyte interface under various pH conditions. Our large-scale simulations, capable of capturing interfacial water dissociation/recombination reactions and electrolytic proton transport, provide unprecedented insights into the detailed structure of the EDL. Moreover, the larger capacitance of the EDL under basic relative to acidic conditions, originating from the higher affinity of the cations for the oxide surface, is found to give rise to distinct charging mechanisms on negative and positive surfaces. Our results are validated by the agreement between the computed EDL capacitance and experimental data.

Chemical physics↗

DOE OSTI2026

A photochargeable semiconductor for highly efficient dehydrogenative coupling of amines

The development of materials with high photocatalytic efficiency is essential for sustainable chemical transformations. Here, in this work, we introduce photochargeable zinc indium sulfide nanocrystals with notable charge storage capacity, enabling highly efficient photocatalytic dehydrogenative coupling of amines. Combined with a nickel cocatalyst, the nanocrystals deliver diamines and hydrogen at rates exceeding 120 mmol per gram of photocatalyst per hour, with > 95% selectivity and an apparent quantum efficiency of up to 39.4% under ambient conditions. The system exhibits excellent scalability, demonstrated by a reaction on a 20-g scale, and broad versatility in promoting amino acid ester coupling and polymerization reactions with concurrent hydrogen evolution. Mechanistic studies attribute the photocharging capability of zinc indium sulfide nanocrystals to in situ-generated trap states such as sulfur vacancies, which extend hydrogen production into the dark catalytic cycle and enhance the overall charge utilization efficiency. These findings position photochargeable semiconductors as promising platforms for a wide range of photocatalytic applications.

nanoscale devices↗

DOE OSTI2022

Implementing the donor–acceptor approach in electronically conducting copolymers via electropolymerization

Electropolymerization has become a convenient method for synthesizing and characterizing complex organic copolymers having intrinsic electronic conductivity, including the donor (D)–acceptor (A) class of electronically conducting polymers (ECPs). This review begins with an introduction to the electrosynthesis of common second-generation ECPs. The information obtainable from electroanalytical studies, charge carriers such as polarons (positive and negative) and bipolarons (positive and negative) and doping will be discussed. The evolutionary chain of ECPs is then presented. ECPs comprising electron-rich D and electron-deficient A moieties have been shown to possess intrinsic electronic conductivity and unique optical and electronic properties. They are third generation ECPs and electropolymerization of mixtures of D and A leads to stoichiometrically controlled block copolymers. These D–A type ECPs are discussed on the basis of selected representative materials. Since the discovery of electropolymerization as a powerful tool to synthesize copolymers of conjugated monomers with a pre-determined ratio of D and A repeat units present in the polymer, the field of D–A type ECPs has grown considerably and the literature available since 2004 to 2021 is summarized and tabulated. Electronic and optical properties of the materials determined by computational chemistry are presented. The data obtained from electrochemical and optical methods are compared with those obtained from computational methods and reasons for discrepancies are given. The literature on the concept of electropolymerization extended to synthesizing triblock and many-block copolymers is reviewed. Finally, applications of D–A polymers in optoelectronic devices (organic solar cells and field-effect transistors) and in bio-imaging are explained quoting appropriate examples.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

Hyperdiffusion of dust particles in a turbulent tokamak plasma

In this work, the effect of plasma turbulence on the trajectories of dust particles is investigated for the first time. The dynamics of dust particles is computed using the ad hoc developed Dust Injection Simulator code, using a 3D turbulent plasma background computed with the TOKAM3X code. As a result, the evolution of the particle trajectories is governed by the ion drag force, and the shape of the trajectory is set by the Stokes number St∝a d /n 0 , with a d the dust radius and n 0 the density at the separatrix. The plasma turbulence is observed to scatter the dust particles, exhibiting a hyperdiffusive regime in all cases. The amplitude of the turbulent spread of the trajectories Δr 2 is shown to depend on the ratio Ku/St, with Ku∝u rms the Kubo number and urms the fluctuation level of the plasma flow. These results are compared with a simple analytical model, predicting Δr 2 ∝(Ku/St) 2 t 3 , or Δr 2 ∝(u rms n 0 /a d ) 2 t 3 . As the dust is heated by the plasma fluxes, thermionic emission sets the dust charge, originally negative, to slightly positive values. This results in a substantial reduction of the ion drag force through the suppression of its Coulomb scattering component. The dust grain inertia is then no longer negligible and drives the transition from a hyperdiffusive regime toward a ballistic one.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2022

Performance in beam tests of irradiated Low Gain Avalanche Detectors for the ATLAS High Granularity Timing Detector

The High Granularity Timing Detector (HGTD) will be installed in the ATLAS detector to mitigate pile-up effects during the High Luminosity (HL) upgrade of the Large Hadron Collider (LHC) at CERN. The design of the HGTD is based on the use of Low Gain Avalanche Detectors (LGADs), with an active thickness of 50 μm, that allow to measure with high-precision the time of arrival of particles. The HGTD will improve the particle-vertex assignment by measuring the track time with a resolution ranging from approximately 30 ps at the beginning of the HL-LHC operations to 50 ps at the end. Performances of several unirradiated, as well as neutron- and proton-irradiated, LGAD sensors from different vendors have been measured in beam test campaigns during the years 2018 and 2019 at CERN SPS and DESY. This paper presents the results obtained with data recorded by an oscilloscope synchronized with a beam telescope which provides particle position information within a resolution of a few μm. Collected charge, time resolution and hit efficiency are presented. In addition to these properties, the charge uniformity is also studied as a function of the position of the incident particle inside the sensor pad.

47 OTHER INSTRUMENTATION↗

DOE OSTI2023

A Novel Honeycomb-DD Multi Coil Design for Wireless Power Transfer Systems

Wireless power transfer (WPT) technology has received significant attention recently as an alternative charging method for batteries in a wide range of power levels. In the literature, many types of coil structures have been well-studied. Honeycomb coil arrays, which have been used mostly for low-power applications, have not been well-studied for high-power-level applications. In this paper, a novel honeycomb-DD coil design is proposed for high-power wireless battery charging systems. The proposed coil design with step by step design process is given and Finite Element Analysis (FEA) was performed to observe the full performance characteristics of the system for a 100 kW system. In addition, the misalignment tolerance of the proposed system was observed by shifting the secondary side charging pad at different misalignment positions, and the electromagnetic compatibility to the standards was investigated. The core and strand losses were obtained. The results show that the honeycomb coil array provides high coupling coefficient and better misalignment tolerance, making it a potential coil topology for WPT applications.

Aydin, Emrullah↗

DOE OSTI2021

Hyperdiffusion of dust particles in a turbulent tokamak plasma

The effect of plasma turbulence on the trajectories of dust particles is investigated for the first time. The dynamics of dust particles is computed using the ad-hoc developed Dust Injection Simulator code, using a 3D turbulent plasma background computed with the TOKAM3X code. As a result, the evolution of the particle trajectories is governed by the ion drag force, and the shape of the trajectory is set by the Stokes number $St\propto a_d/n_0$, with $a_d$ the dust radius and $n_0$ the density at the separatrix. The plasma turbulence is observed to scatter the dust particles, exhibiting a hyperdiffusive regime in all cases. The amplitude of the turbulent spread of the trajectories $\Delta r^2$ is shown to depend on the ratio $Ku/St$, with $Ku\propto u_{rms}$ the Kubo number and $u_{rms}$ the fluctuation level of the plasma flow. These results are compared with a simple analytical model, predicting $\Delta r^2\propto (Ku/St)^2t^3$, or $\Delta r^2\propto (u_{rms}n_0/a_d)^2t^3$. As the dust is heated by the plasma fluxes, thermionic emission sets the dust charge, originally negative, to slightly positive values. This results in a substantial reduction of the ion drag force through the suppression of its Coulomb scattering component. The dust grain inertia is then no longer negligible, and drives the transition from a hyperdiffusive regime towards a ballistic one.

dust↗

DOE OSTI2021

Comments on Brane Recombination, Finite Flux Vacua, and the Swampland

The Swampland program relies heavily on the conjecture that there can only be a finite number of flux vacua (FFV conjecture). Stipulating this FFV conjecture and applying it to some older work in flux vacua construction, we show that within a patch of the landscape the FFV conjecture makes predictions on the nonexistence of otherwise viable nonperturbative objects arising from brane recombination. Future gains in the direct nonperturbative analysis could, therefore, not only test this prediction but also test portions of the Swampland program itself. We also discuss implications of a weaker FFV conjecture on the counting of flux vacua which predicts the positivity of the brane central charge if the EFT analysis is to be qualitatively trusted.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1982

On the dust ring current of Saturn's F-ring

The thin F-ring of Saturn, which is well within the corotating portion of the Saturnian magnetosphere, has been shown by Voyager 1 and 2 observations to be largely composed of small dust grains. Mendis et al. (1982) have argued that with plausible values of the ambient plasma density and temperature near the F-ring, these grains will be charged to around -40 volts. Mendis et al. have shown that within the corotating portion of the magnetosphere such negatively charged grains can move in circular orbits in the equatorial plane. In connection with a relative motion between the negatively charged grains and the corotating positive ions, the F-ring constitutes a ring current. The present investigation has the objective to calculate this current and to show that it would significantly alter the magnetospheric dipole field in the vicinity of the ring. A current of approximately 12,0000 A is obtained. The change in the magnetic field produced by the current could be measured by a spacecraft approaching to within 100 km above or below the F-ring plane.

Hill, J. R.↗

NASA NTRS1989

Jig Aligns Shadow Mask On CCD

Alignment viewed through microscope. Alignment jig positions shadow mask on charge-coupled device (CCD) so metal film deposited on it precisely. Allows CCD package to be inserted and removed without disturbing alignment of mask. Holds CCD packages securely and isolates it electrostatically while providing electrical contact to each of its pins. When alignment jig assembled with CCD, used to move mask under micrometer control.

Matus, Carlos V.↗

NASA NTRS1989

Digital optical spark chambers

The authors constructed and tested a prototype digital readout system for optical spark chambers using a linear, solid-state charge-coupled-device detector array. Position resolution of 0.013 mm (sigma) over a 25-cm field of view has been demonstrated. It is concluded that this technique should permit the construction of economical, lightweight and low-power trajectory hodoscopes for use in cosmic-ray instrumentation on balloons and in spacecraft.

Evenson, Paul↗

NASA NTRS1993

Subpixel Resolution In Depth Perceived Via 3-D Television

Report describes experiment in which two black vertical bars on featureless white background placed near intersection of optical axes of two charge-coupled-device video cameras positioned to give stereoscopic views. Trained human observers found to perceive depths at subpixel resolutions in stereoscopic television images. This finding significant for remote stereoscopic monitoring, expecially during precise maneuvers of remotely controlled manipulators. Also significant for research in processing of visual information by human brain.

Diner, Daniel B.↗