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At least 703 records · Page 39
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Fluorine in meteorites

Microanalysis using a resonant nuclear reaction was used to measure F concentrations in USGS standard rocks and 21 meteorites. The F appears to be a moderately depleted element, but there were significant variations within each sample. Measurements on separated metal phases suggest that about 20% of meteoritic F is in the metal or in a phase closely associated with it. Simultaneous measurements of F, Mg, Na, Al and Si in the nonmagnetic fractions of meteorites suggest plagioclase as a F containing phase.

Allen, R. O., Jr.↗
NASA NTRS1977

Pulsating aurora induced by upper atmospheric barium releases

The paper reports the apparent generation of pulsating aurora by explosive releases of barium vapor near 250 km altitude. This effect occurred only when the explosions were in the path of precipitating electrons associated with the visible aurora. Each explosive charge was a standard 1.5 kg thermite mixture of Ba and CuO with an excess of Ba metal which was vaporized and dispersed by the thermite explosion. Traces of Sr, Na, and Li were added to some of the charges, and monitoring was achieved by ground-based spectrophotometric observations. On March 28, 1976, an increase in emission at 5577 A and at 4278 A was observed in association with the first two bursts, these emissions pulsating with roughly a 10 sec period for approximately 60 to 100 sec after the burst.

Deehr, C.↗
NASA NTRS1976

Origin of the Apollo 17 deep drill coarse-grained layer

A depositional model of the coarse-grained layer of the Apollo 17 deep drill is described which takes into account thermoluminescence, tracks, Na-22 and Al-26 studies. On the basis of this evidence, it appears that the coarse-grained layer was emplaced some 100 m.y. ago associated either with Camelot Crater or the Central Cluster craters; at that time it was capped by some 25 cm of material which were recently (about 2 m.y.) excavated. The resulting depression has partially and gradually filled since.

Crozaz, G.↗
NASA NTRS1977

Io's surface composition based on reflectance spectra of sulfur/salt mixtures and proton-irradiation experiments

Available full-disk reflectance spectra of Io in the range 0.3 to 2.5 microns have been used to determine a surface compositional model for Io that is consistent with Io's other known chemical and physical properties. Results indicate that the surface of Io contains abundant dehydrated salts of high Na, Mg, and Fe(3+) content such as bloedite and ferrous iron sulfate. Experiments were performed studying the irradiation damage effects from low-energy proton bombardment, since Io is immersed in Jupiter's magnetosphere.

Nash, D. B.↗
NASA NTRS1977

Light-activated amino acid transport in Halobacterium halobium envelope vesicles

Vesicles prepared from Halobacterium halobium cell envelopes accumulate amino acids in response to light-induced electrical and chemical gradients. Nineteen of 20 commonly occurring amino acids have been shown to be actively accumulated by these vesicles in response to illumination or in response to an artificially created Na+ gradient. On the basis of shared common carriers the transport systems can be divided into eight classes, each responsible for the transport of one or several amino acids: arginine, lysine, histidine; asparagine, glutamine; alanine, glycine, threonine, serine; leucine, valine, isoleucine, methionine; phenylalanine, tyrosine, tryptophan; aspartate; glutamate; proline. Available evidence suggests that these carriers are symmetrical in that amino acids can be transported equally well in both directions across the vesicle membranes. A tentative working model to account for these observations is presented.

Macdonald, R. E.↗
NASA NTRS1977

Grain disruption in interstellar hydromagnetic shocks

The observed abundance variations of Ca, Fe, Si, and Ti in intermediate-velocity interstellar gas suggest that grains have been disrupted in clouds with velocities as low as 20 to 50 km/s. A simplified hydromagnetic shock model for such clouds is described; the dynamical equations for charged grains in the postshock region are derived, including the collisional drag and 'betatron-acceleration' effect of a magnetic-field gradient; and the fraction of grains destroyed in evaporative collisions with other grains is calculated. It is found that for shocks of 20 to 50 km/s in which the fractional H-ionization remains low, 3-10% of the grain material may be destroyed - sufficient to explain in part the heavy-element depletion pattern in intermediate velocity clouds and the well-known correlation of N(Ca II)/N(Na I) with cloud velocity.

Shull, J. M.↗
NASA NTRS1977

Nebular condensation of moderately volatile elements and their abundances in ordinary chondrites

Two models accounting for the concentrations of moderately volatile elements in ordinary chondrites are discussed. The first relies on an apparent correlation between ordinary chondrite/type-I carbonaceous chondrite abundance ratios and ideal solution-condensation temperatures of such elements as Sn, Cu, Li, Na, and Mn to construct a model in which volatiles are lost as gases before nebular condensation or as finely-divided solids that are incompletely agglomerated, and the condensation/agglomeration efficiency declines as a function of time. The second theory largely discounts this gas-dust diffraction effect and instead proposed condensation on matrix and volatization from chondules and coarse metal grains as mechanisms explaining the apparent existence of three distinct classes of volatile-element abundance in ordinary chondrites.

Wai, C. M.↗
NASA NTRS1977

Differentiation of the matter of the moon

The following facts were uncovered in comparing the basaltic surface rocks of the moon with terrestrial tholeiitic basalts and ordinary chondrites: (1) there is an excess of the so-called refractory chemical elements, including the group of truly refractory elements, the rare earths, U, and Th, in comparison with their content in primitive terrestrial basalts and chondrites; (2) the so-called siderophilic elements have lower contents in the lunar surface rocks than in terrestrial rocks; (3) the low alkali content (Na, K, Rb) in lunar rocks is established; (4) there is a low content of H2O and the ordinary gases CO2, halides, etc.; (5) the low content of metals with high vapor pressure, (In, Tl, etc.) has been established. It is proposed that U and Th were carried from the internal areas to the peripheral rocks of the moon during magmatic activity, i.e., up to 3 billion years ago. This redistribution of U and Th lead to their concentration in surface layers of the moon, and the heat which they generated was lost into surrounding space. The conclusion is then reached that in order to understand processes on the moon, the chondritic model cannot be used.

Vinogradov, A. P.↗
NASA NTRS1977

Formation and composition of the moon

Many of the properties of the Moon, including the enrichment in Ca, Al, Ti, U, Th, Ba, Sr, and the REE and the depletion in Fe, Rb, K, Na, and other volatiles can be understood if the Moon represents a high-temperature condensate from the solar nebula. Thermodynamic calculations show that Ca-, Al-, and Ti-rich compounds condense first in a cooling nebula. The initial high temperature mineralogy is gehlenite, spinel, perovskite, Ca-Al-rich pyroxenes, and anorthite. Inclusions in carbonaceous chondrites such as the Allende meteorite are composed primarily of these minerals and, in addition, are highly enriched in refractories such as REE relative to carbonaceous chondrites. These inclusions can yield basalt and anorthosite in the proportions required to eliminate the europium anomaly, leaving a residual spinel-melilite interior. A deep interior high in Ca-Al does not imply an unacceptable mean density or moment of inertia for the Moon. The inferred high-U content of the lunar interior, both from the Allende analog and the high heat flow, indicates a high-temperature interior. The model is consistent with extensive early melting, with shallow melting at 3 AE, and with presently high deep internal temperatures. It is predicted that the outer 250 km is rich in plagioclase and FeO. The low iron content of the interior in this model raises the interior temperatures estimated from electrical conductivity by some 800 C.

Anderson, D. L.↗
NASA NTRS1978

Trace elemental characteristics of aerosols emitted from municipal incinerators

As part of a continuing investigation of high temperature combustion aerosols, elemental composition of size differentiated aerosols emitted from a local municipal incinerator was studied. Aerosols were aerodynamically separated into eight diameter groups ranging from 0.43 mm to 20 mm, collected, and analyzed by charged particle induced X-ray emission technique. On line data collection and reduction codes generated aerial densities for elements from Na to U with sensitivities in the ng/cu m range for most elements. From the total weights of aerosols collected per stage, their size distribution was determined to be bimodal, with one group centered at a diameter of 0.54 mm and the other at a diameter of 5.6 mm. Measured elemental concentrations in various size ranges indicate that K and S show a strong tendency to concentrate on aerosol surfaces. A weaker trend for surface preference was also observed for Mn and Ni, but other elements show no such trend.

Singh, J. J.↗
NASA NTRS1978

Charging of flexible solar array substrates in kilovolt electron beams

A series of survey tests were conducted to evaluate samples of flexible solar arrays. The samples used woven carbon fibers and/or coatings to increase the surface conductivity of the KAPTON substrate and thereby reduce surface charging. Four different samples were evaluated by exposing them to monoenergetic electron beams of 2 to 20 KeV at a current density of 1 nA sq cm. Simulated eclipse tests were also conducted. The results were as expected; the more continuous the conductive pattern, the lower the surface charging.

Staskus, J. V.↗
NASA NTRS1978

Wide temperature range fiber optic cable: Cable design study

Factors considered in the design and fabrication of a single fiber optic cable intended for spacecraft applications in an environment of temperature extremes from -160 C to 125 C include: abrasion resistance, low temperature flexibility, small size, low weight, and overall temperature stability. Specific requirements were identified for fiber core and overall diameters, fiber loss and NA, and cable tensile load. The single fiber cable will be fabricated by using a chemical vapor step index fiber of .125 mm coated to .3 mm with RTV silicone and then extruded with a jacket of Teflon PFA to a diameter of .5 mm. Six yarns of 1420 denier unimpregnated Kevlar 49 with a helical lay of 1.3 inches will surround the jacketed fiber under an extrusion of PFA. The finished cable diameter will measure 1.8 mm, and the weight of one kilometer length will be approximately 4350grams.

Speed, E. U.↗
NASA NTRS1978

Gamma ray lines from novae

Activities identify the mechanisms responsible for the eruptions characterizing cataclysmic variables are concerned with close binary systems, the properties of which are dominated by the presence of mass transfer from a late-type star onto a white dwarf via an accretion disk. Theories for the outbursts vary in their identification of the eruption mechanism with either gravitational or nuclear energy sources. Existing models for the dwarf novae invoke a dynamical instability in the envelope of the red star which triggers episodic Roche lobe overflow and a concomitant increase in the rate of mass transfer and the outbursts are associated with an increase in the accretion luminosity liberated in the disk. The most successful theoretical models for common nova events involve thermonuclear runaways proceeding in accreted hydrogen envelopes on the white dwarf components of these systems. The characteristics of such runaway events, which can give rise to detectable gamma ray fluxes are discussed. Salient features of existing runaway models are reviewed. Gamma fluxes from Na-22 decay, positron annihilation, and shock induction are predicted.

Truran, J. W.↗
NASA NTRS1978

The 1.06 optical receiver

High performance 1.06 micron m avalanche photodetectors (APDs), fabricated in the GaAlSb system, have high quantum efficiency (90 percent), high speed (risetime less than 60 ps) and low leakage currents (less than 50 na). The dark current represents more than an order of magnitude reduction compared to previously reported results. The high speed avalanche gain of these devices is between 20 and 50. The area uniformity is better than + or - 10 percent. GaAlAs APDs at 0.53 micron m have even faster speed, lower dark currents, and high speed gains of 100 to 200. Optical rangefinders based on measured APD performance parameters have far superior performance when compared to even ideal photomultiplier tubes in either a one color or two color rangefinder system. For a one color system, f factor of two lower time jitter can be achieved with identical transmitted power. The superiority of the APD based two color receiver is significant and exists in the entire range of desired time jitters (less than 100 ps) and received power levels.

Tomasetta, L. R.↗
NASA NTRS1976

The effect of secondary impurities on solar cell performance

Czochralski and float zone sigle crystals of silicon were doped with the primary impurities B or P so that a resistivity of 0.5 ohm cm resulted, and in addition doped with certain secondary impurities including Al, C, Cr, Cu, Fe, Mg, Mn, Na, Ni, O, Ti, V, and Zr. The actual presence of these impurities was confirmed by analysis of the crystals. Solar cell performance was evaluated and found to be degraded most significantly by Ti, V, and Zr and to some extent by most of the secondary impurities considered. These results are of significance to the low cost silicon program, since any such process would have to yield at least tolerable levels of these impurities.

Hill, D. E.↗
NASA NTRS1977

Redox equilibria of multivalent ions in silicate glasses

Experimental studies were made on the compositional dependence of the redox equilibrium of Eu in synthetic silicate liquids, together with an empirical model describing the observed compositional dependence. Electron paramagnetic resonance (EPR) was used to measure the concentration ratio of Eu(2+) to Eu(3+) in various glasses formed by rapidly quenching silicate liquids. The compositional field studied comprised mixtures of SiO2, TiO2, Al2O3, CaO, MgO, and Na2O. The proposed model describes the Eu(2+)/Eu(3+) ratio over the entire compositional field in terms of parameters easily related to each glass composition. The general applicability and utility of the model is further demonstrated by its application to the Fe(2+)-Fe(3+), Ce(3+)-Ce(4+), and Cr(3+)-Cr(6+) redox reactions in binary alkali oxide silicate glasses of Li, Na, and K.

Lauer, H. V., Jr.↗
NASA NTRS1977

Trace element distribution in mineral separates of the Allende inclusions and their genetic implications

Concentrations of the rare earth elements (REE), Sc, Co, Fe, Zn, Ir, Na, and Cr were determined for mineral separates of the coarseand fine-grained types (group I and II) of the Allende inclusions. These data in combination with other data suggest that the minerals in the coarse-grained inclusions (group I) crystallized in a closed system with respect to refractory elements although a totally molten stage is precluded. The data also indicate that fine-grained (group II) inclusions were formed by condensation from a super-cooled nebular gas; REE-rich clinopyroxene and spinel were formed earlier than REE-poor sodalite and nepheline. In addition, pre-existing Mg isotope anomalies in the coarse-grained inclusions must have been erased during the heating stage.

Nagasawa, H.↗
NASA NTRS1977

Experimental vaporization of the Holbrook chondrite

The vapor phase composition obtained by heating samples of the Holbrook L6 chondrite to 1300 C was determined quantitatively by Knudsen cell-quadrupole mass spectrometry. Maximum observed vapor pressures, produced at 1200 C, are reported for Na, K, Fe, and Ni, and the implications of the Na/K ratio are considered. The Fe and Ni data are discussed with attention to their migration in individual equilibrated chondrites. S2 (with minor SO2), H2O, and CO2 were also present in the high-temperature gas phase. Vesicles formed by the release of intrinsically derived volatiles are compared with vesicles in the Ibitira eucrite. Chondrite evolution is briefly discussed.

Gooding, J. L.↗