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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 703 records · Page 39
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

PTA1 Helium Pressurization System Model

A transient model of the Propulsion Test Article 1 (PTA1) Helium Pressurization System was developed using the Generalized Fluid System Simulation Program (GFSSP). The model included feed lines from the facility interface to the engine purge interface and Liquid Oxygen (LOX) and Rocket Propellant 1 (RP-1) tanks, the propellant tanks themselves including ullage space and propellant feed lines to their respective pump interfaces. GFSSPs capability was extended to model a control valve to maintain ullage pressure within a specified limit and pressurization processes such as heat transfer between ullage gas, propellant and the tank wall. The purpose of the model is to predict the flow system characteristics in the entire pressurization system during 80 seconds of pre-pressurization operation, 420 seconds of pressurization stand-by operation and 150 seconds of engine operation. Subsequent to the work presented here, the PTA1 model has been updated to include the LOX and RP-1 pumps, while the pressurization option itself has been modified to include the effects of mass transfer. This updated model will be compared with PTA1 test data as it becomes available.

Steadman, Todd↗
NASA NTRS2001

Numerical Modeling of Helium Pressurization System of Propulsion Test Article (PTA)

A transient model of the Propulsion Test Article (PTA) Helium Pressurization System was developed using the Generalized Fluid System Simulation Program (GFSSP). The model included feed lines from the facility interface to the engine purge interface and Liquid Oxygen (LOX) and Rocket Propellant 1 (RP-1) tanks, the propellant tanks themselves including ullage space and propellant feed lines to their respective pump interfaces. GFSSP's capability was extended to model a control valve to maintain ullage pressure within a specified limit and pressurization processes such as heat transfer between ullage gas, propellant and the tank wall. The purpose of the model is to predict the flow system characteristics in the entire pressurization system during 80 seconds of lower feed system priming, 420 seconds of fuel and LOX pump priming and 150 seconds of engine firing. Subsequent to the work presented here, the PTA model has been updated to include the LOX and RP-1 pumps, while the pressurization option itself has been modified to include the effects of mass transfer. This updated model will be compared with PTA test data as it becomes available.

Steadman, Todd↗
DOE OSTI2022

Drying of a Fully Saturated Porous Medium With Excess Water Layers: A Numerical Study

Abstract Drying of moist porous media can be very energy inefficient. For example, in the pulp and paper industry, paper drying consumes more than two-thirds of the total energy used in paper machines. Novel drying technologies can decrease the energy used for drying and lessen the manufacturing processes' carbon footprint. Developing next-generation drying technologies to dry moist porous media may require an understanding of removing moisture from a fully saturated porous material with excess water. This paper provides a fundamental understanding of heat and mass transfer in a fully saturated porous medium with excess water. This is relevant, for example, in drying tissue as well as pulp or paper for the purpose of thermal insulation where pressing is preferred to be avoided to overcome the reduction in the sheet thickness. For this purpose, a theoretical drying model is developed where the porous medium corresponds to paper and is assumed to be sandwiched between two excess-water layers (bottom and top). The conjugate model consists of energy and mass conservation equations for each layer. The model is validated with corresponding experimental data. In the model, the thickness of each water layer is calculated as a function of drying time based on local temperature and total moisture content. The numerical model is transient and one-dimensional in space (i.e., in the thickness direction). This paper demonstrates the governing equations, boundary conditions, and results when the saturated porous medium with water layers is heated from one side. Moisture and temperature profiles are estimated in the thickness direction of the porous medium as it dries.

Engineering↗
NASA NTRS1998

Observations of Subvisible Cirrus Clouds and Gravity Waves at the Tropical Tropopause

Thin, subvisible cirrus (SVC) clouds at the tropical tropopause have been observed by a number of methods in a variety of observational programs, including in situ sampling and aircraft and space-based lidar. Modeling studies suggest that these clouds play an important role in dehydrating tropospheric air as it enters the stratosphere. This is because particles large enough to have significant fall speeds can form under the conditions of slow cooling that are implied by the large horizontal extent of the SVC sheets. The IR radiation that these clouds absorb, and the upward vertical motion this implies, also makes them candidates for a tropical troposphere-to-stratosphere mass transfer mechanism. They may also play a role in the earth's radiation budget. These sheets were observed on five flights during the Tropical Ozone Transport Experiment (TOTE) by the NASA Langley DIAL lidar aboard NASA's DC-8 research aircraft operating during December 1995 and February 1996 south of Hawaii. The relationship of the SVC's observed during TOTE to convection was not a simple one. One class of SVC's are within 1000 km of the persistent strong convection near 15S (the SPCZ). Trajectory analyses indicated that the SVC air masses have in fact passed through the SPCZ within a few days of observation. These clouds are very close to the tropopause, with maximum potential temperatures not much higher than 370K, consistent with in situ water and total water measurements near the tropopause made during the Stratosphere Troposphere Exchange Project in January 1987 at Darwin, Australia. A second class of SVC's are not immediately downstream of convection. These clouds tend to be higher, reaching potential temperatures of 390K or more. Trajectory analyses indicate that the air in these SVC's originates either in the equatorial western Pacific or along the subtropical jet. In any case, the warm temperatures the SVC air masses encounter just prior to the observation time along the back trajectory imply that the clouds cannot be residual particles from cirrus blowoff, but must form locally as the air move upward and equatorward south of Hawaii. Since all the parcels have encountered colder temperatures than those at the time of observation early in their history, subsynoptic scale temperatures colder than the analysis temperatures appear to be required to explain the formation of ice particles. In fact, the sloping shapes of the SVC's do suggest that they are gravity or inertia-gravity waves. In situ meteorological measurements made by the ER-2 within a day of the DC-8 remote lidar observations show a gravity wave structure near the equator with an estimated period of about 30 hours. This is sufficiently long to allow large particles to form and fall out (thus allowing dehydration). Other ER-2 flights south of Hawaii at other times of year show gravity and inertia-gravity waves with a poleward wavenumber component and significant (5 degrees peak to peak) temperature perturbation.

Pfister, Leonhard↗
NASA NTRS1983

Orbital motion and mass flow in the interacting binary Be star HR 2142

The discovery of an unusual, periodic, two-component shell phase of short duration in the 'classical' Be star HR2142 (HD41335, MWC133) offered convincing evidence that this object is a mass-transfer binary system. A model based solely on the phase-dependent behavior of the hydrogen shell lines in this 80(d).860 binary was developed by Peters and Polidan (1973) and by Peters (1976). The present investigation is concerned with a refinement to the earlier model, taking into account the utilization of an orbital solution obtained from measurements of the wings of the broad photospheric features observed in the rapidly rotating primary. Velocities and equivalent widths from the sharp 'shell' lines, presumably formed in or near the gas stream, provide additional information on the mass flow in the Balmer-line-formation region.

Peters, G. J.↗
NASA NTRS2019

Oxidation of the Mantle Wedge by H+ in Aqueous Fluids: A New Interdisciplinary Approach

The observation that arc magmas are the most oxidized on Earth have led petrologists to question whether the subduction process might cause oxidation of the sub-arc mantle source. A strong correlation between the input of slab-derived aqueous fluid and Fe3(+)/ΣFe in arc magmas has led to the hypothesis that slab fluids may facilitiate the transfer of redox potential from oxidized slab material to mantle wedge and subsequently to primary arc melts. Despite this intuitive link, identifying an efficient and ubiquitous chemical process to transfer oxidation state in slab fluids has been challenging. Pure H2O alone is an inefficient oxidizer in the mantle, necessitating another oxidant within the fluid. Commonly invoked components include S or C, which are likely heterogeneously distributed within subducting slabs, and direct transfer of Fe3(+), which is only possible in very solute-rich fluids. Here we present a new mechanism to explain the oxidation of the sub-arc mantle by slab-derived aqueous fluid, wherein dissolved H(+)(aq) is reduced to H2(aq). Redox equilibrium is satisfied by electron transfer from Fe2(+)(s), which is oxidized in the rock to Fe3(+)(s) in the reaction: 2Fe2(+)(s) + 2H(+)(aq) = 2Fe3(+)(s) + H2(aq). This simple reaction was previously overlooked due to the assumption that all H must be bound by H2O molecules (i.e., no dissolved H), applicable to a pure H2O fluid, but not one with a solute load as addressed here. The application of thermodynamic modeling tools from aqueous geochemistry (DEW, EQ3/6) to mantle petrology predicts this reaction between mantle rock and slab fluid with our own experimentally constrained chemistry and fO2 (QFM+2). Mass transfer model results show an increase in Fe3(+)/ΣFe in mantle rock from MORB- like (0.15) to arc-like (0.2–0.3) values at reasonable fluid fluxes, co-incident with increasing H2 activity in the fluid. This can explain the stark correlation between slab fluid input into the mantle wedge and the observed fO2 of arc magmas. Moreover, it does not require diffusion of hydrogen out of the system. Instead, H2 remains dissolved in fluid in equilibrium with oxidized mantle rock.

Iacovino, Kayla↗
DOE OSTI2024

Accretion onto a Supermassive Black Hole Binary before Merger

While supermassive binary black holes (SMBBHs) inspiral toward merger they may also accrete matter from a surrounding disk. To study the dynamics of this system requires simultaneously describing the evolving spacetime and the magnetized plasma. We present the first relativistic calculation simulating two equal-mass, nonspinning black holes as they inspiral from a 20 M (G = c = 1) initial separation almost to merger. Our results imply important observational consequences: for instance, the accretion rate $\dot{M}$ onto the black holes first decreases and then plateaus, dropping by only a factor of ~3 despite the rapid inspiral. An estimated bolometric light curve follows the same profile, suggesting some merging SMBBHs may be significantly luminous past the predicted circumbinary disk decoupling. The minidisks are nonstandard: Reynolds, not Maxwell, stresses dominate, and they oscillate between two states. In one part of the cycle, "sloshing" streams transfer mass between minidisks, carrying kinetic energy at a rate sometimes as high as the peak minidisk bolometric luminosity. We also discover that episodic accretion drives time-varying minidisk tilts. These complex dynamics all contribute to unique cyclical behavior in the light curves of late-time inspiraling SMBBHs. The poloidal magnetic flux on the black holes is roughly constant at a dimensionless level $\phi$ ~ 2–3, but doubles just before merger; for significant black hole spin, this flux predicts powerful jets with variability driven by binary dynamics, another potentially unique electromagnetic signature. This simulation is the first to employ our multipatch infrastructure PATCHWORK MHD, decreasing the computational expense to ~3% of conventional single-grid methods' cost.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Modeling Heat Transfer and Reaction Kinetics of Biomass in Pyrolysis Feeding Systems

Biomass feedstocks can be used to produce low carbon-intensity chemicals and liquid fuels by displacing fossil-fuel sources. Pyrolysis is the thermal decomposition of biomass in the absence of oxygen and can be used to produce crude biofuels. A typical feeding mechanism for pyrolysis reactors is by lock hopper followed by a horizontal auger feeder. Particle agglomeration and plugging of the auger screw are regularly occurring phenomena that is detrimental to the process since it results in the need for periodic inspection and cleaning. The underlying mechanisms leading to agglomeration and plugging are unclear, but a working hypothesis is that heat from the reactor raises the temperature of the biomass in the feeder to the point at which preliminary decomposition reactions occur and produce "sticky" products. Using principles of heat and mass transfer, we derived one-dimensional differential equations for heat flow from the pyrolysis reactor through the auger feeder. Temperature profiles were solved from the system of one-dimensional differential equations using the shooting method. Subsequently, we used the temperature profiles as a one-way coupling to a reaction model for the biomass in the feeder. Kinetic models were adopted from the literature and used to predict the formation of intermediates, products, char, extractives, and metaplastics as well as phase changes along the auger feeder. Species were identified that correlated with softening of the biomass, causing it to become sticky and plug the feeder. We will discuss the details of this work, our findings, and the direction of future work that includes fully coupled transport and reaction-kinetics simulations.

BIOMASS FUELS↗
NASA NTRS1980

A two-temperature model for the flare of 5 September, 1973

A study of the energetics and mass transfer during the X-ray flare on Sept. 5, 1973, using the observations in the objective grating mode of the spectrographic telescope on Skylab is presented. The data are approximately monochromatic images of a small X-ray source which show a continued rise in the emission for several minutes followed by a decline. The observations are analyzed using a two-temperature model to determine the changes in the distribution of emission measure and of the amount of material as a function of temperature. The development of the flare can be divided into three periods comprising evaporation which drives mass into the entire emitting region, cessation of evaporation, and decline in the emission measure.

Little-Marenin, I. R.↗
NASA NTRS1992

Possible observational consequences of primordial binaries in globular clusters

The paper investigates the observational consequences of the evolution of a primordial binary population in a globular cluster. For those binary systems which begin mass transfer at orbital periods of less than about 1 d, the system is expected to evolve to a contact binary stage and to eventually merge to form a single star. At longer orbital periods, the binary system will enter into a common envelope stage. For periods less than about 10 d, the system is likely to merge, and the outcome of the evolution is a single red giant star. For systems characterized by orbital periods greater than about 15 d, a detached red dwarf-white dwarf binary system is expected to change. As a consequence of the mergers, a range in masses for the red giant stars is possible, leading to a color spread on the RGB of the color magnitude diagram. The luminosity function of stars at high luminosities is expected to steepen as a result of tidal interaction in the binary. It is suggested that the formation of cataclysmic variables via primordial binaries is expected only in loosely bound clusters of low-velocity dispersion.

Taam, Ronald E.↗
NASA NTRS2004

Study of Rapid-Regression Liquefying Hybrid Rocket Fuels

A report describes experiments directed toward the development of paraffin-based hybrid rocket fuels that burn at regression rates greater than those of conventional hybrid rocket fuels like hydroxyl-terminated butadiene. The basic approach followed in this development is to use materials such that a hydrodynamically unstable liquid layer forms on the melting surface of a burning fuel body. Entrainment of droplets from the liquid/gas interface can substantially increase the rate of fuel mass transfer, leading to surface regression faster than can be achieved using conventional fuels. The higher regression rate eliminates the need for the complex multi-port grain structures of conventional solid rocket fuels, making it possible to obtain acceptable performance from single-port structures. The high-regression-rate fuels contain no toxic or otherwise hazardous components and can be shipped commercially as non-hazardous commodities. Among the experiments performed on these fuels were scale-up tests using gaseous oxygen. The data from these tests were found to agree with data from small-scale, low-pressure and low-mass-flux laboratory tests and to confirm the expectation that these fuels would burn at high regression rates, chamber pressures, and mass fluxes representative of full-scale rocket motors.

Zilliac, Greg↗
NASA NTRSDate not supplied

Opposed-flow Spreading Flames: Effect of Sub-atmospheric Pressure on Spread and Burning Rates

Flame spread over solid fuels is a canonical problem in fire science, due to its direct implications on material flammability and importance in fire development. Flames in a microgravity environment can behave very differently than on Earth, posing additional risks for spaceflight life safety. Sub-atmospheric pressures in ground-based experiments have been proposed to approximately replicate the burning behavior of solid fuels in reduced gravity conditions because of similar effects on heat and mass transfer mechanisms from the flame to the solid. In opposed-flow flame spread, the solid fuel is heated by the flame ahead of its leading edge, and this process is strongly affected by the ambient conditions. In this work, we consider flames spreading over flat thin acrylic samples exposed to a forced flow of 20 cm/s, and pressures between 30 and 100 kPa. When radiation losses and chemical kinetic effects are neglected, experimental and theoretical results suggest an independence of the spread rate on pressure. However, the spread rate shows a decreasing trend with lower pressure in the range 30-60 kPa. The mass burning rate, calculated from the samples weight measured before and after the experiments, shows a similar trend. The flame length, on the other hand, shows a non-monotonic behavior, reaching a maximum at 60 kPa. Additionally, gas emissions measured during the experiments are used to estimate the heat release rate of the spreading flames. The comparison of the heat release rate obtained from the measured emissions and the estimated mass burning rates, suggests that chemical kinetics is not driving the decrease in flame spread observed at low pressures, whereas radiation losses could be responsible in analogy to what has been observed in micro and partial gravity studies. These results could provide more information to guide future Earth-based material flammability testing for spacecraft applications.

fire↗
NASA NTRS1989

COLD-SAT: An orbital cryogenic hydrogen technology experiment

The COLD-SAT spacecraft will perform subcritical liquid hydrogen storage and transfer experiments under low-gravity conditions to provide engineering data for future space transportation missions. Consisting of an experiment module mated to a spacecraft bus, COLD-SAT will be placed in an initial 460 km circular orbit by an Atlas I commercial launch vehicle. After deployment, the three-axis-controlled spacecraft bus will provide electric power, experiment control and data management, communications, and attitude control along with propulsive acceleration levels ranging from 10(-6) to 10(-4)g. These accelerations are an important aspect of some of the experiments, as it is desired to know the effects that low gravity levels might have on the heat and mass transfer processes involved. The experiment module will contain the three liquid hydrogen tanks, valves, pressurization equipment, and instrumentation. At launch all the hydrogen will be in the largest tank, which has helium-purged MLI and is loaded and topped off by the hydrogen tanking system used for the Centaur upper stage of the Atlas. The two smaller tanks will be utilized in orbit for performing some of the experiments. The experiments are grouped into two classes on the basis of their priority, and include six regarded as enabling technology and nine regarded as enhancing technology.

Schuster, J. R.↗
NASA NTRS1989

COLD-SAT - An orbital cryogenic hydrogen technology experiment

The COLD-SAT spacecraft will perform subcritical liquid hydrogen storage and transfer experiments under low-gravity conditions to provide engineering data for future space transportation missions. Consisting of an experiment module mated to a spacecraft bus, COLD-SAT will be placed in an initial 460 km circular orbit by an Atlas I commercial launch vehicle. After deployment, the three-axis-controlled spacecraft bus will provide electric power, experiment control and data management, communications, and attitude control along with propulsive acceleration levels ranging from 10 (-6) to 10(-4) g. These accelerations are an important aspect of some of the experiments, as it is desired to know the effects that low gravity levels might have on the heat and mass transfer processes involved. The experiment module will contain the three liquid hydrogen tanks, valves, pressurization equipment, and instrumentation. At launch all the hydrogen will be in the largest tank, which has helium-purged MLI and is loaded and topped off by the hydrogen tanking system used for the Centaur upper stage of the Atlas. The two smaller tanks will be utilized in orbit for performing some of the experiments. The experiments are grouped into two classes on the basis of their priority, and include six regarded as enabling technology and nine regarded as enhancing technology.

Schuster, J. R.↗
NASA NTRS1990

Cryogenic On-Orbit Liquid Depot Storage, Acquisition, and Transfer Satellite (COLD-SAT)

The Cryogenic On-Orbit Liquid Depot Storage, Acquisition, and Transfer Satellite (COLD-SAT) will perform subcritical liquid hydrogen handling experiments under low gravity conditions to provide engineering data for future space transportation missions. Comprising the four Class 1 enabling experiments are tank press control, tank chilldown, tank no-vent fill, and liquid acquisition device fill/refill. The nine Class 2 enhancing experiments are tanker thermal performance, pressurization, low-gravity setting and outflow, liquid acquisition device performance, transfer line chilldown, outflow subcooling, low-gravity vented fill, fluid dumping, and advanced instrumentation. Consisting of an experiment module mated to a spacecraft bus, COLD-SAT will be placed in an initial 1300 km circular orbit by an Atlas commercial launch vehicle, and will perform experiments in a semi-autonomous mode for a period of up to six months. The three-axis controlled spacecraft bus provides electric power, control and data management, communications, and attitude control along with propulsive acceleration levels ranging from 10(exp -6) to 10(exp -4) g. It is desired to understand the effects that low acceleration levels might have on the heat and mass transfer processes involved in some of the experiments. The experiment module contains the three liquid hydrogen tanks, valves, pressurization and pumping equipment, and instrumentation. Within the highly insulated tanks are specialized fluid management equipment that might be used in future space transportation systems. At launch all the liquid hydrogen for the experiments is contained in the largest tank, which has helium-purged insulation to prevent cryo-pumping of air on the launch pad. The tank is loaded by the hydrogen tanking system used for the Centaur upper stage of the Atlas. After reaching orbit the two smaller tanks become receivers for fluid transfers, and when tanked, become the vessels for performing many of the experiments.

Schuster, John R.↗
NASA NTRS2000

Separation Control at Flight Reynolds Numbers: Lessons Learned and Future Directions

Active separation control, using periodic excitation, was studied experimentally at high Reynolds numbers. The effects of compressibility, mild sweep, location o excitation slot and steady momentum transfer on the efficacy of the method were identified. Tests conducted at chord Reynolds numbers as high as 40 x 10(exp 6) demonstrated that active control using oscillatory flow excitation can effectively delay flow separation from and reattach separated flow to aerodynamic surfaces at flight conditions. The effective frequencies generate one to four vortices over the controlled region at all times, regardless of the Reynolds number. The vortices are initially amplified by the separated shear-layer, and after initiating reattachment, the strength of the vortices decay as they are convected downstream. Large amplitude, low frequency vortices break down to smaller ones upon introduction at the excitation slot. The effects of steady mass transfer were compared to those of periodic excitation. It was found that steady blowing is significantly inferior to periodic excitation in terms o performance benefits and that the response to steady blowing is abrupt, and therefore undesirable from a control point of view. Steady suction and periodic excitation are comparable in effectiveness and both exhibit a gradual response to changes in the magnitude of the control input. The combination of weak steady suction and periodic excitation is extremely effective while the addition of steady blowing could be detrimental. Compressibility effects are weak as long as separation is not caused by a shock-wave/boundary-layer interaction The undesirable effects of the shock-induced separation could be alleviated by the introduction of periodic excitation upstream of the shock wave, inside the region of supersonic flow. The effects of mild sweep were also studied and periodic excitation was found to be very effective in reattaching three-dimensional separated flow. Scaling laws that correlate 2D and 3D controlled flows were tested and verified. Several performance benefits could be gained by applying the method to existing configurations, but it is expected that the full potential of the method can only be realized through the design of new configurations. A comprehensive, fully turbulent, database was generated in order to guide the development, and enable validation, of candidate unsteady CFD design tools.

Seifert, Avi↗
NASA NTRS2000

Separation Control at Flight Reynolds Numbers: Lessons Learned and Future Directions

Active separation control, using periodic excitation, was studied experimentally at high Reynolds numbers. The effects of compressibility, mild sweep, location of excitation slot and steady momentum transfer on the efficacy of the method were identified. Tests conducted at chord Reynolds numbers as high as 40 x 10(exp 6) demonstrated that active control using oscillatory flow excitation can effectively delay flow separation from, and reattach separated flow to aerodynamic surfaces at flight conditions. The effective frequencies generate one to four vortices over the controlled region at all times, regardless of the Reynolds number. The vortices are initially amplified by the separated shear-layer, and after initiating reattachment, the strength of the vortices decay as they are convected downstream. Large amplitude, low frequency vortices break down to smaller ones upon introduction at the excitation slot. The effects of steady mass transfer were compared to those of periodic excitation. It was found that steady blowing is significantly inferior to periodic excitation in terms of performance benefits and that the response to steady blowing is abrupt, and therefore undesirable from a control point of view. Steady suction and periodic excitation are comparable in effectiveness and both exhibit a gradual response to changes in the magnitude of the control input. The combination of weak steady suction and periodic excitation is extremely effective while the addition of steady blowing could be detrimental. Compressibility effects are weak as long as separation is not caused by a shock-wave/boundary-layer interaction. The undesirable effects of the shock-induced separation could be alleviated by the introduction of periodic excitation upstream of the shock wave, inside the region of supersonic flow. The effects of mild sweep were also studied and periodic excitation was found to be very effective in reattaching three-dimensional separated flow. Scaling laws that correlate 2D and 3D controlled flows were tested and verified. Several performance benefits could be gained by applying the method to existing configurations, but it is expected that the full potential of the method can only be realized through the design of new configurations. A comprehensive, fully turbulent, database was generated in order to guide the development, and enable validation, of candidate unsteady CFD design tools.

Pack, LaTunia G.↗
DOE OSTI2020

Solution–Processable Thermally Crosslinked Organic Radical Polymer Battery Cathodes

Organic radical polymers are promising cathode materials for next-generation batteries because of their rapid charge transfer and high cycling stability. However, these organic polymer electrodes gradually dissolve in the electrolyte, resulting in capacity fade. Several crosslinking methods have been developed to improve the performance of these electrodes, but they are either not compatible with carbon additives or compromise the solution processability of the electrodes. A one-step post-synthetic, carbon-compatible crosslinking method was developed to effectively crosslink an organic polymer electrode and allow for easy solution processing. The highest electrode capacity of 104 mAh g –1 (vs. a theoretical capacity of 111 mAh g –1 ) is achieved by introducing 1 mol % of the crosslinker, whereas the highest capacity retention (99.6 %) is obtained with 3 mol % crosslinker. In addition, mass transfer was observed in situ by using electrochemical quartz crystal microbalance with dissipation monitoring. Furthermore, these results may guide future electrode design toward fast-charging and high-capacity organic electrodes.

25 ENERGY STORAGE↗