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At least 703 records · Page 39

Dataset for scientific paper "Simulated plant‑mediated oxygen input has strong impacts on fine‑scale porewater biogeochemistry and weak impacts on integrated methane fluxes in coastal wetlands", a modeling study based on field observation at the tidal salt marshes of the Parker River Estuary, Massachusetts, United States

This dataset is the raw and processed data for the paper "Simulated plant ‑ mediated oxygen input has strong impacts on fine ‑ scale porewater biogeochemistry and weak impacts on integrated methane fluxes in coastal wetlands". This study investigated how plant-mediated oxygen input affects subsurface biogeochemical reactions of organic carbon degradation and the resulting methane emissions of coastal wetlands by model simulation. We used the subsurface geochemical simulator PFLOTRAN for the modeling, which produced the simulated changes in porewater chemical substances and methane emissions over 10 days under different scenarios of plant-mediated oxygen input.Specifically, this dataset contains: 1) the input files for PFLOTRAN of all simulation runs conducted in this study. Those files are with an extension of ".in", containing information of the biogeochemical reaction network (stoichiometry, reaction rate, Monod constants, etc), fluid flow rate and oxygen concentration in the fluid which together simulated the plant-mediated oxygen input, the configuration of artificial reactions that simulated the methane fluxes, etc. The PFLOTRAN input files are text files, which can be opened by NotePad, but running these input files will require proper installation of PFLOTRAN (instruction: https://documentation.pflotran.org/user_guide/how_to/installation/installation.html). 2) the raw and processed model output from PFLOTRAN of all simulation runs, and 3) the python scripts used to process the raw model output, including random allocation of root cells, converting raw data into organized formats, calculating the methane fluxes based on the model output, data visualization, etc. The raw and processed model output from PFLOTRAN are in .spydata format, which can be viewed with Python. and 3) the python scripts for data processing and analysis are programming scripts, which can be opened with Python.This modeling work, in particular the model parameterization of root density and initial conditions of porewater concentrations of biogeochemical substances, was based on field measurements at the salt marsh of the Upper Parker River Estuary, Massachusetts, United States.

54 ENVIRONMENTAL SCIENCES↗

Micro weather stations for in situ measurements in the Martian planetary boundary layer

Viking Lander meteorology measurements show that the Martian planetary boundary layer (PBL) has large diurnal and seasonal variations in pressure, wind velocity, relative humidity, and airborne dust loading. An even larger range of conditions was inferred from remote sensing observations acquired by the Mariner 9 and Viking orbiters. Numerical models indicate that these changes may be accompanied by dramatic vertical and horizontal wind shears (100 m/s/km) and rapid changes in the static stability. In-situ measurements from a relatively small number surface stations could yield global constraints on the Martian climate and atmospheric general circulation by providing ground truth for remote sensing instruments on orbiters. A more complete understanding of the meteorology of the PBL is an essential precursor to manned missions to Mars because this will be their working environment. In-situ measurements are needed for these studies because the spatial and temporal scales that characterize the important meteorological processes near the surface cannot be resolved from orbit. The Mars Environmental Survey (MESUR) Program will provide the first opportunity to deploy a network of surface weather stations for a comprehensive investigation of the Martian PBL. The feasibility and utility of a network of micro-weather stations for making in-situ meteorological measurements in the Martian PBL are assessed.

Crisp, D.↗

Sources of atmospheric methane from coastal marine wetlands

Biological methanogenesis in wetlands is believed to be one of the major sources of global tropospheric methane. The present paper reports measurements of methane distribution in the soils, sediments, water and vegetation of coastal marine wetlands. Measurements, carried out in the salt marshes Bay Tree Creek in Virginia and Panacea in northwest Florida, reveal methane concentrations in soils and sediments to vary with depth below the surface and with soil temperature. The fluxes of methane from marsh soils to the atmosphere at the soil-air interface are estimated to range from -0.00067 g CH4/sq m per day (methane sink) to 0.024 g CH4/sq m per day, with an average value of 0.0066 g CH4/sq m per day. Data also demonstrate the important role of tidal waters percolating through marsh soils in removing methane from the soils and releasing it to the atmosphere. The information obtained, together with previous studies, provides a framework for the design of a program based on in situ and remote sensing measurements to study the global methane cycle.

Harriss, R. C.↗

Water Power Technologies Office: 2021-2022 Accomplishments Report

The report details key performance goals for each of WPTO’s activity areas until 2025 and includes long-term, follow-on objectives through 2030. This report serves as a strategic vision and operational guide to help WPTO manage and coordinate its future activities and communicate its mission, goals, and plans. The Multi-Year Program Plan was an integral part of the 2022 Peer Review, providing reviewers insight and guidance on the office’s strategy to which WPTO-funded projects must align.

13 HYDRO ENERGY↗

U.S. Pacific Coast Workshop Report on Preconstruction Research Recommendations (U.S. Offshore Wind Synthesis of Environmental Effects Research (SEER) Project)

In May 2022, the U.S. Offshore Wind Synthesis of Environmental Effects Research (SEER) project team hosted a stakeholder workshop focused on preconstruction (baseline) research needs for potential floating offshore wind (OSW) energy development on the U.S. Pacific Coast, including California, Oregon, and Washington. Prior to the workshop, the SEER team developed a set of initial synthesized research recommendations that were identified based on a review of relevant, publicly available resources and with advisory group input. The workshop covered three marine life breakout groups on subsequent days to discuss research recommendations related to 1) marine mammals and sea turtles, 2) fish and invertebrates, and 3) birds and bats. As part of the workshop, over a hundred participants from the public and private sectors provided feedback on various aspects of the initial research recommendations, including associated data and knowledge gaps, benefits/limitations of available methods and technologies, and technological advancements or infrastructure needed to address the recommendation. Approximately 1,000 total comments were received on the workshop MURAL boards and were synthesized in this report. Based on workshop feedback, SEER developed a final database of over 500 specific research recommendations based on more than 40 resources. In Fall 2022, the full database and a tool with updated synthesized research recommendations were disseminated on Tethys (https://tethys.pnnl.gov) to assist with informing future funding opportunities and research programming. There is a continued need to improve awareness of the potential environmental effects, monitoring technologies, and management strategies for floating OSW energy development on the U.S. Pacific Coast. Coordination of these activities will require the sustained involvement of multiple stakeholders from across sectors. Beyond the baseline considerations discussed in this workshop, future state-of-the-science activities should be planned to consider research needs across wind energy life cycle phases for all relevant wildlife taxa and associated habitat and ecosystem processes.

17 WIND ENERGY↗

The mutation atlas of giant kelp (Macrocystis pyrifera): a mutation database resource for natural knockouts

Giant kelp (Macrocystis pyrifera) is a paramount species of immense ecological and economic importance. It forms dense underwater forests, providing crucial habitat and serving as a foundation species for diverse marine ecosystems. Understanding the genetics of giant kelp is essential for conservation and sustainable farming, safeguarding these valuable ecosystems and their benefits. By analyzing mutations based on their impact, we can gain insights into the potential functional consequences and implications for the organism, helping to identify critical genes or regions that may play a significant role in adaptation, development, and environmental response. To achieve this, we annotated the effects and impact of spontaneous mutations in 559 giant kelp individuals from four different populations. We found over 15.9 million mutations in genes of giant kelp, and classified them into modifier, low, moderate, and high impact depending on their predicted effects. The creation of this mutation effect database, attached to the seedbank of these individuals, offers several applications, including enhancing breeding programs, aiding genetic engineering with naturally occurring mutations, and developing strategies to mitigate the impact of environmental changes.

Plant Sciences↗

SeaWiFS Postlaunch Calibration and Validation Analyses

The effort to resolve data quality issues and improve on the initial data evaluation methodologies of the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Project was an extensive one. These evaluations have resulted, to date, in three major reprocessings of the entire data set where each reprocessing addressed the data quality issues that could be identified up to the time of each reprocessing. The number of chapters (21) needed to document this extensive work in the SeaWiFS Postlaunch Technical Report Series requires three volumes. The chapters in Volumes 9, 10, and 11 are in a logical order sequencing through sensor calibration, atmospheric correction, masks and flags, product evaluations, and bio-optical algorithms. The first chapter of Volume 9 is an overview of the calibration and validation program, including a table of activities from the inception of the SeaWiFS Project. Chapter 2 describes the fine adjustments of sensor detector knee radiances, i.e., radiance levels where three of the four detectors in each SeaWiFS band saturate. Chapters 3 and 4 describe the analyses of the lunar and solar calibration time series, respectively, which are used to track the temporal changes in radiometric sensitivity in each band. Chapter 5 outlines the procedure used to adjust band 7 relative to band 8 to derive reasonable aerosol radiances in band 7 as compared to those in band 8 in the vicinity of Lanai, Hawaii, the vicarious calibration site. Chapter 6 presents the procedure used to estimate the vicarious calibration gain adjustment factors for bands 1-6 using the waterleaving radiances from the Marine Optical Buoy (MOBY) offshore of Lanai. Chapter 7 provides the adjustments to the coccolithophore flag algorithm which were required for improved performance over the prelaunch version. Chapter 8 is an overview of the numerous modifications to the atmospheric correction algorithm that have been implemented. Chapter 9 describes the methodology used to remove artifacts of sun glint contamination for portions of the imagery outside the sun glint mask. Finally, Chapter 10 explains a modification to the ozone interpolation method to account for actual time differences between the SeaWiFS and Total Ozone Mapping Spectrometer (TOMS) orbits.

Hooker, Stanford B.↗

Data management for community research projects: A JGOFS case study

Since the mid 1980s, much of the marine science research effort in the United Kingdom has been focused into large scale collaborative projects involving public sector laboratories and university departments, termed Community Research Projects. Two of these, the Biogeochemical Ocean Flux Study (BOFS) and the North Sea Project incorporated large scale data collection to underpin multidisciplinary modeling efforts. The challenge of providing project data sets to support the science was met by a small team within the British Oceanographic Data Centre (BODC) operating as a topical data center. The role of the data center was to both work up the data from the ship's sensors and to combine these data with sample measurements into online databases. The working up of the data was achieved by a unique symbiosis between data center staff and project scientists. The project management, programming and data processing skills of the data center were combined with the oceanographic experience of the project communities to develop a system which has produced quality controlled, calibrated data sets from 49 research cruises in 3.5 years of operation. The data center resources required to achieve this were modest and far outweighed by the time liberated in the scientific community by the removal of the data processing burden. Two online project databases have been assembled containing a very high proportion of the data collected. As these are under the control of BODC their long term availability as part of the UK national data archive is assured. The success of the topical data center model for UK Community Research Project data management has been founded upon the strong working relationships forged between the data center and project scientists. These can only be established by frequent personal contact and hence the relatively small size of the UK has been a critical factor. However, projects covering a larger, even international scale could be successfully supported by a network of topical data centers managing online databases which are interconnected by object oriented distributed data management systems over wide area networks.

Lowry, Roy K.↗

Forte: A suite of advanced multireference quantum chemistry methods

Software development plays a critical role in advancing quantum chemistry, enabling the exploration of new fundamental theoretical ideas and modeling systems of ever-increasing complexity. In the past decade, the availability of quantum chemistry packages that use modular designs and provide application programming interfaces (APIs) has enabled the creation of specialized software plugins, enhancing the capabilities of the original codes. Here, the availability of well-documented APIs is particularly beneficial in the context of academic scientific software development because it reduces the entry barrier for new developers and shields them from the complexities of large software projects.

74 ATOMIC AND MOLECULAR PHYSICS↗

Computational Simulation of an Additively Manufactured Marine Component

Early work in finite-element analysis of additive manufacturing (AM) components was not able to include distortion and residual stress of the entire build, yielding uncertainty in the computational model predictions. To address this, current versions of recently developed computational tools are being used to understand their role in validation at the Naval Surface Warfare Center, Carderock Division, for laser powder-bed fusion (L-PBF) AM. A 316L stainless steel L-PBF build containing multiple parts, which exhibited the same local part failure over multiple AM fabrication runs, was selected for computational analysis. Single-part simulations analyzed optimization of computational speed and prediction accuracy. Full-build simulations exposed the smallest re-coater tolerances early in part fabrication as a result of part shrinkage and subsequent cupping. This cupping was predicted to change the powder spreading and result in the non-consolidation of the support structures, which paralleled the failures seen in the physical builds. Part redesign of the conventionally produced part to align with AM fabrication requirements was recommended to alleviate the build failures. This project is part of a larger program focused on validation of the computational tools to determine best practices for insertion of AM simulation into the greater Naval enterprise.

36 MATERIALS SCIENCE↗

Application priority of GSHP systems in the climate conditions of the United States

Building energy-performance simulation programs are powerful tools for many aspects of feasibility studies regarding ground source heat pump (GSHP). However, the understanding of the limitations of the energy modelling programs, their capability of predicting energy performance early in the design process, and the complicated functionality of these programs makes the software programs harder to use and less practical. The interactive tool developed in this study seeks to provide analysis information in a straightforward manner that is inexpensive, convenient, and sophisticated. This tool uses an inclusive approach to assess the feasibility of GSHPs by prescreening critical factors such as climate conditions, ground temperatures, energy use, and cost savings. It is interactive and enables the user to do a feasibility analysis with a weighting factor for each feasibility criterion based on the user’s preference and interests. The application of the tool explains feasibility scores of 15 representative cities in various climatic conditions across the US. Results for commercial buildings show that the GSHP systems are more feasible in cold and dry, cool and humid, and very cold areas than warm and dry, very hot and humid, and mixed marine areas, and that most feasibility levels are located on good and moderate.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

SWIM: A Semi-Analytical Ocean Color Inversion Algorithm for Optically Shallow Waters

Ocean color remote sensing provides synoptic-scale, near-daily observations of marine inherent optical properties (IOPs). Whilst contemporary ocean color algorithms are known to perform well in deep oceanic waters, they have difficulty operating in optically clear, shallow marine environments where light reflected from the seafloor contributes to the water-leaving radiance. The effect of benthic reflectance in optically shallow waters is known to adversely affect algorithms developed for optically deep waters [1, 2]. Whilst adapted versions of optically deep ocean color algorithms have been applied to optically shallow regions with reasonable success [3], there is presently no approach that directly corrects for bottom reflectance using existing knowledge of bathymetry and benthic albedo.To address the issue of optically shallow waters, we have developed a semi-analytical ocean color inversion algorithm: the Shallow Water Inversion Model (SWIM). SWIM uses existing bathymetry and a derived benthic albedo map to correct for bottom reflectance using the semi-analytical model of Lee et al [4]. The algorithm was incorporated into the NASA Ocean Biology Processing Groups L2GEN program and tested in optically shallow waters of the Great Barrier Reef, Australia. In-lieu of readily available in situ matchup data, we present a comparison between SWIM and two contemporary ocean color algorithms, the Generalized Inherent Optical Property Algorithm (GIOP) and the Quasi-Analytical Algorithm (QAA).

QAA↗

A Rechargeable Carbon-Oxygen Battery for Efficient, Low-Cost Energy Storage

As part of the Cyclotron Road program, Noon Energy Inc investigated the feasibility of a new class of rechargeable flow battery for long-duration energy storage at the 100+ hour storage capacities needed to make intermittent solar/wind power available 24/7 year-round. Whereas conventional batteries store energy in relatively expensive metals like cobalt, lithium, and vanadium, the new battery stores energy in abundant, ultra-low-cost carbon and oxygen, storage media that cost well below $1 per kWh capacity (less than the cost of their containers). It also can operate with a high roundtrip energy efficiency of ~80% and has 10x higher energy density than conventional aqueous flow batteries, even higher than lithium ion batteries at system level. These properties make it suitable for a variety of potential stationary energy storage applications as well as for electric transportation vehicles (long-haul marine shipping and trucking), so determining the best product-market fit and market entry was a key outcome of Noon’s Cyclotron Road fellowship. Noon had demonstrated initial materials development and proof-of-principle testing before the fellowship. Overall, within the fellowship Noon carried out key initial technology development in market applications, system design, risk assessment and prototyping.

25 ENERGY STORAGE↗

Aerosol Transport Over Equatorial Africa

Long-range and inter-hemispheric transport of atmospheric aerosols over equatorial Africa has received little attention so far. Most aerosol studies in the region have focussed on emissions from rain forest and savanna (both natural and biomass burning) and were carried out in the framework of programs such as DECAFE (Dynamique et Chimie Atmospherique en Foret Equatoriale) and FOS (Fires of Savanna). Considering the importance of this topic, aerosols samples were measured in different seasons at 4420 meters on Mt Kenya and on the equator. The study is based on continuous aerosol sampling on a two stage (fine and coarse) streaker sampler and elemental analysis by Particle Induced X-ray Emission. Continuous samples were collected for two seasons coinciding with late austral winter and early austral spring of 1997 and austral summer of 1998. Source area identification is by trajectory analysis and sources types by statistical techniques. Major meridional transports of material are observed with fine-fraction silicon (31 to 68 %) in aeolian dust and anthropogenic sulfur (9 to 18 %) being the major constituents of the total aerosol loading for the two seasons. Marine aerosol chlorine (4 to 6 %), potassium (3 to 5 %) and iron (1 to 2 %) make up the important components of the total material transport over Kenya. Minimum sulfur fluxes are associated with recirculation of sulfur-free air over equatorial Africa, while maximum sulfur concentrations are observed following passage over the industrial heartland of South Africa or transport over the Zambian/Congo Copperbelt. Chlorine is advected from the ocean and is accompanied by aeolian dust recirculating back to land from mid-oceanic regions. Biomass burning products are transported from the horn of Africa. Mineral dust from the Sahara is transported towards the Far East and then transported back within equatorial easterlies to Mt Kenya. This was observed during austral summer and coincided with the dying phase of 1997/98 El Nino.

Gatebe, C. K.↗

Open Energy Data Initiative (OEDI) FY22-24 (Final Technical Report)

Final technical report for the Open Energy Data Initiative (OEDI) project covering fiscal years FY22 through FY24. The DOE Open Energy Data Initiative (OEDI) is a partnership between the National Renewable Energy Laboratory (NREL), the U.S. Department of Energy (DOE), and major cloud providers including Amazon, Microsoft, and Google to provide universal access to big data in the cloud. At the heart of OEDI is a centralized repository of high-value energy research datasets aggregated from the U.S. Department of Energy's Program Offices, National Laboratories and other collaborators. It aggregates smaller, domain-specific repositories, allows direct data submissions, and includes support for big data through its energy data lakes. OEDI's data lakes make high-value data universally accessible and help researchers, collaborators and the general public overcome many of the obstacles to accessing and using big data.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Method development for comprehensive extraction and analysis of marine toxins: Liquid-liquid extraction and tandem liquid chromatography separations coupled to electrospray tandem mass spectrometry

Toxins from biological sources are recognized as potential chemical weapon threats, with saxitoxin and ricin listed by the chemical weapons convention (CWC) as schedule one agents (CWC reference). These two toxins represent a metabolite (saxitoxin) and protein (ricin) from algal and plant sources, respectively. An array of toxins have been listed as "select agents" by the Health and Human Services (HHS) select agent program, including ricin, abrin, saxitoxin, tetrodotoxin, specific paralytic alpha conotoxin peptides, T-2 toxin, diacetoxyscirpenols, botulinum toxins, and staphylococcal enterotoxins [1]. The quantities of these toxins dictate whether they are considered select agents with federal oversight of their storage and use. While this list captures some of the naturally occurring toxins that may pose a threat to the public, there are a number of other naturally occurring toxins that may also be a concern.

biodetection↗

Upwelling-Induced Primary Productivity in Coastal Waters of the Black Sea: Impact on Algorithms for Remote Sensing

This research program was a collaborative effort to investigate the impact of rapid changes in the water column during coastal upwelling, on biological and optical properties. These properties are important for constructing region or event-specific algorithms for remote sensing of pigment concentration and primary productivity and for comparing these algorithms with those used for the development of large scale maps from ocean color. We successfully achieved the primary objective of this research project which was to study in situ the dynamics of rapid spatial and temporal changes in properties of the water column during, coastal upwelling off the Crimean Coast in the Black Sea. The work was a collaborative effort between a group of biological and physical oceanographers from the Woods Hole Oceanographic Institution and from two oceanographic research institutions in the Crimea, Ukraine, located near the study site, the Marine Hydrophysical Institute (MHI) and the Institute of Biology of the Southern Seas (IBSS). The site was an ideal experimental model, both from a technical and economic standpoint, because of the predictable summer upwelling that occurs in the region and because of the availability of both a ship on call and laboratory and remote sensing facilities at the nearby marine institutes. We used a combination of shipboard measurements and remote sensing to investigate the physical evolution of rapid upwelling events and their impact on photoplankton and water column optical properties. The field work involved a two day cruise for mooring, deployment and a three day baseline survey cruise, followed by an eleven day primary cruise during, a summer upwelling event (anticipated by monitoring local winds and tracked by remote sensing imaging). An MHI ship was outfitted and used for these purposes.

Goldman, Joel C.↗

Coupled Time-Lapse Full-Waveform Inversion for Subsurface Flow Problems Using Intrusive Automatic Differentiation

We describe a novel framework for estimating subsurface properties, such as rock permeability and porosity, from time-lapse observed seismic data by coupling full-waveform inversion (FWI), subsurface flow processes, and rock physics models. For the inverse modeling, we handle the back propagation of gradients by an intrusive automatic differentiation strategy that offers three levels of user control: (1) At the wave physics level, we adopted the discrete adjoint method in order to use our existing high-performance FWI code; (2) at the rock physics level, we used built-in automatic differentiation operators from the TensorFlow backend; (3) at the flow physics level, we implemented customized partial differential equation (PDE) operators for the multiphase flow equations. The three-level coupled inversion strategy strikes a good balance between computational efficiency and programming efforts, and when the gradients are chained together, it constitutes a coupled inverse system. Our numerical experiments demonstrate that the three-level coupled inverse problem is superior in terms of accuracy to a traditional decoupled inversion strategy. Additionally, our method is able to simultaneously invert for parameters in empirical relationships such as the rock physics models. Our proposed inverted model can be used for reservoir performance prediction and reservoir management/optimization purposes.

54 ENVIRONMENTAL SCIENCES↗