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At least 703 records · Page 39

All sources NASA NTRS DOE OSTI

DOE OSTI2015

Experiment attributes to establish tube with twisted tape insert performance cooling plasma facing components

The modeling capability for tubes with twisted tape inserts is reviewed with reference to the application of cooling plasma facing components in magnetic confinement fusion devices. The history of experiments examining the cooling performance of tubes with twisted tape inserts is reviewed with emphasis on the manner of heating, flow stability limits and the details of the test section and fluid delivery system. Models for heat transfer, burnout, and onset of net vapor generation in straight tube flows and tube with twisted tape are compared. As a result, the gaps in knowledge required to establish performance limits of the plasma facing components are identified and attributes of an experiment to close those gaps are presented.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2023

A Manganese Compound I Model with a High Reactivity in the Oxidation of Organic Substrates and Water

In this work, a high-valent manganese(IV)-hydroxo porphyrin π-cation radical complex, [Mn(IV)(OH)(Porp +• )(X)] + , was synthesized and characterized spectroscopically. The Mn porphyrin intermediate was highly reactive in alkane hydroxylation and oxygen atom transfer reactions. More importantly, the Mn porphyrin intermediate reacted with water at a fast rate, resulting in the dioxygen evolution. To the best of our knowledge, we report the first manganese Cpd I model compound bearing a porphyrin π-cation radical ligand with a high reactivity in oxidation reactions, including water oxidation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

The role of nonequilibrium LO phonons, Pauli exclusion, and intervalley pathways on the relaxation of hot carriers in InGaAs/InGaAsP multi-quantum-wells

Under continuous-wave laser excitation in a lattice-matched In 0.53 Ga 0.47 As/In 0.8 Ga 0.2 As 0.44 P 0.56 multi-quantum-well (MQW) structure, the carrier temperature extracted from photoluminescence rises faster for 405 nm compared with 980 nm excitation, as the injected carrier density increases. Ensemble Monte Carlo simulation of the carrier dynamics in the MQW system shows that this carrier temperature rise is dominated by nonequilibrium LO phonon effects, with the Pauli exclusion having a significant effect at high carrier densities. Further, we find a significant fraction of carriers reside in the satellite L-valleys for 405 nm excitation due to strong intervalley transfer, leading to a cooler steady-state electron temperature in the central valley compared with the case when intervalley transfer is excluded from the model. Good agreement between experiment and simulation has been shown, and detailed analysis has been presented. This study expands our knowledge of the dynamics of the hot carrier population in semiconductors, which can be applied to further limit energy loss in solar cells.

42 ENGINEERING↗

NASA NTRS1983

Radiation enhancement by nonequilibrium in earth's atmosphere

The status of knowledge of shock-layer radiation in the low-density, nonequilibrium regime, as appropriate to the flight of the proposed aero-assisted orbital transfer vehicle, is surveyed. The existing laboratory data and the flight data from Apollo and Fire are scrutinized. Nonequilibrium radiation is found to be significant in the flight regime of the vehicle, but a factor of 3 uncertainty is found in its magnitude. The available theoretical models are reviewed, their weaknesses are pointed out, a computer code that approximately reproduces the existing data is introduced, and recommendations are made for future research.

Park, C.↗

NASA NTRS1984

Directional reflectance factor distributions of a cotton row crop

The directional reflectance factor distribution spanning the entire exitance hemisphere was measured for a cotton row crop (Gossypium barbadense L.) with 39 percent ground cover. Spectral directional radiances were taken in NOAA satellite 7 AVHRR bands 1 and 2 using a three-band radiometer with restricted 12 deg full angle field of view at half peak power points. Polar co-ordinate system plots of directional reflectance factor distributions and three-dimensional computer graphic plots of scattered flux were used to study the dynamics of the directional reflectance factor distribution as a function of spectral band, geometric structure of the scene, solar zenith and azimuth angles, and optical properties of the leaves and soil. The factor distribution of the incomplete row crops was highly polymodal relative to that for complete vegetation canopies. Besides the enhanced reflectance for the antisolar point, a reflectance minimum was observed towards the forwardscatter direction in the principle plane of the sun. Knowledge of the mechanics of the observed dynamics of the data may be used to provide rigorous validation for two- or three-dimensional radiative transfer models, and is important in interpreting aircraft and satellite data where the solar angle varies widely.

Kimes, D. S.↗

NASA NTRS1987

Determination of surface shear stress with the naphthalene sublimation technique

Aeolian entrainment and transport are functions of surface shear stress and particle characteristics. Measuring surface shear stress is difficult, however, where logarithmic wind profiles are not found, such as regions around large roughness elements. An outline of a method whereby shear stress can be mapped on the surface around an object is presented. The technique involves the sublimation of naphthalene (C10H8) which is a function of surface shear stress and surface temperature. This technique is based on the assumption that the transfer of momentum, heat and mass are analogous (Reynolds analogy). If the Reynolds analogy can be shown to be correct for a given situation, then knowledge of the diffusion of one property allows the determination of the others. The analytical framework and data acquisition for the method are described. The technique was tested in the Planetary Geology Wind Tunnel. Results show that the naphthalene sublimation technique is a reasonably accurate method for determining shear stress, particularly around objects where numerous point values are needed.

Lee, J. A.↗

DOE OSTI2022

Micro Baselines for Operational Technology Environments

Critical infrastructure stakeholders need to baseline their networks to understand expected communications. Top-down approaches to baselining rely on observables that are generally available but lack properties upon which traditional statistical tools depend. We propose to construct micro-baselines: signatures within operational networks based on observables associated with specific events. Such observables are informed by precursor analysis reports of historical cyber attacks on operational environments developed by Cybersecurity for Operational Technology Environments (CyOTE). Baseline measurements depend upon context beyond the cyber domain. An energy plant's baseline running in the summer may statistically differ from a similar facility in a colder region. Domain knowledge must be integrated to apply general micro-baselining algorithms to a facility-specific context. Therefore, we propose to explore the feasibility of transferring micro baselining algorithms across different facilities. Facilities that implement the same processes in different geographic locations will be compared relative to observable measurements used in micro-baselining for comparable events. One evaluation approach would condition or augment dynamic observables measured within a facility network testbed with additional observables derived from geographic context or infrastructure dependencies such as those provided by the All-Hazards Analysis tool.

97 MATHEMATICS AND COMPUTING↗

NASA NTRS1957

The Principles of Turbulent Heat Transfer

The literature on turbulent heat transfer has in the course of years attained a considerable volume. Since this very complicated problem has not as yet found a complete solution, further studies in this field may be expected. The heat engineer must therefore accomodate himself to a constantly increasing number of theories and formulas. Since the theories generally start from hypothetical assumptions, and since they contain true and false assertions, verified knowledge and pure suppositions often being intermingled in a manner difficult to tell them apart, the specialist had difficulty in forming a correct evaluation of the individual studies. The need therefore arises for a presentation of the problem of turbulent heat transfer which is not initially bound by hypothetical assumptions and in which uninvestigated can be clearly distinguished form each other. Such a presentation will be given in the present treatment. Brief remarks with regard to the development of the theory of local heat transfer are included.

Reichardt, H.↗

NASA NTRS1998

Evaluation of Cabin Crew Technical Knowledge

Accident and incident reports have indicated that flight attendants have numerous opportunities to provide the flight-deck crew with operational information that may prevent or essen the severity of a potential problem. Additionally, as carrier fleets transition from three person to two person flight-deck crews, the reliance upon the cabin crew for the transfer of this information may increase further. Recent research (Chute & Wiener, 1996) indicates that light attendants do not feel confident in their ability to describe mechanical parts or malfunctions of the aircraft, and the lack of flight attendant technical training has been referenced in a number of recent reports (National Transportation Safety Board, 1992; Transportation Safety Board of Canada, 1995; Chute & Wiener, 1996). The present study explored both flight attendant technical knowledge and flight attendant and dot expectations of flight attendant technical knowledge. To assess the technical knowledge if cabin crewmembers, 177 current flight attendants from two U.S. carriers voluntarily :ompleted a 13-item technical quiz. To investigate expectations of flight attendant technical knowledge, 181 pilots and a second sample of 96 flight attendants, from the same two airlines, completed surveys designed to capture each group's expectations of operational knowledge required of flight attendants. Analyses revealed several discrepancies between the present level of flight attendants.

Dunbar, Melisa G.↗

DOE OSTI2020

The Link Between the Ecology of the Prokaryotic Rare Biosphere and Its Biotechnological Potential

Current research on the prokaryotic low abundance taxa, the prokaryotic rare biosphere, is growing, leading to a greater understanding of the mechanisms underlying organismal rarity and its relevance in ecology. From this emerging knowledge it is possible to envision innovative approaches in biotechnology applicable to several sectors. Bioremediation and bioprospecting are two of the most promising areas where such approaches could find feasible implementation, involving possible new solutions to the decontamination of polluted sites and to the discovery of novel gene variants and pathways based on the attributes of rare microbial communities. Bioremediation can be improved through the realization that diverse rare species can grow abundant and degrade different pollutants or possibly transfer useful genes. Further, most of the prokaryotic diversity found in virtually all environments belongs in the rare biosphere and remains uncultivatable, suggesting great bioprospecting potential within this vast and understudied genetic pool. This Mini Review argues that knowledge of the ecophysiology of rare prokaryotes can aid the development of future, efficient biotechnology-based processes, products and services. However, this promise may only be fulfilled through improvements in (and optimal blending of) advanced microbial culturing and physiology, metagenomics, genome annotation and editing, and synthetic biology, to name a few areas of relevance. In the future, it will be important to understand how activity profiles relate with abundance, as some rare taxa can remain rare and increase activity, whereas other taxa can grow abundant. The metabolic mechanisms behind those patterns can be useful in designing biotechnological processes.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2021

AtomSets as a hierarchical transfer learning framework for small and large materials datasets

Abstract Predicting properties from a material’s composition or structure is of great interest for materials design. Deep learning has recently garnered considerable interest in materials predictive tasks with low model errors when dealing with large materials data. However, deep learning models suffer in the small data regime that is common in materials science. Here we develop the AtomSets framework, which utilizes universal compositional and structural descriptors extracted from pre-trained graph network deep learning models with standard multi-layer perceptrons to achieve consistently high model accuracy for both small compositional data (<400) and large structural data (>130,000). The AtomSets models show lower errors than the graph network models at small data limits and other non-deep-learning models at large data limits. They also transfer better in a simulated materials discovery process where the targeted materials have property values out of the training data limits. The models require minimal domain knowledge inputs and are free from feature engineering. The presented AtomSets model framework can potentially accelerate machine learning-assisted materials design and discovery with less data restriction.

Chen, Chi (ORCID:0000000180087043)↗

DOE OSTI2015

Radiative corrections beyond the ultra relativistic limit in unpolarized ep elastic and Møller scatterings for the PRad Experiment at Jefferson Laboratory

The clear 7σ discrepancy between measurements of the proton charge radius from muonic hydrogen Lamb shifts and those from hydrogen Lamb shift and electron scattering lead to both intense theoretical and experimental efforts to understand and explain this difference. In this regard, a new experiment (PRad) based on unpolarized ep elastic scattering cross section measurements normalized to Møller scattering is underway at Jefferson Laboratory to extract the proton charge radius based on new proton electric form factor down to values of momentum transfer squared Q 2 , as low as 10 -4 GeV/c) -2 . Reaching the precision of the experiment in such a small Q 2 region requires reliable knowledge of radiative corrections. In this paper, we present a complete calculation of radiative corrections for unpolarized elastic ep and Møller scatterings performed within a covariant formalism resulting in the set of explicit formulas beyond the ultra relativistic approximation (m e 2 &NestedLessLess; Q 2 ), and numerical results for the kinematics of the PRad experiment.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1974

Space Trajectory Error Analysis Program (STEAP) for halo orbit missions. Volume 1: Analytic and user's manual

Development, test, conversion, and documentation of computer software for the mission analysis of missions to halo orbits about libration points in the earth-sun system is reported. The software consisting of two programs called NOMNAL and ERRAN is part of the Space Trajectories Error Analysis Programs (STEAP). The program NOMNAL targets a transfer trajectory from Earth on a given launch date to a specified halo orbit on a required arrival date. Either impulsive or finite thrust insertion maneuvers into halo orbit are permitted by the program. The transfer trajectory is consistent with a realistic launch profile input by the user. The second program ERRAN conducts error analyses of the targeted transfer trajectory. Measurements including range, doppler, star-planet angles, and apparent planet diameter are processed in a Kalman-Schmidt filter to determine the trajectory knowledge uncertainty. Execution errors at injection, midcourse correction and orbit insertion maneuvers are analyzed along with the navigation uncertainty to determine trajectory control uncertainties and fuel-sizing requirements. The program is also capable of generalized covariance analyses.

Byrnes, D. V.↗

NASA NTRS1974

Space Trajectory Error Analysis Program (STEAP) for halo orbit missions. Volume 2: Programmer's manual

The six month effort was responsible for the development, test, conversion, and documentation of computer software for the mission analysis of missions to halo orbits about libration points in the earth-sun system. The software consisting of two programs called NOMNAL and ERRAN is part of the Space Trajectories Error Analysis Programs. The program NOMNAL targets a transfer trajectory from earth on a given launch date to a specified halo orbit on a required arrival date. Either impulsive or finite thrust insertion maneuvers into halo orbit are permitted by the program. The transfer trajectory is consistent with a realistic launch profile input by the user. The second program ERRAN conducts error analyses of the targeted transfer trajectory. Measurements including range, doppler, star-planet angles, and apparent planet diameter are processed in a Kalman-Schmidt filter to determine the trajectory knowledge uncertainty.

Byrnes, D. V.↗

NASA NTRS1998

Computational Analysis of Shock Layer Emission Measurements in an Arc-Jet Facility

This paper reports computational analysis of radiation emission experiments in a high enthalpy arc-jet wind tunnel at NASA Ames Research Center. Recently, as part of ongoing arc-jet characterization work, spectroscopic radiation emission experiments have been conducted at the 20 MW NASA Ames arc-jet facility. The emission measurements were obtained from the arc-jet freestream and from a shock layer formed in front of flatfaced models. Analysis of these data is expected to provide valuable information about the thermodynamic state of the gas in the arc-jet freestream and in the shock layer as well as thermochemical equilibration processes behind the shock in arc-jet flows. Knowledge of the thermodynamic state of the gas in arc-jet test flows and especially within the shock layer is essential to interpret the heat transfer measurements such as in surface catalysis experiments. The present work is a continuation of previous work and focuses on analysis of the emission data obtained at relatively low-pressure conditions for which the arc-jet shock layer is expected to be in thermal and chemical nonequilibrium. Building blocks of the present computational analysis are: (1) simulation of nonequilibrium expanding flow in the converging-diverging conical nozzle and supersonic jet; (2) simulation of nonequilibrium shock layer formed in front of the flat-faced cylinder model; and (3) prediction of line-of-sight radiation from the computed flowfield. For computations of the nonequilibrium flow in the conical nozzle and shock layer, multi-temperature nonequilibrium codes with the axisymmetric formulation are used. For computations of line-of-sight radiation. a nonequilibrium radiation code (NEQAIR) is used to predict emission spectra from the computed flowfield. Computed line-of-sight averaged flow properties such as vibrational and rotational temperatures, species number densities within the shock layer will be compared with those deduced from the experimental spectra. Detailed comparisons of computational and experimental spectra will also be presented.

Gokcen, Tahir↗

NASA NTRS2010

Human Research Program Exploration Medical Capability

NASA s Human Research Program (HRP) conducts and coordinates research projects that provide human health and performance countermeasures, knowledge, technologies, and tools to enable safe, reliable, and productive human space exploration. The Program is divided into 6 major elements, which a) Provide the Program s knowledge and capabilities to conduct research, addressing the human health and performance risks. b) Advance the readiness levels of technology and countermeasures to the point of transfer to the customer programs and organizations. The National Space Biomedical Research Institute (NSBRI) is a partner with the HRP in developing a successful research program. 3

Barsten, Kristina↗

NASA NTRS2017

Mind the Gap: Exploring the Underground of the NASA Space Cancer Risk Model

The REID quantifies the lifetime risk of death from radiation-induced cancer in an exposed astronaut. The NASA Space Cancer Risk (NSCR) 2012 mode incorporates elements from physics, biology, epidemiology, and statistics to generate the REID distribution. The current model quantifies the space radiation environment, radiation quality, and dose-rate effects to estimate a NASA-weighted dose. This weighted dose is mapped to the excess risk of radiation-induced cancer mortality from acute exposures to gamma rays and then transferred to an astronaut population. Finally, the REID is determined by integrating this risk over the individual's lifetime. The calculated upper 95% confidence limit of the REID is used to restrict an astronaut's permissible mission duration (PMD) for a proposed mission. As a statistical quantity characterized by broad, subjective uncertainties, REID estimates for space missions result in wide distributions. Currently, the upper 95% confidence level is over 350% larger than the mean REID value, which can severely limit an astronaut's PMD. The model incorporates inputs from multiple scientific disciplines in the risk estimation process. Physics and particle transport models calculate how radiation moves through space, penetrates spacecraft, and makes its way to the human beings onboard. Epidemiological studies of exposures from atomic bombings, medical treatments, and power plants are used to quantify health risks from acute and chronic low linear energy transfer (LET) ionizing radiation. Biological studies in cellular and animal models using radiation at various LETs and energies inform quality metrics for ions present in space radiation. Statistical methodologies unite these elements, controlling for mathematical and scientific uncertainty and variability. Despite current progress, these research platforms contain knowledge gaps contributing to the large uncertainties still present in the model. The NASA Space Radiation Program Element (SRPE) defines the knowledge gaps that impact our understanding of the cancer risks. These gaps are outlined in NASA's Human Research Roadmap [4], which identifies the research questions and actions recommended for reducing the uncertainty in the current NSCR model and for formulation of future models. The greatest contributors to uncertainty in the current model include radiation quality, dose rate effects, and the transfer of exposure-based risk from other populations to an astronaut population. Future formulations of the risk model may benefit from including other potential sources of uncertainty such as space dosimetry, errors in human epidemiology data, and the impact of microgravity and other spaceflight stressors. Here, we discuss the current capabilities of the NSCR-2012 model and several immediate research needs, highlighting areas expected to have an operational impact on the current model schema. The following subway-style route map outlines the NSCR-2012 model (Green Line), emphasizing the research gaps in the Human Research Roadmap for risk of radiation-induced carcinogenesis (Stops on Dashed Lines). The map diagrams how these research gaps feed specific portions of the model.

Chappell, L. J.↗

DOE OSTI2026

Validated Reactive Force Field Quantifies MXene Interfacial Properties, Mechanics, and Thermal Transport

MXenes combine rich surface chemistry, mechanical strength, and high conductivity for a multitude of emerging applications. Predictive modeling supports accelerated materials designs and has been limited by the absence of validated and transferable force fields. Here, we introduce an interpretable, reactive INTERFACE force field (IFF and IFF-R) for Ti 3 C 2 T x MXenes that is trained based on chemical knowledge and achieves quantitative agreement with experiments across lattice parameters (<0.5%), density (<0.2%), liquid contact angles, Raman spectra, and the in-plane elastic modulus (∼320 GPa). The models cover surface terminations from hydroxyl (−OH) to fluorine (−F) groups and are extensible to other chemistries. We introduce pH-resolved surface chemistry and identify dopamine adsorption mechanisms at MXene–aqueous interfaces supported by QCM-D and UV–Vis experiments. The data reveal coplanar and perpendicular binding modes and concentration-dependent multilayer assembly. We predict previously inaccessible properties, including termination-dependent cleavage energies, interlayer shear moduli and dynamic shear failure, nanoindentation and brittle fracture, anisotropic in-plane and out-of-plane thermal conductivities, including the role of defects. Agreement with available experimental data is consistently close and exceeds DFT accuracy across the benchmark properties examined. The IFF/IFF-R model is compatible with CHARMM, AMBER, OPLS, and CVFF force fields for simulations of MXenes with diverse surface terminations, electrolyte interfaces, biointerfaces, and polymer composites without additional parameters. Parameter sets, 3D models, and analysis scripts are provided for community use. The validated, reactive, and transferable IFF framework facilitates predictive design of MXene-based films, membranes, sensing interfaces, and composites.

MXene↗