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Significant features in the collision strengths for electron-impact excitation of the fine-structure transition 2P0 1/2 - 2P0 3/2 and the resonance transition 2P0 - 2D in C(+) are discussed based on improved calculations. The former transition gives rise to a well-known (2,3) line in the infrared spectra of many astrophysical sources.
A software-based method for real-time, active stabilization of tunable diode laser spectral scans is described. The procedure is suitable for use with field and laboratory instrumentation where automated, unattended spectrometer operation is required. An autocorrelation of two high-resolution reference gas infrared spectra is computed at regular intervals, and the location of the maximum value of the autocorrelation provides the relative abscissa shift between the spectra. Small adjustments to the laser scan parameters are thereby made to ensure that drifts in the laser output frequency are tracked and compensated. Calculations required for stabilization of a 512-point spectrum can be completed in under 25 ms using an inexpensive, moderate-speed, array processor installed in a PC.
The e-H2O collisional rate for exciting rotational transitions in cometary water is evaluated for conditions found in comet Halley during the Giotto spacecraft encounter. In the case of the O(sub 00) yields 1(sub 11) rotational transition, the e-H2O collisional rate exceeds that for excitation by neutral-neutral collisions at distances exceeding 3000 km from the cometary nucleus. Thus, the rotational temperature of the water molecule in the intermediate coma may be controlled by collisions with electrons rather than with neutral collisions, and the rotational temperature retrieved from high resolution infrared spectra of water in comet Halley may reflect electron temperatures rather than neutral gas temperature in the intermediate coma.
Earlier researchers derived the relative distance between the Coma and Virgo clusters from color-magnitude relations of the early-type galaxies in each cluster. They found that the derived distance was color-dependent and concluded that the galaxies of similar luminosity in the two clusters differ in their red stellar populations. More recently, the color-dependence of the Coma-Virgo distance modulus has been called into question. However, because these two clusters differ so dramatically in their morphologies and kinematics, it is plausible that the star formation histories of the member galaxies also differed. If the conclusions of earlier researchers are indeed correct, then some signature of the resulting stellar population differences should appear in the near-infrared and/or infrared light of the respective galaxies. We have collected near-infrared spectra of 17 Virgo and 10 Coma early-type galaxies; this sample spans about four magnitudes in luminosity in each cluster. Seven field E/S0 galaxies have been observed for comparison. Pseudo-equivalent widths have been measured for all of the field galaxies, all but one of the Virgo members, and five of the Coma galaxies. The features examined are sensitive to the temperature, metallicity, and surface gravity of the reddest stars. A preliminary analysis of these spectral features has been performed, and, with a few notable exceptions, the measured pseudo-equivalent widths agree well with previously published values.
The use of the He I 2.06 microns/Br-gamma ratio as a constraint on the massive stellar population in star-forming galaxies is developed. A theoretical relationship between the He I 2.06 microns/Br-gamma ratio and the effective temperature of the exciting star in H II regions is derived. The effects of collisional excitation and dust within the nebula on the ratio are also considered. It is shown that the He I 2.06 microns/Br-gamma ratio is a steep function of the effective temperature, a property which can be used to determine the upper mass limit of the initial mass function (IMF) in galaxies. This technique is reliable for upper mass limits less than about 40 solar masses. New near-infrared spectra of starburst galaxies are presented. The He I 2.06 microns/Br-gamma ratios observed imply a range of upper mass limits from 27 to over 40 solar masses. There is also evidence that the upper mass limit is spatially dependent within a given galaxy. These results suggest that the upper mass limit is not a uniquely defined parameter of the IMF and probably varies with local physical conditions.
Infrared spectra of dusty galactic environments often contain emission features attributed to polycyclic aromatic hydrocarbons or PAHs, which can be considered to be very small grains or very large molecules. Although IR spectra of starburst galaxies almost always show these emission features, similar spectra of active galaxies are usually featureless. Even in those active galaxies that do exhibit PAH emission, the PAHs still appear to be eradicated from the nuclear region. This dichotomy suggests that PAHs are destroyed by the intense hard radiation field from an AGN. Laboratory experiments show that certain PAHs are, in fact, so effectively destroyed by individual EUV and X-ray photons that they cannot survive even at kiloparsec distances from active nuclei. Regions within active galaxies that do show PAH emission must therefore be shielded from the central X-ray source by a substantial column density of X-ray absorbing gas.
Absorption features of several trace gases have been detected in 0.017-cm-resolution infrared spectra recorded over surface-level paths of 0.5 and 1.5 km at the National Solar Observatory on Kitt Peak, near Tucson, Arizona. Measurements of O3, HCOOH, NH3, and H2CO are briefly discussed.
The paper discusses the correlated k(absorption coefficient)-distribution (CKD) method for radiative transfer in nonhomogeneous atmospheres, in terms of the physical and mathematical conditions under which this method is valid. The CKD approach is theoretically formulated, and the mathematical and physical conditions under which this method is valid are identified. The parameterization for incorporating pressure and temperature effects in the k distribution is presented. The errors of CKD for absorption bands in the solar and thermal infrared spectra are examined, and the errors due to both the CKD method and the use of the optimum number of quadrature points are identified. Finally, an overall treatment for various absorption bands is developed, which will provide high efficiency and accuracy.
The VIMS instrument (Visible and Infrared Mapping Spectrometer) will be flown in the late 1990s on the CASSINI mission to Saturn and its moons. VIMS is designed to generate two-dimensional multispectral images of planetary surfaces and their features in the visible and infrared spectra. Compared to earth-based instruments, the stellar occultation experiment will provide unprecedented thickness resolution and chemical composition of planetary atmospheres. It will also gather high SNR optical depth profiles and particle size distribution of the Saturnian rings. The stellar occultation mode ideally requires continuous data acquisition for periods of up to several hours as the instrument stares at a star. This presents a sizeable challenge to the instrument's operational mode: processes that normally occur during mirror retrace must be shifted to data acquisition cycles, thereby creating timing difficulties in the sequencing of these cycles. The presentation focuses on the analysis of the stellar occultation mode and presents solutions to the challenge of an uninterrupted data stream. Several options will be presented that minimize any possible degradation of the experiment's science content.
Infrared spectra of thin films of pure CH4 have been measured for a range of temperatures from 22 to 68 K. The bandwidth for the fundamental nu3 near 3000/cm varies from 12.7 to 33.2/cm, while that for nu4 near 1300/cm varies from 6.2 to 16.0/cm. The real and imaginary parts of the index of refraction also exhibit significant dependence on temperature. These broadband measurements at low temperatures are useful for an understanding of clouds and hazes in the atmosphere of Uranus, clouds and ices in the atmosphere of Titan, and ices on the surfaces of Pluto and Triton.
The chemical characterization of a thermoplastic resin exposed to the low Earth orbit (LEO) environment for 10 months and for 5.8 years is reported. The resin, processed as a thick film and as a matrix for a graphite fiber reinforced composite, few exposed in the RAM direction on the NASA Long Duration Exposure Facility (LDEF). Differences attributable to environmental exposure were detected in infrared spectra and in various molecular weight parameters of film after 10 months in LEO. Those effects were not as apparent in composites after 5.8 years in LEO. Increased exposure to atomic oxygen toward the end of the LDEF mission probably scrubbed these effects from specimens exposed for 5.8 years. The intent of this study is to increase our fundamental understanding of space environmental effects on polymeric materials and to develop a benchmark for enhancing our methodology for and understanding of the ground-based simulation of space environmental effects.
Accurate frequencies for the lowest rotational transitions of five transition metal hydrides (CrH, FeH, CoH, NiH, and CuH) in their ground electronic states are reported to help the identification of these species in astrophysical sources from their far-infrared spectra. Accurate frequencies are determined in two ways: for CuH, by calculation from rotational constants determined from higher J transitions with an accuracy of 190 kHz; for the other species, by extrapolation to zero magnetic field from laser magnetic resonance spectra with an accuracy of 0.7 MHz.
The surfaces of atmosphereless bodies are subjected to a variety of chemical, thermal, accretionary, and shock processes related to their regolith environment. These processes are responsible for a number of alterations that occur in regoliths. Alterations include particle size commutation, implantation of solar wind gases, formation of agglutinates, spectral darkening, and, in the lunar case, the development of the very strong red continuum slope in the visible and near infrared spectra. A great deal of work has pointed to the role of agglutinates as the principal agent for darkening and reddening the lunar soil. The measures of regolith maturity are strongly linked to the accumulation of agglutinates. Recent work has suggested that the finest fractions of agglutinitic glass are major source of the spectral red slope. In particular, the red slope is most strongly associated with the agglutinitic glasses that are rich in blebs of sub-micron sized metal particles. It is thought that these metal particles, because of their size and scattering efficiently relative to the wavelength of light, are responsible for the red continuum slope. This fine fraction of metal particles is produced primarily by reduction of Fe(+2) from silicates. One mechanism for the reduction process is the reaction of solar implanted wind protons with the regolith soil during impact events. In this case the presence of hydrogen creates a reducing environment and the thermal pulse from the impact greatly speeds the reaction kinetics. To explore other reducing and thermal environments a series of experiments were done using samples in evacuated capsules buffered by Tantalum and heated to subsolidus temperatures.
Spatial variations in infrared spectra of the seasonal south polar cap of Mars were noted by the original Mariner 7 IRS instrument team as well as in subsequent examinations of the Mariner 7 data set. Up to now, however, there has been little effort to synthesize this information to understand variations in the south seasonal cap as a function of position or latitude. An attempt to quantify the spectra is made by providing estimates of CO2 grain sizes as well as upper limits on the amount of water frost contained in the polar collar. The variation in brightness at two wavelengths as well as the band depth of a weak CO2-ice feature at 2.28 microns as a function of spectrum number or subsequent location on the cap is presented. The full spectra, corrected only for the solar incidence angle, of three of the most significant areas are compared.
During the Galileo spacecraft encounter with the Earth-Moon system in December, 1992, a variety of spectral data and imagery were obtained for the eastern limb region as well as much of the lunar nearside. In order to support this encounter, we have been collecting near-infrared spectra and other remote sensing data for that portion of the northeastern nearside (NEM region) for which the highest resolution Galileo data were obtained. Analysis of spectra obtained for highlands units in the NEN region indicates that most surface units are dominated by anorthositic norite. To date, no pure anorthosites have been identified in the region. Several dark-haloed impact craters have exposed mare material from beneath highlands-rich surface units. Hence, ancient mare volcanism occurred in at least a portion of the NEN region. Endogenic dark-haloed craters in the region are the source of localized dark mantle deposits (LDMD) of pyroclastic origin and at least two compositional groups are present. The Galileo spacecraft obtained very high-resolution remote sensing data for the northeastern part of the nearside of the Moon. In order to prepare for and support this encounter, we have collected and analyzed a variety of spectral data for the NEN region. Numerous unanswered questions exist for this region. These include: (1) the composition and stratigraphy of the local highlands crust, (2) the nature and mode of formation of regional light plains, (3) the composition of localized pyroclastic deposits, and (4) the distribution of possible cryptomare in the region. The purpose of this paper is to present the preliminary results of our analyzes of remote sensing data of remote sensing data obtained for the NEN region.
The crater Bullialdus is a 61 km, Eratosthenian-age impact crater located on the western edge of Mare Nubium. Previous analysis of the spatial distribution of materials in the area using nine telescopic near-infrared spectra suggested a possible three-layer structure prior to the impact event: two shallow gabbroic layers and one deeper noritic layer (from a potential depth of 5.5 km). The initial interpretation of this stratigraphy was that Bullialdus may have tapped a layered mafic pluton, such as have been invoked to explain the existence of Mg-suite rocks. High-spatial resolution CCD images of Bullialdus were analyzed to better map the spatial distribution of the observed lithologies, and to assess the plausibility of the pluton interpretation.
Supernova 1993J in the nearby galaxy M81 is one of the closest - and hence brightest - supernovae to be witnessed this century. The early spectrum of SN1993J showed the characteristic hydrogen signature of type II supernovae, but its subsequent evolution is atypical for this class of supernova. Here we present optical and infrared spectra of SN1993J up to 43 days after outburst, which reveal the onset of the helium absorption and emission features more commonly associated with hydrogen-free type Ib supernovae. Corresponding model spectra show that the progenitor star must have possessed an unusually thin (for type II supernovae) hydrogen-rich envelope overlying a helium-rich mantle. Moreover, the supernova ejecta must have remained compositionally stratified, with little transport of the hydrogen-rich material down into the underlying helium layer or mixing of heavier elements outwards. SN1993J therefore represents a transition object between hydrogen-dominated type II supernovae, and hydrogen-free, helium-dominated type Ib supernovae.
The remote sensing of objects in the solar system using infrared radiation is discussed. Theories of radiative transfer, molecular spectroscopy, and atmospheric physics are used to show how infrared spectra of model planetary atmospheres are calculated. Instrumental techniques are described and the effect of instruments on the measurement of the emerging radiation field is addressed. Techniques that allow the retrieval of atmospheric and surface parameters from observations are examined. All the planets except Pluto are studied, and many of the planetary satellites.