Phase I Final Technical Report Award Number: DE-SC0017227 Microwave-Fluidized Catalytic Reactor for the Direct Conversion of Methane to Higher Hydrocarbons
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03 NATURAL GAS↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Disentangling the effects of non-adiabatic interactions upon ion self-diffusion within warm dense hydrogen
Warm dense matter is a material state in the region of parameter space connecting condensed matter to classical plasma physics. In this intermediate regime, we investigate the significance of non-adiabatic electron-ion interactions upon ion dynamics. To disentangle non-adiabatic from adiabatic electron-ion interactions, we compare the ion self-diffusion coefficient from the non-adiabatic electron force field computational model with an adiabatic, classical molecular dynamics simulation. A classical pair potential developed through a force-matching algorithm ensures the only difference between the models is due to the electronic inertia. Here, we implement this new method to characterize non-adiabatic effects on the self-diffusion of warm dense hydrogen over a wide range of temperatures and densities. Ultimately we show that the impact of non-adiabatic effects is negligible for equilibrium ion dynamics in warm dense hydrogen.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Triton torus and Neptune aurora
Triton is shown to be the dominant source of plasma for L equal to or greater than 7 in the magnetosphere of Neptune. Triton maintains a neutral hydrogen torus of average density comparable to a greater than that of the Titan torus at Saturn. The Triton torus may be detectable in H Lyman-alpha emissions. However, the energy source from plasma outward transport and mass loading in the Triton torus is insufficient to explain the Neptune aurora. It is proposed that Neptune's aurora is driven mainly by a solar wind interaction.
Cheng, Andrew F.↗
The low energy plasma in the Uranian magnetosphere
The Plasma Science experiment on Voyager 2 detected a magnetosphere filled with a tenuous plasma, rotating with the planet. Temperatures of the plasma, composed of protons and electrons, ranged from 10 eV to about 1 keV. The sources of these protons and electrons are probably the ionosphere of Uranus or the extended neutral hydrogen cloud surrounding the planet. As at earth, Jupiter, and Saturn, there is an extended magnetotail with a central plasma sheet. Although similar in global structure to the magnetospheres of these planets, the large angle between the rotation and magnetic axes of the planet and the orientation of the rotation axis with respect to the solar wind flow make the Uranian magnetosphere unique.
Mcnutt, R. L., Jr.↗
Plasma-parameter dependence of ro-vibrational temperatures for H 2 in LHD divertor
We analyzed a thousand visible spectra of Fulcher-α band measured for divertor plasmas in Large Helical Device. With a coronal model and Bayesian inference, the population distribution of hydrogen molecule in the electronic ground state was estimated. The non-thermal population distribution was recovered with a two-temperature model, which has two sets of rotational and vibrational temperatures, as well as their mixture coefficient. The lower rotational temperature significantly changes according to the plasma parameters. Its nearly linear dependence on the electron density was found, which is consistent with previous works. The lower vibrational temperature also shows a small density dependence, as reported by a previous work. On the other hand, the higher rotational and vibrational temperatures as well as the mixture coefficient only show slight changes over the broad range of plasma parameters. These population parameters show a significant correlation; with higher electron density, all the temperatures and the fraction of the higher-temperature component increase simultaneously. In conclusion, this suggests that the electron impact plays an important role to determine the population distribution.
42 ENGINEERING↗
Predicted satellite plasma tori in the magnetosphere of Uranus
The paper formulates the rate equations for twelve species: water, hydroxyl, molecular and atomic oxygen, molecular and atomic hydrogen, and their respective first ions for conditions expected to hold in the magnetosphere of Uranus. These equations have been solved numerically for maximal and minimal source strengths of the five known satellites, and the expected neutral and plasma number densities in the tori predicted to be associated with them have been calculated. It is found that under most conditions, there should be a sensible plasma torus associated with each satellite whose orbit is enclosed within the assumed magnetosphere.
Eviatar, A.↗
Hollow-cathode chemical vapor deposition of thick, low-stress diamond-like carbon films
A radio-frequency (RF), hollow-cathode plasma source with confining magnetic field is described for the chemical vapor deposition of thick ( > 10 µm), amorphous diamond-like carbon ablator films for inertial confinement fusion applications. Plasma is characterized by optical emission spectroscopy, while properties of the resultant films are measured by a combination of profilometry, Rutherford backscattering spectrometry, elastic recoil detection analysis, X-ray diffraction, Raman spectroscopy, and atomic force microscopy. The dependence of the deposition rate, film density, elemental composition, self-bias and residual stress is reported as a function of RF power. Higher density films were found when using Ar plasma, than N 2 or H 2 plasma. The coatings produced are x-ray amorphous, exhibit low compressive stress ( ~ 100 MPa), high density ( < 1.7 g/cm 3 ), hydrogen content of ~ 30 at.%, and a low average roughness of 0.75 nm. Finally, applications of these films as tunable-density ablators for inertial confinement fusion experiments are discussed.
36 MATERIALS SCIENCE↗
Neutral Atom Imaging of the Solar Wind-Magnetosphere-Exosphere Interaction Near the Subsolar Magnetopause
Energetic neutral atoms (ENAs) created by charge-exchange of ions with the Earth's hydrogen exosphere near the subsolar magnetopause yield information on the distribution of plasma in the outer magnetosphere and magnetosheath. ENA observations from the Interstellar Boundary Explorer (IBEX) are used to image magnetosheath plasma and, for the first time, low-energy magnetospheric plasma near the magnetopause. These images show that magnetosheath plasma is distributed fairly evenly near the subsolar magnetopause; however, low-energy magnetospheric plasma is not distributed evenly in the outer magnetosphere. Simultaneous images and in situ observations from the Magnetospheric Multiscale (MMS) spacecraft from November 2015 (during the solar cycle declining phase) are used to derive the exospheric density. The ~11–17 cm –3 density at 10 R E is similar to that obtained previously for solar minimum. Thus, these combined results indicate that the exospheric density 10 R E from the Earth may have a weak dependence on solar cycle.
79 ASTRONOMY AND ASTROPHYSICS↗
Simulator test to study hot-flow problems related to a gas cooled reactor
An advance study of materials, fuel injection, and hot flow problems related to the gas core nuclear rocket is reported. The first task was to test a previously constructed induction heated plasma GCNR simulator above 300 kW. A number of tests are reported operating in the range of 300 kW at 10,000 cps. A second simulator was designed but not constructed for cold-hot visualization studies using louvered walls. A third task was a paper investigation of practical uranium feed systems, including a detailed discussion of related problems. The last assignment resulted in two designs for plasma nozzle test devices that could be operated at 200 atm on hydrogen.
Poole, J. W.↗
Plasma observations near Saturn - Initial results from Voyager 2
Results of plasma measurements made by Voyager 2 in the vicinity of Saturn are discussed and compared with those made by Pioneer 11 and Voyager 1 in a more limited range of latitudes. The initial bow shock crossing on the inbound trajectory closely agreed with the shock position inferred from the external ram pressure in the solar wind, although boundaries on the outbound pass were much further out than expected. Magnetospheric plasma observations reveal the presence of (1) shocked solar wind plasma in the magnetosheath between 30 and 22 Saturn radii; (2) a variable density region between 17 Saturn radii and the magnetopause; (3) an extended thick plasma sheet between 17 and 7 Saturn radii; and (4) an inner plasma torus probably originating from local sources. The ratio of heavy to light ions was observed to vary with distance to the equatorial plane in the dayside magnetosphere, with the heavy ions, probably O(+), more closely confined to the equatorial plane. The plasma data also account for the observed inner boundary of the neutral hydrogen torus discovered by Voyager 1.
Bridge, H. S.↗
Space observations of comet Halley
Observations of comet Halley by the Solar Maximum Mission, the International Ultraviolet Explorer, the Pioneer Venus Orbiter, the Dynamics Explorer 1, and by sounding rockets are reviewed. Visual images taken through the wide-band blue filter showed an extended coma elongated approximately in the antisolar direction. Preperihelion observations show definite evidence for both a plasma and a dust tail. The ultraviolet observations indicate that an extensive hydrogen cloud extends to well over 10 billion km from the nucleus. The derived water production rate for the comet showed very large changes around the time of perihelion. The rocket observations showed strong H I, O I, and C I emissions, several CO fourth positive bands, and the C II emissions at 1335 A extending into the tail.
Brandt, J. C.↗
Experimental identification of electrostatic plasma waves within ion conic acceleration regions
The identification of electrostatic modes in the ionospheric and magnetospheric plasma is a difficult process. Some success has been achieved with electrostatic hydrogen cyclotron waves where Doppler broadening is insignificant and with zero-frequency turbulence where the spectrum is entirely Doppler shifted. However, it is not yet possible to identify specific modes in regions of transverse ion acceleration. If the modes are assumed to exist, some limits can be placed on their electric field amplitudes. An experimental technique to measure wavelength directly, thereby circumventing problems created by Doppler shifting, is reviewed.
Kintner, P. M.↗
Antiproton powered propulsion with magnetically confined plasma engines
Matter-antimatter annihilation releases more energy per unit mass than any other method of energy production, making it an attractive energy source for spacecraft propulsion. In the magnetically confined plasma engine, antiproton beams are injected axially into a pulsed magnetic mirror system, where they annihilate with an initially neutral hydrogen gas. The resulting charged annihilation products transfer energy to the hydrogen propellant, which is then exhausted through one end of the pulsed mirror system to provide thrust. The calculated energy transfer efficiencies for a low number density (10(14)/cu cm) hydrogen propellant are insufficient to warrant operating the engine in this mode. Efficiencies are improved using moderate propellant number densities (10(16)/cu cm), but the energy transferred to the plasma in a realistic magnetic mirror system is generally limited to less than 2 percent of the initial proton-antiproton annihilation energy. The energy transfer efficiencies are highest for high number density (10(18)/cu cm) propellants, but plasma temperatures are reduced by excessive radiation losses. Low to moderate thrust over a wide range of specific impulse can be generated with moderate propellant number densities, while higher thrust but lower specific impulse may be generated using high propellant number densities. Significant mass will be required to shield the superconducting magnet coils from the high energy gamma radiation emitted by neutral pion decay. The mass of such a radiation shield may dominate the total engine mass, and could severely diminish the performance of antiproton powered engines which utilize magnetic confinement. The problem is compounded in the antiproton powered plasma engine, where lower energy plasma bremsstrahlung radiation may cause shield surface ablation and degradation.
Lapointe, Michael R.↗
Thermal coatings for titanium-aluminum alloys
Titanium aluminides and titanium alloys are candidate materials for use in hot structure and heat-shield components of hypersonic vehicles because of their good strength-to-weight characteristics at elevated temperature. However, in order to utilize their maximum temperature capability, they must be coated to resist oxidation and to have a high total remittance. Also, surface catalysis for recombination of dissociated species in the aerodynamic boundary layer must be minimized. Very thin chemical vapor deposition (CVD) coatings are attractive candidates for this application because of durability and very light weight. To demonstrate this concept, coatings of boron-silicon and aluminum-boron-silicon compositions were applied to the titanium-aluminides alpha2 (Ti-14Al-21Nb), super-alpha2 (Ti-14Al-23-Nb-2V), and gamma (Ti-33Al-6Nb-1Ta) and to the titanium alloy beta-21S (Ti-15Mo-3Al-3Nb-0.2Si). Coated specimens of each alloy were subjected to a set of simulated hypersonic vehicle environmental tests to determine their properties of oxidation resistance, surface catalysis, radiative emittance, and thermal shock resistance. Surface catalysis results should be viewed as relative performance only of the several coating-alloy combinations tested under the specific environmental conditions of the LaRC Hypersonic Materials Environmental Test System (HYMETS) arc-plasma-heated hypersonic wind tunnel. Tests were also conducted to evaluate the hydrogen transport properties of the coatings and any effects of the coating processing itself on fatigue life of the base alloys. Results are presented for three types of coatings, which are as follows: (1) a single layer boron silicon coating, (2) a single layer aluminum-boron-silicon coating, and (3) a multilayer coating consisting of an aluminum-boron-silicon sublayer with a boron-silicon outer layer.
Cunnington, George R.↗
Investigation of Coronal Large Scale Structures Utilizing Spartan 201 Data
Two telescopes aboard Spartan 201, a small satellite has been launched from the Space Shuttles, on April 8th, 1993, September 8th, 1994, September 7th, 1995 and November 20th, 1997. The main objective of the mission was to answer some of the most fundamental unanswered questions of solar physics-What accelerates the solar wind and what heats the corona? The two telescopes are 1) Ultraviolet Coronal Spectrometer (UVCS) provided by the Smithsonian Astrophysical Observatory which uses ultraviolet emissions from neutral hydrogen and ions in the corona to determine velocities of the coronal plasma within the solar wind source region, and the temperature and density distributions of protons and 2) White Light Coronagraph (WLC) provided by NASA's Goddard Space Flight Center which measures visible light to determine the density distribution of coronal electrons within the same region. The PI has had the primary responsibility in the development and application of computer codes necessary for scientific data analysis activities, end instrument calibration for the white-light coronagraph for the entire Spartan mission. The PI was responsible for the science output from the WLC instrument. PI has also been involved in the investigation of coronal density distributions in large-scale structures by use of numerical models which are (mathematically) sufficient to reproduce the details of the observed brightness and polarized brightness distributions found in SPARTAN 201 data.
Guhathakurta, Madhulika↗
Three-Dimensional Magnetohydrodynamic Modeling of the Solar Wind Including Pickup Protons and Turbulence Transport
To study the effects of interstellar pickup protons and turbulence on the structure and dynamics of the solar wind, we have developed a fully three-dimensional magnetohydrodynamic solar wind model that treats interstellar pickup protons as a separate fluid and incorporates the transport of turbulence and turbulent heating. The governing system of equations combines the mean-field equations for the solar wind plasma, magnetic field, and pickup protons and the turbulence transport equations for the turbulent energy, normalized cross-helicity, and correlation length. The model equations account for photoionization of interstellar hydrogen atoms and their charge exchange with solar wind protons, energy transfer from pickup protons to solar wind protons, and plasma heating by turbulent dissipation. Separate mass and energy equations are used for the solar wind and pickup protons, though a single momentum equation is employed under the assumption that the pickup protons are comoving with the solar wind protons.We compute the global structure of the solar wind plasma, magnetic field, and turbulence in the region from 0.3 to 100 AU for a source magnetic dipole on the Sun tilted by 0 deg - .90 deg and compare our results with Voyager 2 observations. The results computed with and without pickup protons are superposed to evaluate quantitatively the deceleration and heating effects of pickup protons, the overall compression of the magnetic field in the outer heliosphere caused by deceleration, and the weakening of corotating interaction regions by the thermal pressure of pickup protons.
Usmanov, Arcadi V.↗
Fabrication of Diamond Membranes for MEMS using Reactive Ion Etching of Silicon
Polycrystalline diamond thin film has been grown on a silicon substrate using high pressure microwave plasma-assisted chemical vapor deposition from a gas mixture of methane and hydrogen at a substrate temperature of 950 degrees celcius.
diamond↗
Outer satellite atmospheres: Their extended nature and planetary interactions
Highly developed numerical models are applied to interpret extended-atmosphere data for the sodium cloud of Io and the hydrogen torus of Titan. Solar radiation pressure was identified and verified by model calculations as the mechanism to explain two different east-west asymmetries observed in the sodium cloud. Analysis of sodium line profile data, suggesting that a Jupiter magnetospheric wind may be responsible for high speed sodium atoms emitted from Io, and preliminary modeling of the interaction of the Io plasma torus and Io's sodium cloud are also reported. Models presented for Titan's hydrogen torus are consistent both with the recent Pioneer 11 measurements and earlier Earth-orbiting observations by the Copernicus satellite. Progress is reported on developing models for extended gas and dust atmospheres of comets.
Smyth, W. H.↗