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At least 703 records · Page 39

Laser-fluorescence measurements of nitric oxide in low-pressure H2/O2/NO flames

The concentration profiles of NO in low-pressure (76 Torr) H2/O2/Ar flames to which nitric oxide is added are measured by pulsed laser-induced fluorescence. Temporally resolved fluorescence measurements are used to determine the collisional deexcitation rates needed to convert time-integrated fluorescence signal into oxide concentration. Five flames are studied with H2/O2 equivalence ratios of 0.88, 0.98, 1.22, 1.37, and 1.50. In these flames the collisional deexcitation rate decreases rapidly above the burner surface as the density decreases with increasing temperature. A 20 percent decrease is observed for the lean flames, and a 30 percent decrease for the rich flames. Within the precision of the measurement technique (+ or - 10 percent), no significant removal of nitric oxide is observed in these flames.

Cattolica, R. J.↗

Near-Limit Flame Spread over a Thin Solid Fuel in Microgravity

Diffusion flame spread over a thin solid fuel in quiescent and slowly moving atmospheres is studied in microgravity. The flame behavior is observed to depend strongly on the magnitude of the relative velocity between the flame and the atmosphere. In particular, a low velocity quenching limit is found to exist in low oxgen environments. Using both the microgravity results and previously published data at high opposed-flow velocities, the flame spread behavior is examined over a wide velocity range. A flammability map using molar oxygen percentages and characteristic relative velocities as coordinates is constructed. Trends of flame spread rate are determined and mechanisms for flame extinction are discussed.

Olson, Sandra L.↗

Stability of a premixed flame in stagnation-point flow against general disturbances

Previously, the stability of a premixed flame in a stagnation flow was discussed for a restricted class of disturbances that are self-similar to the basic undisturbed flow; thus, flame fronts with corrugations only in the cross stream direction were considered. Here, we consider a more general class of three-dimensional flame front perturbations which also permits corrugations in the streamwise direction. It is shown that, because of the stretch experienced by the flame, the hydrodynamic instability is limited only to disturbances of short wavelength. If in addition diffusion effects have a stabilizing influence, as would be the case of mixtures with Lewis number greater than one, a stretched flame could be absolutely stable. Instabilities occur when the Lewis number is below some critical value less than one. Neutral stability boundaries are presented in terms of the Lewis number, the strain rate, and the appropriate wavenumbers. Beyond the stability threshold, the two-dimensional self-similar modes always grow first. However, if disturbances of long wavelength are excluded, it is possible for the three-dimensional modes to be the least stable one. Accordingly, the pattern that will be observed on the flame front, at the onset of instability, will consist of either ridges in the direction of stretch or the more common three-dimensional cellular structure.

Jackson, Thomas L.↗

The effect of surface radiation on flame spread in a quiescent, microgravity environment

In most theories of laminar flame spread over solid combustibles, radiation is neglected. However, when gas motion is completely absent, which may occur in the quiescent, microgravity environment of a spacecraft, the importance of radiation compared to convection is enhanced. Here, a theoretical model is developed of flame spread over a thin solid fuel into an opposing flow of oxidizer, the opposing flow being present in the quiescent environment in flame-fixed coordinates, including the effects of radiative heat transfer from the fuel surface. Numerical solutions to the conservation equations in the gas and the solid phase that describe the spreading flame are presented for a variety of ambient conditions and surface emittances. When surface radiation is significant, the solid surface acts as a heat sink, causing the flame to cool, shrink in size, and spread more slowly. Better agreement with experiment for net heat transfer to the surface is obtained when surface radiation is included. For low ambient oxygen levels, radiative effects lead to flame extinction. A radiation/conduction parameter is identified that adequately describes the importance of surface radiation.

Bhattacharjee, S.↗

Effect of gravity on the stability and structure of lean hydrogen-air flames

Detailed, time-dependent, 2D numerical simulations with full hydrogen-oxygen chemistry are used to investigate the effects of gravity on the stability and structure of laminar flames in lean, premixed hydrogen-air mixtures. The calculations show that the effects of gravity becomes more important as the lean flammability limit is approached. In a 12 percent hydrogen-air mixture, gravity plays only a secondary role in determining the multidimensional structure of the flame with the stability and structure of the flame controlled primarily by the thermo-diffusive instability mechanism. However, in leaner hydrogen-air mixtures gravity becomes more important. Upward-propagating flames are highly curved and evolve into a bubble rising upwards in the tube. Downward-propagating flames are flat or even oscillate between structures with concave and convex curvatures. The zero-gravity flame shows only cellular structures. Cellular structures which are present in zero gravity can be suppressed by the effect of buoyancy for mixtures leaner than 11 percent hydrogen. These observations are explained on the basis of an interaction between the processes leading to buoyancy-induced Rayleigh-Taylor instability and the thermo-diffusive instability.

Patnaik, G.↗

Laminar flames in premixed gases

Numerical simulation of laminar flames in premixed gases is addressed. Various efforts to solve the laminar flame problem are briefly described, and basic equations to be modeled in a comprehensive description of laminar flames are discussed along with the physical and chemical processes represented by these equations and the numerical requirements to model them. Two flame methods are discussed in some detail: a numerical model for studying transient phenomena and its 2D counterpart method. The various input parameters needed for the models are addressed, and the use of the models is illustrated in several studies of laminar flames in premixed gases. Flammability limits and multidimensional flame propagation are also examined.

Kailasanath, K.↗

Soot formation and radiation in turbulent jet diffusion flames under normal and reduced gravity conditions

Most practical combustion processes, as well as fires and explosions, exhibit some characteristics of turbulent diffusion flames. For hydrocarbon fuels, the presence of soot particles significantly increases the level of radiative heat transfer from flames. In some cases, flame radiation can reach up to 75 percent of the heat release by combustion. Laminar diffusion flame results show that radiation becomes stronger under reduced gravity conditions. Therefore, detailed soot formation and radiation must be included in the flame structure analysis. A study of sooting turbulent diffusion flames under reduced-gravity conditions will not only provide necessary information for such practical issues as spacecraft fire safety, but also develop better understanding of fundamentals for diffusion combustion. In this paper, a summary of the work to date and of future plans is reported.

Ku, Jerry C.↗

Flame spread across liquid pools

For flame spread over liquid fuel pools, the existing literature suggests three gravitational influences: (1) liquid phase buoyant convection, delaying ignition and assisting flame spread; (2) hydrostatic pressure variation, due to variation in the liquid pool height caused by thermocapillary-induced convection; and (3) gas-phase buoyant convection in the opposite direction to the liquid phase motion. No current model accounts for all three influences. In fact, prior to this work, there was no ability to determine whether ignition delay times and flame spread rates would be greater or lesser in low gravity. Flame spread over liquid fuel pools is most commonly characterized by the relationship of the initial pool temperature to the fuel's idealized flash point temperature, with four or five separate characteristic regimes having been identified. In the uniform spread regime, control has been attributed to: (1) gas-phase conduction and radiation; (2) gas-phase conduction only; (3) gas-phase convection and liquid conduction, and most recently (4) liquid convection ahead of the flame. Suggestions were made that the liquid convection was owed to both vuoyancy and thermocapillarity. Of special interest to this work is the determination of whether, and under what conditions, pulsating spread can and will occur in microgravity in the absence of buoyant flows in both phases. The approach we have taken to resolving the importance of buoyancy for these flames is: (1) normal gravity experiments and advanced diagnostics; (2) microgravity experiments; and (3) numerical modelling at arbitrary gravitational level.

Ross, Howard↗

On the structure of gaseous confined laminar diffusion flames: Numerical investigation

The structure and characteristics of gaseous confined laminar diffusion flames are investigated by numerically solving the time-dependent two-dimensional axisymmetric conservation equations. The numerical model accounts for the important chemical and physical processes involved, including axial diffusion, viscous effects, radial convection, and finite-rate chemistry. The numerical results clearly show that the flame has a finite thickness and leakage of fuel vapor into the flame zone is possible. The effect of heat release is found to induce some radial flow. Predicted flame shape and dimensions are compared to the classical Burke-Schumann flame. The numerically calculated flame is observed to be about 15 percent taller and 5 percent narrower than that of the Burke-Schumann solution under the same conditions.

Mawid, M. A.↗

The structure of particle cloud premixed flames

The structure of premixed flames propagating in combustible systems containing uniformly distributed volatile fuel particles in an oxidizing gas mixture is analyzed. This analysis is motivated by experiments conducted at NASA Lewis Research Center on the structure of flames propagating in combustible mixtures of lycopodium particles and air. Several interesting modes of flame propagation were observed in these experiments depending on the number density and the initial size of the fuel particle. The experimental results show that steady flame propagation occurs even if the initial equivalence ratio of the combustible mixture based on the gaseous fuel available in the particles, phi sub u, is substantially larger than unity. A model is developed to explain these experimental observations. In the model, it is presumed that the fuel particles vaporize first to yield a gaseous fuel of known chemical composition which then reacts with oxygen in a one-step overall process. The activation energy of the chemical reaction is presumed to be large. The activation energy characterizing the kinetics of vaporization is also presumed to be large. The equations governing the structure of the flame were integrated numerically. It is shown that the interplay of vaporization kinetics and oxidation process can result in steady flame propagation in combustible mixtures where the value of phi sub u is substantially larger than unity. This prediction is in agreement with experimental observations.

Seshadri, K.↗

Lewis number effect on the propagation of premixed flames in closed tubes

The evolution of a premixed flame under conditions of confinement is studied theoretically. The analysis is based on a hydrodynamic model in which the flame is treated as a surface of discontinuity. The flame structure is assumed to be quasi-steady with a high activation energy and a large heat release. Its resolution in the postignition period yields a coupled system of equations for the determination of the pressure and the burning rate. The analysis also resolves the thermal and flow fields on either side of the flame and determines the instantaneous location of the flame front together with the overall time required for the flame to reach the end of the tube. The results indicate that qualitatively distinct behaviors are possible for mixtures depending on whether their Lewis numbers Le are less or greater than one.

Mcgreevy, J. L.↗

Fundamental flame velocities of pure hydrocarbons II : alkadienes

Data are presented for the fundamental flame velocities of 10 pure alkadienes that have isolated, conjugated, or cumulative double-bond systems. On the basis of this limited amount of data and the flame velocities previously reported, it is concluded that unsaturation changes the flame velocity in the order alkanes ? alkenes ? alkadienes with isolated double bonds ?= alkadienes with conjugated double bonds ? alkadienes with cumulative double bonds ?= alkynes. There were no significant differences in the flame velocities of cis and trans 1,3-pentadiene. The alkadienes 1,2-pentadiene and 2,3-pentadiene, with different positions of the cumulative double bond in the straight chain, have similar flame velocities. Methyl substitution in a hydrocarbon reduces the flame velocity; the extent of the reduction increases with the degree of unsaturation of the hydrocarbon.

Levine, Oscar↗

DNS and modeling of the interaction between turbulent premixed flames and walls

The interaction between turbulent premixed flames and walls is studied using a two-dimensional full Navier-Stokes solver with simple chemistry. The effects of wall distance on the local and global flame structure are investigated. Quenching distances and maximum wall heat fluxes during quenching are computed in laminar cases and are found to be comparable to experimental and analytical results. For turbulent cases, it is shown that quenching distances and maximum heat fluxes remain of the same order as for laminar flames. Based on simulation results, a 'law-of-the-wall' model is derived to describe the interaction between a turbulent premixed flame and a wall. This model is constructed to provide reasonable behavior of flame surface density near a wall under the assumption that flame-wall interaction takes place at scales smaller than the computational mesh. It can be implemented in conjunction with any of several recent flamelet models based on a modeled surface density equation, with no additional constraints on mesh size or time step.

Poinsot, T. J.↗

Stretch-induced quenching in flame-vortex interactions

The flame-vortex interaction problem is a natural configuration in which several issues relevant to turbulent combustion can be addressed: effect of strain-rate and curvature, effect of the Lewis number, effect of heat losses, effect of complex chemistry, and flame-generated turbulence. In such an approach, the interaction of an isolated vortex with a laminar premixed flame is viewed as a unit process of a turbulent premixed flame in which the reaction zone keeps a laminar like structure locally; this is precisely the case of the wrinkled flame or flamelet regime in turbulent combustion. The present work complements previous studies and involves the study of the interaction of a vortex pair and a laminar premixed flame in a planar two-dimensional geometry, together with numerical simulations. This geometry is quite unique since most studies have considered axisymmetric vortex rings. Such a geometry offers several advantages over previous studies.

Samaniego, J.-M.↗

Direct numerical simulations of turbulent non-premixed methane-air flames modeled with reduced kinetics

Turbulent non-premixed stoichiometric methane-air flames modeled with reduced kinetics have been studied using the direct numerical simulation approach. The simulations include realistic chemical kinetics, and the molecular transport is modeled with constant Lewis numbers for individual species. The effect of turbulence on the internal flame structure and extinction characteristics of methane-air flames is evaluated. Consistent with earlier DNS with simple one-step chemistry, the flame is wrinkled and in some regions extinguished by the turbulence, while the turbulence is weakened in the vicinity of the flame due to a combination of dilatation and an increase in kinematic viscosity. Unlike previous results, reignition is observed in the present simulations. Lewis number effects are important in determining the local stoichiometry of the flame. The results presented in this work are preliminary but demonstrate the feasibility of incorporating reduced kinetics for the oxidation of methane with direct numerical simulations of homogeneous turbulence to evaluate the limitations of various levels of reduction in the kinetics and to address the formation of thermal and prompt NO(x).

Card, J. M.↗

The coupling between flame surface dynamics and species mass conservation in premixed turbulent combustion

Current flamelot models based on a description of the flame surface dynamics require the closure of two inter-related equations: a transport equation for the mean reaction progress variable, (tilde)c, and a transport equation for the flame surface density, Sigma. The coupling between these two equations is investigated using direct numerical simulations (DNS) with emphasis on the correlation between the turbulent fluxes of (tilde)c, bar(pu''c''), and Sigma, (u'')(sub S)Sigma. Two different DNS databases are used in the present work: a database developed at CTR by A. Trouve and a database developed by C. J. Rutland using a different code. Both databases correspond to statistically one-dimensional premixed flames in isotropic turbulent flow. The run parameters, however, are significantly different, and the two databases correspond to different combustion regimes. It is found that in all simulated flames, the correlation between bar(pu''c'') and (u'')(sub S)Sigma is always strong. The sign, however, of the turbulent flux of (tilde)c or Sigma with respect to the mean gradients, delta(tilde)c/delta(x) or delta(Sigma)/delta(x), is case-dependent. The CTR database is found to exhibit gradient turbulent transport of (tilde)c and Sigma, whereas the Rutland DNS features counter-gradient diffusion. The two databases are analyzed and compared using various tools (a local analysis of the flow field near the flame, a classical analysis of the conservation equation for (tilde)(u''c''), and a thin flame theoretical analysis). A mechanism is then proposed to explain the discrepancies between the two databases and a preliminary simple criterion is derived to predict the occurrence of gradient/counter-gradient turbulent diffusion.

Trouve, A.↗

Japan's research on gaseous flames

Although research studies on gaseous flames in microgravity in Japan have not been one-sided, they have been limited, for the most part, to comparatively fundamental studies. At present it is only possible to achieve a microgravity field by the use of drop towers, as far as gaseous flames are concerned. Compared with experiments on droplets, including droplet arrays, which have been vigorously performed in Japan, studies on gaseous flames have just begun. Experiments on ignition of gaseous fuel, flammability limits, flame stability, effect of magnetic field on flames, and carbon formation from gaseous flames are currently being carried out in microgravity. Seven subjects related to these topics are introduced and discussed herein.

Niioka, Takashi↗

Forced Flow Flame Spreading Test: Preliminary Findings From the USMP-3 Shuttle Mission

The Forced Flow Flame spreading Test (FFFT) is a study of flame spreading over solid fuels in very low-speed air flows. The FFFT experiment is part of research entitled Solid Inflammability Boundary at Low Speeds, (SIBAL) intended for operations on the Space Station. In the FFFT experiment, a series of 15 experiments conducted aboard the space shuttle during the United States Microgravity Payload (USMP-3) mission provided information about the structure and spreading characteristics of flames in low-speed, concurrent flows. The test samples included flat sheets of cellulose and cast cylinders of cellulose, burned in air at velocities of approximately 1 to 8 cm/sec. The test results have been successfully compared to theoretical predictions of the SIBAL program, a fundamentally based numerical simulation of concurrent flow flame spread. Additionally, some guidance for the design characteristics of the SIBAL flight experiment have been obtained including some verification of the theoretical predictions of flame size versus the required size of the SIBAL flow duct, and the effect of the presence of thermocouples in the vicinity of near-limit flames in microgravity.

Sacksteder, Kurt R.↗