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At least 703 records · Page 39

Analysis of furnace contamination on superconducting radio frequency niobium using secondary-ion mass spectrometry

Detection of surface contamination on niobium materials used in superconducting radio frequency (SRF) applications is difficult due to quantitative sensitivity and near-atomic depth resolution needed. Inspection of samples known to have experienced surface contamination was found to have inconsistent nitride coverage after high-temperature nitrogen gas exposure (“doping”). Here we compare contaminating species found on samples treated in several different vacuum furnaces, both “exposed” directly in the chamber and “protected” by containment shielding from evaporative sources with “furnace caps.” Typically, furnace caps are used to impede contamination from reaching the interior surface of cavities during the high-temperature vacuum bake that immediately precedes exposure to nitrogen gas. Although, to date, little is known about the effectiveness of these caps, SIMS results showed that they were effective in limiting contamination arising from the furnace environment. Inspection of sample surfaces by SEM showed a lack of nitrides present on contaminated specimens. TEM with energy dispersive spectroscopy performed on these samples revealed that a carbon-rich layer now existed, indicating that a relatively high contaminant load prevents the nucleation and growth of surface nitrides, while thus inhibiting interstitial nitrogen uptake. Except in extreme cases, subsequent removal of the top several micrometers of the surface via electropolishing appears to effectively eliminate any strong influence on the subsequent SRF cavity performance. With the absence of furnace cleaning, carbon contamination was found to be nearly 10× higher for protected nitrogen-doped and electropolished samples, with minimal metallic contamination detected for both processes. SIMS analysis was also performed to compare the cleanliness of samples fully prepared by such nitrogen “doping” with those prepared by a related process, involving the dissolution of niobium surface oxide and diffusion of oxygen into the surface. This oxygen doping or alloying process offers attractive advantages.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Parallel operation of two Brayton-cycle alternators with parasitic speed controllers

The experimental paralleling characteristics of two 1200 Hz Brayton-cycle alternators are presented. Since the Brayton power conversion system uses electric speed controllers, the paralleling requirements are somewhat different from those for conventional ground-based systems. Results include the transient effects of synchronizing the two alternators with various phase-angle, voltage, and frequency differences. Based on these results, the effects of synchronizing differences can be defined, and adjustment requirements of the parasitic speed controllers during synchronizing can be established. Data indicate that parasitically loaded alternators are able to parallel over a wide range of synchronizing differences. However, equilibrium could not be reached in extreme cases where alternator load differences were great and, at the same time, the phase-angle error was large (150 deg or more).

Perz, D. A.↗

Atlas/Centaur-29 Intelsat IV (F5) flash flight report

ATLAS/CENTAUR-29 was launched from ETR Complex 36B, June 13, 1972, at a flight azimuth of 101 degrees. The ETR test number was 1240. The launch vehicle consisted of an ATLAS SLV-3C first stage and a CENTAUR second stage. The spacecraft was INTELSAT 4 (F-5). The launch occurred at the opening of the window. Indications are that the spacecraft was injected into the required transfer orbit and has achieved it's final orbit. All orbital parameters were extremely close to nominal. A nominal apogee motor burn took place at 2101 EDT on June 14, 1972 at 124 degrees East longitude and the final duty station of the spacecraft will be at 62 degrees East longitude. A two week communications checkout was started on or about June 15, 1972.

Source record↗

Some aspects of the ozone-depletion problem in the stratosphere

A preliminary investigation of O3 depletion by NOx in the exhaust of an SST wake is presented. Initial calculations were made using a model employing a two-step chemistry mechanism consisting of an NOx catalytic cycle and assuming total NOx and the ratio NO/NO2 to be conserved. The results indicate O3 depletion in the wake much less severe than reported in earlier investigations which used a much larger reaction rate constant. Subsequent investigation revealed, however, that even the current O3 depletion rates appear too large. Because of the apparent deficiencies in the two-step chemical model, a model is presented with a more realistic chemical mechanism without the requirement for NO conservation. Results indicate that total NOx and initial NO/NO2 ratio play an important role in determining O3 depletion. Furthermore, only in the case of rather extreme concentrations of water vapor or unrealistically large photolysis rates is there any significant conversion of NOx to HNO3.

Gupta, R. N.↗

The local interstellar helium density - Corrected

An upper bound for the number density of neutral helium in the local interstellar medium of 0.004 + or - 0.0022 per cu cm was previously reported, based on extreme-ultraviolet telescope observations at 584 A made during the 1975 Apollo-Soyuz Test Project. A variety of evidence is found which indicates that the 584-A sensitivity of the instrument declined by a factor of 2 between the last laboratory calibration and the time of the measurements. The upper bound on the helium density is therefore revised to 0.0089 + or - 0.005 per cu cm.

Freeman, J.↗

Composition anomalies in solar flares

Flares with anomalies in He-3 and Fe enrichment and unusual abundances of heavy ions are discussed. Enrichment in heavy elements including O, Ne, Mg, Si, S-Ca group, and Fe is found in small flares enriched in He-3 and Fe; the flares enriched in He-3 and all heavy elements through Fe show depletion of the carbon abundance. An extreme case of the carbon abundance depletion with the C/O ratio of 0.01 contrasting with the normal solar flare C/O ratio of 0.5 indicates new constraints on acceleration models for small Fe-rich events.

Mason, G. M.↗

Amorphous metallizations for high-temperature semiconductor device applications

The initial results of work on a class of semiconductor metallizations which appear to hold promise as primary metallizations and diffusion barriers for high temperature device applications are presented. These metallizations consist of sputter-deposited films of high T sub g amorphous-metal alloys which (primarily because of the absence of grain boundaries) exhibit exceptionally good corrosion-resistance and low diffusion coefficients. Amorphous films of the alloys Ni-Nb, Ni-Mo, W-Si, and Mo-Si were deposited on Si, GaAs, GaP, and various insulating substrates. The films adhere extremely well to the substrates and remain amorphous during thermal cycling to at least 500 C. Rutherford backscattering and Auger electron spectroscopy measurements indicate atomic diffussivities in the 10 to the -19th power sq cm/S range at 450 C.

Wiley, J. D.↗

Comment on 'Time-optimal orbit transfer trajectory for solar sail spacecraft'

An analytic proof is presented to show that the orbital transfer times of an earth-to-Mars solar-sail propelled spacecraft trajectory as calculated by Jayaraman (1980) are incorrect. In particular, different boundary conditions are defined, which indicate that a minimization of the Hamiltonian, which Jayaraman used, can yield the wrong stationary solution. Transfer times are calculated using a neighboring extremal algorithm based on numerical differentiation in conjunction with Krogh's variable order, variable step size integrator, resulting in a transfer time of 322 days at 2 mm/sec-sq, with endpoint restraints satisfied to within 1/1 billion. Finally, it is concluded that minimization of flight time is secondary in importance to maximization of delivered payload and minimization of overall mission cost and risk.

Wood, L. J.↗

A second supernova inside Puppis A?

Narrow-band images of an unusual swirl structure located near the center of the Puppis A supernova remnant are presented which reveal three overlapping filamentary systems of highly diverse composition. One is dominated by emission lines of nitrogen, one by oxygen, and one by sulfur. Spectra indicate that these small rings have high velocities and a corresponding kinematic age of less than 800 yr. Heavy-element abundances are extremely high and different in each system, some reminiscent of knots in Cas A, and others of circumstellar matter observed surrounding supernova 1987A. The youth and unusual chemistry lead to the suggestion that a second supernova has exploded within the shell of Puppis A, giving rise to the swirl structure.

Winkler, P. F.↗

The kinematics of Milky Way halo gas. I - Observations of low-ionization species

Ultraviolet interstellar line day observed with the IUE toward 70 halo stars and four extragalactic sight lines are analyzed in a study of the large-scale kinematic properties of the Milky Way halo gas. The motions of the low-ionization gas is focused on. Large systematic velocities are found, and a pronounced asymmetry in the absorption characteristics of halo gas toward the Galactic poles is indicated. In the north, substantial amounts of material are falling toward the disk at velocities up to about 120 km/s in the most extreme case. Toward the south, low-ionization material shows no extreme or systematic motions.

Danly, Laura↗

Mission analysis for coincident measurements of the Upper Atmosphere Research Satellite and Space Shuttle experiments

The launch and orbital characteristics of Space Shuttle missions which will maximize the coincident measurement opportunities between the Atmospheric Laboratory for Applications and Science (ATLAS) and the Upper Atmosphere Research Satellite (UARS) experiments are presented. Updated UARS orbit conditions are used and several ATLAS orbit constraints are incorporated, and the study is expanded to include other classes of instruments on the two satellites. The effects of launch time, altitude, and orbit inclination on the number and latitudinal distribution of coincident measurement opportunities for the UARS and Shuttle experiments are investigated. Large numbers of coincident measurements are possible for UARS and ATLAS limb-viewing experiments, but their distribution is greatly dependent on the inclination of the satellites and initial equatorial crossing times. Results indicate that a great number of coincident measurements may be obtained between limb-scanning devices (300-400) and that observation of the extreme latitudes (70-80 degrees) is obtained with an ATLAS inclination of 57 degrees.

Harrison, Edwin F.↗

H II regions in the dwarf galaxy UGC-A 86

The uncertain nature of the dwarf irregular galaxy UGC-A 86 (VIIZw009) makes it a very interesting object for studying star formation at the low end of the galaxy luminosity function. Saha and Hoessel (1991) find that this object is composed of two main parts, one of which appears more resolved than the other. The more resolved component has an excess of blue stars, suggesting that it is currently undergoing star formation. Thus, they argue that UGC-A 86 could be either a superposition of unrelated galaxies, two interacting galaxies, or a single galaxy. However, surface photometry performed by Richter et al. (1991) indicates that it is a single galaxy with an exponential luminosity profile. Richter et al. also find UGC-A 86 to be extremely dusty and to be associated with the infrared source IRAS 3550+6657. The uncertainty is compounded by the large ambiguity in the distance, though a heliocentric H1 velocity of 80 plus or minus 7 km s(sup -1) suggests that it is either a member of the Local Group or perhaps the IC 342 group. A distance of 1.5 Mpc and a reddening of E(B - V) = 0.65 is adopted. UGC-A 86 in H-alpha was observed in order to measure its current star formation rate. This is part of a larger project to study the star formation rates and histories of a complete sample of dwarf galaxies in the Local Group and other nearby groups. The H region luminosity function and size distribution for UGC-A 86 are presented and compared with previous observations of similar dwarf galaxies.

Miller, Bryan W.↗

Tidal interaction: A possible explanation for geysers and other fluid phenomena in the Neptune-Triton system

Discovery of geyser-like plumes on the surface of Triton was a highlight of Voyager 2's passage through the Neptune planetary system. Remarkable as these observations were, they were not entirely without precedent. Considering the confirmed predictions for the 1979 Voyager Jovian passage, it was logical to consider other solar system bodies beside Io where tidal effects could be a significant factor in surface processes. It was our intuition that the Neptune-Triton gravitational bond acting at high inclination to the Neptune equator and the fact that Neptune was a fluid body was significant oblateness would produce tidal and mechanical forces that could be transformed into thermal energy vented on Triton's surface. Prior to the Voyager flyby, others have noted that capture and evolution of Triton's orbit from extreme eccentricity to near circular state today would have resulted in significant tidal heating, but these analysts disregard current day forces. Our calculations indicate that the time varying forces between Neptune-Triton fall midway between those exerted in the Earth-Moon and Jupiter-Io systems, and considering the low level of other energy inputs, this source of internal energy should not be ignored when seeking an explanation for surface activity. In each planet-satellite case, residual or steady-state eccentricity causes time-varying stresses on internal satellite strata. In the case of Jupiter the residual eccentricity is due largely to Galilean satellite interactions, particularly Io-Europa, but in the case of Neptune-Triton, it is the effect of Triton's inclined orbit about an oblate primary.

Kelly, W. D.↗

Locating Noctiluca Miliaris in the Arabian Sea: An Optical Proxy Approach

Coincident with shifting monsoon weather patterns over India, the phytoplankter Noctiluca miliaris has recently been observed to be dominating phytoplankton blooms in the northeastern Arabian Sea during the winter monsoons. Identifying the exact environmental and/or ecological conditions that favor this species has been hampered by the lack of concurrent environmental and biological observations on time and space scales relevant to ecologic and physiologic processes. We present a bio-optical proxy for N. miliaris measured on highly resolved depth scales coincident with hydrographic observations with the goal to identify conducive hydrographic conditions for the bloom. The proxy is derived from multichannel excitation chlorophyll a fluorescence and is validated with microscopy, pigment composition, and spectral absorption. Phytoplankton populations dominated by either diatoms or other dinoflagellates were additionally discerned. N. miliaris populations in full bloom were identified offshore in low-nutrient and low-N : P ratio surface waters within a narrow temperature and salinity range. These populations transitioned to high-biomass diatom-dominated coastal upwelling populations. A week later, the N. miliaris blooms were observed in declining phase, transitioning to very-low-biomass populations of non-N. miliaris dinoflagellates. There were no clear hydrographic conditions uniquely associated with the N. miliaris populations, although N. miliaris was not found in the upwelling or extremely oligotrophic waters. Taxonomic transitions were not discernible in the spatial structure of the bloom as identified by the ocean color Chl imagery, indicating that in situ observations may be necessary to resolve community structure, particularly for populations below the surface.

Arabian Sea↗

Ultrasonic measurement of temperature distributions in extreme environments: Electrical power plants testing in utility-scale steam generators

Thermal heterogeneities within energy conversion and storage, material processing, nuclear processes, aerospace, and military applications are often inaccessible to characterization by insertion sensors. When sensor deployment is possible, conventional pointwise temperature probes quickly degrade when inserted into harsh environments typical of such processes. We developed spatially-resolved ultrasonic thermometry to noninvasively measure the spatial distributions of thermal properties in such applications, even when sizable thermal gradients are present. Our method divides the path of ultrasonic propagation into segments bound by echogenic features, which create echoes in pulse-echo mode, encoding the information about interior temperature distributions. We use the acquired ultrasonic responses to estimate the internal temperature distributions by solving an inverse problem or concatenating segmental estimates. This work describes the implementation and industrial testing of the developed method at a coal-fired electrical power generation plant. We inserted an echogenically segmented Inconel 625 waveguide into the combustion zone of the utility-scale boiler and continuously acquired ultrasonic data while keeping sensitive components away from the damaging combustion environment. The accuracy of the time-dependent temperature distributions reconstructed from the ultrasonic measurements was comparable to that of thermocouples. The resiliency of ultrasonic thermometry to harsh combustion conditions was far superior to conventional insertion sensors. The measurements obtained during plant operation captured daily steam generation cycles in response to changing customer demand and intermittent contributions of renewable power sources to the power grid. These measurements have revealed new insights into the relationship between the dynamic power generation load and the conditions inside the steam generator. As a result, the successful industrial testing of spatially-resolved ultrasonic thermometry in solids indicates that the developed technology has matured to become an attractive alternative to conventional sensing in solving challenging problems of long-term thermal characterizations in extreme environments.

42 ENGINEERING↗

Jimsphere wind and turbulence exceedance statistic

Exceedance statistics of winds and gusts observed over Cape Kennedy with Jimsphere balloon sensors are described. Gust profiles containing positive and negative departures, from smoothed profiles, in the wavelength ranges 100-2500, 100-1900, 100-860, and 100-460 meters were computed from 1578 profiles with four 41 weight digital high pass filters. Extreme values of the square root of gust speed are normally distributed. Monthly and annual exceedance probability distributions of normalized rms gust speeds in three altitude bands (2-7, 6-11, and 9-14 km) are log-normal. The rms gust speeds are largest in the 100-2500 wavelength band between 9 and 14 km in late winter and early spring. A study of monthly and annual exceedance probabilities and the number of occurrences per kilometer of level crossings with positive slope indicates significant variability with season, altitude, and filter configuration. A decile sampling scheme is tested and an optimum approach is suggested for drawing a relatively small random sample that represents the characteristic extreme wind speeds and shears of a large parent population of Jimsphere wind profiles.

Adelfang, S. I.↗

Evaluating Drought Indices for Early Warning in East and Southern Africa

Sparsely populated regions of east and southern Africa often have little ground based data to monitor drought, crops, and water resources. The Regional Hydrologic Extremes Assessment System (RHEAS) is a NASA supported data assimilation framework that combines both a hydrologic and crop model, which provide another monitoring approach. RHEAS can also be run in forecast mode, providing outlook on drought and crop yield.

Miller, Sara↗

Simulation of Unique Pressure Changing Steps and Situations in Psa Processes

A more rigorous cyclic adsorption process simulator is being developed for use in the development and understanding of new and existing PSA processes. Unique features of this new version of the simulator that Ritter and co-workers have been developing for the past decade or so include: multiple absorbent layers in each bed, pressure drop in the column, valves for entering and exiting flows and predicting real-time pressurization and depressurization rates, ability to account for choked flow conditions, ability to pressurize and depressurize simultaneously from both ends of the columns, ability to equalize between multiple pairs of columns, ability to equalize simultaneously from both ends of pairs of columns, and ability to handle very large pressure ratios and hence velocities associated with deep vacuum systems. These changes to the simulator now provide for unique opportunities to study the effects of novel pressure changing steps and extreme process conditions on the performance of virtually any commercial or developmental PSA process. This presentation will provide an overview of the cyclic adsorption process simulator equations and algorithms used in the new adaptation. It will focus primarily on the novel pressure changing steps and their effects on the performance of a PSA system that epitomizes the extremes of PSA process design and operation. This PSA process is a sorbent-based atmosphere revitalization (SBAR) system that NASA is developing for new manned exploration vehicles. This SBAR system consists of a 2-bed 3-step 3-layer system that operates between atmospheric pressure and the vacuum of space, evacuates from both ends of the column simultaneously, experiences choked flow conditions during pressure changing steps, and experiences a continuously changing feed composition, as it removes metabolic CO2 and H20 from a closed and fixed volume, i.e., the spacecraft cabin. Important process performance indicators of this SBAR system are size, and the corresponding CO2 and H20 removal efficiencies, and N2 and O2 loss rates. Results of the fundamental behavior of this PSA process during extreme operating conditions will be presented and discussed.

Ebner, Armin D.↗