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At least 703 records · Page 39

Tailoring electrophotonic capabilities of atomically thin GeS through controlled organometallic intercalation

The unique structure of van der Waals materials facilitates a robust mechanism for precise control of physical properties. In this study, we present a comprehensive analysis based on the intercalation of organometallics to modulate the optoelectronic behavior of two-dimensional germanium sulfide (GeS). Advanced computational exploration reveals significant and tunable features in the intercalated material. Additionally, the weak chemical interactions between organometallics and GeS support the electric-field-mediated drift and charge–discharge processes in intercalants. Controlling the concentration of organometallics in this manner enables the dynamic emergence of novel characteristics post-intercalation. These include flatbands near the Fermi level, significant enhancement of carrier mobility, and a magnetic ground state that is atypical for pristine GeS. Our findings demonstrate that organometallic intercalation offers a powerful strategy for tailoring the optoelectronic and magnetic characteristics of GeS, paving the way for harnessing emerging features for applications in next-generation devices.

Physics↗

Quadrilateral particle arrangement within shocks in a two-dimensional dusty plasma

The microscopic structure within a two-dimensional shock was studied using data from a dusty plasma experiment. A single layer of charged microparticles, levitated in a glow-discharge plasma, was perturbed by an electrically floating wire that was moved at a steady supersonic speed to excite a compressional shock. A rearrangement of particles was observed, from a hexagonal lattice in the preshock into a quadrilateral microstructure on the front side of the shock. This quadrilateral structure would not be stable in a monolayer of identical repulsive particles, under equilibrium conditions. Glaser-Clark polygon analysis of the microstructure helped in identifying quadrilaterals. Voronoi analysis was used to characterize the defect fraction behind the shock, as an indication of shock-induced melting. Published by the American Physical Society 2025

Kananovich, Anton (ORCID:0000000225374952)↗

Transition to Online Cable Insulation Condition Monitoring

Nuclear power plant cables were originally qualified for 40 year life and generally have not required specific test verification to assure service availability through the initial plant qualification period. However, license renewals to 60 and 80 years of operation require a cable aging management program that depends on some form of test and verification to assure fitness for service. Environmental stress (temperature, radiation, chemicals, water, and mechanical) varies dramatically within a nuclear power plant and, in some cases, cables have degraded and required repair or replacement before their qualified end-of-life period. In other cases, cable conditions have been mild and dependable cable performance confirmed to extend well beyond the initial qualified life. Most offline performance-based testing requires cables to be de-coupled and de-energized for specially trained technicians to perform testing. These offline tests constitute an expensive operational burden that limits the economic viability of nuclear power plants. Although initial investment may be higher, new online test practices are emerging as options or complements to offline testing that avoid or minimize the regularly scheduled offline test burden. These online methods include electrical and fiber-optic partial discharge measurement, spread spectrum time or frequency domain reflectometry, distributed temperature profile measurements, and local interdigital capacitance measurement of insulation characteristics. Introduction of these methods must be supported by research to confirm efficacy plus either publicly financed or market driven investment to support the start-up expense of cost-effective instrumentation to monitor cable condition and assure reliable operation. This work summarizes various online cable assessment technologies plus introduces a new cable motor test bed to assess some of these technologies in a controlled test environment.

Glass, Samuel W.↗

Performance and Durability of Proton Exchange Membrane Vapor-Fed Unitized Regenerative Fuel Cells

With a growing demand for electricity, clean hydrogen production and usage can be an asset not only to mitigate emissions but for long-term energy storage as well. Hydrogen gas, a high-density energy carrier, can be made through electrolysis in charging mode and generate electricity via a fuel cell in discharging mode in a unitized regenerative fuel cell (URFC). While URFCs reduce cost by combining the charging and discharging modes into a singular device, switching between modes becomes burdensome, and water management is a major challenge. One way to mitigate these issues is to operate the entire system in the vapor phase. Vapor-phase operation simplifies the physics of the system but will introduce losses within the system, primarily ohmic and mass transport during the charging mode. In this study, we explore the performance of a Proton-Exchange-Membrane (PEM)-URFC under vapor-phase conditions and the impact of different PEMs, feed gases, and relative humidity on the performance and durability. By tailoring operating conditions and membrane, the vapor-URFC achieves a roundtrip efficiency of 42% and a lifetime of 50,000 accelerated stress test cycles for fully humidified feeds. Discussion of vapor-URFC for energy storage and extensions to look at various applications shows the promise of this technology.

25 ENERGY STORAGE↗

Crystalline Structure-Dependent Mechanical and Thermoelectric Performance in Ag 2 Se 1–x S x System

Self-powered wearable electronics require thermoelectric materials simultaneously with a high dimensionless figure of merit (zT) and good flexibility to convert the heat discharged by the human body into electricity. Ag 2 (S,Se)-based semiconducting materials can well satisfy these requirements, and thus, they are attracting great attention in thermoelectric society recently. Ag 2 (S,Se) crystalizes in an orthorhombic structure or monoclinic structure, depending on the detailed S/Se atomic ratio, but the relationship between its crystalline structure and mechanical/thermoelectric performance is still unclear to date. In this study, a series of Ag 2 Se 1–x S x (x = 0, 0.1, 0.2, 0.3, 0.4, and 0.45) samples were prepared and their mechanical and thermoelectric performance dependence on the crystalline structure was systematically investigated. x = 0.3 in the Ag 2 Se 1–x S x system was found to be the transition boundary between orthorhombic and monoclinic structures. Mechanical property measurement shows that the orthorhombic Ag 2 Se 1–x S x samples are brittle while the monoclinic Ag 2 Se 1–x S x samples are ductile and flexible. In addition, the orthorhombic Ag 2 Se 1–x S x samples show better electrical transport performance and higher zT than the monoclinic samples under a comparable carrier concentration, most likely due to their weaker electron-phonon interactions. This study sheds light on the further development of flexible inorganic TE materials.

36 MATERIALS SCIENCE↗

Remote sensing applications in marine science programs at VIMS

Scientists at the Virginia Institute of Marine Science (VIMS) utilized remote sensing in three programs: (1) tonal variations in imagery of wetlands; (2) use of the thermal infrared to delineate the discharge cooling water at the Virginia Electric and Power Company (VEPCO) nuclear power station on the James River; and (3) the use of aerial photography to determine the volume storage function for water in the marsh-bay complex fed by Wachapreague Inlet on the Eastern Shore of Virginia. Details of the investigations are given, along with significant results.

Gordon, H. H.↗

Low-frequency fluctuation spectra and associated particle transport in the NASA Lewis bumpy-torus plasma

The strong radial electric field associated with the Penning discharge and the strong toroidal magnetic field give rise to a diversity of E/B phenomena, such as rotating waves and spokes, which in turn manifest themselves as space-time fluctuations of the plasma density and potential. Work is done to further understand the nature and origin of the fluctuations and their connection with fluctuation-induced transport. The approach is to monitor the density and potential fluctuations; to digitize the data; and to generate, with the aid of a computer, various spectral properties by means of the fast fourier transform. Of particular interest is the computer-generated transport spectrum that indicates in a quantitative way which fluctuation spectral components contribute to transport and which do not. All experimental measurements of the spectral characteristics of the plasma are given in absolute units rather than as relative values. Preliminary measurements of the transport spectrum of the ion population are given, and it is shown that the fluctuation-induced transport is in order-of-magnitude agreement with that inferred from the steady state current flowing to the electrodes that generate the plasma.

Singh, C. M.↗

A pulse-forming network for particle path visualization

A procedure is described for visualizing nonsteady fluid flow patterns over a wide velocity range using discrete nonluminous particles. The paramount element responsible for this capability is a pulse-forming network with variable inductance that is used to modulate the discharge of a fixed amount of electrical energy through a xenon flashtube. The selectable duration of the resultant light emission functions as a variable shutter so that particle path images of constant length can be recorded. The particles employed as flow markers are hydrogen bubbles that are generated by electrolysis in a water tunnel. Data are presented which document the characteristics of the electrical circuit and establish the relation of particle velocity to both section inductance and film exposure.

Mcalister, K. W.↗

Use of charging control guidelines for geosynchronous satellite design studies

Several of the principle guidelines from the Spacecraft Charging Design Guidelines Handbook are presented with illustrative examples. Use of the geomagnetic substorm specification to qualify satellite designs, the evaluation of satellite designs by using analytical modelling techniques, the use of selected materials and coatings to minimize charging, the tying of all conducting elements to a common ground, and the use of electrical filtering to protect circuits from discharge induced upsets are discussed. Discharge criteria and SCATHA data are excluded.

Steves, N. J.↗

Ground level measurements of air conductivities under Florida thunderstorms

Values of the positive and negative polar conductivities under summer thunderstorms in Florida are highly variable and exhibit a significant electrode effect, but the total conductivity usually remains close to values found in fair weather, 0.4 to 1.8 x 10 exp -14 S/m. With these values a method proposed by Krider and Musser (1982) for estimating the total conductivity from changes in the slope of the electric field recovery following a lightning discharge will be extremely sensitive to small time variations in the local Maxwell current density and must be modified to include these effects.

Blakeslee, Richard J.↗

NASA GRC and MSFC Space-Plasma Arc Testing Procedures

Tests of arcing and current collection in simulated space plasma conditions have been performed at the NASA Glenn Research Center (GRC) in Cleveland, Ohio, for over 30 years and at the Marshall Space Flight Center (MSFC) in Huntsville, Alabama, for almost as long. During this period, proper test conditions for accurate and meaningful space simulation have been worked out, comparisons with actual space performance in spaceflight tests and with real operational satellites have been made, and NASA has achieved our own internal standards for test protocols. It is the purpose of this paper to communicate the test conditions, test procedures, and types of analysis used at NASA GRC and MSFC to the space environmental testing community at large, to help with international space-plasma arcing-testing standardization. Discussed herein are neutral gas conditions, plasma densities and uniformity, vacuum chamber sizes, sample sizes and Debye lengths, biasing samples versus self-generated voltages, floating samples versus grounded samples, test electrical conditions, arc detection, preventing sustained discharges during testing, real samples versus idealized samples, validity of LEO tests for GEO samples, extracting arc threshold information from arc rate versus voltage tests, snapover, current collection, and glows at positive sample bias, Kapton pyrolysis, thresholds for trigger arcs, sustained arcs, dielectric breakdown and Paschen discharge, tether arcing and testing in very dense plasmas (i.e. thruster plumes), arc mitigation strategies, charging mitigation strategies, models, and analysis of test results. Finally, the necessity of testing will be emphasized, not to the exclusion of modeling, but as part of a complete strategy for determining when and if arcs will occur, and preventing them from occurring in space.

Ferguson, Dale C.↗

Dust Removal Technolgy for a Mars In Situ Resource Utilization System

Several In Situ Resource Utilization (lSRU) systems being considered to enable future manned exploration of Mars require capture of Martian atmospheric gas to extract oxygen and other commodities. However, the Martian atmosphere contains relatively large amounts of dust which must be removed in tbe collection systems of the ISRU chambers. The amount of atmospheric dust varies largely with the presence of daily dust devils and the less frequent but much more powerful global dust storms. A common and mature dust removal technology for terrestrial systems is the electrostatic precipitator. With this technology, dust particles being captured are imparted an electrostatic charge by means of a corona discharge. Charged dust particles are then driven to a region of high electric field which forces the particles onto a collector for capture. Several difficulties appear when this technology is adapted to the Martian atmospheric environment At the low atmospheric pressure of Mars, electrical breakdown occurs at much lower voltages than on Earth and corona discharge is difficult to sustain. In this paper, we report on our efforts to obtain a steady corona/glow discharge in a simulated Martian atmosphere of carbon dioxide at 9 millibars of pressure. We also present results on the design of a dust capture system under these atmospheric conditions.

Calle, C. I.↗

Influence of Tailored Applied Magnetic Fields on High-Power MPD Thruster Current Transport and Onset-Related Phenomena

This work investigated the effects of tailored, externally-applied magnetic fields on current transport and near-anode processes in the plasma discharge of a magnetoplasmadynamic thruster (MPDT). Electrical and plasma diagnostics were used to investigate how localized applied magnetic fields could mitigate the effects of the "onset" phenomena, including large-amplitude terminal voltage fluctuations and high anode fall voltages associated with unstable operation and anode erosion. An MPDT with a multi-channel hollow cathode was developed and tested with quasi-steady pulses of 1 millisecond duration at power levels of 36 kilowatts (20 volts, 1800 amperes) to 3.3 milliwatts (255 volts, 13.1 kiloamperes) with argon propellant in three different magnetic configurations: self-field, applied B field tangential to the anode lip near the exit plane, and applied cusp B field. The current pattern and current densities redistributed to follow the applied poloidal magnetic field lines, which created increased conduction paths to the anode. Also, the anode fall voltage was substantially reduced with both applied B field topologies over a large range of currents. For example, at 10.7 kiloamperes, the cusp applied magnetic field decreased anode fall voltages from 45-83 volts down to 15 volts or lower along much of the anode. The amplitude and frequency of the voltage fluctuations were also reduced over a broad range of currents with the applied fields. E.g., the standard deviations of the fluctuations were lowered by 37-49 percent at 8-9 kiloamperes. In addition, decreases in the mean terminal voltages as large as 31 percent were measured with the applied magnetic fields. These effects are shown to be associated with the increased current conduction along the applied magnetic field lines in the near-anode region. These results also suggest a reduction in frequency and intensity of current-concentrating filaments and anode spots, which contribute to erosion. Overall, both applied magnetic field configurations enabled significant reductions in onset-related behaviors relative to self-field operation. These improvements should lead to reduced anode erosion, i.e., improved thruster lifetime, and increased thruster efficiency with the applied fields. The applied fields used in this study differ from both the topologies and relative field strengths typically used in the vast majority of conventional, so-called "applied-field MPD thrusters" (AF-MPDTs). These results suggest a distinctive and more effective approach to influencing the near-anode phenomena and mitigating the deleterious effects of onset with appropriately designed applied magnetic fields.

delta-V↗

Spark Channel Dynamics of Electrostatic Discharges

When two differently-charged objects are brought in close proximity to each other, the resulting high electric fields can cause electron avalanche breakdown of the air gap separating the objects, a process known as electrostatic discharge (ESD). If enough initial charge is stored on the objects, the electrical breakdown can proceed to ionize the air to such a degree that a highly conductive filament of plasma forms in the gap, known as a spark channel. The spark electrically bridges the air gap, resulting in a rapid pulse of current that neutralizes the charge difference. The current pulse produces significant heating of the gas in the spark, resulting in dissociation, ionization, thermal radiation, and hydrodynamic expansion. ESD presents a hazard to electrically-sensitive devices, with consequences such as economic losses (e.g. damaged electronics) or unsafe response (e.g. unintended ignition of flammable gas mixtures, initiation of detonators, etc.). For this thesis, the ESD spark is taken to occur between two conducting electrodes, with the spark channel being axisymmetric in a cylindrical coordinate system centered on the channel. An RLC-type circuit is used for the discharge model of the ESD event. The spark is treated as a time-dependent resistance that is in series with a capacitance, an inductance, and (optionally) a load resistance representing a “victim” component under threat from the ESD event. The primary motivation of this work is to use a numerical hydrodynamic model to understand the energy dissipation and transport processes in the spark. The model consists of the compressible Euler equations of mass, momentum, and energy conservation together with an Eddington/P1 approximation for thermal radiation transport. To close the hydrodynamic system, an equation of state (EOS) was fitted from tabular data for air that accounts for the dissociation and ionization of air species. The hydrodynamic equations are solved using a conservative Lagrangian finite volume method. These partial differential equations are coupled to the circuit equations by calculation of the spark resistance via numerical integration of the electrical conductivity of the channel. Computational results are compared against experimental measurements of discharge current and radial density of the spark channel.

42 ENGINEERING↗