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At least 703 records · Page 39

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NASA NTRS1977

Rate constants for reactions of ClO/x/ of atmospheric interest

Chemical kinetics measurements on 82 gas phase reactions of chlorine containing species are reviewed. Recommended rate constants are given. The principal species of interest are Cl, Cl2, ClO, Cl2O, ClOO, OClO, CINO, HCl and halo derivatives of methane and ethane. Absorption spectra are given for 21 species. In addition the chemical kinetics methods used to obtain these data are discussed with regard to their applicability and reliability.

Watson, R. T.↗

NASA NTRS1977

Delay decomposition at a single server queue with constant service time and multiple inputs

Two networks consisting of single server queues, each with a constant service time, are considered. The external inputs to each network are assumed to follow some general probability distribution. Several interesting equivalencies that exist between the two networks considered are derived. This leads to the introduction of an important concept in delay decomposition. It is shown that the waiting time experienced by a customer can be decomposed into two basic components called self delay and interference delay.

Ziegler, C.↗

NASA NTRS1978

Comparative radiation resistance calculation for graded- and constant-composition n Al/x/Ga/1-x/As-p Al/z/Ga/1-z/As solar cells

The performance and radiation resistance of a new double-graded-band-gap solar cell are theoretically determined. The performance of this device is similar to that of the single-graded-band-gap cell. The power-conversion efficiencies of both graded-band-gap structures are shown to be less sensitive to minority-carrier lifetime degradation than a similar constant-composition heteroface cell.

Hutchby, J. A.↗

NASA NTRS1978

Upper bound and probable value of the rate constant of the reaction OH + HO2 yields H2O + O2

Discharge-flow experiments at 295 K of the OH + HO2 reaction are described in which excess O3 is added to OH through a movable injector; OH concentration is measured downstream by resonance fluorescence with and without addition of excess NO just upstream of the detector so that both OH concentration and OH concentration + HO2 concentration are determined independently. The data are compared with a computer model involving 12 reaction steps. A simple sensitivity analysis is carried out to establish how errors in the other 'known' rate constants affect the data fit. Best agreement is obtained between computer calculations and experiments when k1 for the OH + HO2 reaction is in the range 2-3 x 10 to the -11th cu cm/s. Values above about 5 x 10 to the -11th are very unlikely whereas those below about 1 x 10 to the -11th are less strongly excluded.

Chang, J. S.↗

NASA NTRS1978

A constant heat flux model of the evaporating interline region

An approximate procedure is developed for determining the heat sink capability of an interline region (junction of vapor, evaporating thin film, and nonevaporating thin film), with consideration of the effect of resistance of the solid to heat transfer. The formulation is based on a simple one-dimensional constant heat flux model. The solution is directed toward a limiting case in which the thermal conductance of the solid is controlling. Since the value of the ideal liquid-vapor interfacial heat transfer coefficient is very large, conductance of the solid is found to dominate the overall heat transfer coefficient in the interline region after a small increase in film thickness.

Wayner, P. C., Jr.↗

NASA NTRS1978

Rate constant for the reaction ClO + NO yields Cl + NO2

The rate constant for the reaction ClO + NO yields Cl + NO2 has been determined over the temperature range 226.7-415.4 K in a discharge flow system using a mass spectrometer as a detector. The results, expressed in the Arrhenius form, are compared with previous measurements.

Leu, M. T.↗

NASA NTRS1979

Preparation of dielectric coating of variable dielectric constant by plasma polymerization

A plasma polymerization process for the deposition of a dielectric polymer coating on a substrate comprising disposing of the substrate in a closed reactor between two temperature controlled electrodes connected to a power supply is presented. A vacuum is maintained within the closed reactor, causing a monomer gas or gas mixture of a monomer and diluent to flow into the reactor, generating a plasma between the electrodes. The vacuum varies and controls the dielectric constant of the polymer coating being deposited by regulating the gas total and partial pressure, the electric field strength and frequency, and the current density.

Hudis, M.↗

NASA NTRS1979

The effects of ground hydrology on climate sensitivity to solar constant variations

The effects of two different evaporation parameterizations on the climate sensitivity to solar constant variations are investigated by using a zonally averaged climate model. The model is based on a two-level quasi-geostrophic zonally averaged annual mean model. One of the evaporation parameterizations tested is a nonlinear formulation with the Bowen ratio determined by the predicted vertical temperature and humidity gradients near the earth's surface. The other is the linear formulation with the Bowen ratio essentially determined by the prescribed linear coefficient.

Chou, S. H.↗

NASA NTRS1979

Evolution of the rotation of an artificial earth satellite under the influence of a perturbing moment which is constant in fixed axes

The change in the modulus of the vector of the kinetic moment of a satellite which is noted during the determination of the actual orientation of an artificial earth is discussed. The change is due to the presence of a small perturbing moment, which is constant in fixed axes relative to the satellite. It is also shown that the averaged equations in this problem can be integrated.

Neyshtadt, A. I.↗

NASA NTRS1979

Utilization of satellite-satellite tracking data for determination of the geocentric gravitational constant (GM)

Range rate tracking of GEOS 3 through the ATS 6 satellite was used, along with ground tracking of GEOS 3, to estimate the geocentric gravitational constant (GM). Using multiple half day arcs, a GM of 398600.52 + or - 0.12 cu km/sq sec was estimated using the GEM 10 gravity model, based on speed of light of 299792.458 km/sec. Tracking station coordinates were simultaneously adjusted, leaving geopotential model error as the dominant error source. Baselines between the adjusted NASA laser sites show better than 15 cm agreement with multiple short arc GEOS 3 solutions.

Martin, C. F.↗

NASA NTRS1978

A system concept for wide swath constant incident angle coverage

The multiple beam SAR system concept is developed and shown to readily overcome the radar ambiguity constraints associated with orbital systems, thus permitting imagery over swaths much wider than 100 km. The antenna technique permits imagery at nearly constant incidence angles. When frequency scanning is used, the center angle may be programmed. The redundant use of the antenna aperture during reception results in lower transmitted power and in shorter antenna lengths in comparison with conventional designs.

Claassen, J. P.↗

NASA NTRS1978

Determination of the geocentric gravitational constant from laser ranging on near-earth satellites

Laser range observations taken on the near-earth satellites of Lageos (a = 1.92 e.r.), Starlette (a = 1.15 e.r.), BE-C (a = 1.18 e.r.), and Geos-3 (a = 1.13 e.r.) have been combined to determine an improved value of the geocentric gravitational constant (GM). The value of GM is 398600.61 cu km/sec per sec, based upon a speed of light, c, of 299792.5 km/sec. Using the IAG-adopted value of c equalling 299792.458 km/sec scales GM to 398600.44 cu km/sec per sec. The uncertainty in this value is assessed to be plus or minus 0.02 cu km/sec per sec. Determinations of GM from the data taken on these four satellites individually show variations of only .04 cu km/sec per sec from the combined result. The Lageos information dominated the combined solution, and gave the most consistent results in its data subset solutions. The value obtained for GM from near-earth laser ranging compares quite favorably with the most recent results of the lunar laser and interplanetary experiments.

Lerch, F. J.↗

NASA NTRS1978

The effect of ground hydrology on climate sensitivity to solar constant variations

A zonally averaged climate model is used to investigate the effects of different evaporation parameterizations on climate sensitivity to solar constant variations. The model is based on the annual mean zonally averaged hemispheric climate model of Ohring and Adler (1978), with some modifications on the heating parameterizations. The dynamic model utilizes the two-level quasi-geostrophic potential vorticity equations. The heating processes are related to solar radiation, long-wave radiation, convection, evaporation, latent heat release, and ocean transport. Evaporation parameterization has been improved by using a nonlinear formulation in which the Bowen ratio is determined by the vertical gradients of water vapor and temperature near the earth's surface.

Chow, S.-H.↗

NASA NTRS1979

Elastic constants for superplastically formed/diffusion-bonded sandwich structures

Formulae and the associated graphs are presented for contrasting the effective elastic constants for a superplastically formed/diffusion-bonded (SPF/DB) corrugated sandwich core and a honeycomb sandwich core. The results used in the comparison of the structural properties of the two types of sandwich cores are under conditions of equal sandwich density. It was found that the stiffness in the thickness direction of the optimum SPF/DB corrugated core (i.e., triangular truss core) was lower than that of the honeycomb core, and that the former had higher transverse shear stiffness than the latter.

Ko, W. L.↗

NASA NTRS1979

The reaction N/4S/ + O3 - An upper limit for the rate constant at 298 K

The reaction of N(4S) atoms with ozone was examined at 298 K using discharge flow and flash photolysis techniques, both coupled with resonance fluorescence detection of N(4S). No reaction was detected in either system, and an upper limit of 5 x 10 to the -16th cu cm/molecule/s was estimated for the rate constant. This is 1000 times lower than the presently accepted value of 5.7 x 10 to the -13th cu cm/molecule/s which is based on a discharge flow-mass spectrometric study of the reaction. Potential complications in the latter experiment are discussed.

Stief, L. J.↗

NASA NTRS1979

Rate constants for the reactions of OH with ClO, Cl2, and Cl2O at 298K

Recent concern about the depletion of stratospheric ozone by chlorine species from the decomposition of chlorofluoromethanes has emphasized the need for laboratory studies of the first reaction steps involved, especially those which control the concentration of the OH and ClO radicals in the stratosphere. Rate constants for the reactions of OH with ClO, Cl2, and Cl2O at 298 K have been determined in a discharge flow system using resonance fluoresence detection. The results are (9.1 + or - 1.3) x 10 to the -12th, (5.5 + or - 0.3) x 10 to the -14th, and (6.5 + or - 0.5) x 10 to the -12th (all in units of cu cm/sec), respectively.

Leu, M. T.↗

NASA NTRS1979

Evaluation of the geocentric gravitational constant from Viking Doppler and range data

During the launch and near-earth phase, continuous radio tracking data were acquired from two Viking spacecraft as they receded from earth. Analysis of this data yielded these values for the geocentric gravitational constant GM: 398600.5 + or - 0.1 cu km/sec per sec for Viking 1 and 398600.65 + or - 0.2 cu km/sec per sec for Viking 2. These values include the atmosphere of the earth and are consistent with the currently adopted speed of light (299792.458 km/sec.).

Esposito, P. B.↗

NASA NTRS1978

Evidence for a constant speed of shock propagation between 0.8 AU and 2.2 AU

The results of preliminary analysis of the in situ observations of solar wind plasma and interplanetary magnetic field data are presented. It is indicated that two planetary shocks associated with the August 1972 solar events propagated at approximately constant speed between 0.8 AU and 2.2 AU. This result is contrary to some theoretical expectations and earlier reports for these events of a strong deceleration of these shocks with increasing heliocentric distance. One example given is the difference between observed shock speeds of 700 km/sec and the estimated speeds of 2200 km/sec for Pioneer 9 and 1000 km/sec for Pioneer 10. These higher average speeds associated with the propagation of the shocks from the sun to the spacecraft, therefore, imply an extremely strong deceleration closer to the sun (within 0.8 AU).

Intriligator, D. S.↗