Reclaimed Coal Ash as Low-Cost TES Material
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Over the last several years, NREL has been developing a system to measure large optical surfaces of heliostat mirrors by reflecting computer vision targets. An advantage of this system, called Reflected Target Nonintrusive Assessment (ReTNA), is that it lends itself well to stitching together many images, each reflecting only part of a larger heliostat. In the last few months, this was taken to a new extreme, with a small target (<5m2) being used to measure a >25m2 long focal length heliostat. These measurements were compared with traditional fringe deflectometry methods, which require a >50m2 target, and photogrammetry. The strengths, weaknesses and limitations of ReTNA are discussed. An estimated uncertainty in this new measurement is presented, along with software improvements and a new wireless data collection system. A bill of materials for this measurement system is presented, which has been designed to use all low-cost, off-the-shelf components. Finally, the next steps for future ReTNA development are presented. Overall, ReTNA can be a valuable optics measurement system, complimentary to existing measurement techniques available for large reflective surfaces.
This presentation will cover a new web tool, Solar Thermal Energy Planner (STEP 1), developed to ease the techno-economic analysis of solar thermal systems for industrial process heat.
It is desired to develop heat exchangers able to be operated at high temperatures (750°C) and pressures (3636 psi) for use in advanced Brayton power cycle. Conventional materials have not had the high strength at temperature required for these applications previously, however a fairly new material Inconel 740H developed by Special Metals for the ultra-supercritical water fossil industry has shown good performance under these conditions. In further efforts to capitalize on these new high strength high temperature alloys CompRex has developed a diffusion bonding procedure capable of alloying compact high effectiveness heat exchangers that can perform under these high temperature and high-pressure conditions. Initial tests of the heat exchanger are being conducted at the University of Wisconsin using supercritical CO2 working fluid. The bonding process has been adjusted such that the strength of the bonded block has achieved over 90% yield and tensile strength of the 740H base material values. Grain size before and after bonding were measured to determine the extent of grain growth and grain diffusion across the interface. A discussion of the heat exchanger design, etching and initial tensile tests on sample bonds will be discussed.
Design Basis Documents / Owner’s Technical Specifications are developed for parabolic trough and central receiver power plants using nitrate salt as the heat transport fluid and the thermal storage medium. The goals were to 1) distill the successful experience with nitrate salt systems from as many commercial projects as possible, 2) provide technical bases for equipment design/selection that an owner can impose on an EPC contractor, 3) compile this information in one location to provide guidance on salt systems that is as broadly applicable to as many projects as possible, and 4) work toward an industry consensus on a Design Basis Document that reflects the lessons learned from earlier commercial projects. The document allows an owner to provide design guidance, and to impose a minimum set of requirements, above and beyond those in the normal Codes and Standards, on an EPC contractor in an effort to avoid a repeat of past mistakes. If successful, this would allow salt systems to achieve the same levels of reliability and availability as commercial parabolic trough plants using diphenyl oxide / biphenyl (i.e., Dowtherm A, Therminol VP-1) as the heat transfer fluid. The report consists of 3 volumes: • Volume 1 - Specifications for Parabolic Trough Projects • Volume 2 - Specifications for Central Receiver Projects • Volume 3 - Narrative Volumes 1 and 2 include discussions of the following topics: • Plant functional requirements for the salt systems • Plant operating states, and transitions between states, for the salt systems • Risk analysis of the principal salt components • Plant requirements for the salt systems to meet the functional and the operating requirements • Type of specification for the principal salt components: functional; or prescriptive • Current state of the art for salt systems. Volume 3 discusses a number of cases in which the salt equipment at commercial parabolic trough and central receiver projects has not met the projected levels of reliability and availability. Possible reasons for the sources of the problems are discussed, as is a range of possible alternate designs that could avoid the known problems.
As a follow-on to the NREL Best Practices report, a technical Design Basis Document has been developed for salt systems. The report includes prescriptive specifications for tanks, steam generators, valves, heat tracing, materials, and process engineering, with a goal of achieving a plant availability of 92+ percent.
Free from siting constraints, thermal energy storage (TES) shows promise as an economical alternative to traditional pumped-storage hydropower (PSH) and compressed air energy storage (CAES). As potential thermal energy storage media, many solid particles demonstrate stability over wide temperature ranges which allows for increased sensible energy storage density and is essential in achieving low-cost storage. Silica sand, in the form of a-quartz, is one such candidate. This work presents a brief review of relevant silica thermophysical properties and further investigates the thermal stability of silica particles as a candidate TES media by subjecting them to two different thermal campaigns: (1) a 500-hour thermal treatment at 1200°C under varied atmospheres; and (2) cycling 25, 50, and 100 times between 300°C and 1200°C. For both campaigns, particle stability is examined by means of pre- and post-treatment Mie scattering. An additional XRD analysis is conducted for the 500-hour treatment in air. Results indicate limited changes in both particle distribution and crystallographic structure which is promising for the application as solid particle media for thermal energy storage.
The National Renewable Energy Laboratory (NREL) and Acciona Solar Power (ASP) have developed and are implementing a process that addresses the issue of hydrogen buildup in parabolic trough power plants. Our method selectively removes hydrogen from the expansion tanks of the power plant to control hydrogen levels in the circulating heat-transfer fluid (HTF). During previous work, we developed a sensor that measures hydrogen partial pressure in the expansion-tank headspace gas. We demonstrated that our sensor measures hydrogen levels over a wide range of partial pressure—from 1.33 mbar down to 0.003 mbar. More recently, we conceived and developed an integrated process module that performs both hydrogen sensing and separating functions. The sensor/separator measures hydrogen partial pressure in the headspace gas in the same way as our original sensor design. Additionally, the integrated module separates hydrogen from the headspace gas to reduce hydrogen to the level needed to maintain the performance of receivers in the collector field. We demonstrated the performance of a laboratory-scale version of this module. Testing showed that the module performed as expected: the accuracy of the sensing function was ±7%, and the hydrogen extraction rate for the separating mode was consistent with our modeling predictions. The primary benefit of this module is its simple design, both in terms of function and incorporation into the HTF subsystem of the power plant. Most recently, NREL and ASP planned, specified, and designed a mitigation process that is based on the integrated module. We are currently completing installation of this process at ASP's Nevada Solar One power plant in Boulder City, Nevada, USA. The mitigation process is being installed at ground level below the HTF expansion tanks, where it draws headspace gas from the tanks, removes hydrogen, and returns the treated gas back to the tanks. In this paper, we report progress on the installation and describe some of the many design details and challenges that we addressed during the past year. We will generate initial performance data from the Nevada Solar One mitigation process in early 2020.
The National Renewable Energy Laboratory (NREL) has been conducting exposure experiments on solar reflectors for over four decades. Thousands of mirror samples from over one hundred suppliers have been exposed to and monitored in a range of relevant environments. These test conditions include outdoor test settings and several controlled laboratory environments. These samples have been rigorously individually characterized using a series of reflectance measurements, visual inspections, and in some cases, in-depth composition analysis to identify degradation modes, reflectance losses, and other mirror properties integral to understanding the solar reflector's life cycle. Here, this paper compiles the decades of measurement data into a concise statistical analysis. It includes exposure and degradation data for numerous reflector types, including secondary-surface reflector permutations of polymer and glass superstrates with silver and aluminum reflectors as well as front-surface reflectors. The results herein are intended to analyze environmental stressors and degradation trends among various historical and state-of-the-art solar reflectors. It may be used to support solar reflector design, effective testing methodology, and inform manufacturing decisions moving forward. Presented are the results of the compiled database and an initial analysis for degradation rate modeling using full-spectrum and wavelength-dependent approaches. The database is a growing resource hosted on a live, publicly accessible website. In conjunction with the analysis presented here, it provides a valuable resource to the solar reflector manufacturing and testing industry.
This presentation reviews the major trends that occurred in the solar industry in the Q3 and Q4 of 2019. Major topics of focus will be global and U.S. supply & demand, module & system price, investment trends, and updates on U.S. government programs supporting the solar industry.
An alternate and sustainable form of energy is CSP systems, which capture and store the sun’s energy in the form of heat. Increasing the operational temperature of CSP systems will increase the efficiency of electricity production while operating at temperatures exceeding 700 degrees Celsius also creates novel operational problems. One approach for high-temperature CSP systems is to utilize solid particles as the primary heat transfer medium. As particles flow through this system, the movement of particles creates erosion in the forms of impact, abrasion, and attrition erosion. In the real world, while all three forms of erosion will occur simultaneously, it is imperative to understand the individual effect of each erosion over the lifetime of the powerplant. Besides material erosion and long-term durability concerns, thermal cycling of the particles could also introduce changes in particle thermal performance due to alterations in particle morphology. Current research on the issue of erosion has been limited to industrial applications and does not necessarily coincide with the operating conditions in CSP systems. We focus on attrition erosion resulting from particle-to-wall and particle-to-particle interactions. Research has shown that besides material hardness affecting how fast particles break down, attrition erosion increased as the size of the particles increased due to a higher chance of collision between the particles. Particle attrition is relevant to the CSP community as it may result in material loss, change the system's thermal performance, and generation of fines which could pose an environmental hazard. In this work, we focus on developing a test set up that can isolate and measure particle attrition when subjected to conditions relevant to Gen3 CSP systems.
Fractal coatings on various low-cost and high-temperature metallic substrates such as SS316, SS347, In800H, In740H, In625, Haynes 230, etc. were fabricated employing our patented novel electrodeposition process at various deposition potentials and deposition times, as well as chemical etching. The best combination of the materials and processing conditions were co-optimized for the reliable and repeatable fabrication of the multifunctional coatings. Surface morphologies were examined using SEM and AFM, and fractal characterization was done using a 3D optical surface profiler. Fractal dimension was used to identify successful fabrication and material parameters. The mechanical durability of the coatings was evaluated using several standardized tests, such as sand abrasion (ASTM D968) and adhesion (ASTM D3359), to fully characterize and demonstrate the mechanical durability of the fabricated surfaces. HTF immersion tests on the fractal multifunctional coatings were conducted based on a modification of the ASTM D870, which is established for static water immersion testing. To calculate the corrosion rates and descaled weight loss of the samples subjected to thermal exposure for different time durations (100 h, 300 h, 500 h, and optionally 750 h) to estimate the corrosion rate. While protecting the substrates from corrosion is an important goal, an allied goals is also to examine the post-corrosion temperature stability and properties of the molten salts themselves due to the dissolution of the constituents of the alloys and the corrosion products from the coatings that cause “fouling” of the molten salts. Fouling characteristics of the different molten salt HTFs exposed to coated and uncoated substrates were investigated. Finally, considering a prototype molten salt/sCO2 heat exchanger, cost/performance model is developed to demonstrate that the coatings on low-cost alloys such as stainless steel provide lower levelized cost of heat exchanger compared to high nickel content Ha230.
In this project, to tackle the technical obstacles, we utilized Laser Additive Alloying (LAA), an additive manufacturing (AM) technology, to 3D print the entire absorber tube with optimized helical fins to improve heat transfer at the expense of minimized pressure drop increase. The 3D printed absorber tubes can increase the uniformity of circumferential temperature distribution, reduced the thermal stresses, decrease the heat loss, and reach the target receiver thermal efficiency.
This project built the world’s largest Forward Osmosis (FO) solar thermal desalination plant at the NELHA Hawaii Ocean Science and Technology Park for a high visibility “on sun” demonstration of seawater desalination for agricultural applications. The project included re-commissioning an existing 2MW micro-dish solar thermal array and coupling it to a next-generation 500m3/day FO system. The purpose of the project was to validate FO at commercial scale; to verify that the water produced is safe for potential downstream agricultural users; to gather data on capital cost, energy consumption and operating expense for the technology; and to demonstrate that FO can be successfully coupled to low-grade thermal resources. The plant implemented advancements in FO component technology, including hot nano-filtration, polymeric heat exchangers, draw solutions, and improved FO membranes, and operated from June 2022 to September 2023 - producing 30gpm of permeate water. Thermal energy was below 30kWh/m 3 during operation, establishing a new benchmark in thermal desalination technology, with recovery rates at times exceeding 65%, well above what commercial RO systems can achieve. Combining the plant capital cost (CAPEX) and the operating expenses (OPEX) yields a Levelized Cost of Water (LCOW) that is competitive with existing carbon-intensive technologies such as RO. The ability of the plant to operate from a renewable resource paves the way toward a low-carbon desalination future using low-grade thermal resources.
The CSP Systems Analysis project estimates the current market cost of CSP subsystems and technologies for use by the DOE Program and within NREL analysis tools. The project addresses upgrades to NREL's System Advisor Model (SAM) related to CSP, as well as development of new modules within SAM to expand the types of CSP systems that can be simulated and new tools for evaluating CSP subsystem performance or optimizing CSP system layouts, for example, SolarPILOT and SolTrace. The project evaluates the potential cost and performance of new CSP-relevant technologies and generally includes assessment of CSP technologies in support of the DOE subprogram. A primary goal of the CSP System Analysis project is to provide timely and accurate cost data to the DOE to assess the current state of CSP technologies as well as predict performance and cost for pre-commercial and emerging technologies that may impact the industry. Prior work in this task has produced technology cost reports and roadmaps for DOE and highlighted promising research paths that could reduce overall CSP cost, such as the supercritical CO2 power cycle and molten-salt trough systems. CSP Systems Analysis produces modeling tools to evaluate the performance of CSP systems, subsystems, or components, and journal articles, conference papers, technical reports and databases to disseminate information to the CSP industry. CSP technology costs are estimated and tracked using these tools as well as analysis of literature and industry sources. The CSP modeling tools and NREL analysis results are used by researchers; government, financial, and industry analysts; and other CSP stakeholders. The purpose of this final technical report is to summarize the key accomplishments of the past three years of this project. The project was divided into seven separate tasks, and in what follows, we describe the background, objectives, key accomplishments, and path forward for each task within the project, with one section of this report summarizing each task.
Figure data for report on opportunities for solar technologies to provide industrial process heat in the United States (NREL/TP-6A20-77760).
The Solar Futures Study explores potential pathways for solar energy to drive deep decarbonization of the U.S. electric grid by 2035, and envisions how further electrification could decarbonize the broader U.S. energy system by 2050.
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