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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 703 records · Page 39

Nanostructured Solar Irradiation Control Materials for Solar Energy Conversion

Tailoring the solar absorptivity (alpha(sub s)) and thermal emissivity (epsilon(sub T)) of materials constitutes an innovative approach to solar energy control and energy conversion. Numerous ceramic and metallic materials are currently available for solar absorbance/thermal emittance control. However, conventional metal oxides and dielectric/metal/dielectric multi-coatings have limited utility due to residual shear stresses resulting from the different coefficient of thermal expansion of the layered materials. This research presents an alternate approach based on nanoparticle-filled polymers to afford mechanically durable solar-absorptive and thermally-emissive polymer nanocomposites. The alpha(sub s) and epsilon(sub T) were measured with various nano inclusions, such as carbon nanophase particles (CNPs), at different concentrations. Research has shown that adding only 5 wt% CNPs increased the alpha(sub s) and epsilon(sub T) by a factor of about 47 and 2, respectively, compared to the pristine polymer. The effect of solar irradiation control of the nanocomposite on solar energy conversion was studied. The solar irradiation control coatings increased the power generation of solar thermoelectric cells by more than 380% compared to that of a control power cell without solar irradiation control coatings.

Kang, Jinho↗

A Fully Non-metallic Gas Turbine Engine Enabled by Additive Manufacturing

The Non-Metallic Gas Turbine Engine project, funded by NASA Aeronautics Research Institute (NARI), represents the first comprehensive evaluation of emerging materials and manufacturing technologies that will enable fully nonmetallic gas turbine engines. This will be achieved by assessing the feasibility of using additive manufacturing technologies for fabricating polymer matrix composite (PMC) and ceramic matrix composite (CMC) gas turbine engine components. The benefits of the proposed effort include: 50 weight reduction compared to metallic parts, reduced manufacturing costs due to less machining and no tooling requirements, reduced part count due to net shape single component fabrication, and rapid design change and production iterations. Two high payoff metallic components have been identified for replacement with PMCs and will be fabricated using fused deposition modeling (FDM) with high temperature capable polymer filaments. The first component is an acoustic panel treatment with a honeycomb structure with an integrated back sheet and perforated front sheet. The second component is a compressor inlet guide vane. The CMC effort, which is starting at a lower technology readiness level, will use a binder jet process to fabricate silicon carbide test coupons and demonstration articles. The polymer and ceramic additive manufacturing efforts will advance from monolithic materials toward silicon carbide and carbon fiber reinforced composites for improved properties. Microstructural analysis and mechanical testing will be conducted on the PMC and CMC materials. System studies will assess the benefits of fully nonmetallic gas turbine engine in terms of fuel burn, emissions, reduction of part count, and cost. The proposed effort will be focused on a small 7000 lbf gas turbine engine. However, the concepts are equally applicable to large gas turbine engines. The proposed effort includes a multidisciplinary, multiorganization NASA - industry team that includes experts in ceramic materials and CMCs, polymers and PMCs, structural engineering, additive manufacturing, engine design and analysis, and system analysis.

manufacturing↗

Advanced Gas Turbine (AGT) technology development

A 74.5 kW (100 hp) automotive gas turbine was evaluated. The engine structure, bearings, oil system, and electronics were demonstrated and no shaft dynamics or other vibration problem were encountered. Areas identified during the five tests are the scroll retention features, and transient thermal deflection of turbine backplates. Modifications were designed. Seroll retention is addressed by modifying the seal arrangement in front of the gasifier turbine assembly, which will increase the pressure load on the scroll in the forward direction and thereby increase the retention forces. the backplate thermal deflection is addressed by geometric changes and thermal insulation to reduce heat input. Combustor rig proof testing of two ceramic combustor assemblies was completed. The combustor was modified to incorporate slots and reduce sharp edges, which should reduce thermal stresses. The development work focused on techniques to sinter these barrier materials onto the ceramic rotors with successes for both material systems. Silicon carbide structural parts, including engine configuration gasifier rotors (ECRs), preliminary gasifier scroll parts, and gasifier and power turbine vanes are fabricated.

Source record↗

Environment Conscious Ceramics (Ecoceramics)

Environment conscious ceramics (Ecoceramics) are a new class of materials, which can be produced with renewable natural resources (wood) or wood wastes (wood sawdust). Silicon carbide-based ecoceramics have been fabricated by reactive infiltration of carbonaceous preforms by molten silicon or silicon-refractory metal alloys. These carbonaceous preforms have been fabricated by pyrolysis of solid wood bodies at 1000 C. The fabrication approach, microstructure, and mechanical properties of SiC-based ecoceramics are presented. Ecoceramics have tailorable properties and behave like ceramic materials manufactured by conventional approaches.

Singh, Mrityunjay↗

Developing Materials and Coating Technologies for Mitigation of Lunar Dust Adhesion and Abrasion

In order to support long duration missions on the Moon’s surface, materials resistant to the harsh lunar environment are critically needed. Lunar dust poses a major threat to the durability of components and vehicles due to its fine, jagged morphology and highly abrasive nature, enabling the particles to adhere and embed onto surfaces of components and devices and potentially leading to premature failure. There is significant effort within NASA to develop novel materials and coating technologies to mitigate lunar dust adhesion and abrasion. This effort has been exploring a variety of production routes and examining properties of candidate material systems, including ceramic, metallic and polymeric. Manufacturing methods investigated include ceramic powder processing, additive manufacturing and surface modification via laser ablation patterning of bulk materials and coatings. An overview of ongoing NASA materials and coating research and development efforts to enable lunar surface exploration will be presented.

Materials, Coatings, lunar dust mitigation↗

Abrasive Effects of Lunar Regolith on Material Wear for Long-Term Lunar Applications

Long-term operations on the Moon’s surface require materials that can withstand the harsh lunar environment. Lunar dust and regolith pose significant threats to the long-term durability of materials used in lunar applications. Lunar dust, easily perturbed and dispersed, adheres and abrades materials due to its rough and irregular grain morphology. More closely representing this abrasion action through experimental laboratory testing is critical in assessing the durability of potential lunar candidate materials used in mechanical, sensor, and human-based systems. In this study, the performance of materials using Taber abrasive wheels made from lunar regolith simulant was assessed and compared to results obtained using standard ceramic-based abrasion materials. The results highlight a difference in the abrasive wear rates between the lunar regolith simulant and the standard ceramic-based abrasive. Utilizing the mechanisms and testing capabilities of this two-body abrasive interaction leveraging regolith-based abrasives may more closely represent the interplay between materials and lunar dust, which is vital for assessing the long-term viability of materials for extended lunar missions. Improved lunar testing capabilities may also enhance evaluations of the long-term performance degradation of passive and active dust mitigation methods.

Zachary Stein↗

Carbon Fiber Reinforced Ceramic Composites for Propulsion Applications

Fiber reinforced ceramic composites are materials of choice for gas turbine engines because of their high thermal efficiency, thrust/weight ratio, and operating temperatures. However, the successful introduction of ceramic composites to hot structures is limited because of excessive cost of manufacturing, reproducibility, nonuniformity, and reliability. Intense research is going on around the world to address some of these issues. The proposed effort is to develop a comprehensive status report of the technology on processing, testing, failure mechanics, and environmental durability of carbon fiber reinforced ceramic composites through extensive literature study, vendor and end-user survey, visits to facilities doing this type of work, and interviews. Then develop a cooperative research plan between NASA GRC and NCA&T (Center for Composite Materials Research) for processing, testing, environmental protection, and evaluation of fiber reinforced ceramic composites.

Freedman, Marc↗

Review of acousto-ultrasonic NDE for composites

Acousto-ultrasonics utilizes simulated stress waves to detect and quantify defect states, damage conditions, and variations of mechanical properties in fiber reinforced composites. The term acousto-ultrasonics denotes a combination of aspects of acoustic emission methodology with ultrasonic materials characterization. The acousto-ultrasonic approach was developed to deal primarily with evaluation of the integrated effect of minor flaws and diffuse flaw populations of subcritical flaws in composite and bonded structures. These factors singly and collectively also influence acousto-ultrasonic measurements that, in turn, correlate with dynamic response and mechanical property variations. Since it was first introduced, the acousto-ultrasonic approach was successfully applied to a variety of materials, including polymeric, metallic, and ceramic matrix composites; adhesively bonded materials; paper and wood products; cable and rope; and also human bone. Examples of applications and limitations of the approach are reviewed. Basic methods and guidelines are discussed. The underlying hypothesis and theory development needs are indicated.

Vary, Alex↗

Novel Ceramic Dispersion Strengthened Refractory Metals for Improved Printability and Properties

Refractory metals and alloys are of major interest for nuclear fusion systems, space nuclear power and propulsion, and hypersonic applications due to their desirable properties at elevated temperatures (>1500°C). Limitations of refractory materials include their low ductility, poor oxidation resistance, and high manufacture cost using traditional techniques. Additive manufacturing (AM) can reduce material waste associated with manufacture, but AM fabrication is impacted by the brittleness of these refractory metals, resulting in excessive cracking during printing. Cracking reduces the effectiveness of hot isostatic pressing (HIP) which is commonly used to improve density and mechanical properties of AM components. The goal of this work is to improve refractory metal printability without majorly affecting the material properties which are the main reason these materials are used. Ceramic nanoparticles have been shown to help improve material properties after heat treatment. Results will be shown that demonstrate the effectiveness of adding nanoparticles to refractory metals. Additionally, there will be discussion regarding how these nanoparticles change the effect of heat treatments such as HIP compared with the AM pure metal samples.

Carly J. Romnes↗

Ceramic Fabric Coated With Silicon Carbide

Material used as high-temperature shell. Ceramic fabric coated with silicon carbide (SiC) serves as tough, heat-resistant covering for other refractory materials. Developed to protect reusable insulating tiles on advanced space transportation systems. New covering makes protective glaze unnecessary. Used on furnace bricks or on insulation for engines.

Riccitiello, S. R.↗

A study for development of aerothermodynamic test model materials and fabrication technique

A literature survey, materials reformulation and tailoring, fabrication problems, and materials selection and evaluation for fabricating models to be used with the phase-change technique for obtaining quantitative aerodynamic heat transfer data are presented. The study resulted in the selection of two best materials, stycast 2762 FT, and an alumina ceramic. Characteristics of these materials and detailed fabrication methods are presented.

Dean, W. G.↗

Heat flux measurements on ceramics with thin film thermocouples

Two methods were devised to measure heat flux through a thick ceramic using thin film thermocouples. The thermocouples were deposited on the front and back face of a flat ceramic substrate. The heat flux was applied to the front surface of the ceramic using an arc lamp Heat Flux Calibration Facility. Silicon nitride and mullite ceramics were used; two thicknesses of each material was tested, with ceramic temperatures to 1500 C. Heat flux ranged from 0.05-2.5 MW/m2(sup 2). One method for heat flux determination used an approximation technique to calculate instantaneous values of heat flux vs time; the other method used an extrapolation technique to determine the steady state heat flux from a record of transient data. Neither method measures heat flux in real time but the techniques may easily be adapted for quasi-real time measurement. In cases where a significant portion of the transient heat flux data is available, the calculated transient heat flux is seen to approach the extrapolated steady state heat flux value as expected.

Holanda, Raymond↗

Measurement of Damping of Composite Materials for Turbomachinery Applications

The scientific community has felt that ceramic matrix composite (CMC) materials possess more material damping than the superalloys used in the production of rocket engine turbomachinery turbine-end components. The purpose of this NASA/MFSC study is to quantify the damping in CMC's as compared to a typical super-alloy, Inconel 718. It was observed through testing of beam coupons and disk specimens that the CMC's do indeed possess more material damping than the baselined alloy Inconel 718.

Harris, D. L.↗

Integrated Design Software Predicts the Creep Life of Monolithic Ceramic Components

Significant improvements in propulsion and power generation for the next century will require revolutionary advances in high-temperature materials and structural design. Advanced ceramics are candidate materials for these elevated-temperature applications. As design protocols emerge for these material systems, designers must be aware of several innate features, including the degrading ability of ceramics to carry sustained load. Usually, time-dependent failure in ceramics occurs because of two different, delayedfailure mechanisms: slow crack growth and creep rupture. Slow crack growth initiates at a preexisting flaw and continues until a critical crack length is reached, causing catastrophic failure. Creep rupture, on the other hand, occurs because of bulk damage in the material: void nucleation and coalescence that eventually leads to macrocracks which then propagate to failure. Successful application of advanced ceramics depends on proper characterization of material behavior and the use of an appropriate design methodology. The life of a ceramic component can be predicted with the NASA Lewis Research Center's Ceramics Analysis and Reliability Evaluation of Structures (CARES) integrated design programs. CARES/CREEP determines the expected life of a component under creep conditions, and CARES/LIFE predicts the component life due to fast fracture and subcritical crack growth. The previously developed CARES/LIFE program has been used in numerous industrial and Government applications.

Source record↗

Ceramic Honeycomb Structures and Method Thereof

The present invention relates to a method for producing ceramic articles and the articles, the process comprising the chemical vapor deposition (CVD) and/or chemical vapor infiltration (CVI) of a honeycomb structure. Specifically the present invention relates to a method for the production of a ceramic honeycomb structure, including: (a) obtaining a loosely woven fabric/binder wherein the fabric consists essentially of metallic, ceramic or organic fiber and the binder consists essentially of an organic or inorganic material wherein the fabric/binder has and retains a honeycomb shape, with the proviso that when the fabric is metallic or ceramic the binder is organic only; (b) substantially evenly depositing at least one layer of a ceramic on the fabric/binder of step (a); and (c) recovering the ceramic coated fiber honeycomb structure. In another aspect, the present invention relates to a method for the manufacture of a lightweight ceramic-ceramic composite honeycomb structure, which process comprises: (d) pyrolyzing a loosely woven fabric a honeycomb shaped and having a high char yield and geometric integrity after pyrolysis at between about 700 degrees and 1,100 degrees Centigrade; (e) substantially evenly depositing at least one layer of ceramic material on the pyrolyzed fabric of step (a); and (f) recovering the coated ceramic honeycomb structure. The ceramic articles produced have enhanced physical properties and are useful in aircraft and aerospace uses.

Cagliostro, Domenick E.↗

Optical Characterization of Window Materials for Aerospace Applications

An optical metrology laboratory has been developed to characterize the optical properties of optical window materials to be used for aerospace applications. Several optical measurement systems have been selected and developed to measure spectral transmittance, haze, clarity, birefringence, striae, wavefront quality, and wedge. In addition to silica based glasses, several optical lightweight polymer materials and transparent ceramics have been investigated in the laboratory. The measurement systems and selected empirical results for non-silica materials are described. These measurements will be used to form the basis of acceptance criteria for selection of window materials for future aerospace vehicle and habitat designs.

Tedjojuwono, Ken K.↗

Porous Ceramic Cures at Moderate Temperatures, Is Good Heat Insulator

The problem: To develop a foamed-in-place refractory material that would provide good thermal insulation, mechanical support, and vibration shielding for enclosed objects at temperatures up to 30000 F. The preparation of conventional foamed refractory materials required long curing times (as much as 48 hours) and high temperatures (at least 700 F), rendering such materials unusable for in-place potting of heat-sensitive components. The solution: A foamed ceramic material that has the requisite thermal insulation and strength, and also displays other properties that suggest a wide range of applications.

Eubanks, Alfred G.↗