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At least 703 records · Page 39
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Kinetic aspects of bone mineral metabolism

Two techniques were studied for measuring changes in bone mass in rats. One technique measures the Ar-37 produced from calcium during neutron irradiation and the other measures the changes in the Na-22 content which has been incorporated within the rat bone. Both methods are performed in VIVO and cause no significant physiological damage. The Ar-37 leaves the body of a rat within an hour after being produced, and it can be quantitatively collected and measured with a precision of - or + 2% on the same rat. With appropriate irradiation conditions it appears that the absolute quantity of calcuim in any rat can be determined within - or + 3% regardless of animal size. The Na-22 when uniformly distributed in bone, can be used to monitor bone mineral turnover and this has been demonstrated in conditions of calcium deficiency during growth and also pregnancy coupled with calcium deficiency.

Palmer, H. E.↗
NASA NTRS1973

Gas phase recombination of hydrogen and deuterium atoms

Rate constants for the reaction H + H + M - H2 + M, with M = H2, He, and Ar were measured over the temperature range 77 to 298 K. Hydrogen atoms were produced by thermal dissociation and absolute atom concentrations were measured through use of self-balancing, isothermal catalytic probe detector. The specific rate constants were 8.1 + or - 0.4 x 10 to the minus 33rd power, 7.0 + or - 0.4 x 10 to the minus 33rd power, and 9.2 + or - 0.6 x at 298 K for M = H2, He, and Ar respectively; these values rising to 18.5 + or - 2.2 x 10 to the minus 33rd power, 12.0 + or - 1.5 x 10 to the minus 33rd power, and 27.4 + or - 4.6 x 10 to the minus 33rd power cm to the 6th power/molecules sq/sec at 77 K. for the equivalent deuterium atom process with D2 as the third body, the rate constants are 6.1 + or - 0.3 x 10 to the minus 33rd power cm to the 6th power/molecules sq/sec at 298 K and 15.1 + or - 1.0 x 10 to the minus 33rd power cm to the 6th power/molecules sq/sec at 77 K. These values are compared with previous experimental measurements and with recent theoretical calculations.

Trainor, D. W.↗
NASA NTRS1973

Solubilities of noble gases in magnetite - Implications for planetary gases in meteorites.

Solubilities of noble gases in magnetite were determined by growing magnetite in a noble-gas atmosphere between 450 and 700 K. Henry's law is obeyed at pressures up to .01 atm for He, Ne, Ar and up to .00001 atm for Kr, Xe, with the following distribution coefficients at 500 K: He 0.042, Ne 0.016, Ar 3.6, Kr 1.3, Xe 0.88, some 100 to 100,000 times higher than previous determinations on silicate and fluoride melts. Apparent heats of solution are in sharp contrast with earlier determinations on melts which were small and positive, but are comparable to the values for clathrates. Presumably the gases are held in anion vacancies.

Lancet, M. S.↗
NASA NTRS1974

Duration of magnetic field(s) acting on meteorite parent body(s)

An overview is presented on the efforts being made to estimate the time that the magnetic field(s) existed and acted on meteorite parent bodies. The basic premise is that if a sample exhibits a low K-Ar age, it is the requisite amount of Ar-40. This assumption is applied to a preliminary analysis of the Farmington chondrite.

Rowe, M. W.↗
NASA NTRS1973

Noble gas concentrations and cosmic ray exposure ages of eight recently fallen chondrites

Abundances and isotopic compositions of He, Ne, Ar, and Xe have been measured in eight recently fallen chondrites. Ratios of concentrations of cosmic ray-produced He-3, Ne-21, Ne-22, and Ar-38 indicate that all eight samples experienced less than average cosmic ray shielding. He-3 and Ne-21 exposure ages were calculated using shielding corrected chondritic production rates and the measured Ne-22/Ne-21. Exposure ages calculated from Na-22/Ne-22 and Al-26/Ne-21 ratios and constant relative production rates show a bias between the two ages due to variations in Na-22/Al-26. Arguments are presented that this bias is due to irradiation hardness differences, and therefore the use of constant values for both the Na-22/Ne-22 and Al-26/Ne-21 production ratios is not permitted.

Bogard, D. D.↗
NASA NTRS1973

Lunar atmospheric composition results from Apollo 17

The Apollo 17 mass spectrometer has confirmed the existence of helium, neon, argon, and possibly molecular hydrogen in the lunar atmosphere. Helium and neon concentrations are in agreement with model predictions based on the solar wind as a source and their being noncondensable gases. Ar-40 and Ar-36 both exhibit a predawn enhancement which indicates that they are condensable gases on the nightside and are re-released into the atmosphere at the sunrise terminator. Hydrogen probably exists in the lunar atmosphere in the molecular rather than atomic state, having been released from the surface in the molecular form. Total nighttime gas concentration of known species in the lunar atmosphere is 200,000 molecules/cu cm.

Hoffmann, J. H.↗
NASA NTRS1974

Characterization of charge states of energetic ions in solids from associated K X-ray production

The strong projectile-charge-state dependence of K X-ray production in gases establishes a charge-state scale for ions penetrating solids. Si K X-ray cross sections in gaseous SiH4 were compared to those in solid Si for 40-MeV O (6+ to 8+) and 86-MeV Ar (6+ to 16+) projectiles. For Ar an effective charge of 11 plus or minus one is found compared to an emergent charge of 14.8 plus or minus 0.5. The result is discussed in terms of alternate models for steady-state excitation in solids.

Datz, S.↗
NASA NTRS1975

Measurement of supersmall quantities of Ar37 and H3

The results of measurements made on supersmall quantities of Ar-37 and H-3 by a low-background installation based on miniature proportional counters are presented. The article considers the sensitivity limit for the recording of Ar-37 and H-3.

Kocharov, G. E.↗
NASA NTRS1974

The solar wind as deduced from lunar samples

Lunar surface samples, which have been exposed to the solar wind, can be used to obtain information on the recent and past solar wind. Some of the more important conclusions reached are: The D/H ratio in the solar wind is smaller than 0.000003. The isotopic composition of C, Ar (except Ar-40), and Kr in the solar wind and on the earth are the same within approximately plus or minus 3%. Terrestrial Ne is enriched in the heavier isotopes relative to solar wind Ne. The average solar wind flux in the past was probably higher than at present. The average solar wind energy has varied in the past; however, no long time trend is apparent. Evidence for a secular decrease of the He-4/He-3 ratio with time exists.

Eberhardt, P.↗
NASA NTRS1975

Formation of the lunar atmosphere

Measurements of Ar-40 and helium made by the Apollo 17 lunar surface mass-spectrometer are used in the synthesis of atmospheric supply and loss mechanisms. The argon data indicate that about 8% of the Ar-40 produced in the moon due to decay of K-40 is released into the atmosphere and subsequently lost. Variability of the atmospheric abundance of argon requires that the source be localized, probably in an unfractionated, partially molten core. If so, the radiogenic helium released with the argon amounts to 10% of the atmospheric helium supply. The total rate of helium escape from the moon accounts for only 60% of the solar wind particle influx. This seems to require a nonthermal escape mechanism for trapped solar-wind gases, probably involving weathering of exposed soil-grain surfaces by solar-wind protons.

Hodges, R. R., Jr.↗
NASA NTRS1976

Martian volatiles - Their degassing history and geochemical fate

Implications of the Ar-40 content of the Martian atmosphere for Martian volatile history are considered. It is assumed that the potassium content of both Mars and earth is similar to that of normal chondrites, that Mars possesses a water content similar to that of normal chondrites, and that earth's water content is equal to or somewhat less than Mars'. A simple earth-analogous Mars degassing model is outlined in which the Martian surface volatile inventory is presumed to be identical to earth's, but scaled to the smaller mass and surface area of Mars. Physical storage of volatiles in the Martian regolith is examined along with the occurrence of volatile-containing mineral phases in the regolith, exospheric escape as a massive volatile sink, and the effect of the time history of degassing on the surface volatile inventory. Implications of earth's degassing history for Mars are assessed, and models describing the overall intensity of Mars degassing are presented. It is concluded that the maximum amounts of water and other volatiles that could be stored in the Martian regolith are marginally compatible with those required by the earth-analogous model, although a lower atmospheric Ar-40 concentration and regolith volatile inventory would be easier to reconcile with observational constraints.

Fanale, F. P.↗
NASA NTRS1976

The duration of volcanism in Mare Serenitatis

The crystallization ages of a suite of Apollo 17 basalts from four different stations have been measured using the Ar-39 to Ar-40 stepwise heating technique. The rocks analyzed include all principal petrographic types found at Apollo 17 landing site. A correlation between the ages and the petrographic type exists; plagioclase-poikilitic ilmenite basalts are youngest and olivine porphyritic ilmenite basalts are the oldest. The duration of volcanism in Mare Serenitatis is about 200 million years, the same as observed for Mare Imbrium, and less than observed for Mare Tranquillitatis, 400 million years. A relationship between duration of volcanism and gravity anomalies is noted. The cosmic ray exposure ages (in millions of years) for various locations range as: station 4, 58-315; station 5, 85-440; station 6, 110; station 8, 90-160.

Schaeffer, O. A.↗
NASA NTRS1976

Composition and structure of the Martian atmosphere - Preliminary results from Viking 1

Results from the aeroshell-mounted neutral mass spectrometer on Viking 1 indicate that the upper atmosphere of Mars is composed mainly of CO2 with trace quantities of N2, Ar, O, O2, and CO. The mixing ratios by volume relative to CO2 for N2, Ar, and O2 are about 0.06, 0.015, and 0.003, respectively, at an altitude near 135 kilometers. Molecular oxygen is a major component of the ionosphere according to results from the retarding potential analyzer. The atmosphere between 140 and 200 kilometers has an average temperature of about 180 plus or minus 20 deg K. Atmospheric pressure at the landing site for Viking 1 was 7.3 millibars at an air temperature of 241 deg K. The descent data are consistent with the view that CO2 should be the major constituent of the lower Martian atmosphere.

Nier, A. O.↗
NASA NTRS1976

Large-scale neutral composition gravity waves in the thermosphere observed by ESRO 4

Neutral composition waves with a wavelength of about 5000 km and a wave period of about 2.5 h were observed by ESRO 4 in the altitude region of 250 km. The amplitudes are of the order of 25% for Ar, 15% for N2, and roughly 10% for He and O at 25 deg geographic latitude. The Ar and N2 waves are almost in phase, whereas He is in antiphase, and O is in between. The wave amplitudes are seen to decrease toward lower latitudes, suggesting that the composition waves are launched by auroral sources. Simultaneous ground-based ionosonde measurements of the F2 layer critical frequency at middle and low latitudes show a wave period consistent with the satellite observations. From the relation between wavelength and wave period these waves are identified as gravity waves. The theoretical investigation with a multicomponent model shows that diffusion plays a major role in explaining the observed phase and amplitude relations between atmospheric constituents.

Trinks, H.↗
NASA NTRS1977

The relation between isotopic composition of argon and carbon in natural gases

The methods and results of determination of the argon and carbon isotope compositions of hydrocarbon gases of Mezozoic complexes of Western Siberia are presented. Based on the Ar-36, Ar-40, C-12, C-13 content of the various deposits and on the presumed mechanisms of entry of these isotopes into the deposits, it is concluded that formation of natural gas in some deposits included vertical migration from a lower complex.

Gavrilov, Y. Y.↗
NASA NTRS1977

Recombination lasing in a magnetoplasmadynamic arcjet

The plasmadynamic recombination laser concept is verified experimentally in a high power quasi-steady MPD arcjet operating at 4 kA and 12 g/sec of argon. Measurements of the spatial variation of electron temperature, electron density, and population densities in the arc exhaust flow confirm that inverted populations of the 4p to 4s Ar II transitions are established by collisional-radiative recombination of the Ar III ion. Using an optical cavity aligned transversely to the flow, recombination lasing of four such transitions, 5145, 4880, 4764 and 4727 A, is observed spectro-photographically and photoelectrically over the entire 1-msec discharge.

Campbell, E. M.↗
NASA NTRS1977

Theory of inelastic ion-atom scattering at low and intermediate energies

Ab initio calculations are presented of inelastic energy loss and ionization phenomena associated with Ar(+)-Ar collisions at small distances of closest approach and for laboratory collision energies ranging from several keV to several hundred keV. Outer-shell excitations are handled statistically; inner-shell excitations are calculated from the viewpoint of quasidiabatic molecular orbital promotion. Auger electron yield, average state of ionization, and average inelastic energy loss are calculated per collision as a function of distance of closest approach of the collision partners for several laboratory collision energies. Average charge-state probabilities per collision partner are calculated as a function of the average inelastic energy loss per atom. It is shown that the structure in the data is due to the underlying structure in the inner-shell independent-electron quasimolecular promotion probabilities.

Schmid, G. B.↗
NASA NTRS1977

Rate constant for formation of chlorine nitrate by the reaction ClO + NO2 + M

The pseudo-first-order decay of ClO in a large excess of NO2 was monitored in a discharge flow/mass-spectrometer apparatus in order to measure the rate constant of the reaction ClO + NO2 + M yields ClONO2 + M for M = He, Ar, and N2 over the temperature range from 248 to 417 K. Numerical results are given for He at 248, 299, 360, and 417 K (1 to 9 torr); for Ar at 298 K (1 to 4 torr); and for N2 at 299, 360, and 417 K (1 to 6 torr). Systematic errors are estimated, and identification of the reaction product is discussed. The results obtained are shown to be in excellent agreement with other recent measurements of the same rate constant.

Leu, M. T.↗