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At least 685 records · Page 38

Smooth Modified Surfaces of Silicon for the Study of Ionic Liquid Interfaces by Neutron Reflectometry

Silicon surfaces with termination of hydrogen (H–Si), quartz, native silicon (native-Si), and chemically deposited (Au–Si) cd and sputtered gold (Au–Si) s were fabricated with roughness less than 6 Å to study the solid–liquid interface of the ionic liquid (IL) methyltrioctylammonium bis(trifluoromethylsulfonyl)imide, [N 1888 ][TFSI], by neutron reflectometry (NR). The modifications made to the silicon surface were to obtain a native positive or negative charge similar to a charged surface in electrochemical systems. The differences in scattering length density (SLD) based on mass density and composition of IL were examined. Perpendicular to the substrate surface, a distinct transition between the first ion layer and the bulk liquid is resolved out of the reflectivity data for the gold surfaces and in particular the chemically deposited Au–Si. Other interfaces are best described by a diffuse transition between regions of different SLDs. The diffuse transitions between SLDs observed here suggest that the interfacial structure of IL, while ordered, is best described by a continuous variation in composition as opposed to distinct layers of ions.

25 ENERGY STORAGE↗

Advancing Porous Carbons: Understanding the Importance of Surface Chemistry for the Energy–Environment Nexus

This review intends, in a critical way, the comprehensive view of the importance of porous carbons surface chemistry for their applications in an energy− environment nexus. Surface chemistry is presented as a combination of functional heteroatom-containing groups, dopants, and structural defects. First, we briefly address carbon surface chemical environment and the methods of its modification and characterization, indicating their practical limitations. Then, the effects of surface chemistry on separation, catalysis, energy storage, sensing and microwave absorption are introduced. Besides a critical analysis of published findings on these topics, we also include our views on the advancement in the processes which rely on porous carbons surface chemistry, and identify strategic areas and directions that should deserve further attention. We focus on new findings and important original contributions to the field. Since the community of carbon researchers grows following the strategic application of these materials, the role of functional groups, dopants and structural defects in various cutting-edge applications is emphasized, showing the progress in the field and the evolution of findings. A clear determination of the effects of carbon surface is often a challenge since carbons porosity and the locations of specific bonds/sites/ defects in the carbon texture provide nanoconfinement effects.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Improved Growth Of Diamond Films From Oxyacetylene Torch

Two modifications proposed to improve nucleation and growth of diamond films on surfaces by use of oxyacetylene torch. In one modification, carbon monoxide added to fuel gas; in other, carbon monoxide, methane, and oxygen added in synchronized pulses. Second modification intended not only to improve nucleation and growth of diamond films but also makes films more nearly homogeneous over areas larger than spots of such film grown by oxygen/acetylene-growth technique. Modified technique enables deposition of diamond films on alternative materials-in particular, copper.

Roberts, Floyd E., III↗

Hollow Au Nanosphere-Cu 2 O Core–Shell Nanostructures with Controllable Core Surface Morphology

Design of metal-semiconductor interfaces and heterostructures is of strong interest for various catalytic applications including photocatalysis. Here, a series of hollow Au nanosphere (HGN)-Cu 2 O core-shell nanostructures with varying core surface rugosities are synthesized and investigated for possible photocatalytic applications. HGN surface rugosity is tuned by pH modification during galvanic exchange, and carboxyl groups are utilized as coordination sites to deposit uniform Cu 2 O shells onto the gold surfaces. Final core-shell structures are verified by transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDS), and X-ray diffraction (XRD). Information regarding chemical state and electronic band structure is acquired by X-ray photoelectron spectroscopy (XPS) and ultraviolet photoelectron spectroscopy (UPS). Ultrafast transient absorption (TA) reveals that charge separation in bumpy HGN (bHGN)-Cu 2 O may effectively provide longer-lived photoexcited carriers, offering great potential for utilization in advanced photocatalytic processes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mitigation of Polystyrene Microsphere Surface Contamination for Wind Tunnel Applications

Polystyrene latex (PSL) microspheres have been utilized as seed material for flow visualization in wind tunnels. However, PSL microspheres have been observed to strongly adhere to wind tunnel and model surfaces. Surface contamination on the cleaning screens that remove vorticity and provide laminar flow in the test section, is particularly problematic. Agglomeration of particles on these screens cause constriction of the airflow through the screen resulting in inconsistent airflow properties in the test section. The adhesion mechanism of PSL microspheres to wind tunnel screens and 316 stainless steel flat plates, were evaluated in a contamination apparatus where small sections of screen material were exposed to PSL-seeded airflow. Using a design of experiments (DOE) methodology airflow seeding parameters were changed to evaluate how these modifications affected the degree of surface contamination. The solution composition, comprised of ethanol and water, was determined to be the most significant factor in particle adhesion. Utilizing image analysis software, data were collected from the contaminated surfaces and incorporated to generate predictive particle contamination models. A relationship was identified between the solvent evaporation rate, and the morphology and magnitude of PSL contaminants on the test surfaces. This analysis can be extended to other solvent mixtures to provide insight into simultaneously improving wind tunnel testing capabilities while diminishing facility contamination.

Wohl, Christopher J.↗

Experimental and numerical evaluation of laser shinethrough in polystyrene at 3 ω and 4 ω laser frequencies

In laser-direct-drive inertial confinement fusion (ICF), laser shinethrough is the process associated with laser propagation through the target plastic ablator, polystyrene is often used in ICF experiments, and leads to energy deposition in the target until the critical density is established at the ablator front surface. This process causes material modifications that may change the shock propagation and lead to density and pressure perturbations at the interface between the polystyrene and cryogenic deuterium-tritium (DT) layer. This work reports on experimental observations and numerical investigations of laser shinethrough at the third and the fourth harmonic of ICF class laser systems (1 ω corresponds to a wavelength of ∼1.06 μm ). The experiments evidence that, at 4 ω , the laser is absorbed over a distance of about a few microns and laser shinethrough is completely eliminated in contrast with the behavior at 3 ω . These experimental observations are reproduced by numerical simulations. The laser fluence required to reach the critical density at the ablator front surface is also found to be more than one order of magnitude higher at the third harmonic. Finally, modeling suggests that the back surface of the ablator exhibits ion temperatures greater than the melting temperature of cryogenic DT and electron pressure larger than the bulk and shear moduli of cryogenic DT for the case of using a 3 ω laser.

Pineau, A. [Univ. of Rochester, NY (United States)↗

Simulation of Liquid Lithium Divertor Geometry Using SOLPS-ITER

Here, plasma-facing component (PFC) geometries are evaluated for a Fusion Nuclear Science Facility (FNSF) design to find solutions that are compatible with flowing liquid lithium components while satisfying requirements from the perspective of plasma and neutral particle transport. Flowing liquid metal (LM) divertor systems offer important advantages due to continual regeneration of the surface material, but may require modifications from standard optimized tokamak divertor designs. Scrape Off Layer Plasma Simulator for the International Thermonuclear Experimental Reactor (SOLPS-ITER) simulations are used to compare standard vertical target, open, and balanced baffled geometries. It is found that the open geometry offers little control of neutral particles and has narrow operating windows where the divertor fluxes can be lowered to acceptable levels, while maintaining the required upstream density. The addition of neutral baffles allows greater control over the divertor conditions with less impact on the upstream density. The divertor neutral pressure in the baffled geometry is slightly higher than the open divertor, but not as large with a vertical target. A first-pass coupling of the SOLPS solution with sheath and implantation/erosion models to compute the lithium emission shows that the lithium is largely confined to the near-surface region due to the small ionization mean free path and large main ion flow toward the surface. The lithium source was varied by three orders of magnitude. At the highest rate, when the sourced lithium approaches the level of the main ion recycling flux, a high core lithium concentration (~10%) is observed with only moderate power dissipation to affect the divertor plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Experiments with a prototype titanium hot cavity surface ionization source intended for electromagnetic separation of radioactive samarium and other lanthanide elements

This paper reports experimental results of a prototype titanium surface ionization source. For the first time, a lanthanide ion beam has been produced with a surface ionizer composed completely of titanium metal. Titanium does not readily activate with neutron irradiation. This offers the potential for inserting an ion source made of titanium directly into a reactor with a pre-loaded non-radioactive lanthanide target. This seamlessly integrates target irradiation with isotope separation, eliminating post irradiation sample manipulation. Samarium ion beam currents up to 960 nA have been produced in an off-line test bench equipped with rudimentary beam optics. This is a crucial step toward the development of an ionization source adopted for the electromagnetic isotope separator (EMIS) facility, which has been designed for high throughput separations of radioactive 153 Sm and other lanthanides of interest in the field of nuclear medicine. The ion current and important factors affecting the performance of the ion source, such as the ionizer temperature and thermal gradient, are discussed. Lastly, the experimental results are presented together with a discussion of future modifications to optimize the overall surface ionization source performance.

07 ISOTOPE AND RADIATION SOURCES↗

A Crew and Logistics Lander for the Common Habitat Architecture

The Common Habitat Architecture is a conceptual study that explores the use of a large habitat derived from the Space Launch System (SLS) liquid oxygen tank as a core habitation element that can be used for crew missions or training in 0g, 1/6g, 3/8g, and 1g. This is not part of current NASA Artemis mission planning, but instead represents an architecture that could potentially follow after the Artemis missions and initial human Mars landings. This architecture leverages Starship-derived vehicles for crew landing on and ascent from the Moon and Mars in support of long-duration surface missions with pressurized crew transfer baselined as a nominal capability. This is not the Human Landing System variant of Starship but represents a number of modifications to enable long-duration surface missions with an eight-person crew size. A rapid brainstorming study was conducted in February of 2021, using only public data, to identify options to deliver the 90-ton Common Habitat to the surface and emplace it at the intended habitation site. This study compared three lunar lander concepts and three Mars lander concepts before ultimately selecting the SpaceX Starship as the most viable lander. The Common Habitat Architecture assumes that this Starship variant can further be modified for crew and cargo delivery, assuming that the use of a common system will lead to cost benefits. It is assumed that the Starship will expend too much propellant in landing crew and logistics to be able to launch, given the assumed absence of surface propellant production. Consequently, a separable ascent stage is used for crew ascent. The pressurized elements of this modified Starship are discussed: Starship Ascent Module, Airlock, Transfer Tunnel, Pressurized Crew Transfer Module, and Logistics Modules. For each element, a description, dimensions, rough mass estimates, core capabilities, and design features are presented. Key mechanisms and internal structures of the starship are also discussed. This will include flame diverters for the ascend module, the orbital docking hatch, Pressurized Crew Transfer Module Garage door, Starship Ascent Module fairing, flame diverter blow-out panels, Pressurized Crew Transfer Module lift system, logistics module lift system, contingency crew ascent via the logistics module lift system, internal catwalks, and structural interfaces. Concept of Operations will be discussed for both Moon and Mars. This will include in-space crew rendezvous and transfer, crewed landing, shirtsleeve crew transfer, crew departure, contingency surface operations, and final element disposition. Key differences for Mars will be discussed, such as the Martian atmosphere, dust storms, the absence of crew handover, and Deep Space Exploration Vehicle rendezvous. Contingency microgravity maintenance access will also be discussed. This work will demonstrate viable pressurized crew transfer with a Starship-based lander architecture. Forward work includes Garage lighting and camera systems, Starship Ascent Module propulsion system and docking port trades, contingency habitation trades, and mass/power equipment estimation. Finally, forward work includes developing a heavy cargo return system derived from the Crew and Logistics Starship. The goal of this system is the return of at least 10,000 kg payloads from the surfaces of the Moon and Mars.

Lunar Lander↗

Calibration of a Vertical-Scan Long Trace Profiler at MSFC

The long trace profiler (LTP) is the instrument of a choice for the surface figure measurement of grazing incidence mirrors. The modification of conventional LTP, the vertical-scan LTP, capable of measuring the surface figure of replicated shell mirrors is now in operation at Marshall Space Flight Center. Sources of systematic error for vertical-scan LTP are discussed. Calibration method using a test flat mirror and results of measurements are presented.

Gubarev, Mikhail↗

Interface chemistry informs about cathode and anode degradation during fast charging

Here, the aim of this study is to examine the development and makeup of the Solid Electrolyte Interphase (SEI) and Cathode Electrolyte Interphase (CEI) in lithium-ion batteries during rapid charging. Using X-ray photoelectron spectroscopy (XPS) and depth profiling, we investigate the chemical modifications occurring on the electrode surfaces during the initial formation and subsequent fast charge-discharge cycles. Our research shows that the anode's SEI initially comprises a thin layer rich in ketones, which then transforms into a thicker layer dominated by carbonaceous compounds during rapid charging cycles. Following assembly, lithium fluoride (LiF) quickly becomes a key element of the SEI, and its presence continues to grow substantially during the formation cycle, remaining the primary component throughout subsequent cycles. Initially, the cathode forms a thin oxide layer rich in ketones, with no noticeable carbonaceous CEI. The CEI primarily comprises LiF, which experiences an increase during the formation cycle and retains a thin layer of carbon coating after the initial rapid discharge. These findings show how the interphase layers impact the performance and stability of lithium-ion batteries, especially during fast charging for electric vertical take-off and landing (eVTOL) vehicles.

Fast charging↗

Improved Capacity Retention of Lithium Ion Batteries under Fast Charge via Metal-Coated Graphite Electrodes

A primary barrier preventing repetitive fast charging of Li-ion batteries is lithium metal plating at the graphite anode. One approach toward mitigating Li metal deposition is the deliberate modification of the graphite anode surface with materials demonstrating high overpotentials unfavorable for Li metal nucleation, such as Ni or Cu nanoscale films. This research explores Ni and Cu surface coatings at different areal loadings (3 or 11 μg cm -2 ) on the electrochemistry of graphite/LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC622) type Li-ion batteries. Extended galvanostatic cycling of control and metal-coated electrodes in graphite/NMC622 pouch cells are conducted under high rate conditions. Based on the overpotential of Li deposition on metal foil, both Ni and Cu treatments were anticipated to result in reduced lithium deposition. The higher metal film loadings of 11 μg cm -2 Ni- or Cu-coated electrodes exhibit the highest capacity retention after 500 cycles, with mean improvements of 8% and 9%, respectively, over uncoated graphite electrodes. Li plating quantified by X-ray diffraction indicates that the metal films effectively reduce the quantity of plated Li compared to untreated electrodes, with 11 μg cm -2 Cu providing the greatest benefit.

25 ENERGY STORAGE↗

Kelvin Waves during GOAmazon and Their Relationship to Deep Convection

The 2014–15 Observations and Modeling of the Green Ocean Amazon (GOAmazon) field campaign over the central Amazon near Manaus, Brazil, occurred in coordination with the larger Cloud Processes of the Main Precipitation Systems in Brazil: A Contribution to Cloud-Resolving Modeling and to the Global Precipitation Measurement (CHUVA) project across Brazil. These programs provide observations of convection over the central Amazon on diurnal to annual time scales. Here, we address the question of how Kelvin waves, observed in satellite observations of deep cloud cover over the GOAmazon region during the 2014–15 time period, modulate the growth, type, and organization of convection over the central Amazon. The answer to this question has implications for improved predictability of organized systems over the region and representation of convection and its growth on local to synoptic scales in global models. Our results demonstrate that Kelvin waves are strong modulators of synoptic-scale low- to midlevel free-tropospheric moisture, integrated moisture convergence, and surface heat fluxes. These regional modifications of the environment impact the local diurnal cycle of convection, favoring the development of mesoscale convective systems. As a result, localized rainfall is also strongly modulated, with the majority of rainfall in the GOAmazon region occurring during the passage of these systems.

54 ENVIRONMENTAL SCIENCES↗

Microstructure development in a cold worked SRF Nb sheet undergoing 700°C-900°C/3h heat treatments.

Bulk Nb for TESLA shaped SRF cavities is a mature technology, with high gradient (>35 MV/m) and high Q cavities (>1010, ~2K) routinely fabricated. Significant advances are in order to push Q?s to 1011 (~2K), and involve modifications to the sub-surface Nb layers by impurity doping (N, O). In order to achieve the lowest surface resistance any trapped flux needs to be expelled for cavities to reach high Q?s. There is clear evidence that cavities fabricated from polycrystalline sheets meeting current specifications require higher temperatures beyond 800oC leads to better flux expulsion, and hence improves Q. Recently, cavities fabricated with a non-traditional Nb sheet with initial cold work due to cold rolling expelled flux better after 800°C/3h heat treatment than cavities fabricated using fine-grain polycrystalline Nb sheets. Here, we analyze the microstructure development in Nb from the vendor supplied cold work non-annealed sheet that was fabricated into an SRF cavity as a function of heat treatment building upon the methodology development to analyze microstructure being developed by the FSU-MSU-UT-Austin- JLAB collaboration. The results indicate correlation between full recrystallization and better flux expulsion.

Balachandran, S.↗

Dynamic Rupture Modeling of the M7.1, 2019 Ridgecrest, California, Earthquake

An important part of the simulation technique implemented in the strong motion prediction recipe developed in Japan, originally proposed by Irikura and Miyake (2011) is the earthquake rupture characterization that is based on established empirical scaling relationships between source parameters and seismic moment. These scaling relationships and rupture characterization are derived from recorded data and are tested by simulations. Recent analysis of results obtained with the Recipe for the 2016 M7.1 Kumamoto earthquake performed by several researchers, indicate that in order to reproduce near-fault long-period ground motions with permanent displacements, typical for earthquakes with surface rupturing, the recipe needs modifications. In particular, improvements are required in characterizing the rupture kinematics at shallow depths, above the seismogenic zone (Irikura et al., 2019). Modeling of rupture dynamics for recorded earthquakes, and numerical simulations for different rupture scenarios, provides physical constrains on slip evolution in time and space, which can be used in adjustments of empirical source scaling relationships for large crustal earthquakes. In this study we mainly focused on rupture dynamics modeling of the 2019 M7 Ridgecrest, California earthquake. The characterization of the kinematic rupture model derived from the dynamic rupture models of this earthquake can inform further refinements of rupture modeling proposed by the Recipe. Through different rupture scenarios we investigated potential relationships between characteristics of Long Period Ground Motion Generation Area (LMGA), used in the Recipe, and asperity depth and rupture initiation.

58 GEOSCIENCES↗

Stellar evolution at high mass with semiconvective mixing according to the Schwarzschild criterion

Evolutionary sequences for stellar models with 10, 15, 30, and 60 solar masses, as well as four different initial chemical compositions, are calculated to the end of core helium burning using the Schwarzschild criterion for convection. The results are analyzed in terms of the modifications of interior structure and surface parameters induced by semiconvective mixing as a result of adopting the Schwarzschild criterion. It is found that the main differences from results based on the Ledoux criterion are the great extent of the convectively unstable layers in the intermediate zone and the eventual development of a fully convective zone at the base of the semiconvective one. It is shown that semiconvection develops outside the convective core just after the ZAMS stage for masses greater than 12 solar masses and just before the stage of central hydrogen exhaustion for masses greater than 6 solar masses. The present models are found to be insufficiently hot in comparison with the bulk of observed stable blue supergiants and to predict far too many red supergiants fro the range above 20 solar masses. It is concluded that something is fundamentally wrong with the models, the most likely suspects being the stellar opacities adopted and the neglect of mass loss.

Stothers, R.↗

Performance, emissions, and physical characteristics of a rotating combustion aircraft engine, supplement A

Testing was conducted using the basic RC2-75 engine, to which several modifications were incorporated which were designed to reduce the hydrocarbon emissions and reduce the specific fuel consumption. The modifications included close-in surface gap spark plugs, increased compression ratio rotors, and provisions for utilizing either side or peripheral intake ports, or a combination of the two if required. The proposed EPA emissions requirements were met using the normal peripheral porting. The specific fuel economy demonstrated for the modified RC2-75 was 283 g/kW-hr at 75% power and 101 brake mean effective pressure (BMEP) and 272.5 g/kW-hr at 75% power and 111 BMEP. The latter would result from rating the engine for takeoff at 285 hp and 5500 rpm, instead of 6000 rpm.

Lamping, R. K.↗

Applying Elastomeric Insulation Inside A Round Case

Elastomer wound onto inside surface in continuous strip. Technique being developed to apply elastomeric insulation to inner surfaces of axisymmetric cases. Requires modification of machine wrapping strip of elastomer on outside of rotating mandrel. Intended for coating insides of rocket-motor cases, technique also used to install elastomeric linings in pressure vessels, containers for chemical, and environmental chambers.

Russell, Peter G.↗