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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38

All sources NASA NTRS DOE OSTI

DOE OSTI2025

Gas-phase synthesis of anthracene and phenanthrene via radical-radical reaction induced ring expansions

Unraveling reaction mechanisms of aromatic and resonance-stabilized radicals is critical to understanding molecular mass growth processes to polycyclic aromatic hydrocarbons (PAHs) and carbonaceous nanoparticles in distinct astrophysical environments (molecular clouds, circumstellar envelopes) and combustion systems. Using photoelectron photoion coincidence spectroscopy (PEPICO), we explored the gas-phase reaction of the methyl radical (CH 3 • ) with the aromatic and resonance-stabilized fluorenyl radical (C 13 H 9 • ) under high-temperature conditions in a chemical microreactor. Anthracene and phenanthrene were detected isomer-selectively using photoionization efficiency (PIE) curves and mass-selected threshold photoelectron (ms-TPE) spectra. While phenanthrene is produced through a radical-radical recombination of the carbon-centered radicals, anthracene may plausibly be formed through an unconventional radical addition to a low spin-density fluorenyl carbon. These pathways result in five-membered ring expansion—a critical mechanism crucial to PAH mass growth converting bent PAHs into planar nanostructures.

Goettl, Shane J. [University of Hawai‘i at Mānoa, ↗

DOE OSTI2019

Revealing the Mechanism of Light-Induced Degradation and Regeneration of p-type Cz-Si

The goal of this SIPS project was to develop advanced spectroscopic tools to explore boron- oxygen related defects in p-type Czochralski (Cz) monocrystalline Si (c-Si) to inform processing strategies to permanently suppress these defects and improve cell efficiency. Our work can be divided into three categories: (a) establishment of surface passivation and fast-firing protocols for light induced degradation (LID) and regeneration in p-Cz Si; (b) sample preparation and identification of spectral features for LID and hydrogen in c-Si with vibrational and electron spin resonance (ESR) spectroscopies; (c) demonstration of the interrelation between high-temperature thermal annealing, which breaks nuclei for oxygen precipitates in LID and regeneration. To our knowledge, this is the first study that has identified LID defects using ESR. The magnetic properties of the LID defects will be invaluable in validating the structure of the LID defects through atomistic simulations. The results generated from this project were disseminated through conference presentations and proceedings, and a peer reviewed publication. The tools developed in this project will be used to study other forms of degradation in c-Si including light and elevated-temperature induced degradation in p-type Cz Si and process induced degradation in n-type Cz Si.

14 SOLAR ENERGY↗

NASA NTRS1971

On K-line central reversals

Solar atmosphere vertical temperature and density distribution measurements, using spatially averaged H and K resonance line profiles central reversals

Pasachoff, J. M.↗

NASA NTRS1978

Absolute rate of the reaction of atomic hydrogen with ethylene from 198 to 320 K at high pressure

The rate constant for the H+C2H4 reaction has been measured as a function of temperature. Experiments were performed with high pressures of Ar heat bath gas at seven temperatures from 198 to 320 K with the flash photolysis-resonance fluorescence (FP-RF) technique. Pressures were chosen so as to isolate the addition rate constant k1. The results are well represented by an Arrhenius expression. The results are compared with other studies and are theoretically discussed.

Lee, J. H.↗

NASA NTRS1979

C IV resonance line profiles in O stars

Graphs of normalized fluxes derived from objective-prism spectra (from the S-019 experiment on Skylab), and C IV profiles are presented. The C IV resonance profile, when studied with respect to bolometric magnitude and effective temperature, reveals mass loss conditions without requiring precise mass loss rates. There is a clear trend in the C IV feature toward more fully developed P Cygni profiles at higher luminosities, and a significant velocity shift in the C IV absorption down to bolometric magnitude approximately equal to -7.7.

Parsons, S. B.↗

NASA NTRS1982

Solar atmospheric dynamics. II - Nonlinear models of the photospheric and chromospheric oscillations

The one-dimensional, nonlinear dynamics of the solar atmosphere is investigated, and models of the observed photospheric (300 s) and chromospheric (200 s) oscillations are described. These are resonances of acoustic wave cavities formed by the variation of the temperature and ionization between the subphotospheric, hydrogen convection zone and the chromosphere-corona transition region. The dependence of the oscillations upon the excitation and boundary conditions leads to the conclusion that for the observed amplitudes, the modes are independently excited and, as trapped modes, transport little if any mechanical flux. In the upper photosphere and lower chromosphere, where the two modes have comparable energy density, interference between them leads to apparent vertical phase delays which might be interpreted as evidence of an energy flux.

Leibacher, J.↗

NASA NTRS1984

Direct determination of the ionic charge distribution of helium and iron in He-3-rich solar energetic particle events

The first direct measurement of the ionic charge distribution of the helium isotopes and of iron in (He-3)-Fe-rich solar energetic particle events is reported. No significant contribution of singly ionized helium to the events is found. The two-sigma upper limits for the He-3(+)/He-3(2+) and He-4(+)/He-4(2+) ratios are 0.02 and 0.03, respectively. The mean charge state of iron found by averaging five (He-3)-Fe-rich solar energetic particle events is 19 + or -2, significantly larger than the iron charge state for energetic solar particles in normal composition events. These results appear to favor the resonant heating model proposed by Fisk (1978). It is concluded that temperatures in the source region exceed 5 million K in the events under study.

Klecker, B.↗

NASA NTRS1986

Stability analysis of double-peaked proton distribution functions in the solar wind

Twelve proton velocity distribution functions as measured for different solar wind speeds by the plasma analyzer at the Helios spacecraft are modeled analytically by a superposition of two bi-Maxwellians. The stability of these distributions is investigated by solving the linear dispersion equation for parallel propagation of both left- and right-hand polarized modes. Due to the temperature anisotropy of the main proton component the presence of the resonant left-hand ion cyclotron instability is found to be typical for high-speed streams and is independent of an ion beam. The results indicate that the ratio of the beam density to total particle density and the beam drift velocity are generally close to the threshold values necessary to drive a highly unstable nonresonant right-hand mode. This instability is found for one proton distribution and is a consequence of the beam particles. It is concluded that both the ion cyclotron instability and the ion beam instability act as a regulating mechanism on the shape of solar wind double humped proton distribution functions.

Leubner, Manfred P.↗

NASA NTRS1989

Accelerated Testing Of Photothermal Degradation Of Polymers

Electron-spin-resonance (ESR) spectroscopy and Arrhenius plots used to determine maximum safe temperature for accelerated testing of photothermal degradation of polymers. Aging accelerated by increasing illumination, temperature, or both. Results of aging tests at temperatures higher than those encountered in normal use valid as long as mechanism of degradation same throughout range of temperatures. Transition between different mechanisms at some temperature identified via transition between activation energies, manifesting itself as change in slope of Arrhenius plot at that temperature.

Kim, Soon Sam↗

NASA NTRS1990

Role of hot oxygen in Venusian ionospheric ion energetics and supersonic antisunward flow

The column heating rate of the dayside Venus ionospheric ion gas resulting from transfer of energy from the hot oxygen component of the neutral atmosphere is estimated and found equal to that which, when inserted into ionospheric models at the ionopause, raises the calculated temperature to measured values. The transfer of energy is effected through resonant charge exchange between the relatively cold ionospheric O(+) ions and the hot oxygen neutrals. The hot oxygen density in the nightside hemisphere does not appear to play a significant role in the nightside ion energetics. The hot oxygen neutral gas flowing across the terminator from its dayside source to its nightside sink will exchange momentum with the antisunward flowing ionospheric gas. Although the flow rate of hot oxygen can be estimated only crudely, the estimated rate of deposition and absorption is comparable to that produced by the plasma pressure and should be included in numerical studies of the terminator ionospheric wind.

Knudsen, William C.↗

NASA NTRS1991

Acoustic Levitator With Furnace And Laser Heating

Acoustic-levitation apparatus incorporates electrical-resistance furnace for uniform heating up to temperature of about 1,000 degrees C. Additional local heating by pair of laser beams raise temperature of sample to more than 1,500 degrees C. High temperature single-mode acoustic levitator generates cylindrical-mode accoustic resonance levitating sample. Levitation chamber enclosed in electrical-resistance furnace. Infrared beams from Nd:YAG laser provide additional local heating of sample. Designed for use in containerless processing of materials in microgravity or in normal Earth gravity.

Barmatz, Martin B.↗

NASA NTRS1993

The cosmic Doppler instability

The equations governing the behavior of perturbations of a mixture of nearly homogeneous and isotropic matter and radiation are derived, using a diffusion approximation where spatial perturbations in the radiation spectrum are allowed to vary with frequency. A simple model of line opacity leads to dispersion relations which display a new bulk instability. The model is used to derive an approximate dispersion relation for radiation interacting via resonance scattering opacity in atomic hydrogen at low density and low temperature. Possible applications to cosmology are briefly discussed.

Hogan, Craig J.↗

NASA NTRS1996

Reactions of CH3(+) with C2N2, CH2CHCN, and HC3N: A Low-Pressure/High-Pressure Study

The association of CH3(+) with the three molecules C2N2, CH2CHCN, and HCCCN has been examined using ion cyclotron resonance (ICR) and selected ion flow tube (SIFT) techniques at room temperature. In each reaction, the mean lifetime of the complex (CH3 x N-=C-R(+))(sup *) formed in the association has a major influence on the outcome of the reaction and the product channels that are observed using ICR and SIFT. Termolecular rate coefficients are reported for the association of CH3(+) + C2N2 for the bath gases M = He, Ar, N2, and C2N2. k(sub 3) = 8.2 x 10(exp-24) cm(sup 6)/s (M = C2N2). In each system the association product channel occurs in competition with exothermic bimolecular channels. The complex lifetimes in all three systems are in the range 30-70 microsec. Very rapid ion-molecule association reactions have been observed in several systems of hydrocarbons and nitriles, and the implications for Titan ion chemistry are discussed briefly.

McEwan, M. J.↗

NASA NTRS1996

Ion-Molecule Association in Acrylonitrile

The association reaction of the ions CH(sub 2)CHCN+ and CH(sub 2)CHCN have been examined using ion cyclotron resonance (ICR) and selected ion flow tube (SIFT) techniques at room temperature.

Ion- molecule acrylonitrile↗

NASA NTRS2012

Uncertainty Analysis of the Grazing Flow Impedance Tube

This paper outlines a methodology to identify the measurement uncertainty of NASA Langley s Grazing Flow Impedance Tube (GFIT) over its operating range, and to identify the parameters that most significantly contribute to the acoustic impedance prediction. Two acoustic liners are used for this study. The first is a single-layer, perforate-over-honeycomb liner that is nonlinear with respect to sound pressure level. The second consists of a wire-mesh facesheet and a honeycomb core, and is linear with respect to sound pressure level. These liners allow for evaluation of the effects of measurement uncertainty on impedances educed with linear and nonlinear liners. In general, the measurement uncertainty is observed to be larger for the nonlinear liners, with the largest uncertainty occurring near anti-resonance. A sensitivity analysis of the aerodynamic parameters (Mach number, static temperature, and static pressure) used in the impedance eduction process is also conducted using a Monte-Carlo approach. This sensitivity analysis demonstrates that the impedance eduction process is virtually insensitive to each of these parameters.

Brown, Martha C.↗

DOE OSTI2021

Two-Dimensional Superconducting Fluctuations Associated with Charge-Density-Wave Stripes in La 1.87 ⁢Sr 0.13 ⁢Cu 0.99 ⁢Fe 0.01 ⁢O 4

The presence of a small concentration of in-plane Fe dopants in La 1.87 Sr 0.13 Cu 0.99 Fe 0.01 O 4 is known to enhance stripelike spin and charge density wave (SDW and CDW) order and suppress the superconducting T c . Here, we show that it also induces highly two-dimensional superconducting correlations that have been argued to be the signatures of a new form of superconducting order, the so-called pair density wave (PDW) order. In addition, using resonant soft x-ray scattering, we find that the two-dimensional superconducting fluctuation is strongly associated with the CDW stripe. In particular, the PDW signature first appears when the correlation length of the CDW stripe grows over eight times the lattice unit (~8 a). In conclusion, these results provide critical conditions for the formation of the PDW order.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2025

Spectrally sharp magnetic excitations above the critical temperature in a frustrated Weyl semimetal

The rare-earth α-pyrochlore iridates are a prospective class of conducting frustrated magnets where electronic correlations, large spin-orbit coupling, and geometrical frustration interplay, leading to a rich set of magnetic and electronic phases. Despite their intriguing properties, the magnetic order and excitations in this fundamental class of topological quantum materials remain poorly understood due to challenges in growing large single crystals and insufficient microscopic information on their temperature-dependent phases. Here, by combining state-of-the-art thin-film synthesis, resonant elastic and inelastic X-ray scattering, spin wave analysis, and dynamical spin susceptibility calculations, we unequivocally reveal the presence of spectrally sharp, gapped magnetic excitations in Y 2 Ir 2 O 7 that surprisingly persist well above the Néel transition temperature, signaling the presence of a quasi-universal regime connected to fluctuations on frustrated lattices. This finding implies the existence of a highly unusual cooperative paramagnetic (CP) phase above the ordering temperature and offers an explanation for the puzzling high-temperature magnetic behavior observed across the family of metallic pyrochlore crystals. Understanding such magnetic excitations at technologically relevant temperatures opens up possibilities for novel topological spintronic devices.

36 MATERIALS SCIENCE↗

DOE OSTI2023

High-energy spin excitations in the quantum spin liquid candidate Zn-substituted barlowite probed by resonant inelastic x-ray scattering

A quantum spin liquid is a novel ground state that can support long-range entanglement between magnetic moments, resulting in exotic spin excitations involving fractionalized $S$ = $\frac{1}{2}$ spinons. Here, we measure the excitations in single crystals of the spin liquid candidate Zn-barlowite using resonant inelastic X-ray scattering. By analyzing the incident polarization and temperature dependences, we deduce a clear magnetic scattering contribution forming a broad continuum that surprisingly extends up to ~ $200$ meV (~14$J$, where $J$ is the magnetic exchange). In conclusion, the excitation spectrum reveals that significant contributions arise from multiple pairs of spinons and/or antispinons at high energies.

36 MATERIALS SCIENCE↗