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At least 685 records · Page 38

Differences Between OCO‐2 and GOME‐2 SIF Products From a Model‐Data Fusion Perspective

Space-borne retrievals of solar-induced chlorophyll fluorescence (SIF) over land surfaces have recently become a resource for studying and quantifying the broad scale dynamics of gross carbon uptake (gross primary productivity—GPP) across ecosystems. To prepare for the assimilation of SIF data in terrestrial biosphere models, we examine how differences between SIF products (due to differences in acquisition characteristics and processing chain) may affect the optimization of model parameters and the resultant GPP estimate. We compare recent daily mean SIF products (one from the Orbiting Carbon Observatory-2 [OCO-2] and two from the Global Ozone Monitoring Experiment–2 [GOME-2], GlobFluo [GF] and NASA-v28 [N28], missions), averaged at 0.5° × 0.5° spatial resolution and 16-day temporal resolution, at the biome level. Phase differences between these products are relatively small. A first-order correction of the difference in spectral sampling between the two instruments shows that OCO-2 and N28 are consistent in terms of magnitude and amplitude, while GF is twice as large as the others. Using a bias-blind toy data assimilation framework, we analyze how biases between SIF products, and between model and products, can be partially alleviated by optimizing the slope and intercept parameters of a linear GPP-SIF operator. As observation biases can transfer to biases in other optimized process-based parameters and to modeled carbon fluxes— thereby resulting in unidentified inaccurate parameter values—we argue that potential SIF biases should be treated cautiously in real-world experiments in order to achieve realistic and reliable future simulations.

Gross primary production↗

An Off-Axis Four-Quadrant Phase Mask (FQPM) Coronagraph for Palomar: High-Contrast Near Bright Stars Imager

Direct detection of planets around nearby stars requires the development of high-contrast imaging techniques because of the high difference between their respective fluxes. This led us to test a new coronagraphic approach based on the use of phase mask instead of dark occulting ones. Combined with high-level wavefront correction on an unobscured off-axis section of a large telescope, this method allows imaging very close to the star. Calculations indicate that for a given ground-based on-axis telescope, use of such an off-axis coronagraph provides a near-neighbor detection capability superior to that of a traditional coronagraph utilizing the full telescope aperture. Setting up a laboratory experiment working in near infrared allowed us to demonstrate the principle of the method, and a rejection of 2000:1 has already been achieved.

coronagraphy↗

Fluoroarene Separations in Metal-Organic Frameworks with Two Proximal Mg 2+ Coordination Sites

Fluoroarenes which are widely used in medicinal, agricultural, and materials chemistry, and yet their production remains a critical challenge in organic synthesis. Indeed, the nearly identical physical properties of these vital building blocks hinders their purification by traditional methods, such as flash chromatography or distillation. As a result, the Balz-Schiemann reaction is currently employed to prepare fluoroarenes instead of more atom-economical C-H fluorination reactions, which produce inseparable mixtures of regioisomers. Herein, we propose an alternative solution to this problem: the purification of mixtures of fluoroarenes using metal-organic frameworks (MOFs). Specifically, we demonstrate that controlling the interaction of fluoroarenes with adjacent coordinatively unsaturated Mg 2+ centers within a MOF enables the separation of fluoroarene mixtures with unparalleled selectivities. Liquid-phase multicomponent equilibrium adsorption data and breakthrough measurements coupled with van der Waals-corrected density functional theory calculations reveal that the materials Mg 2 (dobdc) (dobdc 4- = 2,5-dioxidobenzene-1,4-dicarboxylate) and Mg 2 ( m -dobdc) ( m -dobdc 4- = 2,4-dioxidobenzene-1,5-dicarboxylate) are capable of separating the difluorobenzene isomers from one another. Additionally, these frameworks facilitate the separations of fluoroanisoles, fluorotoluenes, and fluorochlorobenzenes. In addition to enabling currently unfeasible separations for the production of fluoroarenes, our results suggest that carefully controlling the interaction of isomers with not one but two strong binding sites within a MOF provides a general strategy for achieving challenging liquid-phase separations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Codimension-2 defects and higher symmetries in (3+1)D topological phases

(3+1)D topological phases of matter can host a broad class of non-trivial topological defects of codimension-1, 2, and 3, of which the well-known point charges and flux loops are special cases. The complete algebraic structure of these defects defines a higher category, and can be viewed as an emergent higher symmetry. This plays a crucial role both in the classification of phases of matter and the possible fault-tolerant logical operations in topological quantum error-correcting codes. In this paper, we study several examples of such higher codimension defects from distinct perspectives. We mainly study a class of invertible codimension-2 topological defects, which we refer to as twist strings. We provide a number of general constructions for twist strings, in terms of gauging lower dimensional invertible phases, layer constructions, and condensation defects. We study some special examples in the context of \mathbb{Z}_2 ℤ 2 gauge theory with fermionic charges, in \mathbb{Z}_2 \times \mathbb{Z}_2 ℤ 2 × ℤ 2 gauge theory with bosonic charges, and also in non-Abelian discrete gauge theories based on dihedral ( D_n D n ) and alternating ( A_6 A 6 ) groups. The intersection between twist strings and Abelian flux loops sources Abelian point charges, which defines an H^4 H 4 cohomology class that characterizes part of an underlying 3-group symmetry of the topological order. The equations involving background gauge fields for the 3-group symmetry have been explicitly written down for various cases. We also study examples of twist strings interacting with non-Abelian flux loops (defining part of a non-invertible higher symmetry), examples of non-invertible codimension-2 defects, and examples of the interplay of codimension-2 defects with codimension-1 defects. We also find an example of geometric, not fully topological, twist strings in (3+1)D A_6 A 6 gauge theory.

Barkeshli, Maissam↗

Antiferromagnetic ordering and possible lattice response to dynamic uranium valence in U 3 O 8

Determining the correct electronic structure of U 3 O 8 remains a formidable experimental and theoretical challenge. In the low-temperature phase, two crystallographic U sites are separated into a distinct 2U(V)+1U(VI) oxidation configuration. At low temperatures, the U(V) sites form a distorted honeycomb lattice, but the U(VI) sit on a triangular sublattice, suggesting potential for magnetic frustration effects. The spin configuration of the unpaired f electrons on the U(V) sites is likely antiferromagnetic (AFM) from susceptibility measurements, but this has not been confirmed. Here in this paper, we present a neutron scattering investigation of the structure and dynamics of U 3 O 8 from 1.7 to 600 K. We confirm static AFM ordering onset at between 22 and 25 K, which is present down to at least 1.7 K with AFM peaks corresponding to [0.5 1 1] and [0.5 2 2] in the orthorhombic phase. These measurements rule out static AFM order along the a axis of the Amm2 phase, a configuration previously suggested by theory. Above 100 K a quasielastic scattering channel opens that we speculate arises from a lattice relaxation response to thermally activated electron hopping. This term does not conform to a magnetic form factor, so it is not related to spin relaxations. If correct, this mechanism stabilizes a continuous valence transition from 2U(V)+1U(VI) in the low-temperature (T<600 K) orthorhombic phase to the hexagonal phase that contains only one degenerate U site, wherein the U valence can be dynamically stabilized between U(V)↔U(VI) by phonon-assisted electron hopping.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Single Electron Self-coherence and Its Wave/Particle Duality in the Electron Microscope

Intensities in high-resolution phase-contrast images from electron microscopes build up discretely in time by detecting single electrons. A wave description of pulse-like coherent-inelastic interaction of an electron with matter implies a time-dependent coexistence of coherent partial waves. Their superposition forms a wave package by phase decoherence of 0.5 - 1 radian with Heisenbergs energy uncertainty ΔE H = $\hbar$/2 Δt -1 matching the energy loss ΔE of a coherent-inelastic interaction and sets the interaction time Δt. In these circumstances, the product of Planck's constant and the speed of light hc is given by the product of the expression for temporal coherence λ 2 /Δλ and the energy loss ΔE. Experimentally, the self-coherence length was measured by detecting the energy-dependent localization of scattered, plane matter waves in surface proximity exploiting the Goos–Hänchen shift. Chromatic-aberration Cc-corrected electron microscopy on boron nitride (BN) proves that the coherent crystal illumination and phase contrast are lost if the self-coherence length shrinks below the size of the crystal unit cell at ΔE > 200 eV. Finally, in perspective, the interaction time of any matter wave compares with the lifetime of a virtual particle of any elemental interaction, suggesting the present concept of coherent-inelastic interactions of matter waves might be generalizable.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Dynamical topological phase realized in a trapped-ion quantum simulator

Nascent platforms for programmable quantum simulation offer unprecedented access to new regimes of far-from-equilibrium quantum many-body dynamics in almost isolated systems. Here achieving precise control over quantum many-body entanglement is an essential task for quantum sensing and computation. Extensive theoretical work indicates that these capabilities can enable dynamical phases and critical phenomena that show topologically robust methods to create, protect and manipulate quantum entanglement that self-correct against large classes of errors. However, so far, experimental realizations have been confined to classical (non-entangled) symmetry-breaking orders. In this work, we demonstrate an emergent dynamical symmetry-protected topological phase, in a quasiperiodically driven array of ten 171 Yb + hyperfine qubits in Quantinuum’s System Model H1 trapped-ion quantum processor. This phase shows edge qubits that are dynamically protected from control errors, cross-talk and stray fields. Crucially, this edge protection relies purely on emergent dynamical symmetries that are absolutely stable to generic coherent perturbations. Here, this property is special to quasiperiodically driven systems: as we demonstrate, the analogous edge states of a periodically driven qubit array are vulnerable to symmetry-breaking errors and quickly decohere. Our work paves the way for implementation of more complex dynamical topological orders that would enable error-resilient manipulation of quantum information.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Interactions Remove the Quantization of the Chiral Photocurrent at Weyl Points

The chiral photocurrent or circular photogalvanic effect (CPGE) is a photocurrent that depends on the sense of circular polarization. In a disorder-free, non-interacting chiral Weyl semimetal, the magnitude of the effect is approximately quantized with a material-independent quantum $e^3/h^2$ for reasons of band topology. We study the first-order corrections due to the Coulomb and Hubbard interactions in a continuum model of a Weyl semimetal in which known corrections from other bands are absent. We find that the inclusion of interactions generically breaks the quantization. The corrections have a weaker dependence on the form of the cutoff than previously studied interaction corrections to the (non-topological) linear optical conductivity of graphene, and a potentially observable frequency dependence. Here, we conclude that, unlike the quantum Hall effect in gapped phases or the chiral anomaly in field theories, the quantization of the CPGE in Weyl semimetals is not protected but has perturbative corrections in interaction strength.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Microwave Oscillators Based on Nonlinear WGM Resonators

Optical oscillators that exploit resonantly enhanced four-wave mixing in nonlinear whispering-gallery-mode (WGM) resonators are under investigation for potential utility as low-power, ultra-miniature sources of stable, spectrally pure microwave signals. There are numerous potential uses for such oscillators in radar systems, communication systems, and scientific instrumentation. The resonator in an oscillator of this type is made of a crystalline material that exhibits cubic Kerr nonlinearity, which supports the four-photon parametric process also known as four-wave mixing. The oscillator can be characterized as all-optical in the sense that the entire process of generation of the microwave signal takes place within the WGM resonator. The resonantly enhanced four-wave mixing yields coherent, phase-modulated optical signals at frequencies governed by the resonator structure. The frequency of the phase-modulation signal, which is in the microwave range, equals the difference between the frequencies of the optical signals; hence, this frequency is also governed by the resonator structure. Hence, further, the microwave signal is stable and can be used as a reference signal. The figure schematically depicts the apparatus used in a proof-of-principle experiment. Linearly polarized pump light was generated by an yttrium aluminum garnet laser at a wavelength of 1.32 microns. By use of a 90:10 fiber-optic splitter and optical fibers, some of the laser light was sent into a delay line and some was transmitted to one face of glass coupling prism, that, in turn, coupled the laser light into a crystalline CaF2 WGM disk resonator that had a resonance quality factor (Q) of 6x10(exp 9). The output light of the resonator was collected via another face of the coupling prism and a single-mode optical fiber, which transmitted the light to a 50:50 fiber-optic splitter. One output of this splitter was sent to a slow photodiode to obtain a DC signal for locking the laser to a particular resonator mode. The other output of this splitter was combined with the delayed laser signal in another 50:50 fiber-optic splitter used as a combiner. The output.of the combiner was fed to a fast photodiode that demodulated light and generated microwave signal. In this optical configuration, the resonator was incorporated into one arm of a Mach-Zehnder interferometer, which was necessary for the following reasons: It was found that when the output of the resonator was sent directly to a fast photodiode, the output of the photodiode did not include a measurable microwave signal. However, when the resonator was placed in an arm of the interferometer and the delay in the other arm was set at the correct value, the microwave signal appeared. Such behavior is distinctly characteristic of phase-modulated light. The phase-modulation signal had a frequency of about 8 GHz, corresponding to the free spectral range of the resonator. The spectral width of this microwave signal was less than 200 Hz. The threshold pump power for generating the microwave signal was about 1 mW. It would be possible to reduce the threshold power by several orders of magnitude if resonators could be made from crystalline materials in dimensions comparable to those of micro-resonators heretofore made from fused silica.

Maleki, Lute↗

Lateral conduction effects on heat-transfer data obtained with the phase-change paint technique

A computerized tool, CAPE, (Conduction Analysis Program using Eigenvalues) has been developed to account for lateral heat conduction in wind tunnel models in the data reduction of the phase-change paint technique. The tool also accounts for the effects of finite thickness (thin wings) and surface curvature. A special reduction procedure using just one time of melt is also possible on leading edges. A novel iterative numerical scheme was used, with discretized spatial coordinates but analytic integration in time, to solve the inverse conduction problem involved in the data reduction. A yes-no chart is provided which tells the test engineer when various corrections are large enough so that CAPE should be used. The accuracy of the phase-change paint technique in the presence of finite thickness and lateral conduction is also investigated.

Maise, G.↗

The Development of the GSFC DORIS Contribution to ITRF2014

The NASA GSFC DORIS analysis center has processed data from January 1993 to December 2014 and provided 1141 weekly solutionsin the form of normal equations for incorporation into the DORIS solution for ITRF2014. The solution time series, designated asgscwd26, were based on tracking data to eleven DORIS satellites divided generally into seven-day arcs. With respect to the ITRF2008 submission (Le Bail et al., 2010), the measurement model was updated to model the beacon frequency variations at certain DORIS sites,to apply the DORIS antenna phase law for the Starec and Alcatel antennae, and to apply the antenna offset corrections in the NASAGSFC orbit determination software rather than using the data-supplied corrections. We show that computing the antenna offset correctionsin the orbit determination software is superior to using the offset corrections that are supplied with the DORIS data, and that thisimproves the RMS of fit for SPOT-2, Envisat, SPOT-4, and SPOT-5. The updates for the force model included: (1) the development of improved nonconservative force modeling for SPOT-2, SPOT-3, SPOT-5, Envisat, and HY-2A, and (2) the application of an updatedstatic gravity model based on GRACE and GOCE data, and weekly models of the variations in the low degree gravity field deducedindependently from tracking by Satellite Laser Ranging (SLR) and DORIS. The post-ITRF2008 DORIS coordinate WRMS afterthe launch of Envisat and SPOT-5 is improved from 11.20 to 12.45 mm with ITRF2008 (Le Bail et al., 2010), to between 8.50 and9.99 mm with the gscwd26 SINEX solution. The application of the DORIS antenna phase laws shifts the DORIS scale wrt DPOD2008by +6.0 mm from 19930103 to 20020606, and by +11.4 mm from 20020613 to 20111030. The application of more detailed models of time-variable gravity reduces the slopes in the Helmert transformation parameters Tx, and Ty (w.r.t. DPOD2008) after 2005. The annual amplitude in these parameters is reduced from 3.2 mm (for Tx), 4.1 mm (for Ty), to 1.7 mm (for Tx) and 2.8 mm (for Ty).

Lemoine, F. G.↗

Measurement of the $H \rightarrow \gamma \gamma $ and $H \rightarrow ZZ^* \rightarrow 4 \ell $ cross-sections in $pp$ collisions at $\sqrt{s}=13.6$ TeV with the ATLAS detector

The inclusive Higgs boson production crosssection is measured in the di-photon and the Z Z* → 4$\ell$ decay channels using 31.4 and 29.0 fb –1 of pp collision data respectively, collected with the ATLAS detector at a centreof-mass energy of $\sqrt{s}$ = 13.6 TeV. To reduce the model dependence, the measurement in each channel is restricted to a particle-level phase space that closely matches the channel’s detector-level kinematic selection, and it is corrected for detector effects. These measured fiducial cross-sections are σ fid,γγ = $76^{+14}_{–13}$ fb, and $σ_{\text{fid,4}\ell}$ = 2.80 ± 0.74 fb, in agreement with the corresponding Standard Model predictions of 67.6±3.7 fb and 3.67±0.19 fb. Assuming Standard Model acceptances and branching fractions for the two channels, the fiducial measurements are extrapolated to the full phase space yielding total cross-sections of σ (pp → H) = $67^{+12}_{–11}$ pb and 46±12 pb at 13.6 TeV from the di-photon and Z Z* → 4$\ell$ measurements respectively. The two measurements are combined into a total cross-section measurement of σ (pp → H) = 58.2±8.7 pb, to be compared with the Standard Model prediction of σ (pp → H) SM = 59.9 ± 2.6 pb.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

FLUID: A numerical interpolation procedure for obtaining thermodynamic and transport properties of fluids

A computer program subroutine, FLUID, was developed to calculate thermodynamic and transport properties of pure fluid substances. It provides for determining the thermodynamic state from assigned values for temperature-density, pressure-density, temperature-pressure, pressure-entropy, or pressure-enthalpy. Liquid or two-phase (liquid-gas) conditions are considered as well as the gas phase. A van der Waals model is used to obtain approximate state values; these values are then corrected for real gas effects by model-correction factors obtained from tables based on experimental data. Saturation conditions, specific heat, entropy, and enthalpy data are included in the tables for each gas. Since these tables are external to the FLUID subroutine itself, FLUID can implement any gas for which a set of tables has been generated. (A setup phase is used to establish pointers dynamically to the tables for a specific gas.) Data-table preparation is described. FLUID is available in both SFTRAN and FORTRAN

Fessler, T. E.↗

Statistically bias-corrected and downscaled climate models underestimate the adverse effects of extreme heat on U.S. maize yields

Abstract Efforts to understand and quantify how a changing climate can impact agriculture often rely on bias-corrected and downscaled climate information, making it important to quantify potential biases of this approach. Here, we use a multi-model ensemble of statistically bias-corrected and downscaled climate models, as well as the corresponding parent models from the Coupled Model Intercomparison Project Phase 5 (CMIP5), to drive a statistical panel model of U.S. maize yields that incorporates season-wide measures of temperature and precipitation. We analyze uncertainty in annual yield hindcasts, finding that the CMIP5 models considerably overestimate historical yield variability while the bias-corrected and downscaled versions underestimate the largest weather-induced yield declines. We also find large differences in projected yields and other decision-relevant metrics throughout this century, leaving stakeholders with modeling choices that require navigating trade-offs in resolution, historical accuracy, and projection confidence.

54 ENVIRONMENTAL SCIENCES↗

Electroweak Phase Transition with Spontaneous $Z_2$-Breaking

This work investigates a simple, representative extension of the Standard Model with a real scalar singlet and spontaneous $Z_2$ breaking, which allows for a strongly first-order phase transition, as required by electroweak baryogenesis. We perform analytical and numerical calculations that systematically include one-loop thermal effects, Coleman-Weinberg corrections, and daisy resummation, as well as evaluation of bubble nucleation. We study the rich thermal history and identify the conditions for a strongly first-order electroweak phase transition with nearly degenerate extrema at zero temperature. This requires a light scalar with mass below 50 GeV. Exotic Higgs decays, as well as Higgs coupling precision measurements at the LHC and future collider facilities, will test this model. Additional information may be obtained from future collider constraints on the Higgs self-coupling. Gravitational-wave signals could potentially be probed by future gravitational wave experiments.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Chemical Compensation Challenges in Processing Antiferroelectric PbZrO 3 Thin Films

The electric field-induced antipolar-to-polar phase transition in antiferroelectric materials is accompanied by large changes in the structural and functional response, making them attractive for many applications ranging from pulsed energy capacitors to high-strain-high (blocking-)force actuators, solid-state heating and cooling systems, and optoelectronic devices. PbZrO 3 , as an end member of the PZT, (x)PbZr 1–x Ti x O 3 , solid solution, has been the subject of many studies. However, processing of perovskite PbZrO 3 is extremely challenging due to phase instabilities induced by Pb loss at the temperatures necessary for perovskite crystallization. Here, we discuss the challenges associated with Pb loss, as well as its compensation through bulk Pb overstoichiometry and interfacial PbO additions, in chemical solution processed, highly oriented PbZrO 3 thin films. For both 042 o - and 001 o -oriented (o-orthorhombic distortion) PbZrO 3 thin films, the crystallization interfaces are the most important contributors to Pb loss and off-stoichiometric outcomes, and no single approach was sufficient to address these challenges. Pb-rich and Pb-deficient nonperovskite phases including ZrO x were only observable through microscopic characterization, and X-ray diffraction alone could not rule out the presence of such secondary phases. “Ideal” macroscopic antiferroelectric polarization-electric field double hysteresis curves were observed despite (at times) the large presence of secondary phases. However, reduced saturation polarization and increased phase transition electric fields were observed concomitantly with the presence of secondary phase(s) and tentatively assigned to the voltage drop across the ZrO x nanocrystals. Based on these results, it is imperative that the presence of secondary phases always be addressed (beyond X-ray diffraction spectra) in order to correctly evaluate the properties of antiferroelectric films.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Bragg coherent diffraction imaging by simultaneous reconstruction of multiple diffraction peaks

Bragg coherent diffractive imaging (BCDI) is a non-invasive microscopy technique that can visualize the morphology and internal lattice deviations of crystals with nanoscale spatial resolution and picometer deformation sensitivity. While BCDI has been successfully applied in various studies of materials, it is less successful for highly-strained crystals. Specifically, it is difficult to correctly reconstruct the electron density of a highly-strained object using conventional phase retrieval algorithms. Although various algorithms have been developed to overcome this challenge, most of them require a priori knowledge that is not always available in practice. Here we report on a new phase retrieval workflow that can invert diffraction patterns from multiple Bragg peaks simultaneously. The new workflow is explored via simulated diffraction from crystals with various strain conditions. Furthermore, reconstructions from the new workflow consistently demonstrate more accurate electron density maps, in comparison with the conventional method. For highly-strained crystals, the new workflow improves the reliability and consistency of BCDI phase retrieval significantly.

36 MATERIALS SCIENCE↗

Improving generative model-based unfolding with Schrödinger bridges

Machine learning-based unfolding has enabled unbinned and high-dimensional differential cross section measurements. Two main approaches have emerged in this research area; one based on discriminative models and one based on generative models. The main advantage of discriminative models is that they learn a small correction to a starting simulation while generative models scale better to regions of phase space with little data. We propose to use Schrödinger bridges and diffusion models to create , an unfolding approach that combines the strengths of both discriminative and generative models. The key feature of is that its generative model maps one set of events into another without having to go through a known probability density as is the case for normalizing flows and standard diffusion models. We show that achieves excellent performance compared to state of the art methods on a synthetic Z + jets dataset. Published by the American Physical Society 2024

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗