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At least 685 records · Page 38

Uniform Dust Deposition System for Dust Tolerance Studies

Future missions to the Moon will require mechanisms and materials to effectively and reliably operate in the presences of lunar regolith. One of the challenges of developing such technologies is terrestrial testing with lunar dust simulants. Dust has a stochastic nature of depositing and it can be difficult to accurately apply it to surfaces of interest. Deposition density, particles size distribution, and percent coverage are all factors that affect the quality of dust mitigation testing. Therefore, to enable such testing the dust mitigation and seals teams at NASA Glenn Research Center (GRC) have developed a system that can uniformly and repeatably deposit lunar simulants on a range of surfaces. Testing of the Dust Deposition System (DDS) and an associatedsimulant preparation methodology have quantified the levels of uniformity and precision for this system. Furthermore, the deposition system has been paired with automated micrograph capturing and machine learning image analysis to correlate the images of dust on a surface to deposition density (in g/cm2). This correlation alleviates the need for tested samples to be accurately weighed with milligram precision and may be a useful tool for in-situ contamination evaluation on the Moon. This paper covers the design and validation testing for the DDS.

Stephen Gerdts↗

Uniform Dust Deposition System for Dust Tolerance Studies

Future missions to the Moon will require mechanisms and materials to effectively and reliably operate in the presences of lunar regolith. One of the challenges of developing such technologies is terrestrial testing with lunar dust simulants. Dust has a stochastic nature of depositing and it can be difficult to accurately apply it to surfaces of interest. Deposition density, particles size distribution, and percent coverage are all factors that affect the quality of dust mitigation testing. Therefore, to enable such testing the dust mitigation and seals teams at NASA Glenn Research Center (GRC) have developed a system that can uniformly and repeatably deposit lunar simulants on a range of surfaces. Testing of the Dust Deposition System (DDS) and an associated simulant preparation methodology have quantified the levels of uniformity and precision for this system. Furthermore, the deposition system has been paired with automated micrograph capturing and machine learning image analysis to correlate the images of dust on a surface to deposition density (in g/cm2). This correlation alleviates the need for tested samples to be accurately weighed with milligram precision and may be a useful tool for in-situ contamination evaluation on the Moon. This paper covers the design and validation testing for the DDS.

Dust↗

Preface

Crystallization via nonclassical pathways is important during the formation of minerals in nature and has become a popular method to synthesize advanced materials on both laboratory and industrial scales. Unlike classical crystal growth pathways via monomer-by-monomer addition, crystallization via nonclassical pathways, such as particle-by-particle attachment, can form larger crystals more quickly. Materials prepared via nonclassical crystallization have been applied in various fields such as energy, catalysis, environment, biomedicine, optics, electrics, and magnetics. Understanding nonclassical crystallization pathways could provide new insights into synthesizing novel materials. This ACS Book series aims to provide updated information on fundamental nonclassical crystallization research, including theory and experiments. It is also intended for experienced researchers, to reinforce their knowledge of the developmental scope of new techniques–especially state-of-the-art in situ characterization tools–to understand mechanisms of crystallization via nonclassical pathways. Topics covered in this book series include: (1) nonclassical nucleation; (2) cluster assembly; (3) particle-based crystallization; (4) crystal formation from amorphous intermedium phases; (5) biomineralization via nonclassical pathways; (6) theoretical developments to simulate nonclassical crystallization; (7) observation of the nonclassical crystallization pathways via various characterization techniques; and (8) the application of nonclassical crystallization. Volume II of the Nonclassical Crystallization Book Series will cover a broad range of topics including particle-based crystallization, biomolecular self-assembly, biomineralization, nanoscale imaging, and applications of nonclassical crystallization.

Zhang, Xin↗

Exascale granular microstructure reconstruction in 3D volumes of arbitrary geometries with generative learning

Reconstructing 3D granular microstructures within volumes of arbitrary geometries from limited 2D image data is crucial for predicting the material properties, as well as performances of structural components accounting for material microstructural effects. We present a novel generative learning framework that enables exascale reconstruction of granular microstructures within complex 3D geometric volumes. Building upon existing transfer learning techniques using pre-trained convolutional neural networks (CNN), we introduce several key innovations to overcome the difficulties inherent in arbitrary geometries. Our framework incorporates periodic boundary conditions using circular padding techniques, ensuring continuity and representativeness of the reconstructed microstructures. We also introduce a novel seamless transition reconstruction (STR) method that creates statistically equivalent transition zones to integrate multiple pre-existing 3D microstructure volumes. Based on STR, we propose a cost-effective strategy for reconstructing microstructures within complex geometric volumes, minimizing computational waste. Validation through numerical experiments using kinetic Monte Carlo simulations demonstrates accurate reproduction of grain statistics, including grain size distributions and morphology. A case study involving the reconstruction of a 4-blade propeller microstructure illustrates the method’s capability to efficiently handle complex geometries. In conclusion, the proposed framework significantly reduces computational demands while maintaining high reconstruction quality, paving the way for scalable microstructure reconstruction in materials design and analysis.

36 MATERIALS SCIENCE↗

Dynamic nanodomains dictate macroscopic properties in lead halide perovskites

Lead halide perovskites have emerged as promising materials for solar energy conversion and X-ray detection owing to their remarkable optoelectronic properties. However, the microscopic origins of their superior performance remain unclear. Here we show that low-symmetry dynamic nanodomains present in the high-symmetry average cubic phases, whose characteristics are dictated by the A-site cation, govern the macroscopic behaviour. We combine X-ray diffuse scattering, inelastic neutron spectroscopy, hyperspectral photoluminescence microscopy and machine-learning-assisted molecular dynamics simulations to directly correlate local nanoscale dynamics with macroscopic optoelectronic response. Our approach reveals that methylammonium-based perovskites form densely packed, anisotropic dynamic nanodomains with out-of-phase octahedral tilting, whereas formamidinium-based systems develop sparse, isotropic, spherical nanodomains with in-phase tilting, even when crystallography reveals cubic symmetry on average. We demonstrate that these sparsely distributed isotropic nanodomains present in formamidinium-based systems reduce electronic dynamic disorder, resulting in a beneficial optoelectronic response, thereby enhancing the performance of formamidinium-based lead halide perovskite devices. By elucidating the influence of the A-site cation on local dynamic nanodomains, and consequently, on the macroscopic properties, we propose leveraging this relationship to engineer the optoelectronic response of these materials, propelling further advancements in perovskite-based photovoltaics, optoelectronics and X-ray imaging.

Materials Science↗

Development of a directly driven multi-shell platform: Laser drive energetics

Simulations predict that directly driven multi-shell targets can provide a robust alternative to conventional high-convergence implosion concepts by coupling two to three times more energy into the final igniting thermonuclear fuel assembly than indirect-drive concepts. The three-shell directly driven Revolver concept [K. Molvig, M. J. Schmitt, B. J. Albright, E.S. Dodd, N.M. Hoffman, G.H. McCall, and S.D. Ramsey, Phys. Rev. Lett. 116, 255003 (2016)] utilizes a design that maximizes laser energy conversion into inward kinetic energy of the outermost ablator shell (~9%) while minimizing the DT fuel convergence (~9) to reduce the mixing of material from the innermost shell into the fuel. Inherent in this design concept is the use of 192 narrow beams (with a 1/e laser beam-to-capsule diameter ratio of 0.33) from the National Ignition Facility laser pointed in a polar direct drive laser configuration. In this paper, we demonstrate that low average laser intensity at the capsule surface (≤300 TW/cm 2 ) limits the measured laser backscatter, indicating that a greater amount of laser energy is coupled into the target. Omega experiments have been performed to determine the coupling of laser energy to the outermost shell of a scaled Revolver target (i.e., the ablator shell) by measuring capsule implosion trajectories and scattered-light fractions for two different drive configurations. Comparisons of simulated shell trajectory and velocity profiles with experimental data obtained from self-emission images show good agreement and are consistent with measured scattered light data. Furthermore, the low levels of scattered light measured are consistent with post-shot simulation results that show high hydro-coupling efficiency. These results strengthen the case for using narrow beams at low intensity to drive large ablator capsules for future direct-drive, multi-shell ignition concepts.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

TomoGAN: low-dose synchrotron x-ray tomography with generative adversarial networks: discussion

Synchrotron-based x-ray tomography is a noninvasive imaging technique that allows for reconstructing the internal structure of materials at high spatial resolutions from tens of micrometers to a few nanometers. In order to resolve sample features at smaller length scales, however, a higher radiation dose is required. Therefore, the limitation on the achievable resolution is set primarily by noise at these length scales. We present TomoGAN, a denoising technique based on generative adversarial networks, for improving the quality of reconstructed images for low-dose imaging conditions. We evaluate our approach in two photon-budget-limited experimental conditions: (1) sufficient number of low-dose projections (based on Nyquist sampling), and (2) insufficient or limited number of high-dose projections. In both cases, the angular sampling is assumed to be isotropic, and the photon budget throughout the experiment is fixed based on the maximum allowable radiation dose on the sample. Evaluation with both simulated and experimental datasets shows that our approach can significantly reduce noise in reconstructed images, improving the structural similarity score of simulation and experimental data from 0.18 to 0.9 and from 0.18 to 0.41, respectively. Furthermore, the quality of the reconstructed images with filtered back projection followed by our denoising approach exceeds that of reconstructions with the simultaneous iterative reconstruction technique, showing the computational superiority of our approach.

42 ENGINEERING↗

Fast Hyperspectral Neutron Tomography

Hyperspectral neutron computed tomography is a tomographic imaging technique in which thousands of wavelength-specific neutron radiographs are measured for each tomographic view. In conventional hyperspectral reconstruction, data from each neutron wavelength bin are reconstructed separately, which is extremely time-consuming. These reconstructions often suffer from poor quality due to low signal-to-noise ratios. Consequently, material decomposition based on these reconstructions tends to produce inaccurate estimates of the material spectra and erroneous volumetric material separation. In this paper, we present two novel algorithms for processing hyperspectral neutron data: fast hyperspectral reconstruction and fast material decomposition. Both algorithms rely on a subspace decomposition procedure that transforms hyperspectral views into low-dimensional projection views within an intermediate subspace, where tomographic reconstruction is performed. The use of subspace decomposition dramatically reduces reconstruction time while reducing both noise and reconstruction artifacts. We apply our algorithms to both simulated and measured neutron data and demonstrate that they reduce computation and improve the quality of the results relative to conventional methods.

Chowdhury, Mohammad Samin Nur [Purdue University]↗

Characterization of Ablation Product Radiation Signatures of PICA and FiberForm

Emission spectroscopy measurements in the post-shock layer in front of low density ablative material samples of different shapes were obtained in the NASA Langley HYMETS arcjet facility. A horizontal line of measurement positions was imaged on the entrance slit of the spectrometer allowing detection of the entire stagnation line in front of the samples. The stagnation line measurements were used to compare the post-shock layer emission signatures in front of PICA and FiberForm. The emission signatures of H, NH, and OH are characteristic for pyrolysis gases and consequently were only observed in front of the PICA samples. CN and C were found in front of both materials and are mainly due to interactions of the carbon fibers with the plasma. In all tests with instrumented samples, the emission of Mn, Cr, and Ni was observed when the thermocouple temperatures reached or exceeded ~1,500 K, strongly indicating erosion of the molten thermocouple tips. Temperatures in the post-shock layer were estimated from comparing the CN band emission to spectral simulation. The resulting rotational and vibrational temperatures were on the order of 7,000 to 9,000 K and close to each other indicating a plasma condition close to equilibrium. In addition to the stagnation line configurations, off-axis lines of observation were investigated to gather information about spalled particles in the flow. From a comparison of measured continuum emission with simulated Planck radiation, average particle temperatures along the measured line of observation were determined for two cases. Particle temperatures between 3,500 and 2,000 K were found. A comprehensive investigation of the entire amount of data set is ongoing.

Winter, Michael↗

Electromagnetic Scattering Analysis of Large Size Asteroids/Comets for Reflection/Transmission Tomography (RTT)

A precise knowledge of the interior structure of asteroids, comets, and Near Earth Objects (NEO) is important to assess the consequences of their impacts with the Earth and develop efficient mitigation strategies. Knowledge of their interior structure also provides opportunities for extraction of raw materials for future space activities. Low frequency radio sounding is often proposed for investigating interior structures of asteroids and NEOs. For designing and optimizing radio sounding instrument it is advantageous to have an accurate and efficient numerical simulation model of radio reflection and transmission through large size bodies of asteroid shapes. In this presentation we will present electromagnetic (EM) scattering analysis of electrically large size asteroids using (1) a weak form formulation and (2) also a more accurate hybrid finite element method/method of moments (FEM/MOM) to help estimate their internal structures. Assuming the internal structure with known electrical properties of a sample asteroid, we first develop its forward EM scattering model. From the knowledge of EM scattering as a function of frequency and look angle we will then present the inverse scattering procedure to extract its interior structure image. Validity of the inverse scattering procedure will be presented through few simulation examples.

Deshpande, Manohar↗

A Survey of Modeling Activities by NASA’s Orbital Debris Program Office

NASA’s Orbital Debris Program Office (ODPO) develops and maintains a number of modeling tools to analyze and simulate the orbital debris environment. One of the most important products produced by the NASA ODPO is the Orbital Debris Engineering Model (ORDEM). This model can be used by satellite designers and operators to design missions for better protection against the debris environment. The ODPO is currently working on the next generation, designated ORDEM 4.0. ORDEM 4.0 will include many known features from previous models, such as the ability to input a spacecraft orbit and time and the ability to compute the flux as a function of debris size, impact speed, impact direction, and debris material densities, as well as uncertainty information on the flux. A new addition will be a parameterized debris shape model based on laboratory hypervelocity impact tests, including DebriSat. ORDEM is primarily based on dedicated debris measurements, such as by the Haystack Ultrawideband Satellite Imaging Radar (HUSIR), NASA’s Goldstone radar, and observations of geosynchronous orbits (GEO) using the Eugene Stansbery-Meter Class Autonomous Telescope (ES-MCAT). In addition to ORDEM, the ODPO also maintains other models, such as the LEO-to-GEO Environment Debris (LEGEND) model for studies of long-term evolution of Earth’s debris environment, with the ability to study various mitigation and remediation strategies. Another model, the Satellite Breakup Risk Assessment Model (SBRAM), is used to analyze how satellite breakups may affect critical space missions (such as the ISS) on short notice. In addition to these models, the ODPO maintains other secondary models used to model satellite explosions and collisions, analyze radar, optical, and in situ data, and to model such things as solar activity and orbit evolution. In this presentation, a survey of these models will be presented, showing how the different models are used together to create a comprehensive picture of Earth’s debris environment.

Mark Matney↗

Examining phase separation and crystallization in glasses with X-ray nano-computed tomography

X-ray nano-computed tomography (nano-CT) is a powerful technique to characterize and visualize 3 dimensional (3D) phenomena in complex glasses at the nanoscale. This technique can offer a unique opportunity to explore the intricate morphology of multicomponent glass and glass-ceramic samples, due to its low X-ray energy and high spatial resolution (down to 50 nm). In the current demonstration paper, nano-CT provided insight into crystallization and phase separation, as well as a variety of other phenomena, including corrosion, fracture, and porosity. At scales ranging from 100 to 20 μm, the microstructures of phase separation in borosilicate, complex silicate, and chalcogenide glass compositions were examined. In addition, crystallites present in simulant nuclear waste glasses, volcanic glasses, and other related samples were explored. Nano-CT analysis can add to the understanding of (1) the formation processes, (2) distributions, interactions, and compositions of phases, and (3) the mechanisms, structures, and growth of crystallization and phase separation. Nano-CT offers wide potential in the field of glass science, especially when (1) common characterization methods are insufficient, (2) simple sample preparation is required, (3) 3D rendering is needed, or (4) compelling images of small, complex features are desired.

36 MATERIALS SCIENCE↗

In situ observation of the magnetization configuration and reversal in cylindrical nanowires

Curvilinear magnetic structures often have unique magnetic behavior compared to their rectilinear counterparts. This is due to the unique curvilinear boundary conditions as well as the curvature induced Dzyaloshinskii–Moriya-like interaction and the curvature induced anisotropy. The effects of a curvilinear geometry are best studied in 3D structures, where the curvature can have a significant spatial extent. Of these 3D structures, the simplest structure to study is the cylindrical nanowire. Here, we have simulated the magnetization reversal in cylindrical NiFe nanowires and present in situ Lorentz TEM images to support the findings of the simulations. We studied the domain formation and reversal of nanowires with two distinct diameters that give rise to a different reversal behavior. We have, thus, found that the zero-field magnetization configuration in these wires can take on a double helix type of configuration. The reversal in these structures then proceeds through the winding and unwinding of these helical configurations rather than through domain wall propagation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Isotopic gamma lines for identification of shielding materials

Identifying the constituting materials of concealed objects is crucial in a wide range of sectors, such as medical imaging, geophysics, nonproliferation, national security investigations, and so on. Existing methods face limitations, particularly when multiple materials are involved or when there are challenges posed by scattered radiation and large areal mass. Here we introduce a novel brute-force statistical approach for material identification using high spectral resolution detectors, such as HPGe. The method relies upon updated semianalytic formulae for computing uncollided flux from source of gamma radiation, shielded by a sequence of nested spherical or cylindrical materials. These semianalytical formulae make possible rapid flux estimation for material characterization via combinatorial search through all possible combinations of materials, using a high-resolution HPGe counting detector. An important prerequisite for the method is that the geometry of the objects is known (for example, from X-ray radiography). We demonstrate the viability of this material characterization technique in several use cases with both simulated and experimental data in spherical geometry.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Maximizing the quantum efficiency of microchannel plate detectors - The collection of photoelectrons from the interchannel web using an electric field

High quantum efficiency and two-dimensional imaging capabilities make the microchannel plate (MCP) a suitable detector for a sky survey instrument. The Extreme Ultraviolet Explorer satellite, to be launched in 1987, will use MCP detectors. A feature which limits MCP efficiency is related to the walls of individual channels. The walls are of finite thickness and thus form an interchannel web. Under normal circumstances, this web does not contribute to the detector's quantum efficiency. Panitz and Foesch (1976) have found that in the case of a bombardment with ions, electrons were ejected from the electrode material coating the web. By applying a small electric field, the electrons were returned to the MCP surface where they were detected. The present investigation is concerned with the enhancement of quantum efficiencies in the case of extreme UV wavelengths. Attention is given to a model and a computer simulation which quantitatively reproduce the experimental results.

Taylor, R. C.↗

In-situ imaging of nucleation and growth of superlattices from nanoscale colloidal nanoparticles

Nanoparticle-based superlattices have attracted extensive research efforts due to their versatile composition and packing-dependent optical, magnetic, electronic, catalytic, mechanical properties. Yet the experimental understanding of the thermodynamics and pathways of the crystallization processes for these systems, which govern their ultimate morphology, size, and packing structure, has for long remained underexplored. Here, this minireview highlights recent integration of liquid-phase transmission electron microscopy, which allows for real-space, real-time direct imaging of the crystallization processes at the single-particle level, with simulation and the conceptual framework established by pioneers such as Dr. A. A. Chernov. Different aspects of superlattice formation were revealed by direct imaging for the first time, such as the existence of prenucleation precursor in nonclassical crystallization, surface energy-dependent growth, and coalescence, allowing for the charting of phase coordinates and thermodynamic quantities at the nanoscale. We discuss the similarities and differences of crystal growth behaviors in atomic and nanoparticle systems, as well as engineering opportunities to fashion, shape, and achieve quality control in superlattice formation from nanoparticles, for next-generation optical and mechanical metamaterials.

36 MATERIALS SCIENCE↗

Material Inspectability Assessment Related to Lunar Construction Technology Development

For the building of lunar structures on the Moon using lunar regolith-based construction materials, ensuring their structural integrity and employing methods optimal for such tasks is crucial. In this technical memorandum (TM) the detectability of simulated void defects in a cementitious-based lunar construction material is compared between different nondestructive evaluation (NDE) methods, especially methods which have potential to be developed into space qualified instruments. Primarily, simulated voids, introduced during fabrication as foam spheres, were used for this evaluation. Furthermore, smaller, unintended void defects were used to assess the detectability. The results highlights trade-offs between the NDE methods in terms of detection limit, correct size indication, penetration depth, and potential for reduction in size, weight, and power (SWaP).

Nondestructive Evaluation↗