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At least 685 records · Page 38
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Pulse Detonation Rocket MHD Power Experiment

A pulse detonation research engine (MSFC (Marshall Space Flight Center) Model PDRE (Pulse Detonation Rocket Engine) G-2) has been developed for the purpose of examining integrated propulsion and magnetohydrodynamic power generation applications. The engine is based on a rectangular cross-section tube coupled to a converging-diverging nozzle, which is in turn attached to a segmented Faraday channel. As part of the shakedown testing activity, the pressure wave was interrogated along the length of the engine while running on hydrogen/oxygen propellants. Rapid transition to detonation wave propagation was insured through the use of a short Schelkin spiral near the head of the engine. The measured detonation wave velocities were in excess of 2500 m/s in agreement with the theoretical C-J velocity. The engine was first tested in a straight tube configuration without a nozzle, and the time resolved thrust was measured simultaneously with the head-end pressure. Similar measurements were made with the converging-diverging nozzle attached. The time correlation of the thrust and head-end pressure data was found to be excellent. The major purpose of the converging-diverging nozzle was to configure the engine for driving an MHD generator for the direct production of electrical power. Additional tests were therefore necessary in which seed (cesium-hydroxide dissolved in methanol) was directly injected into the engine as a spray. The exhaust plume was then interrogated with a microwave interferometer in an attempt to characterize the plasma conditions, and emission spectroscopy measurements were also acquired. Data reduction efforts indicate that the plasma exhaust is very highly ionized, although there is some uncertainty at this time as to the relative abundance of negative OH ions. The emission spectroscopy data provided some indication of the species in the exhaust as well as a measurement of temperature. A 24-electrode-pair segmented Faraday channel and 0.6 Tesla permanent magnet assembly were then installed on Marshall Space Flight Center's (MSFC's) rectangular channel pulse detonation research engine. Magnetohydrodynamic (MHD) electrical power extraction experiments were carried out for a range of load impedances in which cesium hydroxide seed (dissolved in methanol) was sprayed into the gaseous oxygen/hydrogen propellants. Positive power extraction was obtained, but preliminary analysis of the data indicated that the plasma electrical conductivity is lower than anticipated and the near-electrode voltage drop is not negligible. It is believed that the electrical conductivity is reduced due to a large population of negative OH ions. This occurs because OH has a strong affinity for capturing free electrons. The effect of near-electrode voltage drop is associated with the high surface-to-volume ratio of the channel (1-inch by 1-inch cross-section) where surface effects play a dominant role. As usual for MHD devices, higher performance will require larger scale devices. Overall, the gathered data is extremely valuable from the standpoint of understanding plasma behavior and for developing empirical scaling laws.

Litchford, Ron J.↗
DOE OSTI2026

Controlled Placement of Trivalent Heteroatoms in MFI Zeolite Frameworks Using Structure-Directing Agents

MFI zeolites contain distinct confining pore environments, either smaller (∼0.55 nm) channels or larger (∼0.70 nm) intersections. The substitution of trivalent heteroatoms generates Brønsted acid sites of varying acid strength, which, together with their location within different pore environments, dictates the stability of transition states via electrostatic (ion-pair) and van der Waals interactions. Here, we report that structure-directing agents (SDAs) that control Al 3+ substitutional patterns during MFI crystallization analogously position other trivalent heteroatoms (Ga 3+ , Fe 3+ , B 3+ ), altering the distribution of acid sites between channels and intersections, as probed by low-temperature (403 K) toluene methylation kinetics. Heteroatom-substituted MFI crystallized with tetrapropylammonium result in low selectivity toward p-xylene (<30%), while those crystallized using (co-)SDAs containing peripheral hydrogen-bonding groups (e.g., ethylenediamine) show high p-xylene selectivity (∼80%). These selectivities are consistent with DFT-calculated Gibbs free energy barriers for intersection-dominant and channel-dominant active site distributions, respectively. Transition states to form each xylene isomer are similar in size and charge; thus, their rate constants decrease with acid strength similarly, causing isomer selectivity to depend strongly on confinement but not on acid strength. These generalizable synthetic strategies enable independently controlling acid site strength and location in MFI zeolites and, in turn, catalytic rates and selectivities.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Infrared spectroscopy of the syn -methyl-substituted Criegee intermediate: A combined experimental and theoretical study

An IR–vacuum ultraviolet (VUV) ion-dip spectroscopy method is utilized to examine the IR spectrum of acetaldehyde oxide (CH3CHOO) in the overtone CH stretch (2νCH) spectral region. IR activation creates a depletion of the ground state population that reduces the VUV photoionization signal on the parent mass channel. IR activation of the more stable and populated syn-CH3CHOO conformer results in rapid unimolecular decay to OH + vinoxy products and makes the most significant contribution to the observed spectrum. The resultant IR–VUV ion-dip spectrum of CH3CHOO is similar to that obtained previously for syn-CH3CHOO using IR action spectroscopy with UV laser-induced fluorescence detection of OH products. The prominent IR features at 5984 and 6081 cm−1 are also observed using UV + VUV photoionization of OH products. Complementary theoretical calculations utilizing a general implementation of second-order vibrational perturbation theory provide new insights on the vibrational transitions that give rise to the experimental spectrum in the overtone CH stretch region. The introduction of physically motivated small shifts of the harmonic frequencies yields remarkably improved agreement between experiment and theory in the overtone CH stretch region. The prominent features are assigned as highly mixed states with contributions from two quanta of CH stretch and/or a combination of CH stretch with an overtone in mode 4. The generality of this approach is demonstrated by applying it to three different levels of electronic structure theory/basis sets, all of which provide spectra that are virtually indistinguishable despite showing large deviations prior to introducing the shifts to the harmonic frequencies.

Chemistry↗
DOE OSTI2024

Fracture Dynamics in Silicon Anode Solid-State Batteries

Solid-state batteries (SSBs) with silicon anodes could enable improved safety and energy density compared to lithium-ion batteries. However, degradation arising from the massive volumetric changes of silicon anodes during cycling is not well understood in solid-state systems. Here, we use operando X-ray computed microtomography to reveal micro- to macro-scale chemo-mechanical degradation processes of silicon anodes in SSBs. Mud-type channel cracks driven by biaxial tensile stress form across the electrode during delithiation. We also find detrimental cracks at the silicon/ solid electrolyte interface that form due to local reaction competition between neighboring domains of different sizes. Continuum phase-field damage modeling quantifies stress-driven channel cracking and shows that the lithiated silicon stress state is critical for determining the extent of interfacial fracture. This work reveals the mechanisms that govern SSBs compared to conventional lithium-ion batteries and provides guidelines for engineering chemomechanically resilient electrodes for high-energy batteries.

25 ENERGY STORAGE↗
NASA NTRS1978

Complementary DMOS-VMOS integrated circuit structure

A high speed CMOS formed on a single semiconductor substrate includes a DMOS having an asymmetric channel and a VMOS with a relatively short channel length. The short channel length of the VMOS is achieved by forming a double diffusion along one edge of a V groove, or ion implanting boron into the apex of the V groove and diffusing a single layer to a relatively deep depth along both edges of the groove.

Jhabvala, M. O.↗
NASA NTRS1993

Observations of the nightside Venus ionosphere: Final encounter of the Pioneer Venus Orbiter Ion Mass Spectrometer

During the last orbital sequences of the Pioneer-Venus spacecraft prior to final encounter and atmospheric entry, data were obtained by the Orbiter Ion Mass Spectrometer (OIMS) at the lowest periapsis altitudes of the mission. These data verified OIMS observations of the nightside ionospheric peak reported earlier in the mission, and revealed additional details related to composition, energetics and maintenance of the nightside ionosphere. OIMS observations of the ion peak during the final encounter sequence are compared with radio occultation data and OIMS peak observations obtained earlier. OIMS ion density and Orbiter Electron Temperature Probe (OETP) electron density are found to correlate near the peak. Coupling of mass channels 30 and 32 during nightside passes is observed and its interpretation considered. Changes in high altitude composition of the nightside ionosphere, especially the relative changes in O(+) and H(+), are described.

Cloutier, P. A.↗
NASA NTRS1993

Observations of the Nightside Venus Ionosphere: Final Encounter of the Pioneer Venus Orbiter Ion Mass Spectrometer

During the last orbital sequences of the Pioneer Venus spacecraft prior to final encounter and atmospheric entry, data were obtained by the Orbiter Ion Mass Spectrometer (OIMS) at the lowest periapsis altitudes of the mission. These data verified OIMS observations of the nightside ionospheric peak reported-earlier in the mission, and revealed additional details related to composition, energetics and maintenance of the nightside ionosphere. OIMS observations of the ion peak during the final encounter sequence are compared with radio occultation data and OIMS peak observations obtained earlier. OIMS ion density and Orbiter Electron Temperature Probe (OETP) electron density are found to correlate near the peak. Coupling of mass channels 30 and 32 during nightside passes is observed and its interpretation considered. Changes in high altitude composition of the nightside ionosphere, especially the relative changes in O(+) and H(+), are described.

Cloutier, P. A.↗
DOE OSTI2022

Investigating the role of strangeness in baryon–antibaryon annihilation at the LHC

Annihilation dynamics plays a fundamental role in the baryon–antibaryon interaction ($B–\bar{B}$) at low-energy and its strength and range are crucial in the assessment of possible baryonic bound states. Experimental data on annihilation cross sections are available for the $p–\bar{p}$ system but not in the low relative momentum region. Data regarding the $B–\bar{B}$ interaction with strange degrees of freedom are extremely scarce, hence the modeling of the annihilation contributions is mainly based on nucleon–antinucleon ($N–\bar{N}$) results, when available. In this letter we present a measurement of the $p–\bar{p}$, $p–\bar{Λ}$⊕$p–{Λ}$ and $Λ–\bar{Λ}$ interaction using correlation functions in the relative momentum space in high-multiplicity triggered pp collisions at $\sqrt{s}$=13 TeV recorded by ALICE at the LHC. In the $p–\bar{p}$ system the couplings to the mesonic channels in different partial waves are extracted by adopting a coupled-channel approach with recent χEFT potentials. The inclusion of these inelastic channels provides good agreement with the data, showing a significant presence of the annihilation term down to zero momentum. Predictions obtained using the Lednický–Lyuboshits formula and scattering parameters obtained from heavy-ion collisions, hence mainly sensitive to elastic processes, are compared with the experimental $p–\bar{Λ}$⊕$p–{Λ}$ and $Λ–\bar{Λ}$ correlations. The model describes the $Λ–\bar{Λ}$ data and underestimates the $p–\bar{Λ}$⊕$p–{Λ}$ data in the region of momenta below 200 MeV/c. The observed deviation indicates a different contribution of annihilation channels to the two systems containing strange hadrons.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS2002

Cross Scale Coupling of Alfven Turbulence in the Polar Wind Region

Ionosphere-magnetosphere coupling phenomena are extremely complex and diverse, involving a whole series of processes operating over a wide range of spatial and temporal scales. One of the fundamental aspects of understanding this coupling is the polar wind, which is a dominant mechanism of mass transport from the ionospheric source region to the magnetosphere and strongly influences the plasma parameters above the F2 density peak. The combined effects of photoelectrons, and the ponderomotive force will be presented based on our polar wind model. The presence of photoelectrons and low frequency oscillations (that create the ponderomotive force) increase ion outflows. It is also demonstrated that large-amplitude low-frequency waves (LFW) may generate lower hybrid waves (LHW) in the auroral zone. The excitation of LHW by a LF wave may lead to the appearance of an additional channel of energy transfer from, for example, Alfven or fast magnetosonic waves, to particles. This process then influences the formation of the plasma distribution function at the expense of acceleration in the tail of the distribution during the collapse of the LHW. The ion energization due to the LHW can be comparable with that produced by the ponderomotive force of the LFW.

Khazanov, George V.↗
DOE OSTI2025

Imaging a light-induced molecular elimination reaction with an X-ray free-electron laser

Tracking the motion of individual atoms during chemical reactions represents a severe experimental challenge, especially if several competing reaction pathways exist or if the reaction is governed by the correlated motion of more than two molecular constituents. Here we demonstrate how ultrashort X-ray pulses combined with coincident ion imaging can be used to trace molecular iodine elimination from laser-irradiated diiodomethane (CH 2 I 2 ), a reaction channel of fundamental importance but small relative yield that involves the breaking of two molecular bonds and the formation of a new one. We map bending vibrations of the bound molecule, disentangle different dissociation pathways, image the correlated motion of the iodine atoms and the methylene group leading to molecular iodine ejection, and trace the vibrational motion of the formed product. Our results provide a quantitative mechanistic picture behind previously suggested reaction mechanisms and prove that a variety of geometries are involved in the molecular bond formation.

Atomic and molecular interactions with photons↗
DOE OSTI2021

Infrared spectroscopy of RG–Co + (H 2 O) complexes (RG = Ar, Ne, He): The role of rare gas “tag” atoms

RG n –Co + (H 2 O) cation complexes (RG = Ar, Ne, He) are generated in a supersonic expansion by pulsed laser vaporization. Here, complexes are mass-selected using a time-of-flight spectrometer and studied with infrared laser photodissociation spectroscopy, measuring the respective mass channels corresponding to the elimination of the rare gas “tag” atom. Spectral patterns and theory indicate that the structures of the ions with a single rare gas atom have this bound to the cobalt cation opposite the water moiety in a near-C 2v arrangement. The O–H stretch vibrations of the complex are shifted compared to those of water because of the metal cation charge-transfer interaction; these frequencies also vary systematically with the rare gas atom attached. The efficiencies of photodissociation also vary with the rare gas atoms because of their widely different binding energies to the cobalt cation. The spectrum of the argon complex could only be measured when at least three argon atoms were attached. In the case of the helium complex, the low binding energy allows the spectra to be measured for the low-frequency H–O–H scissors bending mode and for the O–D stretches of the deuterated analog. The partially resolved rotational structure for the antisymmetric O–H and O–D stretches reveals the temperature of these complexes (6 K) and establishes the electronic ground state. The helium complex has the same 3 B 1 ground state as the tag-free complex studied previously by Metz and co-workers (2013), but the A rotational constant is contaminated by vibrational averaging from the bending motion of the helium.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Off-state magnetoresistance in long-channel germanium Schottky-barrier MOSFETs

An increasing magnetic field perpendicular to an undoped semiconductor surface at low temperature is known to strengthen the binding of localized electrons to stationary ions, as the wavefunction's tails evolve from exponential to Gaussian. It is also known that application of a high bias voltage to a depleted semiconductor can liberate bound charge and induce a large drop in electrical resistance. We connect these established results to experimental electrical transport measurements on off-state germanium Schottky-barrier metal–oxide–semiconductor field-effect transistor (MOSFETs) with an aluminum oxide insulating dielectric and platinum germanide contacts. We make measurements at the three distinct orientations of the magnetic field with respect to the substrate and the current. At 6 K, we observe sharp attenuation of current by more than 2 orders of magnitude, within 60 mT, at a crossover magnetic field perpendicular to the substrate. A 1 T magnetic field attenuates the current by more than 4 orders of magnitude. The strength of the attenuation and the value of the crossover field are controlled by both the gate–source and drain–source voltages. The attenuation is much weaker when the magnetic field is parallel to the current. Finally, we orient the magnetic field parallel to the substrate, but perpendicular to the current, allowing us to distinguish charge hopping at the oxide interface from charge hopping in the bulk. In conclusion, this large off-state magnetoresistance can be exploited for cryogenic magnetic- and photo-detection, and for high-bias, low-leakage MOSFETs.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Nonresonant Diffusion in Alpha Channeling

The gradient of fusion-born alpha particles that arises in a fusion reactor can be exploited to amplify waves, which cool the alpha particles while diffusively extracting them from the reactor. Furthermore, the corresponding extraction of the resonant alpha particle charge has been suggested as a mechanism to drive rotation. By deriving a coupled linear-quasilinear theory of alpha channeling, we show that, for a time-growing wave with a purely poloidal wave vector, a current in the nonresonant ions cancels the resonant alpha particle current, preventing the rotation drive but fueling the fusion reaction.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1985

Growth of zeolite crystals in the microgravity environment of space

Zeolites are hydrated, crystalline aluminosilicates with alkali and alkaline earth metals substituted into cation vacancies (Equation A) M(sub 2/n) 0-Al203-XSi02-YH20 A They have a uniform internal channel system which makes them ideal for use as catalysts and adsorbents. Presently zeolite materials constitute a 1-2 mi 11 ion dol lar/year business. Typically zeolite crystals are 3-8 µm along their characteristic dimension (e.g., edge). Larger zeolite crystals are desirable. Large crystals will allow more detail characterization of their complex crystal structures. Also, they will help improve reactor performance, may be used as membrane separators, and they should enhance basic studies in molecular diffusion in zeolites. Large zeolite crystals have been produced (100-200 µm) ; however, they have taken restrictively long times to grow. It has been proposed if the rate of nucleation or in some other way the number of nuclei can be lowered, fewer, larger crystals will be formed. provide an ideal condition to achieve rapid growth of large zeolite crystals (e.g., >l00 µm). Since settling crystals are believed to cause secondary nucleation, by limiting crystal movement by suspension in the zero gravity environment, fewer crystals will form, but they will grow larger. The objective of the project is to establish if large zeolite crystals can be formed rapidly in space.

A. Sacco, Jr.↗
NASA NTRS1987

Change in interplanetary shock acceleration preceding STIP Interval 17

The intensity and frequency of shock acceleration events in the interplanetary medium decreased dramatically in early 1985. Low energy ions were observed by IMP 8 at 1 AU and Voyagers 1 and 2 at 22 and 16 AU, respectively. Voyager 1 was at 25 deg heliographic latitude while IMP 8 and Voyager 2 were near the solar equatorial plane. The decrease in low energy shock events led to a drop in the average ion flux by a factor of 20 to 50. It started about day 10 of 1985 in the approximately .5 MeV channel on IMP8 and took approximately 75 days to reach the new, lower, background level. The decrease at the Voyagers started approximately 50 days later. The time delay between the start of the decrease at IMP and at Voyager 2 implies that decrease was convected outward with a velocity of approximately 535 km/sec. The intensity and frequency of interplanetary shock events remained at the lower level for at least 1.5 years.

Gold, R. E.↗
NASA NTRS1989

Solar flare hard and soft x ray relationship determined from SMM HXRBS and BCS data

The exact nature of the solar flare process is still somewhat a mystery. A key element to understanding flares if the relationship between the hard x rays emitted by the most energetic portions of the flare and the soft x rays from other areas and times. This relationship was studied by comparing hard x ray light curved from the Hard X-Ray Burst Spectrometer (HXRBS) with the soft x ray light curve and its derivation from the Bent Crystal Spectrometer (BCS) which is part of the X-Ray Polychrometer (XRP), these instruments being on the Solar Maximum Mission spacecraft (SMM). Data sample was taken from flares observed with the above instruments during 1980, the peak of the previous maximum of solar activity. Flares were chosen based on complete coverage of the event by several instruments. The HXRBS data covers the x ray spectrum from about 25 keV to about 440 keV in 15 spectral channels, while the BCS data used covers a region of the Spectrum around 3 angstroms including emission from the Ca XIX ion. Both sets of data were summed over their spectral ranges and plotted against time at a maximum time resolution of around 3 seconds. The most popular theory of flares holds that a beam of electrons produces the hard x rays by bremsstrahlung while the soft x rays are the thermal response to this energy deposition. The question is whether the rate of change of soft x ray emission might reflect the variability of the electron beam and hence the variability of the hard x rays. To address this, we took the time derivative of the soft x ray light curve and compared it to the hard flares, 12 of them showed very closed agreement between the soft x ray derivative and the hard x ray light curve. The other five did not show this behavior but were similar to each other in general soft x ray behavior. Efforts to determine basic differences between the two kinds of flares continue. In addition the behavior of soft x ray temperature of flares was examined.

Toot, G. David↗
NASA NTRS1993

Plasma waves observed at low altitudes in the tenuous Venus nightside ionosphere

The Pioneer Venus (PV) Orbiter Electric Field Detector (OEFD) measured many plasma wave bursts throughout the low altitude ionosphere during the final entry phase of the spacecraft. Apart from 100 Hz bursts observed at very low altitudes (approx. 130 km), the bursts fall into two classes. The first of these is a wideband signal that is observed in regions of low magnetic field, but average densities, in comparison to the prevailing ionospheric condition. This wideband signal is not observed in the 30 kHz channel of the OEFD, but is resricted to the 5.4 kHz channel and lower. Since these bursts are observed with roughly constant burst rate above 160 km altitude, we attribute them to ion acoustic mode waves generated by precipitating solar wind electrons. The second type of signal is restricted to 100 Hz only, and is observed in the regions of low electron beta, consistent with whistler-mode waves. These waves could be generated by lightning in the Venus atmosphere if the vertical component of the magnetic field greater than 3.6 nT. Because the ionosphere is very different during the entry phase, compared to the ionosphere as observed early in the Pioneer Venus mission, any conclusions regarding the source of the plasma waves detected during entry phase cannot be applied directly to the earlier observations.

Strangeway, R. J.↗
NASA NTRS1993

Plasma Waves Observed at Low Altitudes in the Tenuous Venus Nightside Ionosphere

The Pioneer Venus Orbiter Electric Field Detector (OEFD) measured many plasma wave bursts throughout the low altitude ionosphere during the final entry phase of the spacecraft. Apart from 100 Hz bursts observed at very low altitudes (approx. 130 km), the bursts fall into two classes. The first of these is a wideband signal that is observed in regions of low magnetic field, but average densities, in comparison to the prevailing ionospheric condition. This wideband signal is not observed in the 30 kHz channel of the OEFD, but is restricted to the 5.4 kHz channel and lower. Since these bursts are observed with roughly constant burst rate above 160 km altitude, we attribute them to ion acoustic mode waves generated by precipitating solar wind electrons. The second type of signal is restricted to 100 Hz only, and is observed in regions of low electron beta, consistent with whistler-mode waves. These waves could be generated by lightning in the Venus atmosphere if the vertical component of the magnetic field greater than 3.6 nT. Unfortunately, the spacecraft spin axis is mainly horizontal, and only that component of magnetic field can be measured. Alternatively, the 100 Hz bursts could be generated locally through gradient drift instabilities, provided the ambient magnetic field is horizontal. Because the ionosphere is very different during the entry phase, compared to the ionosphere as observed early in the Pioneer Venus mission, any conclusions regarding the source of the plasma waves detected during entry phase cannot be applied directly to the earlier observations.

Strangeway, R. J.↗