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At least 685 records · Page 38
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Ultra-wide bandgap β-Ga 2 O 3 films: Optical, phonon, and temperature response properties

Optical and phonon interactions of Ga 2 O 3 thin films with nanocrystalline morphology were studied at extreme temperatures. The films were grown using a sputtering technique and analyzed via temperature response transmission, Raman scattering, and high-resolution deep-UV photoluminescence (PL). Raman modes indicated that the structure corresponds to the β-phase. The optical-gap at the range of 77–620 K exhibited a redshift of ~200 meV, with a temperature coefficient of ~0.4 meV/K. The optical-gap at room-temperature is 4.85 eV. The electron–phonon interaction model at that temperature range pointed to a low energy phonon, ~31 meV, that is involved in the thermal properties of the optical-gap. Detailed Urbach energy analysis indicated that defects are the dominant mechanism controlling the band-edge characteristics even at an elevated temperature regime where phonon dominance is usually expected. Defects are attributed to the disordered forms of graphite that were detected via Raman scattering and to the granular morphology of the film. A deep-UV laser with an above bandgap exaction line of 5.1 eV was employed to map the PL of the films. The highly resolved spectra, even at room-temperature, show a strong emission of ~3.56 eV attributed to self-trapped holes (STHs). The STH is discussed and modeled in terms of the self-trapped exciton. Moreover, a very distinct but low-intensity emission was found at 4.85 eV that agrees with the value of the optical-gap and is attributed to bandgap recombination. The intensity ratio between the STH and that of the bandgap was found to be 6:1.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Enhanced antiferromagnetic resonance linewidth in NiO/Pt and NiO/Pd

In this paper, we investigate the enhancement of the antiferromagnetic damping in the sintered NiO-HM (where HM is heavy metal) granular systems having NiO/HM interfaces, where HM = Pt or Pd. Under the assumption of the spin pumping model, we derive the effective interfacial damping conductance g eff , the parameter which characterizes the upper-bound estimate of the spin pumping effect, to be 12 ± 1 nm ₋2 and 5 ± 1 nm ₋2 for the NiO/Pt and the NiO/Pd interfaces, respectively, at room temperature. We report $g_{\text{eff}}$ experimentally derived in this study are an important milestone in antiferromagnetic spintronics, giving a guideline for various spin current transfer and spin interaction phenomena with antiferromagnets where the spin mixing conductance is involved.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2026

Optimal binning of correlated measurements

Experimental measurements are commonly represented on a discrete grid, requiring a balance between granularity and statistical noise. Two strategies have traditionally been used to improve such representations: selecting an appropriate bin width to control discretization error and applying kernel-based smoothing to suppress fluctuations. Despite their shared goal, these approaches have largely developed independently, without a unified statistical description of how discretization and correlation jointly determine measurement precision. Here, we extend the discussion of optimal interval averaging to a correlation-aware setting by Gaussian process regression, which explicitly accounts for correlations among neighboring bins. Starting from first principles, we derive the mean-squared error of discretized measurements and obtain closed-form asymptotic expressions for the optimal bin width and correlation length. When recast in reduced variables, the theory reveals distinct universal scaling laws governing the error in the correlation-free and correlation-controlled regimes. Characterized by intrinsically smooth intensity profiles and counting-based statistics, neutron scattering measurements are well suited for demonstrating the enhanced error contraction enabled by inter-bin correlations. We show that such improvement is achievable over the experimentally accessible Q-range and across multiple instruments and material systems. These results show that explicitly accounting for correlations systematically reshapes the limits of precision in discretized, noise-limited measurements. More broadly, the framework provides a transferable statistical foundation for optimizing data representation, inference, and experimental design across the physical and data sciences.

Tung, Chi-Huan [ORNL] (ORCID:0000000221972074)↗
NASA NTRS2015

Pathways Intern Report

During my time at NASA, I worked with the Granular Mechanics and Regolith Organization (GMRO), better known as Swamp Works. The goal of the lab is to find ways to utilize resources found after the astronaut or robot has landed on another planet or asteroid. This concept is known as in-situ resource utilization and it is critical to long term missions such as those to Mars. During my time here I worked on the Asteroid and Lava Tube Free Flyer project (ALTFF). A lava tube, such as the one shown in figure 1, is a long tear drop shaped cavern that is produced when molten lava tunnels through the surrounding rock creating large unground pathways. Before mining for resources on Mars or on asteroids, a sampling mission must be done to scout out useful resource deposits. ALTFF's goal is to provide a low cost, autonomous scout robot that can sample the surface and return to the mother ship or lander for further processing of the samples. The vehicle will be looking for water ice in the regolith that can be processed into either potable water, hydrogen and oxygen fuel, or a binder material for 3D printing. By using a low cost craft to sample, there is much less risk to the more expensive mother ship or lander. While my main task was the construction of a simulation environment to test control code in and the construction of the asteroid free flyer prototype, there were other tasks that I performed relating to the ALTFF project.

Pathways↗
DOE OSTI2026

Determining the Solubility Behavior of Kogarkoite in Simulated Nuclear Waste

Kogarkoite (Na 3 FSO 4 ) is a sparingly soluble fluoride–sulfate double salt that has been identified in high level nuclear waste sludge at the Hanford Site and, more recently, in sludge batch compilation samples at the Savannah River Site (SRS). Due to its complex dissolution behavior, which exhibits an inverse dependence on sodium ion activity, the presence of this mineral poses significant challenges to waste retrieval and processing. Incomplete dissolution during sludge washing can lead to the retention of fluoride and sulfate in the high-level waste feed, potentially causing the formation of corrosive, immiscible molten salt layers, known as "glass gall,” in vitrification melters. Current efforts to optimize flowsheet parameters and wash-water volumes are hindered by the absence of a commercially available, certified reference material, which prevents the accurate calibration of analytical methods and the verification of dissolution kinetics. To address this critical gap, this research focuses on the laboratory synthesis of pure Kogarkoite to serve as a standard for comprehensive solubility and washing performance testing. A coupled synthesis and simulant campaign was executed using an evaporative crystallization protocol designed to replicate the dynamic concentration effects observed in tank farm operations. Thirteen simulant matrices were prepared by dissolving systematically varied ratios of sodium fluoride (NaF) and sodium sulfate (Na 2 SO 4 ) in deionized water under three distinct caustic regimes: 0.0 g (control), 4.0 g (~1 M), and 12.0 g (~3 M) sodium hydroxide (NaOH). While thermodynamic equilibrium models suggest that high-caustic environments should favor the stability of the double salt7, results from this evaporative study at 25 0 C revealed a distinct kinetic divergence. Simulants with high hydroxide loading predominantly yielded large, blocky crystals of sodium sulfate decahydrate (Na 2 SO 4 .10H 2 O). Successful synthesis of pure Kogarkoite was achieved exclusively in specific NaOH-free compositional windows, where the precipitate manifested as fine, opaque granular aggregates. Ion chromatography (IC) analysis confirmed phase purity through the simultaneous stoichiometric depletion of both fluoride and sulfate from the supernatant. This successful synthesis establishes a reproducible route to generate bulk Kogarkoite, enabling the subsequent phase of quantitative dissolution testing using inhibited water to optimize sludge-batch assembly.

Sarker, Md Sharif [Florida International Univ. (FI↗
DOE OSTI2023

A Primer on Nuclear "Recoil" Data

For many years the ENDF-6 format has existed to contain evaluated nuclear data. One primary driver for the format and the data is neutron transport calculations. Evaluated data can be processed by a code like NJOY into either continuous energy form (ACE format) for Monte Carlo codes like MCNP or into multi-group form (NDI tables) for deterministic codes like Partisn. The reaction cross sections are found in the MF 3 section of the ENDF-6 format. If the reaction produces one or more neutrons as outputs, then secondary neutron data must also be given in MF 4,5 or 6 sections of the format. Energy and angular distributions for the output neutrons must be given in one of several available formats. The most general formats are found in MF 6. MF 4 is for angular distributions, MF 5 is for Energy distributions, and MF 6 contains both. In recent years, more interest has developed in the other output particles (i.e., the “recoil” particles) from neutron induced reactions. This has been driven by interest in charged particle transport and in more specialized partial kermas. ( A separate total neutron kerma has been available for a long time.) Partial kermas are a breakdown of the Kinetic Energy Released into the MAterial by output particle or by neutron reaction. The sum of the partial kermas should be equal to the total kerma on a group-wise basis. The ENDF-6 format is general enough for these new data requirements. Ideally, evaluated data would exist for every output particle (including the secondary neutrons) from every neutron-induced reaction. In the MF 6 format section, data for multi-particle outputs may be entered using the LAW =1 option. This option explicitly allows energy and angular output distributions for each particle produced in the reaction. Such information should preserve the balance between partial kermas and the total kerma at the groupwise level as well as the individual particle averaged energies. For simpler 2-body reactions, LAW = 2 is available. This allows the evaluation to specify only enough data to specify the 2-body reaction fully. Such a simplification does not exist for 3 (or more) body breakups. A simplified form of LAW 2, i.e., LAW 3, also exists to generate approximate recoil output distributions in the absence of full data. However, evaluated data does not generally exist at this fine granularity for reactions involving more than 2 output particles ( e.g., the 3-body break-up reaction). When the multi-body detailed output distribution data is not available, LAW=6 may be employed in NJOY. LAW 6 produces approximate output distributions for all the particles produced in the reaction. Just like in the 2-body case, the smaller particles will generally carry off more energy. At any particular energy, the balance between the sum of the partial kermas and the total kerma will not necessarily be preserved. However, the average energy of each output particle from a reaction is preserved.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2019

Origin of enhanced anisotropy in FePt-C granular films revealed by XMCD

We study the effect of carbon segregants on the spin and orbital moments of L 1 0 FePt granular media using x-ray magnetic circular dichroism (XMCD) spectroscopy and report an effective decoupling of the structural film properties from the magnetic parameters of the grains. The carbon concentration reduces the grain size from (200 ± 160) nm 2 down to (50 ± 20) nm 2 for 40 mol. %C and improves sphericity and the order of grains, while preserving the crystalline order, spin and orbital moments, and perpendicular magnetocrystalline anisotropy. Here, we identify the primary cause of enhanced saturation and coercive fields as the reduced demagnetization fields of individual grains. The ability to shrink grains without impairing their magnetic properties is a critical requirement for the commercialization of Heat-Assisted Magnetic Recording.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Effect of Heat Input on M-A Constituent and Toughness of Coarse Grain Heat-Affected Zone in an X100 Pipeline Steel

The joining of 14.8 mm thick pipeline steels was achieved with developments in high-power fiber laser by laser welding or hybrid laser arc welding. However, there were few studies on the effects of single-pass welding heat input on the M-A component and impact toughness of the heat-affected zone. In this study, single-pass welding thermal cycle was performed on Gleeble 3800 thermal simulation tester; the effect of heat input on microstructure, M-A constituent, hardness, toughness and corrosion resistance of coarse-grained heat-affected zone of X100 pipeline steel was studied. The results showed: The microstructure was lath martensite with a heat input of less than 8 kJ/cm. When the heat input was 26-36 kJ/cm, the microstructure was granular bainite. The heat input had not obvious effect on hardness (only 16% hardness reduction in this heat input arrange). However, the impact toughness was strongly influenced by heat input, with an 88% hardness reduction compared to base metal, due to M-A constituent and prior austenite grain size. Few finer M-A constituent dispersing in austenite was obtained instead of necklace-like M-A constituent at the prior austenite grain boundary when the welding heat input was less than 15 kJ/cm, which was beneficial to improve the impact toughness and corrosion resistance of welded joints of X100 pipeline steels.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Single particle trace element analysis of uranium oxide standards with laser-induced breakdown spectroscopy

Femtosecond Laser-Induced Breakdown Spectroscopy (LIBS) was used to analyze over 1000 individual particles of uranium oxide trace element standard CRM124. Intra-granular analysis showed elemental concentrations were consistent across different surface locations on each uranium grain. However, inter-granular comparison revealed large heterogeneity between different grains of the same sample. By comparing the distribution of elemental concentrations across the particle populations, we were able to correctly identify a manufacturing process involving wet chemistry, rather than a dry mixing of two powders to give an overall chemical average. In conclusion, this demonstrates the utility of LIBS as a large-scale single particle analysis tool for nuclear forensics.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2025

Interplay of surface energy and rheology in biopolymer soil enhancement

Biopolymers such as xanthan gum (XG) and locust bean gum (LBG) hold great potential as eco-friendly alternative soil binders. In this work, we investigated the impact of XG/LBG mixtures on the unconfined compressive strength (UCS) of sand. The high strength of dry biopolymer/sand arises from the cohesion between solid polymer films and sand particles which supported by work of adhesion calculation and soil mechanics measurement. LBG exhibits much lower sand reinforcement efficacy because polymers unevenly distributed within sand matrix. The formation of a core-shell structure in LBG/sand is an interplay of surface free energy and viscoelastic properties of polymer solutions. This structure is altered when LBG mixed with XG at varying ratios as those physical properties changed due to the complexity of polymer chains association. By probing these factors, we aim to elucidate the role of surface energies and polymer physics in governing the strength of the sand/polymer network, thereby contributing to a more comprehensive understanding polymer-sand interface. The low strength of gels (G’ ∼10Pa) cannot solely account for the increased UCS of wet sand over 10 kPa. Instead, the high strength of biopolymer/sand is more likely derived from the granular particles with biopolymers as solid glue.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Microstructural Evolution and Toughness of the Various HAZs in 1300-MPa-Grade Ultrahigh-Strength Structural Steel

The effect of heat input on the microstructure and toughness of simulated subregions was investigated by welding thermal simulations and Charpy impact tests. The results indicate that the microstructures of the simulated coarse and fine grain heat affected zone (CGHAZ and FGHAZ) gradually changed from lath martensite to a mixture of lath martensite/lath bainite and finally to granular bainite with the increase in heat input. The microstructure of the simulated intercritical heat affected zone (ICHAZ) was mainly composed of granular bainite and blocky martensite regardless of heat input. When the heat input increased, the toughness of the simulated CGHAZ and ICHAZ continuously decreased. Nevertheless, the simulated FGHAZ still displayed good toughness (53.16 J) due to its fine structure. The occurrence of martensite-austenite (M-A) constituents was the main reason for the decrease in crack initiation energy of the simulated CGHAZ and ICHAZ at high values of heat input, and the toughness deteriorated as the size of M-A constituents increased. It should be noted that high-misorientation packet and block boundaries can effectively deviate or arrest the propagation of microcracks. When the heat input was in the approximate range of 8.63-14.95 kJ cm{sup −1}, all of the simulated subregions exhibited good toughness.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Epitaxial Growth of Large-Scale 2D CrTe 2 Films on Amorphous Silicon Wafers With Low Thermal Budget

2D van der Waals (vdW) magnets open landmark horizons in the development of innovative spintronic device architectures. However, their fabrication with large scale poses challenges due to high synthesis temperatures (>500 °C) and difficulties in integrating them with standard complementary metal-oxide semiconductor (CMOS) technology on amorphous substrates such as silicon oxide (SiO 2 ) and silicon nitride (SiN x ). Here, a seeded growth technique for crystallizing CrTe 2 films on amorphous SiN x /Si and SiO 2 /Si substrates with a low thermal budget is presented. This fabrication process optimizes large-scale, granular atomic layers on amorphous substrates, yielding a substantial coercivity of 11.5 kilo-oersted, attributed to weak intergranular exchange coupling. Field-driven Néel-type stripe domain dynamics explain the amplified coercivity. Moreover, the granular CrTe 2 devices on Si wafers display significantly enhanced magnetoresistance, more than doubling that of single-crystalline counterparts. Current-assisted magnetization switching, enabled by a substantial spin–orbit torque with a large spin Hall angle (85) and spin Hall conductivity (1.02 × 10 7 ℏ/2e Ω -1 m -1 ), is also demonstrated. These observations underscore the proficiency in manipulating crystallinity within integrated 2D magnetic films on Si wafers, paving the way for large-scale batch manufacturing of practical magnetoelectronic and spintronic devices, heralding a new era of technological innovation.

2D magnetic thin films↗
DOE OSTI2023

Studies of time resolution, light yield, and crosstalk using SiPM-on-tile calorimetry for the future Electron-Ion Collider

We recently proposed a high-granularity calorimeter insert for the Electron-Ion Collider (EIC) that is based on plastic scintillator tiles readout with silicon photomultipliers. In this work, we concretize its design by characterizing its building blocks with measurements of light yield, optical crosstalk, and timing resolutions using cosmic-rays, an LED, and a beta source. We also compared two approaches for the optical isolation of cells: "megatiles" with grooved boundaries between cells, and a 3D-printed plastic frame hosting individual cells. Further, we found that the latter suppresses optical crosstalk to negligible levels while providing an easier assembly method. Overall, these performance studies can help inform calorimeter design and realistic simulations of 5D showers (time, energy, position) for the EIC and other experiments.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Microscale mechanical modeling of deformable geomaterials with dynamic contacts based on the numerical manifold method

Abstract Micromechanical modeling of geomaterials is challenging because of the complex geometry of discontinuities and potentially large number of deformable material bodies that contact each other dynamically. In this study, we have developed a numerical approach for micromechanical analysis of deformable geomaterials with dynamic contacts. In our approach, we detect contacts among multiple blocks with arbitrary shapes, enforce different contact constraints for three different contact states of separated, bonded, and sliding, and iterate within each time step to ensure convergence of contact states. With these features, we are able to simulate the dynamic contact evolution at the microscale for realistic geomaterials having arbitrary shapes of grains and interfaces. We demonstrate the capability with several examples, including a rough fracture with different geometric surface asperity characteristics, settling of clay aggregates, compaction of a loosely packed sand, and failure of an intact marble sample. With our model, we are able to accurately analyze (1) large displacements and/or deformation, (2) the process of high stress accumulated at contact areas, (3) the failure of a mineral cemented rock samples under high stress, and (4) post-failure fragmentation. The analysis highlights the importance of accurately capturing (1) the sequential evolution of geomaterials responding to stress as motion, deformation, and high stress; (2) large geometric features outside the norms (such as large asperities and sharp corners) as such features can dominate the micromechanical behavior; and (3) different mechanical behavior between loosely packed and tightly packed granular systems.

58 GEOSCIENCES↗
DOE OSTI2019

Significance of Finish Cooling Temperature to Microstructure and Property Relationship of Low-Carbon V-N-Cr Microalloyed High-Strength Steel

Herein, three final cooling temperatures were employed to achieve high strength and toughness communication in the V-N-Cr microalloyed steels. This study shows that V-N-Cr microalloyed steel primarily consisted of ferrite, granular bainite, acicular ferrite, and a small quantity of M/A phase at the final cooling temperature of 600 °C, while the polygonal ferrite, lamellar bainite, granular bainite, and a small fraction of acicular ferrite were obtained at 450 °C. The width of lamellar bainite was ~ 200-400 nm, and acicular ferrite was composed of fine non-parallel ferrite platelet structures with high dislocations densities. As the final cooling temperature decreased further, the microstructure included granular bainite and lath bainite at 350 °C. The nanoscale precipitates of V-N-Cr microalloyed steel were divided into two types, large-scale precipitates near the grain boundary that precipitated at high temperatures and small precipitates of diameter 5-10 nm at low temperatures, which significantly contributed toward strength. The hot rolled low-carbon V-N-Cr microalloy steel exhibited optimal mechanical properties at the final rolling temperature of 830 °C, as well the final cooling temperature was 450 °C. The highest yield strength and tensile strength of V-N-Cr microalloyed steel were 835 MPa and 989 MPa, respectively. The outstanding impact toughness of 161 J tested at − 60 °C was received. The transformation strengthening and precipitation hardening played a crucial role in affecting the thermo-mechanical properties.

36 MATERIALS SCIENCE↗
NASA NTRS2013

Kennedy Space Center: Swamp Works

When I began my internship with the Granular Mechanics and Regolith Operations laboratory (GMRO), also known as Swamp Works, I was given the unique opportunity to shadow many teams working on various projects, and decide what projects I wanted to take part in. Before I go into details of my experiences at Swamp Works, I would like to take a moment to explain what I discovered Swamp Works to be. Swamp Works is a family of hardworking, dedicated, and driven people from various backgrounds and skill sets. These people all work to advance technologies and make science fiction science fact through means of rapid prototyping. They support and encourage failure as an option when learning new things, as long as lesson learned from said failure. In fact, their motto states "Fail, Fast, Forward." What this means is, not if but when one fails he or she must do so quickly and spring forward from the failure so that his or her progress is not delayed. With this acceptance, it provided me the confidence to dive into a multitude of projects working in various fields and with a wide range of skill sets. The first project I joined was Badger. My motivation for taking on this project was the opportunity I would have to obtain valuable experience working with 3D modeling and 3D printing technologies. Badger was a digging apparatus to be used in a highly dusty environment in a material known as Regolith. Regolith is a scientific term for the dirt or top soil found on planetary bodies. Regolith contains a large quantity of sediments less than lOppm and as a result poses a challenge of keeping it out of any cracks and crevices. Furthermore, regolith can create high levels of electrostatic energy, which can prove damaging to sensitive electrical hardware. With these characteristics in mind, I decided to take on the task of designing and manufacturing a dust proof cover for the sensitive electrical hardware. When I began this project, I did not have the slightest idea as to how to use 3D modeling software or a means of manufacturing a viable product. As I went along with variants of the design, I became very proficient with a 3D modeling program known as CREO 2.0. Upon completion of my 3D design, I then had the task of manufacturing and having, in my hands, a usable model. To do this I had to work with additive printing technologies also known as 3D printing. Through my experiences working with Badger, I realized that 3D modeling is the focal point in much of engineering. With this in mind, I have embraced this fact and decided to further my experience with this software so that I may become a more valuable asset to any firm later in my career. Mid-way through work with Badger, I picked up another project in which I found much interest. I ha~ the opportunity to work side by side with a materials and composites guru in manufacturing carbon composite coupons (test strips) for performing stress, strain, and sheer analysis on. Being from a surfing, kiteboarding, and other water sport background I have always been interested in board design. With this in mind, it is no wonder why I found interest in such a project. I had the opportunity to refine Mold preparatory, composite layup, and composite curing techniques. Following manufacturing of these composite strips, I then performed various stress tests and logged my results. With these results, future teams could create lighter, stronger, and more cost effective composite structures for use in varieties of applications. After my experiences with materials and composites testing, I have obtained crucial appreciation for detailed documentation and analysis that material sciences involve. However, as interesting as composite materials testing has been, I do not feel this is where my future career lies. Another, more on the side, project I have been involved in is building a 626 cubic foot regolith containment chamber for doing full scale testing of robotic systems. This chamber is built of high strength aluminum scaffold materials, 80/20, and massive panels of Lexan. Once the chamber is completed, it is be filled with 120 tons of regolith and dubbed the largest regolith test chamber in the world. Through my experiences with building "Big Bin" as we called it, I discovered my demand for engaging and hands on activities. Through all of my incredible experiences working with the Swamp Works at Kennedy Space Center; I have obtained crucial knowledge, insights, and experiences that have fuelled, shaped, and will continue to drive me toward my ultimate goal of obtaining not only a degree in Engineering, but obtaining a job that I can call a career. I want to give much thanks to all of those who mentored me along my journey, and to all who made this opportunity a reality.

DeFilippo, Anthony Robert↗
DOE OSTI2026

Fabrication of thin-walled tubes from alloy 602 CA using shear assisted processing and extrusion

Thin-walled tube is usually produced seamlessly via an expensive multi-step process or via welding of thin sheets but at reduced performance. To overcome the current process and performance inefficiencies, advanced manufacturing methods need to be investigated. In this investigation, shear assisted processing and extrusion (ShAPE) was used to fabricate thin-walled Inconel 602 tube in a single-step. Tubes measuring 0.83 m length with a 12 mm outer diameter and 1 mm wall thickness were fabricated with an average surface roughness, Ra of 1.6 µm and Rz of 15 µm. Tensile testing of tubes in the as-fabricated condition showed strength increases of 4-35% over current offerings while maintaining or improving elongation. Electron microscopy analysis revealed the recrystallized microstructure with refined inter- and intra-granular carbides. Preliminary results obtained in this investigation shows the feasibility of producing thin-wall high temperature tube in single-step via ShAPE. This achievement marks a significant step towards manufacturing larger diameter nickel alloy tubes for the U.S. Department of Energy’s Waste Treatment and Immobilization Plant.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Influence of Al doping concentration on the opto-electronic chattels of SnS thin films readied by NSP

Herein, we limelight the key features of SnS thin films coated by spray pyrolysis process with different Al doping concentrations. The SnS thin films coated with different Al concentration (0, 2, 4, 6 at wt%) were characterized by various techniques. Structural parameters studied by XRD data revealed that all the prepared films were orthorhombic crystal structure with (111) as a preferential direction. Raman spectroscopy showed the presence of Ag, B{sub 1g}, B{sub 2g}, and B{sub 3g} vibration modes at their corresponding wave numbers. Concentration dependent granular change of Al:SnS films were shown by AFM images. The presence of Sn, S and Al element without any other impurities was confirmed through EDAX picture. UV studies revealed the shrinkage of band gap from 1.97 to 1.72 eV on increasing the Al doping concentration from 0% to 4 at wt%. Room temperature PL showed a high intense red shift, as emission observed at 722 nm for 4% of Al doped SnS thin film. Hall measurements exhibited p-type conducting nature of undoped and Al doped SnS films. The films showed a lowest resistivity of 2.695×10{sup −1} Ω cm for 4 at wt% Al doping concentration. 0.093% efficiency was obtained for the solar cell device fabricated by 4 at wt% of Al doped SnS thin film.

77 NANOSCIENCE AND NANOTECHNOLOGY↗