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At least 685 records · Page 38

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NASA NTRS1977

Potentially improved glasses from space environment

The benefits of processing glasses in a low-gravity space environment are examined. Containerless processing, the absence of gravity driven convection, and lack of sedimentation are seen as potential advantages. Potential applications include the formation of glass-ceramics with a high content of active elements for ferromagnetic devices, the production of ultrapure chalcogenide glasses for laser windows and IR fiber optics, and improved glass products for use in optical systems and laser fusion targets.

Nichols, R.↗

NASA NTRS1977

Research on graphite reinforced glass matrix composites

The results of research for the origination of graphite-fiber reinforced glass matrix composites are presented. The method selected to form the composites consisted of pulling the graphite fiber through a slurry containing powdered glass, winding up the graphite fiber and the glass it picks up on a drum, drying, cutting into segments, loading the tape segment into a graphite die, and hot pressing. During the course of the work, composites were made with a variety of graphite fibers in a glass matrix.

Bacon, J. F.↗

NASA NTRS1978

Studies and testing of antireflective (AR) coatings for soda-lime glass

Processes for producing antireflection films on glass are concentrated in three areas: acid etching of glass, plasma etching of glass, and acid development of sodium silicate films on glass. The best transmission was achieved through the acid etching technique, while the most durable films were produced from development of sodium silicate films. Control of the acid etching technique is presently inadequate for production implementation. While films having excellent antireflective properties were fabricated by plasma etching techniques, all were water soluble.

Pastirik, E. M.↗

NASA NTRS1977

Shock-produced olivine glass - First observation

Transmission electron microscope (TEM) observations of an experimentally shock-deformed single crystal of natural peridot, /Mg(0.88)Fe(0.12)/2SiO4, recovered from peak pressures of about 56 billion pascals revealed the presence of amorphous zones located within crystalline regions with a high density of tangled dislocations. This is the first reported observation of olivine glass. The shocked sample exhibits a wide variation in the degree of shock deformation on a small scale, and the glass appears to be intimately associated with the highest density of dislocations. This study suggests that olivine glass may be formed as a result of shock at pressures above about 50 to 55 billion pascals and that further TEM observations of naturally shocked olivines may demonstrate the presence of glass.

Jeanloz, R.↗

NASA NTRS1975

The source of sublimates on the Apollo 15 green and Apollo 17 orange glass samples

Elemental analyses of the thin film of micromounds which coat the surfaces of Apollo 15 green glass and Apollo 17 orange glass are reported. It is thought that Zn, Ga, Pb, Cu, Tl, S, F, and Cl condensed as a sublimate on the outside surface of these glass particles in lava fountains about 3.4 and 3.6 b.y. ago (Apollos 15 and 17, respectively). The heavy metals enriched in these samples may have been mobilized in a halide- and sulfide-rich vapor, while the source of these elements and of the glass may be a sulfide- and halide-rich pyroxenite inside the moon. The isotopic composition of lead on the surface of individual particles was determined, and the composition is considered with respect to the evolution of the source region. The lead on the surfaces is similar to lead that has been mixed into other soils and breccias at nearby sites.

Meyer, C., Jr.↗

NASA NTRS1975

Volatiles on the surface of Apollo 15 green glass and trace-element distributions among Apollo 15 soils

Zn, Ge, Cd, In, and Au have been detected in surficial deposits on Apollo 15 green-glass spherules, and it is suggested that these deposits are condensates from the magmatic gas phase which was responsible for the pneumatic expulsion of the green glass from the lunar interior. Thermodynamic data indicate that chlorides and fluorides were the dominant forms of the volatile metals. The Ar-40x content of a nongreen-glass soil fraction is greater than that found in green-glass. Mare and low-K Fra Mauro basalts seem to be the most prominent components of Apollo 15 soil. The correlation of Zn with Ar-40x and with Pb-204 is studied, and the distribution of quartz-normative and olivine-normative basalts is considered.

Chou, C.-L.↗

NASA NTRS1978

A chemical study of the impact glasses and basalts from Lonar Crater, India

Twenty-nine elements were determined by instrumental neutron activation analysis in two impact glasses and four basalts from Lonar Crater, India, and the glasses and the underlying core basalt samples are found to be very similar in major, minor, and trace element abundances. This finding seems to indicate that impact-induced chemical fractionation during formation of the glasses from basalt is minimal for many of the principal rock and mineral-forming elements. Since most volatile trace elements were not determined in this study, differences in the volatile trace element contents of the glasses and basalts can not be excluded.

Stroube, W. B., Jr.↗

NASA NTRS1979

Repairing cracked glass

Filing procedure consisting of machined lightweight fused-silica tiles coated with thin-layer of borosilicate glass produces homogeneous seal in thin glass. Procedure is useful in repairing glass envelopes, X-ray tub windows, Dewar flasks, and similar thin glass objects.

Helman, D. D.↗

NASA NTRS1979

Evaluation of the effects of solar radiation on glass

The degradation of glass used on space structures due to electromagnetic and particulate radiation in a space environment was evaluated. The space environment was defined and a simulated space exposure apparatus was constructed. Four optical materials were exposed to simulated solar and particulate radiation in a space environment. Sapphire and fused silica experienced little change in transmittance, while optical crown glass and ultra low expansion glass darkened appreciably. Specimen selection and preparation, exposure conditions, and the effect of simulated exposure are discussed. A selective bibliography of the effect of radiation on glass is included.

Firestone, R. F.↗

NASA NTRS1979

Radiation effects on the transmission of various optical glasses and epoxies

A recent study for the Dynamics Explorer satellite project involved the determination of the effects of gamma radiation (at 1.33 and 1.17 MeV) on the transmission of several optical glasses and epoxies to be used in the construction of interference filters. The samples studied included a control sample of pure fused silica, a cerium-stabilized radiation-resistant glass (Schott BK-7G), two pieces of quartz cemented with EPO-TEK 305 optical epoxy, two pieces of quartz cemented with APCO 5313 epoxy, a sample of Schott OG-590 glass, and a sample of Corning Corion glass. The transmission of different optical components was measured as a function of wavelength for several radiation doses.

Shetter, M. T.↗

NASA NTRS1979

Proton-induced coloring of multicomponent glasses

The paper describes the coloring induced by 85-MeV protons in three Schott glasses representative of glass types used as focusing elements in the International Ultraviolet Explorer Fine Error Sensor. It is shown that the absorption (i.e., coloring) induced in each glass by the radiation can be resolved into three optical absorption bands in the near UV-visible range. It is also discussed how that absorption grows with increasing dosages of protons, thus providing the means to predict degradation in any of the three glasses for a particular fluence of proton radiation.

Bartusiak, M. F.↗

NASA NTRS1980

Study of curved glass photovoltaic module and module electrical isolation design requirements

The design of a 1.2 by 2.4 m curved glass superstrate and support clip assembly is presented, along with the results of finite element computer analysis and a glass industry survey conducted to assess the technical and economic feasibility of the concept. Installed costs for four curved glass module array configurations are estimated and compared with cost previously reported for comparable flat glass module configurations. Electrical properties of candidate module encapsulation systems are evaluated along with present industry practice for the design and testing of electrical insulation systems. Electric design requirements for module encapsulation systems are also discussed.

Source record↗

NASA NTRS1979

A note on the Apollo 15 green glass vitrophyres

The paper discusses the vitrophyric fraction of Apollo 15 green glasses which contain skeletal crystals of olivine. Although the crystals are uniform in composition, the coexisting glass shows a range in composition and an olivine subtraction trend. The data suggest that the vitrophyres are part of the traditional Apollo 15 green glass suite composition; the natural trend of rapid low pressure crystal-fractionation suggests that other VLT rock types cannot be derived from Apollo 15 green glass magma.

Basu, A.↗

NASA NTRS1981

Containerless processing of glass

Ground-based research on the containerless melting of glass and experiments performed during a flight on the SPAR 6 are described. Experiments leading to selection of the flight sample composition, a silica-modified gallia/calcia glass, and the preparation of a one quarter inch diameter flight sample are described. During the flight experiment, a sample of the glass was containerless melted and cooled to a clear glass in a single axis acoustic positioning apparatus. The functioning of the flight experimental hardware was evaluated. The evaluation of the sample is presented.

Happe, R. A.↗

NASA NTRS1980

On the barrier to crystal nucleation in lunar glasses

The paper describes an analytical method for calculating in detail the size distributions of small crystallites and nuclei in supercooled liquids as they are being quenched to form a glass and subsequently reheated above the glass transition to produce crystallization. This method is applied to experiments performed using differential thermal analysis (DTA) to estimate the barriers to crystal nucleation and the cooling rates required to form glasses or bodies with various degrees of crystallinity. DTA data and derived nucleation barriers are reported for anorthite and for the following lunar compositions: 15498, 15418, matrix and intrusion compositions of breccia 15286, Apollo 15 green glass, Luna 24 highland basalt, and 65016.

Yinnon, H.↗

NASA NTRS1982

Simplified model evaluation of cooling rates for glass-containing lunar compositions

The simplified model of glass formation and the development of partial crystallinity in cooled bodies has been applied to lunar compositions 10060, 15028, 15086, 15101, 15286, 15301, 15498, 15499, 60255, 65016, 77017, Apollo 15 green glass and LUNA 24 highland basalt. The critical cooling rates for glass formation predicted by the simplified model are found to be in good agreement (to within an order of magnitude) with those predicted by the exact treatment of crystallization statistics. These predicted critical cooling rates are in even better agreement (a factor of 2) with measured values of the rates required to form glasses of the materials.

Uhlmann, D. R.↗

NASA NTRS1982

The relationship of the lunar regolith less than 10-microns fraction and agglutinates. II - Chemical composition of agglutinate glass as a test of the 'fusion of the finest fraction' /F3/ model

Agglutinate glasses from nine Apollo soils have been studied using an automated electron microprobe technique in order to test the fusion of the finest fraction model proposed by Papike (1981). The nine average agglutinate glass compositions are compared with the calculated fused-soil-free compositions, the bulk compositions and the 90-20 micron fraction compositions of the soils in which they are found. It is found that the agglutinate glass data are consistent with the composition of most of the fractions finer than 10 microns, allowing for the volatile loss of K2O and Na2O; some inconsistencies that do arise may result from the degree of soil maturity and the amount of material finer than 10 microns. It is concluded that the fusion of the finest fraction model is a good first approximation of mechanisms affecting the formation of agglutinate glass.

Walker, R. J.↗

NASA NTRS1982

KREEP glass and the exotic provenance and formation of polymict breccia 66055

The Apollo 16 site polymict breccia 66055 contains abundant brown KREEP glass, as well as related brown glassy breccias having fluid forms. Most of the rock is composed of clasts of poikiloblastic breccia and mesostasis-rich impact melt which predate 66055's assembly, while the KREEP glass was created in the rock-producing impact. KREEP compositions are not common at the Apollo 16 site, leading to the speculation that 66055 originated in terrains to the west of the landing site. The presence of a granitic glass fragment that is embedded in the KREEP glass suggests that it is igneous, with a local volcanic origin which is more consistent with spatial relationships deduced from orbital geochemical data than with a basin ejecta deposit origin.

Ryder, G.↗