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At least 685 records · Page 38

Characterization of volcanic tuff pores pre- and post-underground nuclear detonation using ultra-small and small angle neutron scattering

The ability to accurately model the subsurface transport of radionuclides is fundamental to the remote detection and characterization of underground nuclear explosion (UNE) events. Developing more sophisticated transport models presents a significant opportunity to enhance monitoring capabilities, particularly in the reliable prediction of signature migration. Experimentally determined characterization of geologic materials associated with transport properties is the pertinent base information for such robust model development and calibration. Here, we report results from an unprecedented study demonstrating changes to the pore and fracture network structures in geological materials in response to UNEs over nanometer to micrometer length scales. Volcanic tuffs of five different lithological formations from pre- and post-UNE environments were collected from the Nevada National Security Site. Combined ultra-small and small-angle neutron scattering techniques were used to characterize the tuff pore structure. The results demonstrate measurable differences in the specific surface area and porosity of samples pre- and post-shot from texturally similar lithological formations, indicating that pore properties can serve as a direct physical signature of a UNE. The results also provide experimentally determined transport parameters in support of advanced model development through the integration of gas migration, hydrodynamic simulations, and geologic framework models.

54 ENVIRONMENTAL SCIENCES↗

Towards the usage of quarry blasts as an active seismic source for subsurface characterization and imaging

SUMMARY Active or man-made seismic sources are often used to delineate subsurface geological structures via seismic imaging techniques. Although conventional controlled seismic sources have provided high-resolution subsurface images, the high cost of data acquisition necessitates improved use of cheaper alternative seismic sources for subsurface imaging, such as traffic noise, quarry blasts and earthquakes. Here, we explore the potential use of quarry blasts as an active seismic source for subsurface imaging. The goal of our study is to demonstrate the utility of quarry blasts as seismic sources for investigating subsurface structure with a field experiment in Mill Creek, southern Oklahoma. We deployed a 7455-m-long receiver line of 72 receivers (105 m spacing) extending away from a quarry, with a recording time of 28 d. We analyse similarities between blasts, wave types, origin time and excitation location of quarry blasts, which is important information for using such signal as an active source. Given a relative homogeneous geological condition in the study area, we could not observe clear reflected waves. However, the use of P- and S-wave velocities led to the delineation of a major basement damage zone in the study area, which further demonstrates the viability of quarry blasts as a useful seismic source for subsurface geological imaging.

58 GEOSCIENCES↗

Interpreting and reporting 40 Ar/ 39 Ar geochronologic data

The 40Ar/39Ar dating method is among the most versatile of geochronometers, having the potential to date a broad variety of K-bearing materials spanning from the time of Earth’s formation into the historical realm. Measurements using modern noble-gas mass spectrometers are now producing 40Ar/39Ar dates with analytical uncertainties of ~1%, thereby providing precise time constraints for a wide range of geologic and extraterrestrial processes. Analyses of increasingly smaller subsamples have revealed age dispersion in many materials, including some minerals used as neutron fluence monitors. Accordingly, interpretive strategies are evolving to address observed dispersion in dates from a single sample. Moreover, inferring a geologically meaningful “age” from a measured “date” or set of dates is dependent on the geological problem being addressed and the salient assumptions associated with each set of data. We highlight requirements for collateral information that will better constrain the interpretation of 40Ar/39Ar data sets, including those associated with single-crystal fusion analyses, incremental heating experiments, and in situ analyses of microsampled domains. To ensure the utility and viability of published results, we emphasize previous recommendations for reporting 40Ar/39Ar data and the related essential metadata, with the amendment that data conform to evolving standards of being findable, accessible, interoperable, and reusable (FAIR) by both humans and computers. Our examples provide guidance for the presentation and interpretation of 40 Ar/ 39 Ar dates to maximize their interdisciplinary usage, reproducibility, and longevity.

58 GEOSCIENCES↗

Self-Sealing Mafic Sills for Carbon and Hydrogen Storage

Tabular igneous intrusions (sills) are common features in sedimentary basins and have the potential to be useful seals for fluids (e.g., CO 2 or H 2 ) in geological storage scenarios, and may be important as the need for geologic carbon sequestration and alternative fuel storage increases. This is advantageous in regions without ready access to large-volume reservoirs in depleted hydrocarbon plays and saline aquifers, like the northeastern United States. Moreover, geological H 2 storage requires more demanding conditions than typically associated with oil and gas. An enhanced seal will have the properties of a traditional seal - competent, low permeability, and laterally extensive - with the addition of being able to self-seal pre-existing and induced fractures. Self-sealing will occur along fluid pathways like fractures where CO 2 , water, and minerals like plagioclase, olivine, and pyroxene react together. Dolerite sills from the Gettysburg Basin, Pennsylvania, have remarkably low permeability and homogeneous compositions that include minerals that will readily react with CO 2 dissolved in water. Here, we characterize the physical properties and chemical gradients within several mafic sills cored in five boreholes. In addition, preliminary CO 2 -reaction experiments on dolerite samples demonstrated rapid carbonate mineralization.

58 GEOSCIENCES↗

Induced seismicity potential based on probabilistic geomechanics for the San Juan Basin CarbonSAFE project

Although geologic carbon sequestration projects have yet to induce — or may never induce — a damaging earthquake, experiences from other deep injection industries such as hydraulic fracturing, enhanced geothermal systems, and saltwater disposal suggest that effective quantitative seismic risk assessment is necessary for deep saline carbon capture and sequestration (CCS) projects. One such imminent CCS project is the San Juan Basin CarbonSAFE Phase III program. We use Monte Carlo probabilistic geomechanical analyses combined with observations of the geologic and operational parameters of the San Juan Basin site and suggest that this project is of low-induced seismic risk. The primary analysis is split into four sections. First, we assess the literature for faults and past seismicity, and at least five faulting scenarios are directly relevant. Second, we develop and calibrate an integrated earth model for the project site. Third, we perform Monte Carlo simulations that consider reasonable uncertainties of the geomechanical parameters. Of five tested faulting scenarios, only one presents high Coulomb failure functions, but fourth, we determine the risk to be low based on the combined lack of historical seismicity, the geologic framework of the faulting scenario, and the presence of saltwater injection at the same depth as the proposed supercritical carbon dioxide injection. The most sensitive parameters in the geomechanical calculations are the fault dip and the coefficient of friction. The least sensitive are the fault strike and the orientation of the maximum horizontal principal stress.

58 GEOSCIENCES↗

Time-lapse seismic data inversion for estimating reservoir parameters using deep learning

Geologic carbon sequestration involves the injection of captured carbon dioxide ([Formula: see text]) into subsurface formations for long-term storage. The movement and fate of the injected [Formula: see text] plume is of great concern to regulators because monitoring helps to identify potential leakage zones and determines the possibility of safe long-term storage. To address this concern, we design a deep-learning framework for [Formula: see text] saturation monitoring to determine the geologic controls on the storage of the injected [Formula: see text]. We use different combinations of porosities and permeabilities for a given reservoir to generate saturation and velocity models. We train the deep-learning model with a few time-lapse seismic images and their corresponding changes in saturation values for a particular [Formula: see text] injection site. The deep-learning model learns the mapping from the change in the time-lapse seismic response to the change in [Formula: see text] saturation during the training phase. We then apply the trained model to data sets comprising different time-lapse seismic image slices (corresponding to different time instances) generated using different porosity and permeability distributions that are not part of the training to estimate the [Formula: see text] saturation values along with the plume extent. Our algorithm provides a deep-learning assisted framework for the direct estimation of [Formula: see text] saturation values and plume migration in heterogeneous formations using the time-lapse seismic data. Our method improves the efficiency of time-lapse inversion by streamlining the large number of intermediate steps in the conventional time-lapse inversion workflow. This method also helps to incorporate the geologic uncertainty for a given reservoir by accounting for the statistical distribution of porosity and permeability during the training phase. Tests on different examples verify the effectiveness of our approach.

Geochemistry & Geophysics↗

Subsurface Characterization and Machine Learning Predictions at Brady Hot Springs Results

Geothermal power plants typically show decreasing heat and power production rates over time. Mitigation strategies include optimizing the management of existing wells - increasing or decreasing the fluid flow rates across the wells - and drilling new wells at appropriate locations. The latter is expensive, time-consuming, and subject to many engineering constraints, but the former is a viable mechanism for periodic adjustment of the available fluid allocations. Data and supporting literature from a study describing a new approach combining reservoir modeling and machine learning to produce models that enable strategies for the mitigation of decreased heat and power production rates over time for geothermal power plants. The computational approach used enables translation of sets of potential flow rates for the active wells into reservoir-wide estimates of produced energy and discovery of optimal flow allocations among the studied sets. In our computational experiments, we utilize collections of simulations for a specific reservoir (which capture subsurface characterization and realize history matching) along with machine learning models that predict temperature and pressure timeseries for production wells. We evaluate this approach using an "open-source" reservoir we have constructed that captures many of the characteristics of Brady Hot Springs, a commercially operational geothermal field in Nevada, USA. Selected results from a reservoir model of Brady Hot Springs itself are presented to show successful application to an existing system. In both cases, energy predictions prove to be highly accurate: all observed prediction errors do not exceed 3.68% for temperatures and 4.75% for pressures. In a cumulative energy estimation, we observe prediction errors that are less than 4.04%. A typical reservoir simulation for Brady Hot Springs completes in approximately 4 hours, whereas our machine learning models yield accurate 20-year predictions for temperatures, pressures, and produced energy in 0.9 seconds. This paper aims to demonstrate how the models and techniques from our study can be applied to achieve rapid exploration of controlled parameters and optimization of other geothermal reservoirs. Includes a synthetic, yet realistic, model of a geothermal reservoir, referred to as open-source reservoir (OSR). OSR is a 10-well (4 injection wells and 6 production wells) system that resembles Brady Hot Springs (a commercially operational geothermal field in Nevada, USA) at a high level but has a number of sufficiently modified characteristics (which renders any possible similarity between specific characteristics like temperatures and pressures as purely random). We study OSR through CMG simulations with a wide range of flow allocation scenarios. Includes a dataset with 101 simulated scenarios that cover the period of time between 2020 and 2040 and a link to the published paper about this project, where we focus on the Machine Learning work for predicting OSR's energy production based on the simulation data, as well as a link to the GitHub repository where we have published the code we have developed (please refer to the repository's readme file to see instructions on how to run the code). Additional links are included to associated work led by the USGS to identify geologic factors associated with well productivity in geothermal fields. Below are the high-level steps for applying the same modeling + ML process to other geothermal reservoirs: 1. Develop a geologic model of the geothermal field. The location of faults, upflow zones, aquifers, etc. need to be accounted for as accurately as possible 2. The geologic model needs to be converted to a reservoir model that can be used in a reservoir simulator, such as, for instance, CMG STARS, TETRAD, or FALCON 3. Using native state modeling, the initial temperature and pressure distributions are evaluated, and they become the initial conditions for dynamic reservoir simulations 4....

15 GEOTHERMAL ENERGY↗

Subsurface Characterization of Hydraulic Fracture Test Site-2 (HFTS-2), Delaware Basin

Hydraulic Fracturing Test Site-2 (HFTS-2) is a field-based research experiment performed in the Wolfcamp Formation of the Permian (Delaware) Basin. This paper focuses on integration, advanced geological characterization, and 3D subsurface modeling of the comprehensive HFTS-2 dataset. The study showcases a multidisciplinary reservoir characterization approach that incorporates geology, petrophysics, geochemistry, geomechanics, microseismic, and subsurface engineering analysis. Subsurface characterization of organic-rich mudstone formations requires understanding complex hydraulic fracture network growth in relation to inherent lithology, geomechanical properties, and interaction with pre-existing natural fractures. This paper presents a characterization workflow incorporating pre- and post-stimulation subsurface data, unique to the HFTS-2 dataset. The study integrated: (1) rock properties from logs, cores, and thin sections; (2) natural and hydraulic fracture descriptions from cores and image logs; (3) local and regional stresses; (4) geomechanics; (5) microseismic; (6) fiber optic (FO) and bottomhole pressure gauge (BHPG) response; and (7) produced fluids analysis. During a stimulation treatment, creation of the stimulated rock volume (SRV) is influenced by several subsurface factors. Key contributing factors include structural context, stress conditions, lithology, facies architecture, pre-existing natural fractures, and geomechanical properties. The HFTS-2 subsurface data integration indicates that the SRV is comprised of a complex juxtaposition of hydraulic fracture swarms, as evidenced by image logs analysis, core description, and microseismic monitoring. The HFTS-2 microseismic event density was used to generate 3D heat maps that serve as a representative SRV footprint, corroborated by secondary datasets. These maps were further integrated with petrophysical and geomechanical characteristics, as well as responses from FO and BHPG, to estimate the lateral and vertical dimensions of the effective fractures. The geological characterization for the HFTS-2 dataset combined with 3D modeling for petrophysical and geomechanical properties provides a strong foundation for subsurface simulation and optimization studies. Downloaded from http://onepetro.org/URTECONF/proceedings-pdf/21URTC/1-21URTC/D011S005R001/2477501/urtec-2021-5243-ms.pdf/1 by Carol Worster on 28 February 2022 URTeC 5243 The workflow improved our understanding of HFTS-2 hydraulic fracture propagation and characteristics in relation to offset pressure depletion and interaction with pre-existing natural fractures. Analysis showed that fracture geometry varies by stage and by well, and a complex fracture network is generated with varying fracture density. The multidisciplinary workflow presented herein for integration and characterization serves as a foundation to evaluate completion efficiency and estimate areal and vertical stimulation and depletion extent for the project. Furthermore, the workflow and learnings can also be transferred to other unconventional plays.

58 GEOSCIENCES↗

Crustal Strain Rates in the Western United States and Their Relationship with Earthquake Rates

Abstract We present a suite of strain rate models for the western United States based on geologic and geodetic data. The geologic data consist of Quaternary fault-slip rates and the geodetic data consists of a new compilation of Global Positioning System (GPS) velocities derived from continuous, semicontinuous, and campaign measurements. We remove postseismic deformation from the GPS time series in order for our geodetic strain rate model to best capture the interseismic strain accumulation rate. We present models based on either geologic or geodetic data, but also create a hybrid model. Although there are some differences between the models, the large-scale features are the same, with the noticeable exception for the Pacific Northwest where interseismic strain is naturally more distributed than the long-term strain release. We also present a map of earthquake rate densities based on mainshocks, and the result has similar spatial features similar to the strain rate models (at least in the southwestern United States). We perform a general correlation analysis between strain rate and seismicity rate (south of Cascadia) and find a change in linearity between seismicity and strain rates from slow to faster deforming areas with seismicity rates relatively lower for the latter. The extent of that change depends a bit on assumptions made on the declustering and completeness of the catalog, but the finding of a change in slope is robust across the different strain rate models. Linearity for all areas is only expected when Gutenberg–Richter parameters and parameters involved in the conversion from strain to moment rate are uniform across the study area. We discuss these qualifications, but find no single satisfactory explanation for our observation. Moreover, when considering a rather short time and space, theoretical considerations of sampling from a power-law distribution actually predict there to be a power law instead of a linear relationship, generally consistent with our observation.

Geochemistry & Geophysics↗

Core Analysis E-Reports Produced for the Southwest Regional Partnership on Carbon Sequestration for Wells 13-10A, 13-14, and 32-8 of the Farnsworth Unit, Texas

The submission is three electronic reports (e-reports) produced by Terra Tek, a former Schlumberger company, for and under the oversight of the Southwest Regional Partnership on Carbon Sequestration (SWP). The SWP designed and implemented a coring and core analysis program in conjunction with the previous field operator Chaparral Energy, L.L.C. The main SWP contacts who oversaw the coring and core analysis program, including geologic core descriptions and sample selection for testing by the Terra Tek, are listed below in the Authors section. The three reports are for Wells 13-10A, 13-14, and 32-8 of the Farnsworth Unit, TX, a site of the SWP's CO2 storage and enhanced oil recovery project. The e-reports include many data types that are not listed in full detail here, but may include: geomechanical, geochemical, and petrophysical measurements; white light and UV core photos; spectral gamma logs on the core; and Heterogeneous Rock Analysis logs. Fracture core review reports are included for Wells 13-14 and 32-8. The three e-reports each have many subfolders with the various types of data in spreadsheets, pdfs, image files, or other formats. The main e-reports for each well are listed by the well name. The sub-folder “E-Report” for each well has a Report.html file, which, when opened, will have hyperlinks to the various data sets and information. The files in the zipped folder will need to be extracted for the Report.html files to work properly. These authors thank Joseph Hall, a geologist formerly of Chaparral Energy, L.L.C., for assistance in designing the coring program, his geologic expertise of the Farnsworth Unit, and his assistance with characterizing the core. Christopher Gillespie, of Terra Tek at the time, managed the myriad geomechanical, geochemical, and petrophysical measurements provided by Terra Tek for this project. The core from which the samples were collected for this project are housed at the Subsurface Data and Core Libraries of the New Mexico Bureau of Geology and Mineral Resources, Socorro, New Mexico, USA. Funding for this project is provided by the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) through the Southwest Regional Partnership on Carbon Sequestration (SWP) under Award No. DE-FC26-05NT42591. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525. These e-reports describe objective technical results and analysis. Any subjective views or opinions that might be expressed in the reports do not necessarily represent the views of the US Department of Energy or the United States Government.

Caprock↗

Characterization of Most Promising Sequestration Formations in the Rocky Mountain Region

The project Characterization of Most Promising Sequestration Formations in the Rocky Mountain Region is one of 9 site characterization projects that were implemented as part of ARRA (American Recovery and Reinvestment Act). Data from this project was used to improve resolution of data in NATCARB in the area of study. Data related to this study has already been incorporated in NATCARB Atlas. The Rocky Mountain Carbon Capture and Storage (RMCCS) project investigated multiple geologic formations and characterized a local site on the Colorado Plateau for future CCS opportunities. The RMCCS project focused on the Cretaceous Dakota, Jurassic Entrada, and Pennsylvanian Weber Sandstones, the three largest regional formations. All formations in this project are potential CO2 storage resources for future power plants, natural gas processing plants, cement plants, and oil shale development projects. The area adjacent to Craig, Colorado, (Sand Wash Basin) was the area selected for detailed geologic characterization on the RMCCS project. The basin was selected in part because the geology can be extrapolated to other sites on the Colorado Plateau. Field mapping and seismic surveys were conducted to identify and evaluate the basin's structural configuration. A 9,745-foot deep characterization well was drilled to collect 131 feet of core and a suite of geophysical well log data. Petrophysical tests on samples of core were used to calibrate geophysical log data, which can be used to obtain storage resource estimates and evaluate associated uncertainty as well as simulate the hydrologic behavior of injected CO2. A detailed analysis of the primary formations (Dakota, Entrada and Weber sandstones) yielded a more accurate CO2 storage resource assessment for these formations within the Colorado Plateau; RMCCS estimates indicate a total CO2 storage resource of more than 38,000 million metric tons. The characterization of the Sand Wash Basin (2-D seismic surveys, multiple well logs and lithological, petrophysical and geochemical analyses) allowed for a detailed 3-D model to be constructed. The model served as the framework for analyses ranging from CO2 storage resource, injectivity, and subsurface flow to uncertainty estimates to evaluation of risk.

2-D seismic↗

Central Plateau Vadose Zone Geoframework

The objective of this environmental calculation file (ECF) is to document the revision of the three dimensional (3D) geoframework model (GFM) of the Central Plateau Vadose Zone (CPVZ) on the Hanford Site. CP-60925, Model Package Report: Central Plateau Vadose Zone Geoframework, documents the original version of the CPVZGFM (herein after called the CPVZ-Rev.0) and is the underlying basis for the CPVZ conceptual model. The CPVZ GFM provides a more detailed interpretation of the vadose zone hydrostratigraphic units (HSUs) in the Central Plateau area of the greater Hanford South geoframework model (HSGFM) (ECF-HANFORD-13-0029, Development of the Hanford South Geologic Framework Model, Hanford Site, Washington). The development of the CPVZ GFM provides a consistent vadose zone geologic framework that is needed to support the 3D, multiple-waste-site modeling approach proposed in CP-60405, Hanford Site Composite Analysis Technical Approach Description: Vadose Zone, while incorporating an appropriate level of geologic data and interpretations for the size of the model using current site-standard HSUs. Future more detailed site-specific investigations within the Central Plateau can then use the CPVZ GFM as a starting point instead of the larger scale HSGFM. This GFM was developed using the site standard and approved for use IHS Kingdom software. This ECF is a revision to the original model described in CP-60925, but the underlying assumptions and conceptual model are unchanged. Therefore, this revision is a new calculation of version 1.0 of the CPVZ GFM and not a new version of the GFM. Throughout this report, the original model documented in CP-60925 is called CPVZ-Rev.0and the calculation for this revision of the model is called CPVZ-Rev.1.

58 GEOSCIENCES↗

Characterizing Baselines and Change in Gas Hydrate Systems using EM Methods

The objective of this project was to advance our understanding of gas hydrate systems in nature by characterizing their electrical properties in the field and in the laboratory. In the laboratory measurements, methane hydrate was synthesized from pure water ice and flash frozen seawater, with varying amounts of sand or silt added. Electrical conductivity was determined by impedance spectroscopy, using equivalent circuit modeling to separate the effects of electrodes and to gain insight into conduction mechanisms. Silt and sand increase the conductivity of pure hydrate, inferred to be contaminant NaCl contributing to conduction in hydrate, to a peak conductivity in agreement with peak resistivities observed in well logs through massive hydrate (3,000--10,000 Ωm). The addition of silt and sand lowers the conductivity of hydrate synthesized from seawater, by an amount consistent with Archie's Law. All samples were characterized using cryogenic scanning electron microscopy and energy dispersive spectroscopy, which shows good connectivity of salt and brine phases. Electrical conductivity measurements of pure hydrate and hydrate mixed with silt during pressure-induced dissociation supports previous conclusions that sediment increases dissociation rate. In order to characterize gas hydrate systems in the field, we collected 360 line kilometers of controlled-source electromagnetic data on Walker Ridge 313, Orca Basin (WR100), Mad Dog (GC781), and Green Canyon 955 in the Gulf of Mexico, all areas with known or seismically inferred gas hydrate deposits and which have be drilled or targeted for future drilling. We deep-towed an EM transmitter that generates an alternating electric field which propagates through the seafloor geology. Data were recorded on 6 receivers towed behind the transmitter at distances between 550 and 1550 m. In the presence of conductive geology, the electric fields will be attenuated, and conversely, in resistive geology the fields will be preserved. Our data were inverted using a 2D inversion method that first optimizes the model-data misfit, then finds the smoothest model fitting the data. This ensures that resistivity structures present in the final model are likely necessary. At each of the proposed drilling sites we found increased resistivity, interpreted as increased hydrate concentrations. However, not only were the primary drilling sites not always more resistive than the alternate sites, at WR313 the strongest resistors were not at the locations targeted for drilling.

03 NATURAL GAS↗

Eight County Permian Basin Residual Oil Zone (ROZ) Database

This document describes the spreadsheet geologic database named ROZ_SanAnd_8.xlsm used in the report, ''An Eight-County Appraisal of the San Andres Residual Oil Zone (ROZ) 'Fairway' of the Permian Basin''. The dataset provides geologic properties for ROZ partitions in San Andres formation in eight counties in the Permian Basin. The geologic data is used to estimate total oil in place in each partition and provides the inputs needed to estimate the oil that can be produced and CO 2 stored from the application of CO 2 EOR to a partition. The database and the appraisal report are available on NETL's website under the Collection Name: Eight-County San Andres ROZ Appraisal.

02 PETROLEUM↗

Four County Permian Basin San Andres Residual Oil Zone (ROZ) Database

This document describes the spreadsheet geologic database named ROZ_SanAnd_4.xlsm used in the report ''A Four-County Appraisal of the San Andres Residual Oil Zone (ROZ) 'Fairway' of the Permian Basin''. The dataset provides geologic properties for ROZ partitions in San Andres formation in four counties in the Permian Basin. The geologic data is used to estimate total oil in place in each partition and provides the inputs needed to estimate the oil that can be produced and CO 2 stored from the application of CO 2 EOR to a partition. The database and the appraisal report are available on NETL's website under the Collection Name: Four-County San Andres ROZ Appraisal.

02 PETROLEUM↗

Decovalex-2019 (Executive Summary)

The DECOVALEX Project is an on-going international research collaboration, established in 1992, to advance the understanding and modeling of coupled Thermal (T), Hydrological (H), Mechanical (M) and Chemical (C) processes in geological in geological systems. DECOVALEX was initially motivated by the recognition that prediction of these coupled effects is an essential part of the performance and safety assessment of geologic disposal systems for radioactive waste and spent nuclear fuel. Later it was realized that these processes also play a critical role in other subsurface engineering activities, such as subsurface CO 2 storage, enhanced geothermal systems, and unconventional oil and gas production through hydraulic fracturing. Research teams from many countries (e.g., Canada, China, Czech Republic, Finland, France, Germany, Japan, Republic of Korea, Spain, Sweden, Switzerland, Taiwan, United Kingdom, and the United States) various institutions have participated in the DECOVALEX Project over the years, providing a wide range of perspectives and solutions to these complex problems. These institutions represent radioactive waste management organizations, national research institutes, regulatory agencies, universities, as well as industry and consulting groups. The overall aim of DECOVALEX-2019 was to increase the understanding of various thermo-hydro-mechanical-chemical processes of importance for radionuclide release and transport from a repository to the biosphere and how they can be described and modelled using mathematical models. The scientific and technical objectives are: to increase the basic understanding of T-H-M-C coupled processes in fractured rocks (crystalline, sedimentary, argillaceous) and buffer materials; to investigate the predictive capabilities of different codes to field experiments and to perform verification of codes; to exchange experimental data, and improve the understanding of the constitutive behavior of crystalline and argillaceous rock masses and buffer materials; and to perform THMC calculations in a performance/safety assessment context.

58 GEOSCIENCES↗

Decovalex-2019 (Task A Final Report)

The DECOVALEX Project is an on-going international research collaboration, established in 1992, to advance the understanding and modeling of coupled Thermal (T), Hydrological (H), Mechanical (M) and Chemical (C) processes in geological in geological systems. This document is the final report of Task A which was proposed by the DECOVALEX Project and coordinated by the British Geological Survey (BGS), presenting the technical definitions of the problems studied, approaches applied, achievements made and outstanding issues for future research. The purpose of Task A under DECOVALEX-2019 is to better understand the processes governing the advective movement of gas in both low-permeability argillaceous repository host rocks and clay-based engineered barriers. Special attention is given to the mechanisms controlling gas entry, flow and pathway sealing and their impact on the performance of the engineered clay barrier. Previous work suggests gas flow may be accompanied by the creation of dilatant pathways whose properties change temporally and spatially within the medium. Thus, new numerical representations for the quantitative prediction of gas migration fluxes through argillaceous rock formations have been developed. These provide an invaluable tool with which to assess the impact of gas flow on repository layout and therefore design of any future facility. In addition, experience gained through this task is of direct relevance to other clay-based engineering issues where immiscible gas flow is a consideration including shale gas, hydrocarbon migration, carbon capture and storage and landfill design.

58 GEOSCIENCES↗