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At least 685 records · Page 38

Calculation of CO concentration for liquid fueled gas turbine combustor

The extensive computation time required for the numerical integration of the differential equations obtained in studies of the concentrations of pollutants emitted by gas turbine combustors, can be reduced significantly by assuming the heat releasing hydrocarbon reactions to be in local equilibrium. In determining the CO and NO concentrations produced in spray combustion, it is, therefore, tempting to use the same local equilibrium assumption in order to simplify the kinetic calculations. An investigation of the validity of the local equilibrium assumption is conducted by using a simple analytical model, and then by actually carrying out the kinetic and local equilibrium calculations for typical case.

Patil, P. B.↗

Stratospheric NO and HNO3 observations in the Northern Hemisphere for three seasons

NO, HNO3, and O3 levels and air temperature were measured as a function of latitude in the 18 to 21 km region of the stratosphere, and the sum of odd nitrogen, equal to NO + NO2 + HNO3, was calculated and compared with model predictions. (NO2 values were inferred from photochemical equilibrium characteristics.) The data show that NO measurements generally exhibit good agreement with model predictions for low and midlatitudes but poor agreement at high latitudes. The experimental sum of odd nitrogen mixing ratios and model predictions agree within a factor of 2-1/2 or better at both 20 and 40 deg N, and show excellent agreement for latitudinal dependence.

Loewenstein, M.↗

Statistical mechanics of light elements at high pressure. VI - Liquid-state calculations with Thomas-Fermi-Dirac theory

A model free energy is developed for hydrogen-helium mixtures based on solid-state Thomas-Fermi-Dirac calculations at pressures relevant to the interiors of giant planets. Using a model potential similar to that for a two-component plasma, effective charges for the nuclei (which are in general smaller than the actual charges because of screening effects) are parameterized, being constrained by calculations at a number of densities, compositions, and lattice structures. These model potentials are then used to compute the equilibrium properties of H-He fluids using a charged hard-sphere model. The results find critical temperatures of about 0 K, 500 K, and 1500 K, for pressures of 10, 100, and 1000 Mbar, respectively. These phase separation temperatures are considerably lower (approximately 6,000-10,000 K) than those found from calculations using free electron perturbation theory, and suggest that H-He solutions should be stable against phase separation in the metallic zones of Jupiter and Saturn.

Macfarlane, J. J.↗

Nonlinear Reynolds stress model for turbulent shear flows

A nonlinear algebraic Reynolds stress model, derived using the renormalization group, is applied to equilibrium homogeneous shear flow and fully developed flow in a square duct. The model, which is quadratically nonlinear in the velocity gradients, successfully captures the large-scale inhomogeneity and anisotropy of the flows studied. The ratios of normal stresses, as well as the actual magnitudes of the stresses are correctly predicted for equilibrium homogeneous shear flow. Reynolds normal stress anisotropy and attendant turbulence driven secondary flow are predicted for a square duct. Profiles of mean velocity and normal stresses are in good agreement with measurements. Very close to walls, agreement with measurements diminishes. The model has the benefit of containing no arbitrary constants; all values are determined directly from the theory. It seems that near wall behavior is influenced by more than the large scale anisotropy accommodated in the current model. More accurate near wall calculations may well require a model for anisotropic dissipation.

Barton, J. Michael↗

Calculated lamellar binding. I

Van der Walls bound lamellar solids interlayer binding energy computational model, discussing talc and pyrophyllite equilibrium stacking arrangements and force constants

Phillips, J. M.↗

Polynomial coefficients of thermochemical data for the C-H-O-N system

Thermodynamic data are required input for the finite kinetics and equilibrium computer programs needed for modeling the combustion of hydrocarbons in the fields of energy and pollution research. Least squares determined coefficients of the curve-fitted thermodynamic data for 193 species in the C-H-O-N system are presented in card image form and are of suitable format for use by common computer programs.

Wakelyn, N. T.↗

Analysis of OSO data to determine the structure and energy balance of the solar chromosphere

A detailed reexamination of the temperature-density structure of the photosphere and low chromosphere shows that the middle and upper chromosphere, which directly emits most of the OSO spectrum, is sensitive to conditions in this underlying region of the atmosphere. A model of this region is based on a unified compilation of all recently published broadband flux and central intensity observations of the solar spectrum from 500 microns in the far infrared to 1220 A in the far ultraviolet. This extensive compilation includes the OSO 4 and 6 observations in the wavelength range 1400 to 1220 A. A model is presented of the quiet solar atmosphere in the height range between the temperature minimum and the upper part of the chromosphere-corona transition region. This model is based on statistical equilibrium calculations of H, He 1, He 2, Si 1, C 1, and other ions.

Avrett, E. H.↗

Critical examination of two-equation turbulence closure models

Comparison of the Jones-Launder, Ng-Spalding, Saffman-Wilcox, and Wilcox-Traci two-equation turbulence models has been conducted. It was shown that the Saffman-Wilcox and Wilcox-Traci dissipation-rate formulations admit straightforward integration through the viscous sublayer, whereas integration through the viscous sublayer is a more difficult issue with the Jones-Launder dissipation-function and the Ng-Spalding length-scale formulations. Numerical computations were conducted in which the models were applied to four equilibrium boundary layer flows including adverse, zero, and favorable pressure gradients. Computations of zero pressure gradient flow over a convex wall composed the final part of the comparison.

Chambers, T. L.↗

Departures of the electron energy distribution from a Maxwellian in hydrogen. I - Formulation and solution of the electron kinetic equation. II - Consequences

The problem of calculating the steady-state free-electron energy distribution in a hydrogen gas is considered in order to study departures of that distribution from a Maxwellian at sufficiently low degrees of ionization. A model kinetic equation is formulated and solved analytically for the one-particle electron distribution function in a steady-state partially ionized hydrogen gas, and it is shown that the formal solution can be accurately approximated by using the WKB method. The solutions obtained indicate that the high-energy tail of the distribution is susceptible to distortion by imbalanced inelastic collisions for ionization fractions not exceeding about 0.1 and that such departures from a Maxwellian can lead to significant changes in the collisional excitation and ionization rates of ground-state hydrogen atoms. Expressions for the electron-hydrogen collision rates are derived which explicitly display their dependence on the hydrogen departure coefficients. The results are applied in order to compare self-consistent predictions with those based on the a priori assumption of a Maxwellian distribution for models of the thermal ionization equilibrium of hydrogen in the optically thin limit, spectral-line formation by a gas consisting of two-level atoms, and radiative transfer in finite slabs by a gas of four-level hydrogen atoms.

Shoub, E. C.↗

Pyrolysis of organic compounds in the presence of ammonia The Viking Mars lander site alteration experiment

The influence of ammonia on the pyrolysis pattern of selected organic substances sorbed on an inorganic phase was investigated. The thermal degradation products were identified by gas chromatography-mass spectrometry. The feasibility of this technique was tested on a meteoritic sample. All substances examined react with ammonia at the pyrolysis temperature of 500 C, the major products being nitriles and heterocyclic compounds in which nitrogen was incorporated. Based on these results, a model for the non-equilibrium production of organic compounds on Jupiter is discussed. The investigation was performed in connection with the Viking lander molecular analysis. The results obtained indicate that the concentrations of ammonia in the retrorocket fuel exhaust would have been probably too small to produce significant changes in the Martian soil organic compounds if any were found.

Holzer, G.↗

Tropical sea surface temperature - An interactive one-dimensional atmosphere-ocean model

It is shown that the (cumulus) convective processes in the tropics may be described by a one-dimensional cloud model, while the near-surface ocean may similarly be described by a one-dimensional mixed-layer model. The coupling is achieved through a sea surface flux budget combined with the flux parameterizations implied by Monin-Obukhov similarity theory. The coupled one-dimensional atmosphere-ocean model is applied to the equilibrium situation in which all temperatures reach a steady state. For the ocean, the fluxes must vanish in equilibrium, but the atmosphere maintains a stable lapse rate by balancing cumulonimbus heating against net radiative cooling. All water precipitating from cumulonimbus clouds must have evaporated from the sea. It is shown that this equilibrium system is closed and determinable solely in terms of the solar constant.

Sarachik, E. S.↗

Hektor - Nature and origin of a binary asteroid

It is argued that the elongated single body model (Dunlap and Gehrels, 1969) which reproduces the rotational light curve of 624 Hektor is unstable with respect to binary fission. It is shown that a contact binary model with ellipsoidal components of equilibrium shape matches the observed amplitude. Hektor's bulk density is inferred to be about 2.5 g/cu cm.

Weidenschilling, S. J.↗

Amplitude distributions of the spider heartpulse in response to gravitational stimuli

The arachnid Nuctenea sclopetaria (Clerck) which possesses a neurogenic heart, measuring the heartbeat is under efferent control through a dorsal nerve arising from a brain center is discussed. It was shown that the heartrate of this spider is also modulated by an afferent input associated with small increments of gravity. A compressive force on the order of 40 micron is sufficient to elicit a threshold change in heart rate for a typical (100mg) spider. This obtains in a hyper-Gz field less than 1.001. The functional relationship between gravity and heartrate is logarithmic between the absolute threshold and at least 1.5 Gz. A model was proposed in which equilibrium and movement are maintained by changes in blood pressure. It is concluded that the arachnid equilibrium system is like a weight detector which employs a hydraulic compensatory mechanism.

Finck, A.↗

Protostellar formation in rotating interstellar clouds. IV Nonisothermal collapse

Radiative transfer in the Eddington approximation is included in a multidimensional, self-gravitational, hydrodynamical computer code. Details of the numerical solution and thermodynamic relations are given. Comparison calculations with previous spherically symmetrical models of protostellar collapse are used to validate the basic approach and the artifices which allow the explicit hydrodynamics code to follow the accretion of gas onto a quasi-equilibrium core. A series of axisymmetric models is used to investigate the importance of rotation in collapsing clouds, as the initial amount of angular momentum is lowered, with an emphasis on the possible formation of rings. Rings readily form even in the nonisothermal regime except for very low initial angular momenta; even these clouds may experience ring formation prior to reaching stellar densities. The models imply that other effects (such as gravitational torques or turbulent viscosity) may be necesary to avoid binary formation and thus result in a presolar nebula consistent with the assumptions of either Safronov or Cameron.

Boss, A. P.↗

Application of program LAURA to three-dimensional AOTV flowfields

Program LAURA (Langley Aerothermodynamic Upwind Relaxation Algorithm) is a robust, finite volume, single-level storage, implicit upwind differencing algorithm which has been documented and tested on several three-dimensional blunt-body flows. The algorithm can run at unlimited Courant numbers (relaxing the steady-state equations) but requires the inversion of only a 5 x 5 matrix per computational cell. An alternating directional sweep Gauss-Seidel substitution strategy is used to relax the governing equations. At present, the Euler and thin-layer Navier-Stokes equations using Sutherland's law for viscosity have been modeled for a perfect gas, equilibrium air, and nonequilibrium air chemistry neglecting diffusion. The equilibrium and nonequilibrium air chemistry options have been described in a companion paper. Good comparisons with experimental data and another calculation method for pressure distributions, aerodynamic coefficients, and heat-transfer distributions have been demonstrated for three-dimensional blunt-body flows.

Gnoffo, P. A.↗

Polar warming in the middle atmosphere of Mars

During the 1984 Mars opposition, ground-based laser heterodyne spectroscopy was obtained for the nonthermal core emission of the 10.33-micron R(8) and 10.72-micron P(32) lines of C-12(O-16)2 at 23 locations on the Martian disk. It is deduced on the basis of these data that the temperature of the middle Martian atmosphere varies with latitude, and a meridional gradient of 0.4-0.9 K/deg latitude is indicated. The highest temperatures are noted to lie at high latitudes in the winter hemisphere; as in the terrestrial case of seasonal effects at the menopause, this winter polar warming in the Martian middle atmosphere requires departures from radiative equilibrium. Two-dimensional circulation model comparisons with these results indicate that atmospheric dust may enhance this dynamical heating at high winter latitudes.

Deming, D.↗

Bifurcations in unsteady aerodynamics

Nonlinear algebraic functional expansions are used to create a form for the unsteady aerodynamic response that is consistent with solutions of the time dependent Navier-Stokes equations. An enumeration of means of invalidating Frechet differentiability of the aerodynamic response, one of which is aerodynamic bifurcation, is proposed as a way of classifying steady and unsteady aerodynamic phenomena that are important in flight dynamics applications. Accomodating bifurcation phenomena involving time dependent equilibrium states within a mathematical model of the aerodynamic response raises an issue of memory effects that becomes more important with each successive bifurcation.

Tobak, M.↗