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At least 685 records · Page 38

Plasma observations near Saturn - Initial results from Voyager 1

The Voyager 1 encounter with Saturn and its satellites yielded extensive measurements of magnetospheric low-energy plasma electrons and positive ions, both heavy and light, probably of hydrogen and nitrogen or oxygen. At radial distances between 15 and 7 Saturn radii on the inbound trajectory, the plasma appears to corotate with a velocity within 20% of that theoretically expected for rigid corotation. The Titan data, taken while the moon was inside the Saturn magnetosphere, shows a clear signature characteristic of the interaction between a subsonic corotating magnetospheric plasma and the atmospheric or ionospheric exosphere of Titan.

Bridge, H. S.↗

Synchrotron radiation as a probe of the inner magnetosphere of Jupiter

A short review is given on the characteristics of Jupiter's inner magnetosphere derived from radio observations in the decimetric wavelength range. A comparison of the data with sophisticated model calculations yields information on the magnetic field configuration and the electron distribution, its density, energy spectrum, and pitch angle dependence as a function of spatial coordinates. The latter information can be used to derive, e.g., the radial diffusion parameters plus the effects of the satellites, Jupiter's ring, and wave-particle interactions upon the electron distribution.

De Pater, I.↗

Photometry, polarimetry, spectroscopy, and spectropolarimetry of the enigmatic Wolf-Rayet star EZ Canis Majoris

New observations of the peculiar Wolf-Rayet star EZ Canis Majoris collected since 1987 are presented, and photometric, polarimetric, spectroscopic, and spectropolarimetric data are discussed. Linear polarization data are well fitted with an eccentric binary model where an additional free parameter is included to allow for epoch-dependent changes of the geometrical electron distribution in the W-R envelope. This yields a set of basic parameters, including an eccentricity e = 0.39 +/- 0.02 and an orbital inclination i = 114 deg +/- 3 deg. The spectroscopic data show global profile variations for all three observed strong emission lines He II 5412 A, C IV 5807 A, and He I 5876 A. Radial velocities of the lines vary with the 3.766-day period. Radially expanding inhomogeneities are superposed on the line profiles and variable polarization in the lines is observed.

Robert, Carmelle↗

The Ulysses solar wind plasma investigation - Experiment description and initial in-ecliptic results

During the in-ecliptic flight of Ulysses from the Earth toward its encounter with Jupiter, the Los Alamos solar wind plasma experiment has performed well. Briefly described, the instrumentation contains two independent electrostatic analyzers, one for ions and one for electrons. Initial analysis of solar wind electron core temperatures obtained between 1.15 and 3.76 AU yields a gradient of T (proportional to) R(exp -0.7) which is flatter than expected for adiabatic expansion of a single-temperature Maxwellian velocity distribution and steeper than that obtained from Mariner-Voyager.

Bame, S. J.↗

Evolution of miniature detectors and focal plane arrays for infrared sensors

Sensors that are sensitive in the infrared spectral region have been under continuous development since the WW2 era. A quest for the military advantage of 'seeing in the dark' has pushed thermal imaging technology toward high spatial and temporal resolution for night vision equipment, fire control, search track, and seeker 'homing' guidance sensing devices. Similarly, scientific applications have pushed spectral resolution for chemical analysis, remote sensing of earth resources, and astronomical exploration applications. As a result of these developments, focal plane arrays (FPA) are now available with sufficient sensitivity for both high spatial and narrow bandwidth spectral resolution imaging over large fields of view. Such devices combined with emerging opto-electronic developments in integrated FPA data processing techniques can yield miniature sensors capable of imaging reflected sunlight in the near IR and emitted thermal energy in the Mid-wave (MWIR) and longwave (LWIR) IR spectral regions. Robotic space sensors equipped with advanced versions of these FPA's will provide high resolution 'pictures' of their surroundings, perform remote analysis of solid, liquid, and gas matter, or selectively look for 'signatures' of specific objects. Evolutionary trends and projections of future low power micro detector FPA developments for day/night operation or use in adverse viewing conditions are presented in the following test.

Watts, Louis A.↗

Plasma Characteristics Measured in the Plume of a NEXT Multi-Thruster Array

Plasma properties in the plume produced by a 3+1 NEXT thruster array operating at full power were mapped using a series of planar Langmuir probes. The Langmuir probes were swept across the diameters of each thruster as well as the centerline of the array at multiple downstream axial locations to produce a plasma map of the plume produced by the array. Such maps yielded the spatial distribution of the plasma density, the electron temperature and the plasma potential in the near field of the array. This spatial information provides insight into local plasma particle flow. Flow direction is particularly important from both an array lifetime and spacecraft-plume plasma interaction standpoint. The variation in the plume plasma parameters tended to vary in a manner consistent with both plume shape and overlap of adjacent plumes.

Foster, John E.↗

Solar Energy Reporting

Last year the people of Cleveland, Ohio were troubled by natural gas shortages during one of the coldest winters on record. The severe winter generated a great deal of interest in solar energy as an alternative source of heat. Home owners, home builders and civic officials wanted to know just how much solar energy is available in Cleveland. Now they get a daily report through the city's news media, from information supplied as a community service by NASA's Lewis Research Center. Lewis routinely makes daily measurements of solar energy as part of its continuing research in behalf of the Department of Energy. The measuring device is a sun sensor called a pyranometer (upper photo) located atop a building at the NASA Center. To make the information conveniently available to news media, Lewis developed a Voice Output Integrating Insolometer, an automated system that acquires information from the sun sensor and translates it into a recorded telephone message. The Lewis pyranometer collects sun data for 15 hours daily and measures the total solar energy yield. For reporting to the public, the information is electronically converted to a specific reading. A media representative calling in gets a voice-synthesized announcement of a two or three digit number; the number corresponds to the kilowatt-hours of solar energy that would be available to a typical 500-square-foot solar collector system. Response in Cleveland has been favorable and interest is developing in other parts of the country.

Source record↗

Superconducting Hot-Electron Submillimeter-Wave Detector

A superconducting hot-electron bolometer has been built and tested as a prototype of high-sensitivity, rapid-response detectors of submillimeter-wavelength radiation. There are diverse potential applications for such detectors, a few examples being submillimeter spectroscopy for scientific research; detection of leaking gases; detection of explosive, chemical, and biological weapons; and medical imaging. This detector is a superconducting-transition- edge device. Like other such devices, it includes a superconducting bridge that has a low heat capacity and is maintained at a critical temperature (T(sub c)) at the lower end of its superconducting-transition temperature range. Incident photons cause transient increases in electron temperature through the superconducting-transition range, thereby yielding measurable increases in electrical resistance. In this case, T(sub c) = 6 K, which is approximately the upper limit of the operating-temperature range of silicon-based bolometers heretofore used routinely in many laboratories. However, whereas the response speed of a typical silicon- based laboratory bolometer is characterized by a frequency of the order of a kilohertz, the response speed of the present device is much higher characterized by a frequency of the order of 100 MHz. For this or any bolometer, a useful figure of merit that one seeks to minimize is (NEP)(tau exp 1/2), where NEP denotes the noise-equivalent power (NEP) and the response time. This figure of merit depends primarily on the heat capacity and, for a given heat capacity, is approximately invariant. As a consequence of this approximate invariance, in designing a device having a given heat capacity to be more sensitive (to have lower NEP), one must accept longer response time (slower response) or, conversely, in designing it to respond faster, one must accept lower sensitivity. Hence, further, in order to increase both the speed of response and the sensitivity, one must make the device very small in order to make its heat capacity very small; this is the approach followed in developing the present device.

Karasik, Boris↗

A Data Matrix Method for Improving the Quantification of Element Percentages of SEM/EDX Analysis

A simple 2D M N matrix involving sample preparation enables the microanalyst to peer below the noise floor of element percentages reported by the SEM/EDX (scanning electron microscopy/ energy dispersive x-ray) analysis, thus yielding more meaningful data. Using the example of a 2 3 sample set, there are M = 2 concentration levels of the original mix under test: 10 percent ilmenite (90 percent silica) and 20 percent ilmenite (80 percent silica). For each of these M samples, N = 3 separate SEM/EDX samples were drawn. In this test, ilmenite is the element of interest. By plotting the linear trend of the M sample s known concentration versus the average of the N samples, a much higher resolution of elemental analysis can be performed. The resulting trend also shows how the noise is affecting the data, and at what point (of smaller concentrations) is it impractical to try to extract any further useful data.

Lane, John↗

PACE OCI Short-Wave Infrared Detection Assembly frequency-dependent linearity characterization and uncertainty analysis

The Ocean Color Instrument (OCI), the primary payload of the Plankton, Aerosol, Cloud, ocean Ecosystem (PACE)observatory, will collect data to monitor the health of Earth’s oceans and atmosphere. The Short-Wave Infrared(SWIR) Detection Assembly (SDA) was built and characterized by the Utah State University Space DynamicsLaboratory (SDL) and is a subsystem of OCI. The SDA measures seven bands centered at 940, 1038, 1250, 1378,1615, 2130, and 2260 nm, with standard- and high-gain varieties for the 1250 and 1615 nm bands, resulting in nine total detection configurations in the SWIR. The delivery of high-quality science data is critically dependent upon accurately characterizing the linearity of the SDA. Two metrology techniques were employed to measure the linearity and characterize the frequency-dependent linearity uncertainty of the system. The first technique used superposition linearity measurements to determine the DC linearity, and the second technique involved an oscillating small-signal response at seven frequencies to determine the frequency-dependent linearity. Discrepancies between the DC and frequency-dependent linearities constrain the uncertainty between the two. Examining the difference between these two methods for all SDA channels, we find most channels experience an uncertainty below0.2% with a worst-case measurement uncertainty of 0.31%. Averaging SDA channels with similar detectors, optical filters, and electronics to simulate the flight-like data products yields a worst-case frequency-dependence linearity uncertainty of 0.12%, demonstrating minimal frequency dependence, implying an excellent linearity knowledge.Detailed performance knowledge, including linearity performance, verifies data quality and builds confidence in the success of the PACE mission.

PACE↗

EXPERIMENTAL STUDIES OF NONLINEAR INTEGRABLE OPTICS

State-of-the-art accelerators at energy and intensity frontiers require increasingly bright and powerful particle beams. In conventional linear lattices, intense beams suffer from collective instabilities, resulting in beam losses and maximum beam intensity limits. This thesis presents experimental studies of a novel lattice design concept, the nonlinear integrable optics (NIO), aimed at enhancing beam stability limits with little to no beam dynamics degradation. Single-particle beam dynamics measurements of two NIO devices, the quasi-integrable octupole system and the fully integrable Danilov-Nagaitsev system, were carried out at the purpose-built Integrable Optics Test Accelerator (IOTA) at Fermilab. Their simulation, hardware design, and commissioning process are presented. Extensive model and analysis algorithm development and benchmarking is described. Electron beam data from two scientific runs is analyzed, yielding frequency and phase space dynamics consisten t with m odels. These results demonstrate viability and advantages of the NIO design, providing the groundwork for proton studies in the strong space-charge regime and future integrable accelerators.

Kuklev, Nikita↗

Electronic structure modulation of MoS2 by substitutional Se incorporation and interfacial MoO3 hybridization: Implications of Fermi engineering for electrocatalytic hydrogen evolution and oxygen evolution

The design of earth-abundant electrocatalysts that can facilitate water splitting at low overpotentials, provide high current densities, and enable prolonged operational lifetimes is central to the production of sustainable fuels. The distinctive atomistic and electronic structure characteristics of the edges of MoS2 imbue high reactivity toward the hydrogen evolution reaction. MoS2 is nevertheless characterized by significantly high overpotentials as compared to platinum. Here, we demonstrate that modulation of the electronic structure of MoS2 through interfacial hybridization with MoO3 and alloying of selenium on the anion sublattice allows for systematic lowering of the conduction band edge and raising of the valence band edge, respectively. The former promotes enhanced electrocatalytic activity toward hydrogen evolution, whereas the latter promotes enhanced activity toward the oxygen evolution reaction. Such alloyed heterostructures prepared by sol-gel reactions and hydrothermal selenization expose a high density of edge sites. The alloyed heterostructures exhibit low overpotential, high current density, high turnover frequency, and prolonged operational lifetime. The mechanistic origins of catalytic activity have been established based on electronic structure calculations and x-ray absorption and emission spectroscopy probes of electronic structure, which suggest that interfacial hybridization at the MoO3 interface yields low-lying conduction band states that facilitate hydrogen adsorption. In contrast, shallow Se 4p-derived states give rise to a raised effective valence band maximum, which facilitates adsorption of oxygen intermediates and engenders a low overpotential for the oxygen evolution reaction. The findings illustrate the use of electronic structure modulation through interfacial hybridization and alloying to systematically improve electrocatalytic activity.

Parija, Abhishek↗

Searching for a route to synthesize in situ epitaxial Pr 2 Ir 2 O 7 thin films with thermodynamic methods

In situ growth of pyrochlore iridate thin films has been a long-standing challenge due to the low reactivity of Ir at low temperatures and the vaporization of volatile gas species such as IrO 3 (g) and IrO 2 (g) at high temperatures and high P O2 . To address this challenge, we combine thermodynamic analysis of the Pr-Ir-O 2 system with experimental results from the conventional physical vapor deposition (PVD) technique of co-sputtering. Our results indicate that only high growth temperatures yield films with crystallinity sufficient for utilizing and tailoring the desired topological electronic properties and the in situ synthesis of Pr 2 Ir 2 O 7 thin films is fettered by the inability to grow with P O2 on the order of 10 Torr at high temperatures, a limitation inherent to the PVD process. Thus, we suggest techniques capable of supplying high partial pressure of key species during deposition, in particular chemical vapor deposition (CVD), as a route to synthesis of Pr 2 Ir 2 O 7 .

Chemistry↗

Redox Disproportionation of Glucose as a Major Biosynthetic Energy Source

Previous studies have concluded that very little if any energy is required for the microbial biosynthesis of amino acids and lipids from glucose -- processes that yield almost as much ATP (adenosine triphosphate) as they consume. However, these studies did not establish the strength nor the nature of the energy source driving these biological transformations. To identify and estimate the strength of the energy source behind these processes, we calculated the free energy change due to the redox disproportionation of substrate carbon of (a) 26 redox-balanced fermentation reactions, and (b) the biosynthesis of amino acids, lipids, and nucleotides of E. coli from glucose. A plot of the negative free energy of these reactions per mmole of carbon as a function of the number of disproportionative electron transfers per mmol of carbon showed that the energy yields of these fermentations and biosyntheses were directly proportional to the degree of redox disproportionation of carbon. Since this linear relationship showed that redox disproportionation was the dominant energy source of these reactions, we were able to establish that amino acid and lipid biosynthesis obtained most of their energy from redox disproportionation (greater than 94%). In contrast nucleotide biosynthesis was not driven by redox disproportionation of carbon, and consequently depended completely on ATP for energy. This crucial and previously unrecognized role of sugars as an energy source of biosynthesis suggests that sugars were involved at the earliest stage in the origin of anabolic metabolism.

Weber, Arthur L.↗

Lightweight, High-Yield Photocathode

Layer of Astroquartz (or equivalent) cloth woven from quartz thread multiplies electron current emitted by aluminum photocathode sensitive to ultraviolet light when placed in external steady-state electric field. Desirable in applications where low power consumption required.

Leung, Philip L.↗

Low-diffusion Xe-He gas mixtures for rare-event detection: electroluminescence yield

High pressure xenon Time Projection Chambers (TPC) based on secondary scintillation (electroluminescence) signal amplification are being proposed for rare event detection such as directional dark matter, double electron capture and double beta decay detection. The discrimination of the rare event through the topological signature of primary ionisation trails is a major asset for this type of TPC when compared to single liquid or double-phase TPCs, limited mainly by the high electron diffusion in pure xenon. Helium admixtures with xenon can be an attractive solution to reduce the electron diffusion significantly, improving the discrimination efficiency of these optical TPCs. We have measured the electroluminescence (EL) yield of Xe-He mixtures, in the range of 0 to 30% He and demonstrated the small impact on the EL yield of the addition of helium to pure xenon. For a typical reduced electric field of 2.5 kV/cm/bar in the scintillation region, the EL yield is lowered by ~ 2%, 3%, 6% and 10% for 10%, 15%, 20% and 30% of helium concentration, respectively. This decrease is less than what has been obtained from the most recent simulation framework in the literature. The impact of the addition of helium on EL statistical fluctuations is negligible, within the experimental uncertainties. The present results are an important benchmark for the simulation tools to be applied to future optical TPCs based on Xe-He mixtures.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Capturing multireference excited states by constrained-density-functional theory

The computation of excited electronic states with commonly employed (approximate) methods is challenging, typically yielding states of lower quality than the corresponding ground state for a higher computational cost. In this work, we present a mean-field method that extends the previously proposed excited constrained-density-functional theory (XCDFT) from single Slater determinants to ensemble one-body reduced density matrices for computing low-lying excited states. The method still retains an associated computational complexity comparable to a semilocal density functional theory (DFT) calculation while at the same time it is capable of approaching states with multireference character. Further, we benchmark the quality of this method on well-established test sets, finding good descriptions of the electronic structure of multireference states and maintaining an overall accuracy for the predicted excitation energies comparable to semilocal time-dependent DFT.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Energy from Redox Disproportionation of Sugar Carbon Drives Biotic and Abiotic Synthesis

To identify the energy source that drives the biosynthesis of amino acids, lipids, and nucleotides from glucose, we calculated the free energy change due to redox disproportionation of the substrate carbon of: (1) 26-carbon fermentation reactions and (2) the biosynthesis of amino acids and lipids of E. coli from glucose. The free energy (cal/mmol of carbon) of these reactions was plotted as a function of the degree of redox disproportionation of carbon (disproportionative electron transfers (mmol)/mmol of carbon). The zero intercept and proportionality between energy yield and degree of redox disproportionation exhibited by this plot demonstrate that redox disproportionation is the principal energy source of these redox reactions (slope of linear fit = -10.4 cal/mmol of disproportionative electron transfers). The energy and disproportionation values of E. coli amino acid and lipid biosynthesis from glucose lie near this linear curve fit with redox disproportionation accounting for 84% and 96% (and ATP only 6% and 1 %) of the total energy of amino acid and lipid biosynthesis, respectively. These observations establish that redox disproportionation of carbon, and not ATP, is the primary energy source driving amino acid and lipid biosynthesis from glucose. In contrast, we found that nucteotide biosynthesis involves very little redox disproportionation, and consequently depends almost entirely on ATP for energy. The function of sugar redox disproportionation as the major source of free energy for the biosynthesis of amino acids and lipids suggests that sugar disproportionation played a central role in the origin of metabolism, and probably the origin of life.

Weber, Arthur L.↗