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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

BCS-BEC crossover in a (t 2g ) 4 excitonic magnet

The condensation of spin-orbit-induced excitons in t 2 g 4 electronic systems is attracting considerable attention. At large Hubbard U , antiferromagnetism was proposed to emerge from the Bose-Einstein Condensation (BEC) of triplons ( J eff = 1 ). Furthermore, we show that even at intermediate U regimes, the spin-orbit exciton condensation is possible leading also to staggered magnetic order. The canonical electron-hole excitations (excitons) transform into local triplon excitations at large U , and this BEC strong coupling regime is smoothly connected to the intermediate U excitonic insulator region. We solved the degenerate three-orbital Hubbard model with spin-orbit coupling ( λ ) in one dimension using the density matrix renormalization group, while in two dimensions we use the Hartree-Fock approximation (HFA). Employing these techniques, we provide the full λ versus U phase diagrams for both one- and two-dimensional lattices. Our main result is that at intermediate Hubbard U , increasing λ at fixed U the system transitions from an incommensurate spin-density-wave metal to a Bardeen-Cooper-Schrieffer (BCS) excitonic insulator, with coherence length r coh of O ( a ) and O ( 10 a ) in 1 d and 2 d , respectively, with a being the lattice spacing. Further increasing λ , the system eventually crosses over to the BEC limit (with r coh ≪ a ).

1-dimensional systems↗
DOE OSTI2022

Dipolar Bose-Hubbard model

We study a simple model of interacting bosons on a d-dimensional cubic lattice whose dynamics conserves both total boson number and total boson dipole moment. This model provides a simple framework in which several remarkable consequences of dipole conservation can be explored. As a function of chemical potential and hopping strength, the model can be tuned between gapped Mott insulating phases and various types of gapless condensates. The condensed phase realized at large hopping strengths, which we dub a Bose-Einstein insulator, is particularly interesting: despite having a Bose condensate, it is insulating, and despite being an insulator, it is compressible.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Finite-momentum instability of a dynamical axion insulator

Due to the chiral anomaly, Weyl semimetals can exhibit a signature topological magnetoelectric response known as an axion term which is determined by the microscopic band structure. In the presence of strong interactions Weyl fermions may form a chiral condensate, with the intrinsic dynamics and fluctuations of the associated condensate phase producing a dynamical contribution to the axion response. Here we show that an imbalance in the density of right- and left-handed electrons drives an instability of the chiral condensate towards finite momentum and leads to strong fluctuations in the axion response. We derive a long-wavelength theory of Lifschitz type governing the dynamics of the Goldstone mode and use this to characterize its associated spatial fluctuations, which manifest as an inhomogeneous anomalous Hall effect. In conclusion, we show that these fluctuations produce signatures in inelastic light-scattering experiments across a broad spectrum of frequencies, and can be used to determine the structure factor for the axionic collective mode.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Performance Evaluation of Liquid-Cooled Open Stand-Alone Refrigerated Cases

This project is part of a joint effort between Commonwealth Edison Company (ComEd) and the National Renewable Energy Laboratory (NREL) to evaluate the energy and demand savings potential of emerging efficient buildings technologies. This project quantifies the energy efficiency benefits from retrofitting an air-cooled, constant-speed compression, self-contained medium-temperature open-vertical display case with a high efficiency water-cooled condensing unit. In addition to a water-cooled heat rejection mechanism, the high-efficiency condensing unit utilizes a variable-speed compressor, electronic expansion valve and advanced controls system. The focus of this project, however, was mainly on capturing the energy savings potentials of the water-cooled condenser, variable-speed compression and electronic expansion valve, and not on the advanced controls. The results of this evaluation will be considered by ComEd and CLEAResult for future energy efficiency rebate offerings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Quantum criticality and topology in non-equilibrium systems

A key goal of condensed matter physics research is to identify new phases of matter, and to understand the universal features of the phase transitions between them. In the past decade, physicists have uncovered a wealth of new phases with interesting surface properties, exemplified by the theoretical prediction and subsequent experimental discovery of topological insulators and superconductors. Traditional condensed matter systems are usually in a thermal equilibrium state and typically at very low temperature. Very recently, experimental advances have sparked interest in the non-equilibrium setting. Non-equilibrium systems can host new phases and phenomena with no equilibrium counterpart, and could also enable robust ways to build quantum memory devices to store and manipulate quantum information in a coherent manner. These phases and phenomena are inherently “dynamical”: they are described not by changes in the arrangement or structure of the constituent particles, but instead marked by sharp distinctions in how the particles move and exchange energy or quantum information. The discovery of robust non-equilibrium phases raises many fundamental questions: Can we develop a systematic theory of states of matter and of dynamical transitions between such states? How can such states be realized and probed experimentally? The main goal of this project was to explore the emergence of topological phases and quantum criticality (two cornerstones of modern condensed matter physics in equilibrium) in such non-equilibrium quantum systems. Specific goals included (1) using tensor networks to efficiently represent non-equilibrium states of matter and their phase transitions; (2) studying and designing new probes for periodically driven systems; and (3) developing analytic and numerical tools to analyze non-equilibrium topological phase transitions. Advances in these directions were achieved using novel techniques appropriate to study the non-equilibrium dynamics in many-body quantum systems combining strong interactions and randomness. Taken together, these results provide a new conceptual framework for understanding the emergence of quantum critical and topological properties in quantum systems far from thermal equilibrium.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2026

Electron Correlation and High-Temperature Superconductivity

Strong electron correlation plays a central role in the high-temperature superconductivity (HTSC) of cuprates. However, to date, research has focused only on its role in spin dynamics and related effects, even though it is becoming increasingly clear that spin alone may not be sufficient to create HTSC. Here, we discuss a possible role of electron correlation in the Bose–Einstein condensation (BEC) of Cooper pairs. Recently, we succeeded in observing dynamic electron correlation via inelastic X-ray scattering through results presented in real space. We discovered that electron correlations are strongly modified in the plasmon, proving that electron dynamics significantly affect electron correlation. Earlier, we found that in 4 He, the atom–atom distance in the BE condensate is 10% longer than that in the non-condensate. These results suggest the possibility that the reduction in electron-repulsion energy upon BEC is driving T c to high values. Thus, electron correlation itself could be the origin of the HTSC phenomenon.

Bose–Einstein condensation↗
DOE OSTI2020

Invisible QCD as Dark Energy

We account for the late time acceleration of the Universe by extending the Quantum Chromodynamics (QCD) color to a SU(3) invisible sector (IQCD). If the Invisible Chiral symmetry is broken in the early universe, a condensate of dark pions (dpions) and dark gluons (dgluons) forms. The condensate naturally forms due to strong dynamics similar to the Nambu–Jona-Lasinio mechanism. As the Universe evolves from early times to present times the interaction energy between the dgluon and dpion condensate dominates with a negative pressure equation of state and causes late time acceleration. We conclude with a stability analysis of the coupled perturbations of the dark pions and dark gluons.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Nuclear Power Fault Diagnostics and Preventative Maintenance Optimization

The nuclear industry is beginning to see reactors shut down—even after their operating licenses have been extended—because they are not economically competitive with other energy sources. These early closures happen primarily due to economic reasons, despite excellent safety records. Therefore, it is imperative to reduce costs in order to prevent these early closures. One of the contributors to these economic reasons is the large operations and maintenance costs. This paper showcases recent research on advanced fault diagnostics techniques and preventative maintenance optimization (PMO) for reducing NPP maintenance costs. Specifically, it focuses on the feedwater and condensate system (FWCS) for both pressurized- and boiling-water reactor (BWR) systems. The computerized maintenance management system (CMMS), which contains the plant’s digital record of all corrective maintenance (CM) and preventative maintenance (PM) work orders, provided the ground truth for locating potential faults and labeling the process data as either healthy or faulted. Various feature extraction techniques were used to further differentiate the faulted data from the healthy data. Through a cross-validation procedure, support vectors machines were used to label other test sets of process data as either healthy or faulted. With relatively few faults identified in the BWR system, the potential for PMO opens up, since an unnecessary amount of PM leads to inflated maintenance costs. The steps for PMO are summarized, from component health determinations to recommendations for action. An example of PMO assessment is presented for condensate pumps, condensate booster pumps, and the respective motors that drive them.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2020

Implementation of the Glycolate Destruction Process with Sodium Permanganate in the Defense Waste Processing Facility (DWPF) - 20141

The Savannah River Site (SRS) seeks to replace formic acid with glycolic acid as a chemical reductant in the Defense Waste Processing Facility (DWPF), where borosilicate glass is mixed with high-level radioactive waste, melted at high temperatures, then poured into stainless steel canisters for safe storage. Prior research and development have demonstrated the feasibility and advantages of the new nitric-glycolic acid flowsheet over the current nitric-formic acid flowsheet to chemically adjust the radioactive sludge slurry waste in the Sludge Receipt and Adjustment Tank (SRAT) prior to vitrification. Use of glycolic acid reduces hydrogen and ammonia generation during the reduction process, thus reducing flammability hazards and purge requirements in the DWPF processing vessels. In addition, glycolic acid will support the new Salt Waste Processing Facility (SWPF) by allowing for receipt of higher volumes of waste due to reduction of flammable gases, increased boil-up rates in the vessels, and easing the processing of future sludge batches containing high levels of mercury. However, during DWPF operations, trace amounts of glycolate are anticipated to be entrained in the recycle stream and sent to the Concentration, Storage, and Transfer Facilities (CSTF) via the Recycle Collection Tank (RCT). The RCT receives condensate from the Slurry Mix Evaporator Condensate Tank (SMECT) and Off-gas Condensate Tank (OGCT) that may contain unreacted glycolate. A literature review found the potential for hydrogen generation due to thermolysis of glycolate in caustic CSTF conditions. Savannah River National Laboratory (SRNL) conducted several tests on simulant and radioactive waste from various tanks at SRS and confirmed that glycolate added to waste at concentrations of approximately 1000 mg/L and higher generates hydrogen through thermolysis. There are potential operating scenarios in the future where glycolate concentration could exceed 1000 mg/L in the 2H Evaporator Drop Tank, the highest accumulation point for DWPF organics received via recycle. These findings presented a need to develop another process to mitigate the impact of glycolic acid to the CSTF. Several DWPF compatible options were evaluated for their ability to destroy glycolate in the DWPF recycle stream under various processing conditions, thereby mitigating its introduction to the CSTF. Downselection testing identified sodium permanganate as the most promising and simplest option to oxidize glycolate. It has been demonstrated to be effective in various RCT simulant compositions, operating temperatures, oxidant addition rates, solution pH, and initial glycolate concentrations. A feasibility study identified existing tanks within the facility that could be used for receiving and storing the commercially available sodium permanganate, as well as feeding it to the RCT for processing. The use of existing equipment as well as the ability to purchase the pre-mixed chemical reduces implementation and operational complexity. The downstream impacts of the sodium permanganate reaction were also evaluated and demonstrated to have minimal impact on other chemical species present in the RCT and CSTF, as well as on the materials of construction of the RCT and CSTF vessels and associated piping and instrumentation. Future work is in progress to validate the glycolate destruction process with testing in actual radioactive RCT waste before implementation in DWPF. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Oxidation of Glycolate in the Defense Waste Processing Facility (DWPF) Recycle Collection Tank - 20305

The Savannah River Site's Defense Waste Processing Facility (DWPF) operations are being upgraded with the introduction of the Nitric-Glycolic Flowsheet. Glycolic acid has been shown superior to formic acid as the reducing acid used during chemical processing. The new flowsheet improves or maintains necessary parameters such as 1) reduction of mercury, 2) adjustment of feed rheology and 3) adjustment of melter oxidation/reduction potential. Further, the potential for catalytic hydrogen generation in DWPF processing is virtually eliminated. DWPF process condensates are collected and returned to the SRS Concentration, Storage and Transfer Facilities (CSTF). The Recycle Collection Tank (RCT) collects off-gas condensate during chemical processing, vitrification, and other unit operations performed in DWPF and is the singular return vessel delivering recycle effluent back to CSTF. Each batch of recycle may contain a small amount of glycolate from chemical processing and melter off-gas condensates. To avoid potential flammability issues due to thermolysis of glycolate in the CSTF, chemical oxidation within the RCT has been investigated as an option for mitigating the transfer of glycolate. Sodium permanganate has been down-selected as the best option for oxidation of glycolate. Testing was performed using both 2-L and 22-L reactors (16,800:1 and 1,530:1 scale by volume) with non-radioactive waste simulants to approximate the expected RCT compositions. RCT simulants were evaluated at various process pH and temperature conditions. Also, RCT operations, namely the sequence of addition of corrosion inhibitors (NaOH and NaNO{sub 2}) versus a permanganate strike, were evaluated. Glycolate was introduced via a sludge simulant to mimic both expected entrainment and abnormal process foam-over conditions - the range being between 68 and 5100 mg/kg glycolate. Glycolate destruction was monitored by ion chromatography (IC). The corresponding manganese behavior was monitored in real-time using in situ ultraviolet-visible (UV-Vis) spectroscopy. RCT glycolate content can be reduced to below the IC detection limit within 90 minutes for all concentrations investigated. Ion Chromatography analysis revealed that under alkaline conditions, glycolate is primarily oxidized to oxalate with no significant formation of CO{sub 2} or carbonate, and nitrite is not oxidized to nitrate. Initially, complete oxidation of organics species and nitrite was assumed. Determination of the mechanistic chemical reaction has allowed the required amount of permanganate to be more accurately predicted and the total addition to be significantly reduced. UV-Vis measurements reveal that permanganate (Mn{sup 7+}) is reduced to manganate (Mn{sup 6+}) in the RCT. The oxidant stoichiometry is defined by using the initial permanganate to glycolate (P/G) molar ratio. At low initial glycolate concentration (68 and 140 mg/kg), the minimum required initial permanganate to glycolate (P/G) molar ratio was found to be 5-6. With high initial glycolate concentrations (5100 mg/kg) a lower (P/G) molar ratio of ∼2.5 was needed. The final portion of this effort supporting the nitric/glycolic flowsheet will be to test actual (fully radioactive) RCT samples as per the above simulant tests. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

Numerical Analysis of Water Harvesting from Saturated Vapor with the Electrospray Water Droplet Injection in The Solar-Driven Desalination Applications

Solar-driven seawater desalination systems provide freshwater through environmentally friendly and carbon-neutral processes. Air humidification and dehumidification desalination (HDD) systems extract water directly from moist air. This paper focuses on a new solar-driven seawater desalination system that shares some common traits with HDD systems but in which the air is eliminated from the process. Seawater is vaporized by solar thermal radiation in high-performance solar panels. Water vapor flows to a new electro-condensation chamber and passes through a series of electrosprays, which inject small nuclei of freshwater droplets into the vapor clouds. Here, due to dielectrophoresis and electrohydrodynamic flows, the vapor molecules are captured by the charged droplets, and vapor is condensed at the droplet surface. The water vapor condensation was modeled by using the multiphase flow numerical model. The CFD model, which was also experimentally validated, used SprayFoam solver modules available in the Open FOAM® CFD open-source software. In preliminary results, 802 grams/(hr-m2) (grams per hour per unit area) of water was harvested directly from moist air at 24C and 90% relative humidity. The simulation results indicated that freshwater productivity could increase up to 4,000 grams/(hr-m2) for fully saturated air conditions. This represents about 5 times the water productivity rate of current conventional HDD systems today. In addition, energy consumption could be reduced by 80 percent compared to conventional HDD systems.

Electrospray, electro-condensation, solar, droplet↗
DOE OSTI2023

Modeling salt adsorption in electrical double layer for capacitive deionization

Abstract This work presents an electrical double layer (EDL) model for capacitive deionization (CDI) by intercorrelating the salt adsorption, the electrode voltage, and the surface charge density. The counterion condensation is considered a crucial contribution to salt adsorption because of the high surface charge density in the charged micropores. The counterions condense when the surface charge density exceeds a critical value, which is predicted by the counterion condensation theory. The EDL model accurately correlates the NaCl salt adsorption and electrode voltage with various surface charge densities and well predicts the salt adsorption in a wide range of external salt concentrations. The EDL model reproduces the non‐monotonic relationship between the salt adsorption and the specific surface area observed in experiments and provides an explanation from the modeling perspective. Exhibiting superior accuracy and predictability for salt adsorption, the EDL model could serve as an enabling tool contributing to the development of CDI processes.

Lin, Yu‐Jeng↗
DOE OSTI2025

Acoustic misalignment mechanism for axion dark matter

A rotation in the field space of a complex scalar field corresponds to a Bose-Einstein condensation of U(1) charges. We point out that fluctuations in this rotating condensate exhibit sound-wave modes, which can be excited by cosmic perturbations and identified with axion fluctuations once the U(1) charge condensate has been sufficiently diluted by cosmic expansion. We consider the possibility that these axion fluctuations constitute dark matter and develop a formalism to compute its abundance. We carefully account for the growth of fluctuations during the epoch where the complex scalar field rotates on the body of the potential and possible nonlinear evolution when the fluctuations become non-relativistic. We find that the resultant dark matter abundance can exceed the conventional and kinetic misalignment contributions if the radial direction of the complex scalar field is sufficiently heavy. The axion dark matter may also be warm enough to leave imprints on structure formation. We discuss the implications of this novel dark matter production mechanism — acoustic misalignment mechanism — for the axion rotation cosmology, including kination domination and baryogenesis from axion rotation, as well as for axion searches.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Comprehensive Analysis of the Relative Dispersion of Droplet-Size Distributions and Their Relationships to Key Physical Fog Processes Under Different Aerosol Conditions and Evolutionary Stages

The relative dispersion of cloud and fog droplets has significant impacts on aerosol indirect effects, radiative transfer, and microphysical processes. However, previous studies have been mostly concerned with clouds, with limited studies on fog, particularly those that examine the combined influences of all key physical processes and their roles during fog evolution. As such, this study aims to conduct a comprehensive investigation by examining the relationships between relative dispersion and other microphysical variables, as well as the underlying microphysical and dynamic processes, based on field fog campaigns in polluted and clean conditions. In polluted fog, droplet concentrations are higher, leading to smaller droplets and increased dispersion. The correlation between dispersion and droplet volume-mean radius is positive in the polluted fog, but shifts to negative in clean fog. Here, we attribute the difference to various microphysical processes like aerosol activation, condensation, collision-coalescence, and entrainment-mixing. In polluted fog, high aerosol concentrations, low supersaturations, and strong turbulence (entrainment-mixing) provide suitable conditions for the simultaneous occurrence of droplet condensation and aerosol activation, resulting in a positive correlation between dispersion and volume-mean radius, especially during the fog formation stage. In contrast, during the mature stage in clean fog, condensation is dominant with weak aerosol activation leading to a negative correlation between relative dispersion and volume-mean radius. The collision-coalescence process is more active in the mature stage, increasing radii and leading to the negative correlation between dispersion and volume-mean radius. This result sheds new light on understanding the relative dispersion and mechanisms in fog under different aerosol backgrounds.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Nondestructive neutron imaging diagnosis of acidic gas reduction catalyst after 400-Hour operation in natural gas furnace

Residential natural gas furnaces are the primary space-heating devices in US homes, leading to substantial environmental impact caused by the acidic components in the furnace combustion gases. Here, to experimentally demonstrate acidic gas reduction in a furnace, a monolithic catalyst was fabricated and was called the AGR. A commercially-available condensing furnace was retrofitted with the AGR, and a 400-hour reliability and durability test was conducted. The results showed that the AGR significantly reduced acidic gases in the flue gas and produced condensate with neutral pH. Challenges were also revealed: inappropriate condensate drainage caused incomplete combustion and amorphous carbon deposits. To nondestructively survey the internal state of the AGR, neutron computed tomography (NCT) was employed to produce spatially resolved 2D and 3D representations of the 2-L, aged AGR component. The NCT results confirm the integrity of the AGR component, which consists of two blocks, without deformation or damage to AGR channels. The distribution of the particle accumulation in the middle of the top block was visibly heavier than the entrance and exit of the top block. The representative cross-section views revealed significant aggregation in the central region but not at the rim. The spatially resolved details provide in-depth diagnosis, evaluation, and understanding of the AGR. The insights can enable new AGR designs that realize a uniform and self-cleaning flow pattern, alleviate significant particle aggregation, and thus enhance AGR-enabled furnace performance. The neutron imaging method demonstrates the good potential that can diagnose faults and improve the design, optimization, and production processes of novel catalysts and other components or systems with heavy metal shell.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Effective direct steam regeneration of bis-iminoguanidine solid sorbent used for carbon dioxide capture

A cost-effective, energy-efficient sorbent regeneration process for phase-changing guanidines used for CO 2 capture was developed based on direct-steam stripping. This approach enhances the regeneration rate, simplifies the overall CO 2 capture process, and reduces the energy cost compared to conventional conductive thermal regeneration. A direct-steam sorbent regeneration reactor was developed, demonstrating that aqueous bis(iminoguanidines) (BIG) sorbents, e.g., methylglyoxal-bis(iminoguanidine) (MGBIG) and glyoxal-bis(iminoguanidine) (GBIG), could be efficiently regenerated with up to ~ 99 % CO 2 recovery through direct-steam stripping. Using low-temperature steam at 100 °C, a 4.5 times faster regeneration rate for GBIG carbonate sorbent (e.g., 30 min for 10 g) was demonstrated compared to conductive-heating (e.g., 135 min for 10 g) at 130 °C. Additionally, fully regenerated MGBIG converts into an aqueous MGBIG solution when the steam condenses onto the sorbent surface. Condensed steam with the guanidine can be easily recycled as an aqueous solution into the gas–liquid contactor to achieve a continuous-flow CO 2 -capture process. Molecular dynamics simulation was employed to provide a better understanding of the process. Higher heat transfer rates from steam to guanidine carbonate, compared to air heating, were attributed to the vibration resonance of water molecules within MGBIG with that of vapor molecules and the effective transfer of kinetic energy from vapor to solid. Technoeconomic analysis demonstrated that direct-steam stripping significantly decreases the CO 2 capture cost by 50 % compared to traditional conductive heating methods. Further, enhanced mass transfer facilitated by low-temperature steam and subsequent condensation effectively heats up the H 2 O-containing BIG-carbonate crystals, facilitating the desorption of CO 2 from the solid crystals, thereby leading to fast, effective, and energy-efficient sorbent regeneration.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Energy-efficient sorption-based gas clothes dryer systems

Standard electric resistance and fuel-driven dehydration technologies exhibit a maximum coefficient of performance of well below 1 mainly due to enthalpy losses associated with the air leaving the dehydration system. To improve energy efficiency, condensing dryer systems condense the moisture captured from a product in a closed-loop air circulation cycle. Existing condensing dehydration systems including heat pump dryers, however, need to significantly cool the air to achieve dehumidification. The added cooling and subsequent heating to return the air to a desired drying temperature consume substantial energy and thus reduce drying performance. Here, an innovative sorption-based gas dehydration system is proposed to overcome barriers deteriorating energy efficiency in existing gas, electric, or heat pump dryer systems. Decoupling latent and sensible loads, the system employs a liquid-desiccant solution to directly capture air humidity, thereby allowing circulation of the air in a closed loop to achieve high drying energy efficiency. In other words, the system captures waste latent heat from the moisture produced during the dehydration process and reuses it to improve energy efficiency. This study focuses on a comprehensive quasi-steady-state thermodynamic modeling of the proposed sorption-based dehydration concept employed for a gas clothes dryer application to predict transient response and overall drying performance (i.e., time and energy metrics). The analysis indicates the proposed sorption-based gas clothes dryer system can deliver a specific moisture extraction rate of 1.71 kg of water per kWh (i.e., a combined energy factor of 3.167 kg (6.98 lbm) of dry cloth per kWh) with a drying time of 44 min. This is a 112% energy improvement compared with state-of-the-art gas clothes dryers exhibiting a combined energy factor of 1.50 kg (3.3 lbm) of dry cloth per kWh. The technology pursued here can potentially be employed as a platform for many fuel-driven equipment to take advantage of available waste thermal energy in the environment instead of simply burning a fuel.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2026

Phase change material-to-refrigerant heat exchangers: Experimental validation and uneven melting analysis

Thermal energy storage (TES) using phase change materials (PCMs) enables load shifting and reduces mismatches between the building's thermal demand and the heat pump (HP) system's thermal capacity. While most TES studies have focused on single-phase heat transfer fluids, PCM-to-refrigerant heat exchangers (PRHX), in which the refrigerant undergoes liquid-vapor phase change, remain largely underexplored. Here, to address this gap, this study systematically investigates a shell-and-tube PRHX operating as the condenser in an HP through experiments and simulations. A two-dimensional enthalpy-based finite-volume PRHX model was developed and validated against experimental data, including refrigerant and PCM temperature profiles, PRHX capacity, and system-level performance. Results show three characteristic stages: Stage I, the condenser temperature rapidly increases with PCM in the solid state absorbing sensible heat; Stage II, stable operation during PCM phase change; and Stage III, performance decline once part of the PCM becomes fully melted. Heat transfer analysis revealed that uneven PCM melting along the condenser length was driven primarily by variations in the refrigerant-side heat transfer coefficient, rather than local approach temperature differences. Further study demonstrated that minimizing refrigerant outlet subcooling led to more uniform PCM melting and extended Stages I and II by up to 89%. This paper provides a validated PRHX model, clarifies the mechanisms of uneven PCM melting, and highlights subcooling control as an effective strategy to improve TES performance in HP systems without requiring secondary loops.

Graphite matrix↗