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At least 685 records · Page 38

Condensation in CO2 free jet expansions. I - Dimer formation.

A theoretical and experimental investigation of the kinetics of CO2 dimer formation in the adiabatically expanding core of a free jet expansion has been carried out. The theoretical analysis is based on dimer formation by an efficient termolecular process and dimer destruction by bimolecular collisions. Account is taken of the expected variation of the specific heat ratio during the expansion and of the effective increase in the termolecular collision rate at low temperatures due to the presence of loosely bound orbiting pairs. Experimental dimer concentrations were measured mass spectrometrically by forming a molecular beam from the expanded gas mixture after the onset of molecular flow. Observed dimer concentrations, for a range of pre-expansion conditions of 400 to 900 torr pressure and room temperature, are in good agreement with the theoretical analysis, provided that account is taken of the effect of loosely bound orbiting pairs at low temperatures.

Dorfeld, W. G.↗

Condensation in CO2 free jet expansions. II - Growth of small clusters.

An investigation into the kinetics of molecular clustering processes which occur in the highly supersaturated vapor of a CO2 free jet is described. Terminal cluster concentrations in expansions from room temperature and reservoir pressures in the range from 400 to 900 torr were determined for trimeric CO2 for nozzle diameters of .0076 cm, .015 cm, and .023 cm and in the case of CO2 tetramer and pentamer for .015 cm nozzle diameter. The measurements were made mass spectrometrically in a supersonic molecular beam apparatus. A kinetic analysis was developed from an extension of the critical nucleus concept of nucleation theory and rate equations based on intermolecular collisions. The observed cluster populations could be accounted for by the theory by adopting sticking probabilities of approximately .03 for monomer impinging on dimer, trimer, and tetramer.

Dorfeld, W. G.↗

Study of the effects of condensation on the performance of Pioneer Venus probe windows

The transmission loss of Pioneer Venus Probe radiation windows if their exposed surfaces become contaminated with droplets of water, hydrochloric acid, sulfuric acid, and mercury which may be found in the Venusian atmosphere was investigated. Transmission loss was studied as a function of mass concentration of liquid droplets deposited on one surface of test window materials while the wavelength of the transmitting radiation is in the range of 0.3 to 30 microns. The parameters that affect the transmittance of radiation through a window are: (1) particle size, (2) surface concentration of particles, (3) wavelength of the radiation, (4) angle of acceptance of the radiation by the detector, and (5) the refractive index of the aerosol.

Testerman, M. K.↗

Chemical equilibrium of ablation materials including condensed species

Equilibrium is determined by finding chemical composition with minimum free energy. Method of steepest descent is applied to quadratic representation of free-energy surface. Solution is initiated by selecting arbitrary set of mole fractions, from which point on free-energy surface is computed.

Stroud, C. W.↗

A photographic study of flow condensation in 1-g and zero-gravity environments

The test articles investigated include two full-scale radiator/condenser panels and a system of three parallel-connected fused quartz tubes. Testing was performed initially on the ground, with both horizontal and inclined flow passage orientations, and additionally in an aircraft flying 0-g trajectories. The photographic observations were made with two high speed cameras and a low speed camera. The flow regimes observed are compared with those predicted by the Baker chart (1954). The Baker chart is well in accord with physical reality in the annular flow region. However, a stratified-annular flow regime observed has no counterpart in the Baker categorization.

Keshock, E. G.↗

High temperature condensates among meteors

It is noted that two meteors which exhibited no lines of iron or sodium in their spectra have been tentatively attributed to aubrites in order to explain their lack of iron. It is shown, however, that no meteorites, including aubrites, have simultaneously low abundances of iron and sodium and that possible parent materials other than aubrites must be considered for the observed meteors. Other possible parent materials considered in this letter include melilite and diopside, two minerals containing both Ca and Mg but neither Fe nor Na. It is suggested that meteoroids rich in Ca and Mg but lacking Fe and Na might form a reservoir for the so-called 'lost' elements (Ca, Mg, Al, Ti, the lanthanides, and other refractory elements) which are depleted in ordinary and enstatite chondrites relative to cosmic abundances.

Wilkening, L. L.↗

A condensed form of NASTRAN

The Interactive Graphics Finite Element System, IGFES, is described along with its supporting analysis software, graphics terminal support package and hardware configurations. IGFES provides an interactive design tool for structural engineers via pre- and postprocessing of finite element data. The system currently runs on an IBM 360/44 OS-MFT system or a PDP 11/40 DOS/BATCH system. Graphics devices are supported using an inhouse developed, device independent terminal support package. Support is available for the Calcomp 563 drum plotter, Tektronix 4002A storage display terminal and the Lundy Electronics 20 inch standalone refresh display system. IGFES and its associated systems are written in FORTRAN IV.

Rogers, J. L., Jr.↗

Interaction of NaCl(g) and HCl(g) with condensed NA2SO4

The interaction of Na2SO4(l) with NaCl(g), HCl(g) and H2O(g) was studied in atmospheric pressure flowing air and oxygen at Na2SO4(l) temperatures of 900 and 1000 C. Thermomicrogravimetric and high pressure mass spectrometric sampling techniques were used. Experimental results establish that previously reported enhanced rates of weight loss of Na2SO4(l) in the presence of NaCl(g) are due to the reaction: Na2SO4(c) + 2HCl(g) = 2NaCl(g) + SO2(g) + H2O(g) + 1/2O2(g) being driven to the right in flowing gas systems. The HCl(g) is the product of hydrolysis of NaCl caused by small but significant amounts of H2O(g) present in the system. Thermochemical calculations are used to show that even with sub-ppm levels of H2O(g) present, significant quantities of HCl(g) are produced.

Stearns, C. A.↗