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At least 685 records · Page 38

Evaluation of a Third Generation Single-Component Water-Lean Diamine Solvent for Post-Combustion CO 2 Capture

Here this study describes a comprehensive evaluation of a recently developed water-lean diamine solvent, N1-(2-ethoxyethyl)-N2, N2-diisopropylethane-1,2-diamine (2-EEDIPEDA), to probe its potential post-combustion CO 2 capture performance. This evaluation includes (1) fundamental sorption characterization such as vapor-liquid equilibria, sorption kinetics and viscosity impacts; (2) continuous capture characterization using laboratory scale flow system using flue gas simulant; as well as (3) technoeconomic analysis of the capture process at industrial scale with projections for critical capture performance metrics. Using this evaluation, we compare the performance of 2-EEDIPEDA to our current leading water-lean amine-based solvent, 2-EEMPA, using the same baseline process plant configuration/pricing. From this comparison, we observe lower total cost of capture as low as $46.8/tonne CO 2 with 2-EEDIPEDA (20% cheaper than CANSOLV), as a direct result of solvent chemistry tuning leading to notable cost savings.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

X2000 power system electronics development

The Europa Orbiter mission, currently baselined for launch in March 2008, is intended to follow up on tantalizing results from the Gulileo spacecraft, data from which suggests that there may be a global Ocean underneath the jovian satellite Europa's water ice crust. Scientific objectives for the mission are to ascertain whether or not Europa has a liquid water ocean, to characterize ice layers beneath the surface, and to find the most scientifically enticing landing sites for future missions.

X2000 PSE power system↗

Investigation of the CCN Activity, BC and UVBC Mass Concentrations of Biomass Burning Aerosols during the 2013 BASELInE Campaign

Biomass-burning (BB) aerosols, acting as cloud condensation nuclei (CCN), can influence cloud microphysical and radiative properties. In this study, we present CCN measured near the BB source regions over northern Southeast Asia (Doi Ang Khang, Thailand) and at downwind receptor areas (Lulin Atmospheric Background Station, Taiwan), focusing exclusively on 13-20 March 2013 as part of 2013 spring campaign of the Seven SouthEast Asian Studies (7-SEAS) intensive observation. One of the campaigns objectives is to characterize BB aerosols serving as CCN in SouthEast Asia (SEA). CCN concentrations were measured by a CCN counter at 5 supersaturation (SS) levels: 0.15%, 0.30%, 0.45%, 0.60%, and 0.75%. In addition, PM2.5 and black carbon mass concentrations were analyzed by using a tapered element oscillating microbalance and an aethalometer. It was found the number-size distributions and the characteristics of hygroscopicity (e.g., activation ratio and k) of BB aerosols in SEA have a strong diurnal pattern, and different behaviors of patterns were characterized under two distinct weather systems. The overall average value was low (0.05-0.1) but comparable with previous CCN studies in other BB source regions. Furthermore, a large fraction of UV-absorbing organic material (UVBC) and high Delta-C among BB aerosols were also observed, which suggest the existence of substantial particulate organic matter in fresh BB aerosols. These data provide the most extensive characterization of BB aerosols in SEA until now.

biomass burning aerosol↗

Habitable Exoplanet Imager Optical Telescope Concept Design

The Habitable Exoplanet Imaging Mission (HabEx) is one of four missions under study for the 2020 Astrophysics Decadal Survey. Its goal is to directly image and spectroscopically characterize planetary systems in the habitable zone of Sun-like stars. Additionally, HabEx will perform a broad range of general astrophysics science enabled by 100 to 2500 nm spectral range and 3 x 3 arc-minute FOV. Critical to achieving the HabEx science goals is a large, ultra-stable UV/Optical/Near-IR (UVOIR) telescope. The baseline HabEx telescope is a 4-meter off-axis unobscured three-mirror-anastigmatic, diffraction limited at 400 nm with wavefront stability on the order of a few 10s of picometers. This paper summarizes the opto-mechanical design of the HabEx baseline optical telescope assembly, including a discussion of how science requirements drive the telescope's specifications, and presents analysis that the baseline telescope structure meets its specified tolerances.

mirror↗

Habitable Exoplanet Observatory (HabEx) Telescope: Systems Engineering and STOP Modeling

The Habitable Exoplanet Observatory Mission (HabEx) is one of four missions studied for the 2020 Astrophysics Decadal Survey. Its goal is to directly image and spectroscopically characterize planetary systems in the habitable zone around nearby sun-like stars. Additionally, HabEx will perform a broad range of general astrophysics science enabled by 115 to 1700 nm spectral range and 3 x 3 arc-minute FOV. Critical to achieving its science goals is a large, ultra-stable UV/Optical/Near-IR (UVOIR) telescope. The baseline HabEx telescope is a 4-meter off-axis unobscured three-mirror-anastigmatic, diffraction limited at 400 nm with wavefront stability on the order of a few 10s of picometers. This paper summarizes the opto-mechanical design of the baseline optical telescope assembly, including a discussion of how we applied science driven systems engineering to derive the telescope’s engineering specifications from the mission’s science requirements, and presents analysis that the baseline telescope structure meets its specified tolerances.

Stahl, H. Philip↗

On-Orbit Calibration Assessment of NOAA-21 VIIRS Thermal Emissive Bands and Implications for JPSS-4 VIIRS

The Visible Infrared Imaging Radiometer Suite (VIIRS) instrument onboard the NOAA-21 (N21) satellite has been successfully operating for over three years collecting valuable scientific measurements. A large suite of weather forecasting models and scientific research applications are supported with the VIIRS measurements from N21 combined with those acquired from the VIIRS instrument onboard the S-NPP and NOAA-20 spacecraft. Among the 22 VIIRS spectral bands, there are seven thermal emissive bands (TEB) covering the 3.7 to 12.2 µm spectral range at two different spatial resolutions. The VIIRS TEB detectors are calibrated onboard using a blackbody at a controlled temperature and a space view for background signal measurement. In this paper, we discuss the on-orbit performance of the N21 VIIRS TEB using various parameters such as the detector gain, noise, and offset. This on-orbit assessment provides critical insights into instrument behavior and calibration performance that will inform pre-launch testing and post-launch validation strategies for the upcoming JPSS-4 VIIRS mission scheduled for launch in 2027. The methodologies and lessons learned from characterizing the N21 TEB performance will enable more efficient and comprehensive radiometric assessment of the next VIIRS instrument. Specific focus is placed on identifying performance trends and anomaly signatures observed during the N21 commissioning phase that can enhance the JPSS4 instrument checkout procedures and accelerate the transition to routine on-orbit operations. The established performance baselines and uncertainty estimates will serve as an acceptance criterion for the JPSS-4 commissioning activities, ensuring mission readiness and data continuity for operational users.

Amit Angal↗

A Preliminary Assessment of Cognition and Fatigue During Simulated Lunar Surface Extravehicular Activities

Introduction: Artemis astronauts will be required to complete more rigorous Extravehicular Activity (EVA) schedules than during ever before. While new spacesuits are designed to sustain high physical workloads during exploration EVAs (xEVA), crewmembers must also sustain cognitive performance throughout xEVA timelines. It is therefore necessary to characterize the effects of surface xEVA tasks and timelines on cognition and fatigue. Methods: This study utilized NASA Johnson Space Center’s Active Response Gravity Offload System (ARGOS) to simulate lunar gravity and assess xEVA tasks and cognitive performance. Two subjects completed two ~5-hour EVAs in a pressurized Mark III spacesuit, completing simulated lander operations, cable routing, crew rescue, geology, payload relocation, and traverses. Subjects completed two cognitive assessments (Digit-Symbol Substitution Task (DSST) and Psychomotor Vigilance Task (PVT)) before the first and after the second simulated EVA to assess effects of xEVA tasks on processing speed and vigilant attention. Additionally, sleep (e.g., quality, duration, and efficiency) was monitored (Oura Ring) for ≥7 days prior to the simulated EVAs, as well as between each EVA, to account for possible effects of sleep decrements on cognitive metrics. Results: Cognitive performance changed minimally from pre to post EVA for both DSST (response time (RT): S1 Δ129.1ms, S2 Δ40.7ms; Accuracy: S1 preEVA = 1.0, S1 postEVA = 0.98, S2 preEVA = 1.0, S2 postEVA = 1.0) and PVT (S1 PVT RT Δ17.7 ms, S2 PVT RT Δ-2.7 ms). Subjects’ sleep duration immediately prior to EVA showed minimal deviation from baseline (Δhrs; S1 preEVA1= + 0.67, S1 preEVA2 = -.03, S2 preEVA1 = - 1.1, S2 preEVA2 = -1.39) and efficiency (Δ%; S1 preEVA1 = 0.09, S1 preEVA2 = 9.54, S2 preEVA1 = 0, S2 preEVA2= 12). Notably, sleep waketime shifted earlier for one subject by ~1 hr which may have impacted performance. Conclusion: Understanding the impacts of xEVA workloads on cognitive performance will be instrumental to future exploration mission planning and success. Future work will expand the subject pool and test new spacesuit designs to better characterize cognitive performance and impacts of sleep during simulated xEVA and inform modeling and prediction capabilities for future Artemis xEVA planning.

Taylor E. Schlotman↗

A Novel High‐Performance Electrolyte for Extreme Fast Charging in Pilot Scale Lithium‐Ion Pouch Cells

Realizing extreme fast charging (XFC) in lithium-ion batteries for electric vehicles is still challenging due to the insufficient lithium-ion transport kinetics, especially in the electrolyte. Herein, a novel high-performance electrolyte (HPE) consisting of lithium bis(fluorosulfonyl)imide (LiFSI), lithium hexafluorophosphate (LiPF 6 ) and carbonates is proposed and tested in pilot-scale, 2-Ah pouch cells. Moreover, the origin of improved electrochemical performance is comprehensively studied via various characterizations, suggesting that the proposed HPE exhibits high ionic conductivity and excellent electrochemical stability at high charging rate of 6-C. Furthermore, the HPE-based pouch cells deliver improved discharge specific capacity and excellent long-term cyclability up to 1500 cycles under XFC conditions, which is superior to the conventional state-of-the-art baseline electrolyte.

25 ENERGY STORAGE↗

Measurement of radiolytic hydrogen generation and impact of drying treatments on reactor exposed and surrogate aluminum materials

Technical challenges associated with dry storage of Aluminum-clad Spent Nuclear Fuel (ASNF) include a need to better understand the potential extent of gaseous molecular hydrogen (H 2 ) production through radiolytic degradation of the aluminum (oxy)hydroxide films present on ASNF. The characterization of radiolytic gas generation from ASNF (oxy)hydroxide layers has been identified as a key knowledge gap which poses a technical challenge to the long-term storage of ASNF. Task 2 of the action plan for the extended (>50 years) dry storage of ASNF addresses this gap. Previous radiolysis studies performed under Task 2 established baseline estimates of H 2 generation rates from the attendant hydrated oxides. The results confirmed that net radiolytic H 2 production has a dependency on absorbed gamma dose, as well as relative humidity and cover gas composition (air, nitrogen, and argon). Further experiments revealed that the physisorbed water on the samples may significantly impact the radiolytic H 2 yield. This phenomenon complicates the determination of H 2 generation rates for hydrated oxides, which may lead to inaccurate modeling predictions of the long-term H 2 yields in sealed storage systems containing ASNF, particularly when compared to spent fuel casks which have undergone some drying process intended to remove physically- and chemically-bound water. This report describes the testing methods utilized and the hydrogen generation results obtained in an investigation of the effects of gamma irradiation on aluminum materials for a variety of (oxy)hydroxide surface compositions and drying conditions. The testing methods included small-area aluminum material testing in ampules, and large-area aluminum material testing in steel vessels. Test material preparation, irradiation, and radiolytic H 2 measurement methods are summarized. The measured H 2 concentrations, which reflect the variable initial hydrated inventory and drying treatments, are compared to one another as well as to previously published data, to identify the primary factors affecting radiolytic H 2 generation rates and potential equilibrium H 2 concentrations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Machine Learning Assisted Safety Modeling and Analysis of Advanced Reactors

With the advances in computational power and numerical methods, analysts can now rely on first-principle simulations to predict ultra-fine details in a variety of applications. Advances in machine learning (ML) have produced algorithms that can now learn high-level abstractions via hierarchical models. This project aims to leverage advances in ML techniques and the available high-resolution simulation data to develop a novel modeling and simulation (M\&S) methodology for reactor safety analysis. While application-agnostic ML techniques are available, complex physics constraints need to be incorporated into ML techniques to build ML-based closures for computationally efficient predictive simulations. This project intends to develop a physics-guided data-driven multi-scale methodology for M\&S of advanced reactors. The project focuses on thermal fluid (T/F) phenomena, which play major roles in advanced reactor safety. Specifically, we propose a data-driven coarse-mesh turbulence model based on local flow features for the transient analysis of thermal mixing and stratification in a sodium-cooled fast reactor (SFR). The model has a coarse-mesh setup to ensure computational efficiency, while it is trained by fine-mesh computational fluid dynamics (CFD) data with Reynolds-averaged Navier-Stokes (RANS) turbulence model to ensure accuracy. Three different neural networks are developed and tested for loss-of-flow transients in the hot pool of SFR, i.e. the densely connected convolutional neural network (DCNN), long-short-term-memory network based on proper orthogonal decomposition (POD-LSTM), and the DCNN informed by LSTM (DCNN-LSTM). The performances of these three neural networks are evaluated based on baseline models. The DCNN-LSTM model has been chosen for further hyperparameter optimization. Furthermore, based on a simplified two-dimensional case, uncertainty quantification (UQ) of the developed ML-based closure are investigated with three methods, i.e. Monte Carlo dropout, deep ensemble, and Bayesian neural network. The developed ML-based turbulent viscosity closure relation based on deep ensemble is then integrated into the system analysis module SAM and serves as a term in the conservation equations. Such a SAM-ML based procedure guarantees that the obtained results are consistent with the physical constraints of the thermal-fluid system. The SAM-ML simulation on the same loss-of-flow transient showed comparable accuracy with the CFD simulation but with a much coarser mesh setup. Last but not least, the ML-based closure improvement with the support of higher-fidelity data from large eddy simulation (LES) is discussed. As a first step towards this direction, a baseline LES simulation is performed to obtain comparable data with RANS results. Based on the early results, future investigation on further improving the ML-based closure is discussed. We believe the developed approach that combines scientific machine learning with nuclear system analysis code can benefit the advanced reactor community as more accurate safety analyses will better characterize reactor safety margins and reduce licensing efforts.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Design and control of active vision based mechanisms for intelligent robots

In this paper, we propose a design of an active vision system for intelligent robot application purposes. The system has the degrees of freedom of pan, tilt, vergence, camera height adjustment, and baseline adjustment with a hierarchical control system structure. Based on this vision system, we discuss two problems involved in the binocular gaze stabilization process: fixation point selection and vergence disparity extraction. A hierarchical approach to determining point of fixation from potential gaze targets using evaluation function representing human visual behavior to outside stimuli is suggested. We also characterize different visual tasks in two cameras for vergence control purposes, and a phase-based method based on binarized images to extract vergence disparity for vergence control is presented. A control algorithm for vergence control is discussed.

Wu, Liwei↗

Aerodynamic Characterization of a Thin, High-Performance Airfoil for Use in Ground Fluids Testing

The FAA has worked with Transport Canada and others to develop allowance times for aircraft operating in ice-pellet precipitation. Wind-tunnel testing has been carried out to better understand the flowoff characteristics and resulting aerodynamic effects of anti-icing fluids contaminated with ice pellets using a thin, high-performance wing section at the National Research Council of Canada Propulsion and Icing Wind Tunnel. The objective of this paper is to characterize the aerodynamic behavior of this wing section in order to better understand the adverse aerodynamic effects of anti-icing fluids and ice-pellet contamination. Aerodynamic performance data, boundary-layer surveys and flow visualization were conducted at a Reynolds number of approximately 6.0×10(exp 6) and a Mach number of 0.12. The clean, baseline model exhibited leading-edge stall characteristics including a leading-edge laminar separation bubble and minimal or no separation on the trailing edge of the main element or flap. These results were consistent with expected 2-D aerodynamics and showed no anomalies that could adversely affect the evaluation of anti-icing fluids and ice-pellet contamination on the wing. Tests conducted with roughness and leading-edge flow disturbances helped to explain the aerodynamic impact of the anti-icing fluids and contamination. The stalling characteristics of the wing section with fluid and contamination appear to be driven at least partially by the effects of a secondary wave of fluid that forms near the leading edge as the wing is rotated in the simulated takeoff profile. These results have provided a much more complete understanding of the adverse aerodynamic effects of anti-icing fluids and ice-pellet contamination on this wing section. This is important since these results are used, in part, to develop the ice-pellet allowance times that are applicable to many different airplanes.

Broeren, Andy P.↗

A Celestial Reference Frame at X/ka-Band (8.4/32 Ghz) for Deep Space Navigation

Deep space tracking and navigation are done in a quasi-inertial reference frame based upon the angular positions of distant active galactic nuclei (AGN). These objects, which are found at extreme distances characterized by median redshifts of z = 1, are ideal for reference frame definition because they exhibit no measurable parallax or proper motion. They are thought to be powered by super massive black holes whose gravitational energy drives galactic sized relativistic jets. These jets produce synchrotron emissions which are detectable by modern radio techniques such as Very Long baseline Interferometry (VLBI).

very long baseline interferometry (VLBI)↗

Longitudinal Plasma Proteomic Profiling Reveals Divergent Immune Responses in Durably Cured and Relapsed Pulmonary Tuberculosis

Background: Predicting the risk of tuberculosis (TB) relapse is vital to improving treatment outcomes. Although clinical risk factors of relapse are well characterized, the biological mechanisms driving relapse, particularly host immune responses, remain poorly understood. Elucidating these mechanisms is necessary to better predict relapse risk. Methods: We conducted a longitudinal, global proteomic study on 60 participants with active pulmonary TB, half who were durably cured and half who relapsed. Plasma was collected at seven time-points: at treatment initiation (baseline), during therapy, and 52 weeks post-baseline. Samples were analyzed by high-resolution LC-MS/MS. Results: 2,418 proteins were identified across all samples, with 1,756 being differentially expressed relative to baseline (unadjusted p < 0.05). 956 proteins were differentially abundant between cured and relapsed participants. Relapsed participants showed heightened humoral immunity throughout treatment, as well as upregulated complement activation and HDL particles. Cured participants exhibited elevated recovery-related pathways by week 4, including downregulated epithelial invasion and upregulated oxygen transport. Conclusions: Heightened humoral and innate immune responses were associated with relapse, whereas recovery signatures were associated with durable cure. These findings advance our understanding of host responses to treatment and provide a basis for developing blood-based biomarkers to identify patients at increased risk of relapse.

LC-MS/MS↗

Beam-beam backgrounds for the Cool Copper Collider

In this paper, we present a comprehensive characterization of beam-beam backgrounds for the Cool Copper Collider (C 3 ), a proposed linear e + e - collider designed for precision Higgs studies at center-of-mass energies of 250 and 550 GeV. Using a simulation pipeline based on the Key4hep framework, we evaluate incoherent pair production and hadron photoproduction backgrounds through the SiD detector for baseline, power-efficiency, and high-luminosity C 3 operating scenarios. The occupancy induced by the beam-beam background is evaluated for each scenario, validating the compatibility of the existing SiD detector design with operations at C 3 without substantial modifications. Furthermore, at the same time, the modular simulation framework and analysis methodology presented in this paper offer a versatile toolkit for background studies in future collider proposals, contributing to a common platform for different machine designs.

Analysis and statistical methods↗

Evolution of global snow drought characteristics from 1850 to 2100

Abstract Seasonal snow is an integral part of the global water supply and storage system. Snow droughts impact ecological, agricultural, and urban systems by altering the amount and timing of meltwater delivery. These droughts are characterized by a lack of on-the-ground snow (snow water equivalent, SWE) that can be caused by low total precipitation (dry drought) or low proportion of precipitation falling as snowfall (warm drought), often combined with an early melt. The standardized SWE index (SWEI) ranks the current status of SWE for a given location compared to a baseline condition and identifies the existence, but not the cause, of snow drought. In this work, we use estimates of SWE, temperature, and precipitation from nine coupled model intercomparison project phase 6 (CMIP6) models to quantify the frequency, severity, and type of snow droughts globally for historical and future scenarios. Compared to a historical baseline (1850–1900) total snow drought frequency more than doubles under socio-economic pathway (SSP)2-4.5 and SSP5-8.5; all of the increase in snow drought frequency comes from an increase in warm droughts. The probability distribution of future SWEI in major snowy basins around the world are likely to be centered on more negative values, which corresponds to more severe drought and, with only moderate changes in distribution spread, more frequent drought. CMIP6 simulations pinpoint snow drought as an emerging global threat to water resources and highlight the need to explore higher resolution future models that better capture complex mountain topography, wildland fires, and snow-forest interactions.

CMIP6↗

Estimating CO 2 fluxes through integrating spatial and temporal input layers via deep learning algorithms

Background Accurate estimation of net ecosystem exchange of CO 2 fluxes (Fc) is essential for understanding carbon cycle processes and assessing ecosystem carbon budgets. However, conventional modeling approaches often emphasize temporal dynamics while overlooking the pronounced spatial heterogeneity within the footprint of eddy covariance (EC) towers, potentially limiting predictive accuracy and interpretability of Fc estimates. To address this challenge, we developed a spatiotemporal model that integrates high-resolution footprint-weighted spatial information with sequential environmental drivers. Results The integrated model combines a deeper graph convolutional network to characterize fine-scale spatial variability within EC footprints and a gated recurrent unit network to capture temporal dependencies in biophysical conditions. Using multi-year flux tower observations, remote sensing vegetation indices and footprint modeling, we evaluate the proposed method across three land cover types. This spatiotemporal model consistently outperforms temporal-only and spatial-only baselines, achieving the highest overall accuracy (R 2 = 0.9569) and the lowest RMSE (1.8128 μmol m −2 s −1 ) and MAE (1.1939 μmol m −2 s −1 ). Performance gains are particularly evident in ecosystems with strong vegetation heterogeneity, where spatial structure substantially modulates Fc variability. Conclusions This study demonstrates the importance of joint modeling spatial heterogeneity and temporal dynamics for improving Fc estimation and provides a robust method for advancing footprint-based Fc estimates across diverse ecosystems, supporting refined assessments of terrestrial carbon fluxes, and enhancing scientific foundations for carbon studies.

CO2 flux estimate↗

DMTN-221: Periodicity Analysis in Alert Production

The baselined timeseries features to be computed in Alert Production include a Lomb-Scargle periodogram ran on two classes of variable systems: RR Lyrae and Eclipsing Binaries. Based on a simulated LSST-like cadence light curves taken from the Extended LSST Astronomical Time-series Classification Challenge (ELAsTiCC) we perform an end-to-end test to characterize the periodicity recovery on the Alert Production multi-band light curves. In both variable classes, we found that a single-band Lomb-Scargle implementation yields to a low fraction of recovered periods, with a significant preference on the simple periodic phenomena such as RR Lyrae. We also investigated the results from a multi-band Lomb-Scargle and found an increased fraction of recovered periodicities above 15% for the eclipsing binaries, and over 80$\%$ for the RR Lyrae stars. Our findings suggest that a multi-band Lomb-Scargle should be implemented for searching periodic phenomena through AP. We also asses the computational and scientific performance of several configurations on simulated alert data and find that our current configuration scales linearly with the number of detections while assuming an heuristic frequency grid.

79 ASTRONOMY AND ASTROPHYSICS↗