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At least 685 records · Page 38
All sourcesNASA NTRSDOE OSTI
NASA NTRS1928

Drag of Exposed Fittings and Surface Irregularities on Airplane Fuselages

Measurements of drag were made on fittings taken from a typical fuselage to determine whether the difference between the observed full size fuselage drag and model fuselage drag could be attributed to the effects of fittings and surface irregularities found on the full size fuselage and not on the model. There are wide variations in the drag coefficients for the different fittings. In general those which protrude little from the surface or are well streamlined show very low and almost negligible drag. The measurements show, however, that a large part of the difference between model and full scale test results may be attributed to these fittings.

Wood, Donald H↗
NASA NTRS2022

Determination of Chlorophyll Content in Selected Grass Communities of Krkonoše Mts. Tundra Based on Laboratory Spectroscopy and Aerial Hyperspectral Data

The study focuses on the determination of chlorophyll content in four prevailing grasses in the relict arctic-alpine tundra located in the Krkonoše Mountains National Park, Czech Republic. We compared two methods for determination of leaf chlorophyll content (LCC) – spectrophotometric determination in the laboratory, and the LCC assessed by fluorescence portable chlorophyll meter CCM-300. Relationships were established between the LCCs and vegetation indices calculated from leaf spectra acquired with contact probe coupled with an ASD FieldSpec4 Wide-Res spectroradiometer. Canopy chlorophyll contents (CCC) were computed from the LCCs and green leaf area index (LAI), and modelled based on the field spectra measured by the spectroradiometer and the hyperspectral images acquired by Headwall Nano-Hyperspec® mounted on the DJI Matrice 600 Pro drone. The calculations are performed on datasets acquired in June, July and August 2020 together and separately for species and months. In general, the correlations based on June datasets work the best at both levels: median R 2 for all indices was 0.52 for all species together at leaf level and median R 2 = 0.47 at the canopy level (vegetation indices computed from field spectra). Canopy chlorophyll content map was created based on the results of stepwise multiple linear regression. The R 2 was 0.42 when using four wavelengths from the red and red edge spectral region. We attribute the weak model performance to a combination of several factors: leaf structure may bias LCC from laboratory measurements, effects of LAI variability on CCC, and the sampling design, probably not covering the whole phenology equally for all studied species.

L. Cervena↗
NASA NTRSDate not supplied

A Preliminary Study of Inter-Facility LWC Differences in Appendix C and Supercooled Large Drop Conditions due to Calibration Instruments

The simulation of clouds containing Supercooled Large Droplets has received increasing attention due to the introduction of Appendix O and future associated requirements for means of compliance. Supercooled Large Droplet conditions can cover four orders of magnitude in drop sizes, imposing a larger instrument measurement challenge than for Appendix C conditions. Wind tunnel facilities have adopted different instrumentation for liquid water content measurement, with fundamentally different principles of operation. In order to explore the comparability of the different instruments used for Appendix C and SLD measurement, and its impact on confidence in measurements used for means of compliance, a project was established to conduct a series of dedicated tests at three wind tunnel facilities. To date, liquid water content measurements have been completed using a Multi-Element sensor as the common instrument at two of the facilities. The data have provided preliminary information suggesting that substantial inter-facility differences likely exist in liquid water content estimates in Supercooled Large Droplet conditions that appear to be largely attributable to the choice of calibration instruments. These results are dependent on the assumption that the Multi-Element probe would produce equivalent measurements at the two facilities if the liquid water content were the same, regardless of other environmental differences that may exist between the two facilities. Planned further testing with other liquid water content measurement techniques may provide further information to confirm or refute the results of this study.

aircraft icing↗
NASA NTRSDate not supplied

A Preliminary Study of Inter-Facility LWC Differences in Appendix C and Supercooled Large Droplet Conditions due to Calibration Instruments

The simulation of clouds containing Supercooled Large Droplets has received increasing attention due to the introduction of Appendix O and future associated requirements for means of compliance. Supercooled Large Droplet conditions can cover four orders of magnitude in drop sizes, imposing a larger instrument measurement challenge than for Appendix C conditions. Wind tunnel facilities have adopted different instrumentation for liquid water content measurement, with fundamentally different principles of operation. In order to explore the comparability of the different instruments used for Appendix C and SLD measurement, and its impact on confidence in measurements used for means of compliance, a project was established to conduct a series of dedicated tests at three wind tunnel facilities. To date, liquid water content measurements have been completed using a Multi-Element sensor as the common instrument at two of the facilities. The data have provided preliminary information suggesting that substantial inter-facility differences likely exist in liquid water content estimates in Supercooled Large Droplet conditions that appear to be largely attributable to the choice of calibration instruments. These results are dependent on the assumption that the Multi-Element probe would produce equivalent measurements at the two facilities if the liquid water content were the same, regardless of other environmental differences that may exist between the two facilities. Planned further testing with other liquid water content measurement techniques may provide further information to confirm or refute the results of this study.

aircraft icing↗
DOE OSTI2021

Non-Ohmic negative longitudinal magnetoresistance in a two-dimensional electron gas

Negative longitudinal magnetoresistance (NLMR) has been reported in a variety of materials and has attracted extensive attention as an electrotransport hallmark of topological Weyl semimetals. However, its origin is still under debate. Here, we demonstrate that the NLMR in a two-dimensional electron gas can be influenced by the measurement current. While the NLMR persists up to 130 K, its magnitude and magnetic field response become dependent on the applied current below 60 K. The tunable NLMR at low and high currents can be best attributed to quantum interference and disorder scattering effects, respectively. This work uncovers non-Ohmic NLMR in a non-Weyl material and highlights potential effects of the measurement current in elucidating electrotransport phenomena. Here, we also demonstrate that NLMRs can be a valuable phenomenon in revealing the origins of other properties, such as negative MRs in perpendicular magnetic fields.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2010

RP-2 Thermal Stability and Heat Transfer Investigation for Hydrocarbon Boost Engines

A series of electrically heated tube tests were performed at the NASA Glenn Research Center s Heated Tube Facility to investigate the use of RP-2 as a fuel for next generation regeneratively cooled hydrocarbon boost engines. The effect that test duration, operating condition and test piece material have on the overall thermal stability and materials compatibility characteristics of RP-2 were evaluated using copper and 304 stainless steel test sections. The copper tests were run at 1000 psia, heat flux up to 6.0 Btu/in.2-sec, and wall temperatures up to 1180 F. Preliminary results, using measured wall temperature as an indirect indicator of the carbon deposition process, show that in copper test pieces above approximately 850 F, RP-2 begins to undergo thermal decomposition resulting in local carbon deposits. Wall temperature traces show significant local temperature increases followed by near instantaneous drops which have been attributed to the carbon deposition/shedding process in previous investigations. Data reduction is currently underway for the stainless steel test sections and carbon deposition measurements will be performed in the future for all test sections used in this investigation. In conjunction with the existing thermal stability database, these findings give insight into the feasibility of cooling a long life, high performance, high-pressure liquid rocket combustor and nozzle with RP-2.

VanNoord, J. L.↗
DOE OSTI2020

Control of passivation and compensation in Mg-doped GaN by defect quasi Fermi level control

A defect quasi Fermi level (dQFL) control process based on above bandgap illumination was applied to control H and V N -complexes, which are the main contributors to the passivation and self-compensation, respectively, in Mg:GaN grown via metalorganic chemical vapor deposition. Secondary ion mass spectrometry measurements confirmed that the total Mg incorporation was unaffected by the process. However, the total H concentration was reduced to similar levels obtained by post-growth thermal activation prior to any annealing treatment. Similarly, the 2.8 eV emission in the photoluminescence spectra, attributed to compensating V N and its complexes, was reduced for the dQFL-process samples. After thermal activation and Ni/Au contact deposition, Hall effect measurements revealed lower resistivities (increased mobilities and free hole concentrations) for dQFL-grown samples with Mg doping concentrations above and below 2 × 10 19 cm -3 . All these results demonstrate that the dQFL process can effectively reduce the H-passivation and self-compensation of the Mg:GaN films.

36 MATERIALS SCIENCE↗
NASA NTRS1966

Short Period Fluctuations in Intelligence Final Report

The problem of isolating fluctuations in intellectual function is one that has long intrigued both psychologists and non-psychologists, We are all aware of our own short-period physiological, mood and motivational changes and many believe that their intelligence must undergo similar change. 1965 for a recent review) does not provide support for this kind of argu- ment. It indicates that measures of intelligence - -at least those intended for use with people other than infants --are usually highly stable over both short and rather extended periods of time: the changes which are indicated have almost always been regarded as errors of measurement. Thus in scientific developments (as opposed, perhaps, to common- sense discussions) ;intelligence usually has been regarded as a highly stable attribute of man. But existing scientific evidence (see Tyler, A notable exception to the scientific theory arguing (albeit im- plicitly) that human intellect does not fluctuate over short period of time is that of Moran (1961) and his co-workers (Moran, Kimble & Mefferd, 1960; 1964; Moran & Mefferd, 1959). The work of these in- vestigators has been directed at designing alternate -form tests to measure some of what are now regarded as the major, replicated-by- research dimensions of human intelligence, viz., what are known as the primary mental abilities (French, 1951: French, Ekstrom & Price, 1963; Guilford, 1966; Guilford & Merrifield, 1960). The Repetitive Psychological Measures (RPM) resulting from this work are intended to assess "change in performance with time" (Moran & Mefferd, 1959: p. 269). little has been done to determine whether or not the performances actually assessed do, in fact, change in a reliable manner. Indeed, evidence somewhat contrary to an hypothesis of short-period change is provided by the high (relative to test length) test-retest correlations ob- tained over a period of 3 hours with the RPM tests (Moran & Mefferd, 1959; Table 2). Hence, while a basic hypothesis underlying this work certainly does imply that abilities change over short periods, evidence for this hypothesis either has not been developed or, where it has (as in test-retest correlations), does not provide convincing support for the hypothesis

Intelligence↗
NASA NTRS1994

Continuous measurement of aircraft wing icing

Ice formation on the wings of aircraft is a problem that has plagued air travel since its inception. Several recent incidents have been attributed to ice formation on the lifting surfaces of wings. This paper describes a SBIR Phase 1 research effort on the use of small flat dielectric sensors in detecting a layer of ice above the sensor. The sensors are very small, lightweight, and inexpensive. The electronics package that controls the sensor is also small, and could be even smaller using commonly available miniaturization technologies. Thus, several sensors could be placed on a surface such that a representative ice thickness profile could be measured. The benefits offered by developing this technology go beyond the safety improvements realized by monitoring ice formation on the wings of an aircraft. Continuous monitoring of anti-icing fluid concentrations on the ground would warn the pilot of impending fluid failure as well as allowing the stations to use less de-icing solution per aircraft. This in turn would increase the safety of takeoffs and reduce the overall discharge of de-icing solution into the environment, thus reducing the biohazard of the de-icing procedure.

Yao, Stephen S. C.↗
NASA NTRS1991

Thermal barrier coating life prediction model development, phase 2

The objective of this program was to generate a life prediction model for electron-beam-physical vapor deposited (EB-PVD) zirconia thermal barrier coating (TBC) on gas turbine engine components. Specific activities involved in development of the EB-PVD life prediction model included measurement of EB-PVD ceramic physical and mechanical properties and adherence strength, measurement of the thermally grown oxide (TGO) growth kinetics, generation of quantitative cyclic thermal spallation life data, and development of a spallation life prediction model. Life data useful for model development was obtained by exposing instrumented, EB-PVD ceramic coated cylindrical specimens in a jet fueled burner rig. Monotonic compression and tensile mechanical tests and physical property tests were conducted to obtain the EB-PVD ceramic behavior required for burner rig specimen analysis. As part of that effort, a nonlinear constitutive model was developed for the EB-PVD ceramic. Spallation failure of the EB-PVD TBC system consistently occurred at the TGO-metal interface. Calculated out-of-plane stresses were a small fraction of that required to statically fail the TGO. Thus, EB-PVD spallation was attributed to the interfacial cracking caused by in-plane TGO strains. Since TGO mechanical properties were not measured in this program, calculation of the burner rig specimen TGO in-plane strains was performed by using alumina properties. A life model based on maximum in-plane TGO tensile mechanical strain and TGO thickness correlated the burner rig specimen EB-PVD ceramic spallation lives within a factor of about plus or minus 2X.

Meier, Susan Manning↗
NASA NTRS1993

Critical review of electrical conductivity measurements and charge distribution analysis of magnesium oxide

The electrical conductivity sigma of MgO single crystals shows a sharp increase at 500-800 C, in particular of sigma surface, generally attributed to surface contamination. Charge Distribution Analysis (CDA), a new technique providing information on fundamental properties that was previously unavailable, allows for the determination of surface charges, their sign and associated internal electric field. Data on 99.99% purity, arc-fusion grown MgO crystals show that mobile charge carriers start to appear in the bulk of the MgO crystals between 200 and 400 C when sigma (measured by conventional techniques) is in t he 10(exp -14) to 10(exp -16) /omega/cm range. Above 500 C, as sigma increases to 10(exp -6) to 10(exp -7)/omega/cm, more charges appear giving rise to a strong positive surface charge supported by a strong internal field. This indicates that charges are generated in the bulk and diffuse to the surface by an internally controlled process. On the basis of their positive sign they are identified as holes (defect electrons). Because of the low cation content of these very pure MgO crystals, theses holes cannnot be associated with transition metal impurties. Instead, they are associated with the O(2-) sublattice, e.g. consist of O(-) states or positive holes. This conclusion is supported by magnetic susceptibility data showing the appearance of 1000 +/- 500 ppm paramagnetic species between 200-500 C. The magnetic data are consistent with strongly coupled, diamagnetic O(-) pairs below 200-500 C, chemically equivalent to peroxy anions, O2(2-), and probably associated with cation vacancies in the MgO matrix. The formation of O2(2-) in arc-fusion grown MgO crystals is very unexpected because of the highly reducing growth conditions. Their presence implies an internal redox reaction involving dissolved 'water' by which OH(-) pairs convert to O2(2-) plus H2 molecules. This redox conversion is supported by mass spectroscopic measurements of the H2 release from highly OH(-)-doped, finely divided MgO and by wet-chemical analysis of its oxidant concentration.

Freund, Friedemann↗
NASA NTRS2022

Charging Experiments and Filtration Testing on Facemask Materials: Towards Goals of Full Performance Restoration of Used N95 Masks and Enhancement of Common-Fabric Facemasks

Different techniques have been developed for sanitizing N95 masks while retaining whatever charge remains on them. However, these sanitizing methods do not address the fact that the electrical charge, filtration efficacy, and breathability of such masks may be expected to degrade during long-term use based on mechanisms known in the literature. In this study, approaches to electrically (re)charging facemask filter materials were explored in response to the COVID-19 induced shortage of N95 masks. The effort consisted of charging experiments followed by filtration testing conducted at the coupon level during a month-long period (May 2020). The main focus of the work was to develop a recharging technique which could eventually be adapted and used as part of a broader full-performance restoration process for used N95 masks, e.g., which might employ simple washing by alcohol or soapy water as a preceding step for sanitization and declogging. Most tested coupons were therefore nonwoven meltblown fibrous polypropylene (PP) filter media extracted from decades old N95 masks. Keeping in mind commonly used cloth facemasks, limited trials were also performed with some commercially available fabrics. Charging was done at elevated temperature and was followed by cooling to freeze in the applied charges produced from corona discharges using different electrode configurations and parameter combinations, or from triboelectric rubbing. Charging was also focused on using potentially scalable equipment, e.g., Van de Graaff generators or consumer ionic hair products. Some degree of success was achieved with one of the fabrics and the PP filter media which was first purposefully discharged to have typical filtration efficiency (FE) of ~35%. Numerous attempts at corona charging discharged media resulted in filtration efficiency (FE) ≥ 80 – 85%. Some measure of charge robustness was also established via stable performance during loading testing. However, results where FE ≥ 90% were not reliably repeatable and no results met the FE ≥ 95% goal due to shortcomings of the charging process. The best three trials for PP media statistically met the FE ≥ 90% criteria, amounted to a small percentage of the trials relying on an ionic hair dryer, and are attributed to good embedding of charges via aerodynamic force. Triboelectric charging significantly enhanced the viability of one of the polyester fabrics –measured FE increased from 19% up to 46% while maintaining a reasonably low pressure drop.

N95↗
NASA NTRS2014

Mars' Water Vapor Mapping by the SPICAM IR Spectrometer: Five Martian Years of Observations

The SPICAM IR instrument on the Mars Express mission continuously observes the water vapor in the martian atmosphere starting from 2004 in the 1.38-micrometer spectral band. The water vapor column abundance is retrieved from nadir observations to characterize its spatial, seasonal and interannual variations. A reference set of SPICAM water vapor column abundances (zonally averaged) covering the time period from 2004 to 2013 (martian years 27-31) is available for a grid of 2 deg Ls 2 latitude, along with an average reference map of water vapor abundance combining all the martian years of Mars Express observations. Compared to the previous data retrieval by Fedorova et al. (Fedorova, A., Korablev, O., Bertaux, J.L., Rodin, A., Kiselev, A., Perrier, S. [2006]. J. Geophys. Res. 111, E09S08) the new processing algorithm includes many improvements concerning the calibration and assumed parameters. A major improvement is the account for aerosol scattering based on dust and water ice cloud optical depths measured by THEMIS/Mars Odyssey (Smith, M.D. [2009]. Icarus 202, 444-452). The account for multiple scattering by aerosol particles increases the retrieved water vapor amount by approximately 10% in polar areas during summer, and up to 60-70% for large solar zenith angles. The sensitivity of the results to aerosol properties, surface albedo, solar spectrum, and water vapor vertical distribution has also been studied. The retrieved water vapor reveals nominal annual cycle with maximum abundance of about 60-70 pr. lm for the Northern summer and approximately 20 pr. lm for the Southern summer. The annual average amount of water has been estimated to be of 10-20 pr. micrometers, in agreement with other measurements. From year to year the seasonal cycle of water vapor abundance is very stable. An observed decrease during the MY 28 global dust storm cannot be fully attributed to the masking effect of dust, and indicates a real decrease of water amount near or above the surface. No evidence of diurnal variation of column water vapor amount was found, even though the 1.38-micrometer measurements are sensitive to the few lowermost kilometers above the surface.

Mars water vapor↗
NASA NTRS2011

Effects of Bed Rest on Conduction Velocity of the Triceps Surae Stretch Reflex and Postural Control

Despite rigorous exercise and nutritional management during space missions, astronauts returning from microgravity exhibit neuromuscular deficits and a significant loss in muscle mass in the postural muscles of the lower leg. Similar changes in the postural muscles occur in subjects participating in long-duration bed rest studies. These adaptive muscle changes manifest as a reduction in reflex conduction velocity during head-down bed rest. Because the stretch reflex encompasses both the peripheral (muscle spindle and nerve axon) and central (spinal synapse) components involved in adaptation to calf muscle unloading, it may be used to provide feedback on the general condition of neuromuscular function, and might be used to evaluate the effectiveness of countermeasures aimed at preserving muscle mass and function during periods of unloading. Stretch reflexes were measured on 18 control subjects who spent 60 to 90 days in continuous 6 deg head-down bed rest. Using a motorized system capable of rotating the foot around the ankle joint (dorsiflexion) through an angle of 10 degrees at a peak velocity of about 250 deg/sec, a stretch reflex was recorded from the subject's left triceps surae muscle group. Using surface electromyography, about 300 reflex responses were obtained and ensemble-averaged on 3 separate days before bed rest, 3 to 4 times in bed, and 3 times after bed rest. The averaged responses for each test day were examined for reflex latency and conduction velocity (CV) across gender. Computerized posturography was also conducted on these same subjects before and after bed rest as part of the standard measures. Peak-to-peak sway was measured during Sensory Organization Tests (SOTs) to evaluate changes in the ability to effectively use or suppress visual, vestibular, and proprioceptive information for postural control. Although no gender differences were found, a significant increase in reflex latency and a significant decrease in CV were observed during the bed rest period, with a return to baseline 3 to 5 days after bed rest, depending on the duration of bed rest. In addition, a relationship between CV and loss of muscle strength in the lower leg was observed post bed rest for most subjects. Immediately post-bed rest, most subjects showed decreased performance on SOTs, with the greater decrements on sway-referenced support and head movement conditions. Post-bed rest decrements were less than typically observed following spaceflight. Decrements in postural control and the stretch reflex can be primarily attributed to the unloading mechanisms this ground-based analog provides. The stretch reflex is a concise test measurement that can be obtained during the head-down phase of bed rest, as it does not interfere with the bed rest paradigm. This makes it an ideal tool that can detect, early on, whether a countermeasure is successful in preserving muscle function.

Reschke, M. F.↗
DOE OSTI2021

Scaling of oxygen-methane reacting coaxial jets using x-ray fluorescence to measure mixture fraction

Stoichiometric mixing length L s of reacting coaxial jet flames is a critical scaling parameter for liquid rocket engine combustors. Previous studies have shown that L s for shear coaxial flames can be scaled like their non-reacting counterparts using a non-dimensional momentum flux ratio J. In addition, stoichiometric mixing lengths of reacting and nonreacting coaxial jets collapse upon a single line by altering J using an effective outer flow gas density. This effective density is calculated from a modified version of the equivalence principle, originally developed by Tacina and Dahm [1, 2] and accounts for the effects of heat release on mixing. However, previous studies also required a second nonphysical scaling constant S c for the reacting jets, which is not predicted by the equivalence principle [3]. It was originally hypothesized that S c is attributed to the limitation of hydroxyl (OH) planar laser-induced fluorescence, which only infers L s . Direct quantitative measurement of conserved scalar fields using conventional optical diagnostics is difficult due to the lack of a tracer that easily fluoresces, survives high temperature oxygen flames, and is not dominated by quenching effects. To measure a conserved scalar field, this work implements x-ray fluorescence of Kr and Ar tracers to obtain quantitative mixture fraction fields. From these mixture fraction fields, stoichiometric mixing lengths for two CH 4 /O 2 flames are calculated and scaled against nonreacting coaxial mixing lengths using the equivalence principle. By directly measuring the stoichiometric mixing length, it is established that the additional constant is a byproduct of the OH measurement technique and the equivalence principle fully captures the scaling. Finally, comparison with high-fidelity simulation of the flame further supports this conclusion. In addition to further strengthening this scaling method, this work represents the first use of x-ray fluorescence to make quantitative conserved scalar measurements in turbulent flames.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2023

Polycarbonate‐Based Solid‐Polymer Electrolytes for Solid‐State Sodium Batteries

Solid-polymer electrolytes comprised of polypropylene carbonate (PPC) and varied sodium bis(fluorosulfonyl)imide (NaFSI) salt concentrations are investigated for implementation as a conductive solid polymer electrolyte into solid-state cathode composites utilizing a sodium-layered oxide active material. The ionic conductivity generally increases with NaFSI salt content, reaching ≈1 mS cm −1 at 80 °C at the highest salt concentration (PPC:NaFSI = 0.5:1). Through an all-in-one slurry casting method, Na 2/3 Ni 1/3 Mn 2/3 O 2 cathode composites are fabricated in which the dispersed PPC electrolyte acts as the primary binder. Enabled by a bilayer polymer electrolyte system, cycling performance with the PPC cathode electrolyte is optimized with respect to salt concentration and anode material. The best cyclability is achieved with a moderate salt concentration electrolyte (PPC:NaFSI = 5:1), showcasing an initial capacity of 83 mA h g −1 with a remarkable 80% capacity retention after 150 cycles at C/5 rate and 60 °C. The superior performance of the lower salt concentration electrolyte is attributed to better electrochemical stability, as confirmed by linear sweep voltammetry and online electrochemical mass spectrometry measurements. In conclusion, these results underscore the potential of carbonate-based polymer electrolytes and the importance of balancing electrolyte conductivity and stability in cell design.

25 ENERGY STORAGE↗
DOE OSTI2020

Size Dependence of Lattice Parameter and Electronic Structure in CeO2 Nanoparticles

Intrinsic properties of a compound (e.g. electronic structure, crystallographic structure, optical and magnetic properties) define notably its chemical and physical behavior. In the case of nanomaterials, these fundamental properties depend on the occurrence of quantum mechanical size effects and on the considerable increase of the surface to bulk ratio. However, the literature on this size-dependence and on the involved mechanisms is quite elusive and scarce. Here, we explore the size-dependence of both crystal and electronic properties of CeO2 nanoparticles (NPs) with different sizes by state-of-the art spectroscopic techniques. XRD, XPS and HERFD-XANES demonstrate that the as-synthesized NPs crystallize in the fluorite structure and they are predominantly composed of CeIV ions. The strong dependence of the lattice parameter with the NPs size was attributed to the presence of adsorbed species at the NPs surface thanks to FTIR and TGA measurements. In addition, the size-dependence of the eg level in the Ce LIII XANES spectra was experimentally observed by HERFD-XANES and confirmed by theoretical calculations.

Lanthanide, CeO2, HEFRD-XANES, Electronic structur↗