A Markovian reset problem
Optimal control of systems with time transitions described by finite state stationary Markov chain, noting resetting control
Kolesar, P.↗
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Results for “Transition state”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Magnetism, dimensional changes, and magnetic transitions in hydrated cesium manganese chloride
Dimensional changes (strain) along the three principal crystal axes of the antiferromagnet CsMnCl3-2H2O are studied as a function of magnetic field and temperature in the antiferromagnetic, spin flopped, and paramagnetic phases. Changes in dimensions through the phase transitions between the magnetic states are examined. By applying the molecular field model and utilizing all available information, magnetic properties of CsMnCl3-2H2O are determined. The possible usefulness of this material in a magnetic refrigeration cycle is evaluated.
Woollam, J. A.↗
Can astrophysical abundances be taken seriously.
The essential feature underlying abundance analysis is the assumption that local thermodynamic equilibrium prevails in a stellar atmosphere - i.e., that all relevant distribution functions, except that for the photons themselves, are thermal and determined by the local temperature. It is pointed out that the blanket assumption of local thermodynamic equilibrium in stellar atmospheres is a fundamental weakness. The assumption can only be valid if collisional processes are dominant in bringing about transitions between the excitation states of an atom. It has, however, been shown that the density in a stellar atmosphere is so low that, on the contrary, radiative processes are predominant.
Worrall, G.↗
The oscillator strengths of the SO /A 3Pi/-/X 3Sigma-/ band systems.
The oscillator strengths for these SO transition band systems are calculated using RKR Franck-Condon factors and the radiative lifetime previously derived from electron-beam phase-shift measurements by Smith (1971). The SO transition concerned is of considerable astrophysical importance in the search for SO in the interstellar medium by means of space-based telescopes with monochromators since the transition probability is concentrated, as shown, in relatively few transitions from the ground state.
Smith, W. H.↗
The applications of satellites to communications, navigation and surveillance for aircraft operating over the contiguous United States
The objective was to determine on a priority basis the satellite applications to communications, navigation, and surveillance requirements for aircraft operating beyond 1975 over the contiguous United States and adjacent oceanic transition regions, and to determine if and how satellite technology can meet these requirements in a reliable, efficient, and economical manner. Major results and conclusions are as follows: (1) The satellite applications of greatest importance are surveillance and rapid collision warning communications; and (2) The necessary technology is available as demonstrated by an attractive system concept.
Craigie, J. H.↗
Monte-Carlo analysis of rarefied-gas diffusion including variance reduction using the theory of Markov random walks
Molecular diffusion through a rarefied gas is analyzed by using the theory of Markov random walks. The Markov walk is simulated on the computer by using random numbers to find the new states from the appropriate transition probabilities. As the sample molecule during its random walk passes a scoring position, which is a location at which the macroscopic diffusing flow variables such as molecular flux and molecular density are desired, an appropriate payoff is scored. The payoff is a function of the sample molecule velocity. For example, in obtaining the molecular flux across a scoring position, the random walk payoff is the net number of times the scoring position has been crossed in the positive direction. Similarly, when the molecular density is required, the payoff is the sum of the inverse velocity of the sample molecule passing the scoring position. The macroscopic diffusing flow variables are then found from the expected payoff of the random walks.
Perlmutter, M.↗
Photoemission from CsI - Experiment.
Considerable attention in the investigation was given to the resolution maximization of details in the spectra. Very thin films were used in the measurements, which were conducted at 300 and 77 C with the aid of an improved photoemission apparatus. It was found that the principal features of the photoemission spectra from CsI cannot be explained on the basis of simple transitions from localized ionic states because such a model would predict a doublet instead of the triplet observed in the photoemission data.
Distefano, T. H.↗
Kerr response of nematic liquids.
Description of the results of recent observations of the Kerr effect in nematic liquid crystals in a temperature range just above their nematic-isotropic transition. These results indicate that the intermolecular ordering forces in a nematic substance can enhance the Kerr effect just above the nematic transition in their isotropic state. It is felt that existing theory provides a useful approximation for relating molecular size to response time.
Johnston, A. R.↗
IUS/TUG orbital operations and mission support study. Volume 3: Space tug operations
A study was conducted to develop space tug operational concepts and baseline operations plan, and to provide cost estimates for space tug operations. Background data and study results are presented along with a transition phase analysis (the transition from interim upper state to tug operations). A summary is given of the tug operational and interface requirements with emphasis on the on-orbit checkout requirements, external interface operational requirements, safety requirements, and system operational interface requirements. Other topics discussed include reference missions baselined for the tug and details for the mission functional flows and timelines derived for the tug mission, tug subsystems, tug on-orbit operations prior to the tug first burn, spacecraft deployment and retrieval by the tug, operations centers, mission planning, potential problem areas, and cost data.
Source record↗
A search for microwave emission from CH in Comet Kohoutek /1973f/
A search was conducted for the three 9-cm transitions of the ground state Lambda-doublet of CH in comet Kohoutek, using the CSIRO 64-m radio telescope and the Onsala Space Observatory's 25.6-m telescope. No lines were detected during the observing periods, and upper limits are given for the corresponding antenna temperatures.
Rydbeck, O. E. H.↗
New fine structure cooling rate
One of the dominant electron cooling processes in the ionosphere is caused by electron impact induced fine structure transitions among the ground state levels of atomic oxygen. This fine structure cooling rate is based on theoretical cross sections. Recent advances in the numerical cross section determinations to include polarization effects and more accurate representations of the atomic target result in new lower values. These cross sections are employed in this paper to derive a new fine structure cooling rate which is between 40% and 60% of the currently used rate. A new generalized formula is presented for the cooling rate (from which the fine structure cooling rate is derived), valid for arbitrary mass and temperature difference of the colliding particles and arbitrary inelastic energy difference.
Hoegy, W. R.↗
Calculation of rotational transition probabilities in molecular collisions - Application to N2 + N2
A computational method is proposed to obtain rotational transition probabilities in collisions between two diatomic molecules. The potential method of Rabitz and an exponential approximation are used to solve the semiclassical coupled equations without invoking any perturbational technique. The collision trajectory is determined in the classical modified-wave-number approximation. The method can treat systems involving strong interactions and provide probabilities for transitions even with a multiquantum jump. A simultaneous transition in the rotational states of both molecules, i.e., the rotational-rotational energy transfer, is taken into account. An application to the system N2 + N2 is presented.
Itikawa, Y.↗
New fine structure cooling rate
One of the dominant electron cooling processes in the ionosphere is caused by electron impact induced fine structure transitions among the ground state levels of atomic oxygen. This fine structure cooling rate is based on theoretical cross sections. Recent advances in the numerical cross section determinations to include polarization effects and more accurate representations of the atomic target result in new lower values. These cross sections are employed in this paper to derive a new fine structure cooling rate which is between 40% and 60% of the currently used rate. A new generalized formula is presented for the cooling rate (from which the fine structure cooling rate is derived), valid for arbitrary mass and temperature difference of the colliding particles and arbitrary inelastic energy difference.
Hoegy, W. R.↗
Comment on the relation between the nonadiabatic coupling and the complex intersection of potential energy curves
Simple relations are discussed that provide a correspondence between the complex intersection of two potential surfaces and the nonadiabatic coupling matrix element between those surfaces. These are key quantities in semiclassical and quantum mechanical theories of collision induced electronic transitions. Within the two state approximation, the complex intersection is shown to be directly related to the location and magnitude of the peak in the nonadiabatic coupling. Two cases are considered: the avoided crossing between two potential surfaces; and the spin orbit interaction due to a P-2 halogen atom. Comparisons are made between the results of the two-state model and the results of ab initio quantum chemical calculations.
Jaffe, R. L.↗
Calculation of radiative properties of nonequilibrium hydrogen plasma
A computer program called NEQRAP is described that calculates the radiative properties of nonequilibrium ionized hydrogen. From the given electron temperature, electron density, and atom density values (which do not necessarily satisfy the equilibrium relationship) and intensities of incident radiation, the non-Boltzmann populations of electronic states are computed by solving the equation of quasi-steady-state population distribution. Emission and absorption coefficients are determined as functions of wavelength by invoking the principle of detailed balance between the upper and lower states of each radiative transition. Radiative transport through the medium is computed assuming a one-dimensional uniform slab. The rate of ionic reaction is also computed. When used on a sample case, the program shows that there is a large difference between the calculated intensities of radiation emitted by a bulk of equilibrium and nonequilibrium hydrogen. The accuracy of the program is estimated to be better than 10%.
Park, C.↗
Multiple scattering and charged-particle - hydrogen-atom collisions
Glauber-approximation scattering amplitudes for charged-particle - hydrogen-atom elastic and inelastic collisions are derived directly in terms of the known particle-electron and particle-proton Coulomb scattering amplitudes and the known hydrogen-atom form factors. It is shown that the particle-hydrogen amplitude contains no single-scattering term. The double-scattering term is obtained as a two-dimensional integral in momentum space. It is demonstrated how the result can be used as the starting point for an alternative and relatively simple derivation, in closed form, of the Glauber particle-hydrogen scattering amplitude for transitions from the ground state to an arbitrary (nlm) state.
Franco, V.↗
Effects of angular-momentum-changing collisions on dielectronic satellite spectra
A generalization of the low-density corona-model theory of the intensities of satellite lines of the resonance lines emitted by multiply charged helium-like ions in the X-ray spectra of high-temperature plasmas is developed in order to take account of electron collisional transitions between close autoionizing levels. A formalism for determining the population densities of the autoionizing levels and the satellite line intensities is presented, and the quantum mechanical calculation of autoionization, radiative decay and electron-induced collisional transitions is discussed. Generalized emission rate coefficients corresponding to dielectronic recombination and inner-shell-electron collisional excitation are tabulated as functions of electron density and temperature. The procedure is then used to illustrate the effects of angular-momentum-changing electron collisions on the intensities of the satellites of the 1s2p 1P to 1s2 1S resonance line of the ions Al XII and Si XIII. It is concluded that the collisional transitions have their most significant effect on the intensities of satellite transitions from metastable autoionizing states, which may be useful in determining plasma densities.
Jacobs, V. L.↗
On the dynamics of agglomerating ensembles of clouds
It is shown that for dynamical time scales longer than 10 million years the ensemble of interstellar cold diffuse clouds may be described by equations of mass and momentum conservation where the pressure has the form p/v-squared/ where /v-squared/ is the mass averaged square velocity dispersion. Equilibrium cloud spectra are derived and an equation of state obtained. The equation of state undergoes a phase transition at a critical density close to the local interstellar gas density. At higher densities, more massive clouds are formed and the cloud fluid softens. It is suggested that this mechanism may naturally regulate the interstellar gas density if star formation is very efficient in the cooler high-density systems.
Cowie, L. L.↗