A high-pressure, clinopyroxene-structured polymorph of albite in highly shocked terrestrial and mete
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Soot formation in toluene-, benzene-, and acetylene-oxygen-argon mixtures was investigated to study soot formation in a combustion environment. High concentrations of oxygen completely suppress soot formation. The addition of oxygen at relatively low concentrations uniformly suppresses soot formation at high pressures, while at relatively lower pressures it suppresses soot formation at higher temperatures while promoting soot production at lower temperatures. The observed behavior indicates that oxidation reactions compete with ring fragmentation. The main conclusion to be drawn from the results is that the soot formation mechanism is probably the same for the pyrolysis and oxidation of hydrocarbons. That is, the addition of oxygen does not alter the soot route but rather promotes or inhibits this route by means of competitive reactions. An approach to empirical modeling of soot formation during pyrolysis of aromatic hydrocarbons is also presented.
A macroscopic 'self-consistent' nonlinear two-fluid model is developed for energetic-particle-modeled shocks. The model incorporates particle exchange between a thermal gas and an energetic population via a 'thermal leakage' mechanism. In the model, injection is regarded as a process whereby particles in the cooler thermal core of a total particle distribution are energized sufficiently to cross a 'momentum boundary' into the wings of the distribution. Particles in the wings are identified as 'energetic particles' or 'cosmic rays' and are assumed to propagate according to the diffusive transport equation of cosmic ray theory. Thermal particles are energized either as a result of adiabatic compression in a decelerating flow or directly via anomalous heating within a subshock. It is shown that the nature and model of particle injection directly affects the nature and dynamics of the shock, and hence the efficiency of particle acceleration, and that the shock itself regulates particle injection dynamically.
The interaction of a magnetized solar wind with magnetized interstellar flow is modelled in two dimensions. The VLISM magnetic field and flow velocity are assumed to be parallel to each other and perpendicular to the sun's magnetic axis, contrast to a recent study by Washimi. The more realistic orientation of the axis and VLISM flow requires a less realistic heliospheric field model in two dimensions. The Parker spiral is replaced by a poloidal field which is tangent to the termination shock, and whose magnitude is consistent with estimates of the heliospheric field at termination shock distances. Of particular interest is the effect of the heliospheric field on the heliospheric flow beyond the termination shock, and on the structure and location of the bow shock
Recently, nebular shock waves have become one of the leading candidates for explaining the presence of chondrules in primitive meteorites. While shocks have been shown to be capable of explaining many of the features of chondrules, a major problem with the theory is that the source of the shocks remains unidentified. Among the suggested sources of the shocks are bow shocks created by supersonic planetesimals in the nebula. Recently, we studied the structure of the shocks that would form around such supersonic planetesimals. We found that particles that encountered the shocks at distances greater than 2 planetesimal radii from the planetesimal would cool too quickly to form the textures observed in chondrules. While the region of the shock far away from the planetesimal may not allow chondrules to form, the region closer in has not been studied in detail. In this work we consider the dynamical and thermal evolution of particles that encounter supersonic planetesimals in this region.
The Wolf-Rayet WC7+O4.5 binary WR140 went through the periastron passage of its 8-year eccentric binary orbit in early 2001 as the two stars made their closest approach. Both stars have powerful supersonic stellar winds which crash into each other between the stars to produce X-rays. Chandra grating observations were made when the X-rays were at their brightest making WR140 the brightest hot-star X-ray source in the sky and giving the opportunity to study the velocity profiles of lines, all of which were resolved and blue-shifted. In the general context of shock physics, the measurements constrain the flow of hot gas and where different ions were made. The lower velocity widths of cool ions imply a plasma that was not in equilibrium. The brightness of lines relative to the strong continuum in conjunction with plasma models gives interim abundance estimates for eight different elements in WC-type material including an Ne/S ratio in good agreement with earlier long-wavelength measurements.
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Some open questions in the physics of bow shock formation, the evolution of the particle distributions from solar wind into the magnetosheath, and the acceleration of ions at the moment of the shock are summarized. A layout of the current situation is presented in view of recent theoretical developments and the new diagnostic tools provided by the Cluster mission. The transition of ions across the quasi-perpendicular bow shock and their downstream thermalization are discussed. The processes and spatial scales are found to be species dependent and are discussed for H(+), He(2+), and He(+). The theory of particle acceleration at quasi-parallel shocks are reviewed. It is shown how Cluster can study the time variable structures of the shock as predicted by hybrid simulation. It is emphasized that high time resolution measurement with simultaneous species separation is necessary for the study of the ion acceleration. Suggestions for the spacecraft separations at the bow shock are suggested.
Using multi-spacecraft observations primarily from ACE and WIND, and from IMP 8 and Geotail when available, the 3-dimensional structure of interplanetary shocks on the hundred Earth radii scale will be discussed. The complete magnetic field, and solar wind ion and electron data sets were used to fit the shocks with a full non-linear least squares fit "Rankine-Hugoniot" technique yielding the local shock surface normals and speeds with associated uncertainties. Multi-spacecraft results reveal that on the distance scale of ACE's L1 halo orbit the shocks deviate significantly from a simple planar geometry. This result has important consequences for the prediction of the exact arrival times of interplanetary shocks at the Earth's magnetosphere, and hence, on the reliability of space weather predictions. It also has implications on the coherence scale of solar wind structures and their evolution from the Sun to Earth.
Using multi-spacecraft observations primarily from ACE and WIND and from IMP 8 and Geotail when available, the 3-dimensional structure of interplanetary shocks on the hundred Earth radii scale will be discussed. The complete magnetic field, and solar wind ion and electron data sets were used to fit the shocks with a full non-linear least squares fitting "Rankine-Hugoniot" technique yielding the local shock surface normals and speeds with associated uncertainties. Multi-spacecraft results reveal that on the distance scale of ACE's L1 halo orbit the shocks deviate from a simple planar geometry. This result has important consequences for the prediction of the exact arrival times of interplanetary shocks at the Earth's magnetosphere, and hence, on the reliability of space weather predictions. It also has implications on the coherence scale of solar wind structures and their evolution from the Sun to Earth.
In this work, we explore the structural evolution of highly oriented pyrolytic graphite (HOPG) under detonation-induced shock conditions using in situ synchrotron x-ray diffraction in the ns timescale. We observe the formation of hexagonal diamond (lonsdaleite) at pressures above 50 GPa, in qualitative agreement with recent gas gun experiments. First-principles density functional calculations reveal that under uniaxial compression, the energy barrier for the transition toward hexagonal diamond is lower than that for cubic diamond. Finally, no indication of cubic diamond formation was observed up to >70 GPa.
Shock-wave boundary-layer interactions (SWBLI) pose unique challenges for the slender airframes and sharp control surfaces characteristic of high-speed airbreathing aircraft. Spikes in pressure and thermal loading have been shown to occur in SWBLI regions; thus, predicting their location and behavior proves critical for assuring aircraft structural integrity and fatigue resilience. SWBLIs frequently lead to severe turbulent boundary-layer separation and corresponding unsteady motions characterized by a wide range of frequencies. Low-frequency motion has been shown to couple with the structure of a compliant panel, and turbulent boundary layers thus present a particular danger for thin control surfaces. Previous studies have shown that the thermal loading on a compliant panel in a ramp-induced SWBLI may have a signi cant impact on the panel vibrations. A multitude of studies has investigated the heating on rigid structures, but a charactrization of the heating effects on compliant structures is necessary to fully understand the fluid-thermal-structural interactions (FTSI) occurring in ramp-induced SWBLIs. This studuses infrared thermography and high-frequency Kulite pressure transducers to examine the heating loads on rigid and compliant ramps at various angles and flow conditions at Mach 6.
Mechanisms of decelerating the cloud medium in the large-scale galactic shock are studied. It is shown that the process of cloud-cloud collisions, which results in diffusive momentum transport and hence gives rise to the turbulent viscosity, is very effective in slowing down the cloud medium so that the postshock velocity of the intercloud medium can be matched within a short distance behind the shock front. The drag force exerted by the slow-moving intercloud medium alone is simply not enough to effectively decelerate the cloud medium in the shock. By the use of the results of Shu et al (1972), the internal structure of the shock of the cloud medium is analyzed by including turbulent viscous effects. The thickness of the shock is found to be on the order of 100 pc if the turbulent viscosity is taken proportional to the mean free path of the cloud-cloud collisions. The phase transition takes place in an even thinner layer on the order of 10 pc immediately after the viscous shock front of the intercloud medium.
A numerical study is conducted to investigate aerothermal implications of oblique shock impingement on a highly swept leading edge in hypersonic flow, with flow conditions and geometry relevant to non-propulsive leading edge heating on hypersonic cruise vehicles. In contrast to propulsive inlet leading edge shock impingement, which has been subject to extensive historical study, bow shock impingement on a highly swept wing leading edge has received comparatively little attention in the literature. Distinguishing characteristics of this type of flow include a potentially dominant surface heating contribution from crossflow-induced viscous dissipation, possible wall velocity slip and temperature jump effects, and various modes of shock layer thermal nonequilibrium that can interact with shock impingement flowfield structures. One overall goal of this work is to assess the impact of bow shock impingement and related nonequilibrium phenomena for wing leading edge design, materials selection and thermal management. Another goal is to improve understanding – and thereby reduce associated design margins – for the physical processes and mechanisms that may influence wing leading edge heating in the presence of an impinging shock. A combination of direct simulation Monte Carlo and Reynolds-averaged Navier-Stokes analysis is used to assess surface and flowfield characteristics for a series of hypersonic shock impingement problems, based on historical ground tests and related flight conditions. Favorable comparisons are performed with experimental data, and various thermal nonequilibrium effects are quantified.
Computer-drawn diagrams of the boundaries between quasi-perpendicular and quasi-parallel areas of earth's bow shock are displayed for a few selected cone angles of static interplanetary magnetic field (IMF). The effect on the boundary of variable IMF in the foreshock is also discussed and shown for one nominal case. The boundaries demand caution in applying them to the realistic, dynamic conditions of the solar wind and in interpreting the effects of small cone angles on the distributions of structures at the shock. However, the calculated, first-order boundaries are helpful in defining areas of the shock where contributions from active structures inherent in quasi-parallel geometry may be distinguishable from those derived secondarily from upstream reflected ion dynamics. The boundaries are also compatible with known behavior of daytime ULF geomagnetic waves and pulsations according to models postulating that cone angle-controlled, time-dependent ULF activity around the subsolar point of the bow shock provides the source of geomagnetic excitation.
The microscopic structure within a two-dimensional shock was studied using data from a dusty plasma experiment. A single layer of charged microparticles, levitated in a glow-discharge plasma, was perturbed by an electrically floating wire that was moved at a steady supersonic speed to excite a compressional shock. A rearrangement of particles was observed, from a hexagonal lattice in the preshock into a quadrilateral microstructure on the front side of the shock. This quadrilateral structure would not be stable in a monolayer of identical repulsive particles, under equilibrium conditions. Glaser-Clark polygon analysis of the microstructure helped in identifying quadrilaterals. Voronoi analysis was used to characterize the defect fraction behind the shock, as an indication of shock-induced melting. Published by the American Physical Society 2025
Abstract Benzene (C 6 H 6 ), while stable under ambient conditions, can become chemically reactive at high pressures and temperatures, such as under shock loading conditions. Here, we report in situ x-ray diffraction and small angle x-ray scattering measurements of liquid benzene shocked to 55 GPa, capturing the morphology and crystalline structure of the shock-driven reaction products at nanosecond timescales. The shock-driven chemical reactions in benzene observed using coherent XFEL x-rays were a complex mixture of products composed of carbon and hydrocarbon allotropes. In contrast to the conventional description of diamond, methane and hydrogen formation, our present results indicate that benzene’s shock-driven reaction products consist of layered sheet-like hydrocarbon structures and nanosized carbon clusters with mixed sp 2 - sp 3 hybridized bonding. Implications of these findings range from guiding shock synthesis of novel compounds to the fundamentals of carbon transport in planetary physics.
Achieving practical inertial fusion energy (IFE) requires the development of target designs with well-characterized microstructure and compression response. We measured shock dynamics in low-density (17.5–500 mg/cm 3 ) aerogel and two-photon polymerization (TPP) foams using x-ray phase contrast imaging (XPCI) methods and the Velocity Interferometer System for Any Reflector. By analyzing shock front evolution, we examined how target type and density influence shock propagation and energy dissipation. Talbot-XPCI shows that aerogels support a smooth, bowed shock front due to their homogeneous nanometer-scale pore network. In contrast, TPP foams exhibit irregular, stepwise propagation driven by interactions with their periodic micrometer-scale lattice. Shock velocity follows a power-law relation: aerogels deviate from classical ρ −1/2 scaling due to pore-collapse dissipation, while TPP foams follow the trend with larger uncertainties from density variations. Comparisons with xRAGE simulations reveal systematic underestimation of shock speeds. These results provide the first experimental constraints on shock propagation in TPP foams over a wide density range and highlight the influence of internal structure on anisotropic shock behavior. Our findings support improved benchmarking of EOS and hydrodynamic models and inform the design of foam architectures that promote implosion symmetry in IFE capsules.