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At least 685 records · Page 38

Fusion welding of refractory metals and ZrB 2 -SiC-ZrC ceramics

Molybdenum and a molybdenum alloy were fusion welded to ZrB2-based ceramics to determine if the electrical and thermal properties of the metals and ceramics affected their weldability. Commercial ceramic powders were hot pressed, machined into coupons, and preheated to 1600 °C before joining the ceramics to commercial metals using plasma arc welding. Weldability varied as indicated by the range of porosity observed within the fusion zones. Measured thermal and electrical properties appeared to have little to no effect on the weldability of metal-ceramic welds despite the large range of values measured across each property. Differences in melting temperatures between metal and ceramic coupons did affect weldability by changing the weld penetration depth into ceramic coupons. Finally, future studies on metal-ceramic welds are suggested to investigate the effect that work function, melt viscosity, wetting, or other properties have on weldability.

36 MATERIALS SCIENCE↗

New surface characterization tools for alumina based refractory material exposed to cavitation - Image analysis and pattern recognition approach

Highlights: • Surface degradation was monitored via mass loss measurement. • Observation of surface damage destruction was done using image analysis. • Shape parameters of surface defects change during cavitation. • Shape parameters changes are correlated to mass loss measurements. - Abstract: The aim of this study was to examine the influence of cavitation erosion on the morphology of defects formed on the surfaces of alumina-based materials. The alumina-based samples were exposed to cavitation erosion for 42 min. The damages that occurred were monitored at predefined time intervals by measuring the mass loss and observing the sample surfaces. Digital images of surfaces were processed using an image analysis software package to define morphological characteristics of the damages occurred. The calculated morphological parameters were subjected to analysis by pattern recognition techniques to correlate the appearance of particular morphological characteristics with the behavior of the material during cavitation erosion. The newly established method in describing cavitation erosion which uses pattern recognition approach for treatments of morphological parameters calculated for damages by image analysis tools gave the results efficient for material characterization as the traditional one.

36 MATERIALS SCIENCE↗

Predicting short-range order evolution in WTaCrVHf refractory high-entropy alloys

Short-range order (SRO) in multicomponent concentrated alloys affects their mechanical response. Hence, is paramount to understand how composition modifies the chemical ordering in the system to design materials with optimal properties. Here, in this work, we present a methodology to predict the SRO and thermodynamic properties in chemically complex systems and apply it to the WTaCrVHf quinary alloy. We observe that the addition of Hf significantly modifies the SRO, mainly at intermediate to low temperatures, matching experimental observations.

36 MATERIALS SCIENCE↗

Additive Manufacturing of Ultrahigh Temperature Refractory Metal Alloys

The project advances the manufacture of RMA for ultrahigh-temperature service with three main innovations: a thermodynamically derived high-throughput AM synthesis and characterization using reactive synthesis of elemental powders, a new dimensional number to predict processing parameters, and a novel processing scheme for the fabrication of components with functional grading microstructures. With these advances, the project demonstrates in Phase I the manufacture of RMAs exhibiting room temperature compression ductility above 20%, room temperature fracture toughness above 10 MPam 0.5 , and the fabrication of tensile test samples that have a transformative impact on the manufacturing of RMAs by enabling cost-efficient and large-scale fabrication of components.

33 ADVANCED PROPULSION SYSTEMS↗