Laser metal deposition of compositionally graded TiZrNbTa refractory high-entropy alloys using elemental powder blends
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Molybdenum and a molybdenum alloy were fusion welded to ZrB2-based ceramics to determine if the electrical and thermal properties of the metals and ceramics affected their weldability. Commercial ceramic powders were hot pressed, machined into coupons, and preheated to 1600 °C before joining the ceramics to commercial metals using plasma arc welding. Weldability varied as indicated by the range of porosity observed within the fusion zones. Measured thermal and electrical properties appeared to have little to no effect on the weldability of metal-ceramic welds despite the large range of values measured across each property. Differences in melting temperatures between metal and ceramic coupons did affect weldability by changing the weld penetration depth into ceramic coupons. Finally, future studies on metal-ceramic welds are suggested to investigate the effect that work function, melt viscosity, wetting, or other properties have on weldability.
Highlights: • Surface degradation was monitored via mass loss measurement. • Observation of surface damage destruction was done using image analysis. • Shape parameters of surface defects change during cavitation. • Shape parameters changes are correlated to mass loss measurements. - Abstract: The aim of this study was to examine the influence of cavitation erosion on the morphology of defects formed on the surfaces of alumina-based materials. The alumina-based samples were exposed to cavitation erosion for 42 min. The damages that occurred were monitored at predefined time intervals by measuring the mass loss and observing the sample surfaces. Digital images of surfaces were processed using an image analysis software package to define morphological characteristics of the damages occurred. The calculated morphological parameters were subjected to analysis by pattern recognition techniques to correlate the appearance of particular morphological characteristics with the behavior of the material during cavitation erosion. The newly established method in describing cavitation erosion which uses pattern recognition approach for treatments of morphological parameters calculated for damages by image analysis tools gave the results efficient for material characterization as the traditional one.
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Short-range order (SRO) in multicomponent concentrated alloys affects their mechanical response. Hence, is paramount to understand how composition modifies the chemical ordering in the system to design materials with optimal properties. Here, in this work, we present a methodology to predict the SRO and thermodynamic properties in chemically complex systems and apply it to the WTaCrVHf quinary alloy. We observe that the addition of Hf significantly modifies the SRO, mainly at intermediate to low temperatures, matching experimental observations.
Powder X-ray diffraction data collected at the Advanced Photon Source 16-BM–D, confirms that the alloy with composition Mo 0.20 Nb 0.21 Ta 0.19 V 0.20 W 0.20 crystallizes in a simple body-centered cubic (bcc) structure with all five elements distributed over a single crystallographic site (Wyckoff position 2a of space group Im $\bar{3}$ m ).
The project advances the manufacture of RMA for ultrahigh-temperature service with three main innovations: a thermodynamically derived high-throughput AM synthesis and characterization using reactive synthesis of elemental powders, a new dimensional number to predict processing parameters, and a novel processing scheme for the fabrication of components with functional grading microstructures. With these advances, the project demonstrates in Phase I the manufacture of RMAs exhibiting room temperature compression ductility above 20%, room temperature fracture toughness above 10 MPam 0.5 , and the fabrication of tensile test samples that have a transformative impact on the manufacturing of RMAs by enabling cost-efficient and large-scale fabrication of components.
The stress arising when melt passes through a filter is determined with different positions of the filter in the mold. The compressive strength of the proposed filter is investigated.
Electric field effect on surface kinetics and thermodynamic stability of cesium on tungsten and molybdenum by field emission microscopy
Determination of solubility limits and diffusion constants of oxygen in pure tantalum and niobium and in alloys by electrical resistivity measurements
Iridium coatings for high temperature oxidation protection on tantalum, niobium, molybdenum, and tungsten
Creep tests of arc-cast and vapor deposited tungsten, molybdenum alloys, niobium, and tantalum base alloys for use in advanced power systems
Thermal emittance of cone and cylinder cavities electrically disintegrated in tungsten and molybdenum measured with disappearing-filament pyrometer
High temperature combustion of tantalum and molybdenum in oxygen gas compared with experiments in carbon dioxide, water, argon and mixtures of these gases
Heat treatment and metallographic examination of iridium deposited on tungsten and molybdenum as high temperature protective coating
Fused salt electrodeposition and examination of iridium protective coatings on tungsten, molybdenum, and niobium