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This research focuses on the kinematics and evolution of the hot phase of the interstellar medium in the Galaxy. The plan is to measure the UV spectra for all hot stars observed with International Ultraviolet Explorer (IUE), in order to identify and measure the main component and any high velocity components to the interstellar lines. A total of 1200 stars are candidates for inclusion in this study.
The organic inventory initially available to protostellar disks is the first step on the long chemical path to the development of Life. The early earth may have obtained most its volatile material from the arrival of meteorites and comets at its surface. Determining the most likely distribution of meteoritic and cometary organic molecules that could seed primitive planets is a major goal since it sets the initial conditions for, at least part of, the phase of prebiotic chemical evolution. Observations and measurements of the chemical composition of primitive Solar System organics, and of dense molecular clouds, should allow the construction of coherent theoretical picture of the development of organic complexity from interstellar biogenic material to the beginning of prebiotic evolution.
This research focuses on the kinematics and evolution of the hot phase of the interstellar medium in the Galaxy. The plan was to measure the UV spectra of all hot stars observed with IUE, in order to identify and measure the main component and any high velocity components to the interstellar lines. Collection of data from higher resolution instruments on HST has been proposed for some of the interesting lines of sight. IUE spectra of 240 stars up to 8 kpc in 2 quadrants of the galactic plane have been examined to (1) estimate the total column density per kpc as a function of direction and distance, and (2) to obtain a lower limit to the number of high velocity components to the interstellar lines, thus giving an approximation of the number of conductive interfaces encountered per line of sight. By determining an approximation to the number of components per unit distance we aim to derive statistics on interfaces between hot and cold gas in the Galaxy. We find that 20% of the stars in this sample show at least one high velocity component in the C IV interstellar line. Two successful FUSE programs address this research and collected data for several of the lines of sight identified as locations of hot, expanding gas with the IUE data. One FUSE program is complete for the Vela SNR region. Data from another FUSE program to investigate the Cygnus superbubble region are being analyzed.
In the core accretion model of giant planet formation, when the core reaches critical mass, hydrostatic equilibrium is no longer possible and gas accretion ensues. If the envelope is radiative, the critical core mass is nearly independent of the boundary conditions and is roughly M(sub crit) ~ 10Mass of the Earth (with weak dependence on the rate of planetesimal accretion M(sub core) and the disk opacity k). Given that such a core may form at the present location of Jupiter in a time comparable to its Type I migration time (10(exp 5) - 10(exp 6) years) provided that the nebula was significantly enhanced in solids with respect to the MMSN and stall at this location in a weakly turbulent (alpha approximately less than 10(exp -4) disk, it may be appropriate to assume that such objects inevitably form and drive the evolution of late-phase T Tauri star disks. Here we investigate the final masses of giant planets in disks with one or more than one such cores. Although the presence of several planets would lead to Type II migration (due to the effective viscosity resulting from the planetary tidal torques), we ignore this complication for now and simply assume that each core has stalled at its location in the disk. Once a core has achieved critical mass, its gaseous accretion is governed by the given Kelvin-Helmholtz timescale.
Our goal is to understand the behavior of the outer atmosphere in this intermediate stage to create a comprehensive picture of atmospheric evolution. In the hybrid phase, the large-scale magnetic dynamo activity decays and hydrodynamic processes assume importance. Some hot plasma is still confined close to the star by magnetic loops, yet the confining field is breaking open, the atmosphere can escape through these open field lines, and the diffuse corona may be warm. There may well be a more extended and variable transition process. It remains for FUSE to identify the controlling parameters of the hybrid stars. It shows the positions of our 3 targets in the color-magnitude diagram where it is seen that they are at the extreme end of the hybrid region. Originally we had been awarded the hybrid star Iota Aur, but due to newly imposed pointing constraints of FUSE, that target was not accessible. And so we substituted Iota Dra, a giant of mass similar to our other targets but less evolved. In addition, Iota Dra was recently found to harbor a sub-stellar objects, possibly a planet, and so it could reveal the stellar environment of the planet. This substitution was accepted.
All major classes of chondrites show signs of alteration on their parent bodies (asteroids). The prevalence of oxidation and hydration in alteration pathways implies that water was the major reactant. Sublimation and melting of water ice, generation of gases, formation of aqueous solutions, alteration of primary minerals and glasses and formation of secondary solids in interior parts of asteroids was likely to be driven by heat from the radioactive decay of short-lived radionuclides. Progress of alteration reactions should have affected masses and volumes of solids, and aqueous and gas phases. In turn, pressure evolution should have been controlled by changes in volumes and temperatures, escape processes, and production/ consumption of gases.
The Mars Pathfinder mission, scheduled for launch in December 1996, will use an airbag system to safely deliver a lander to the Martian surface.The airbag landing system has undergone a comprehensive test program during its evolution from initial design phase to final qualification and acceptance testing. This paper outlines the test approach used in the airbag development program, describes the data acquisition system used to obtain and evaluate airbag performance data, and presents test results.
The effects of a 2.0 at.% addition of Ta to a model Ni-10.0Al-8.5Cr (at.%) superalloy aged at 1073 K are assessed using scanning electron microscopy and atom-probe tomography. The gamma'(Ll2)-precipitate morphology that develops as a result of gamma-(fcc)matrix phase decomposition is found to evolve from a bimodal distribution of spheroidal precipitates, to {001}-faceted cuboids and parallelepipeds aligned along the elastically soft {001}-type directions. The phase compositions and the widths of the gamma'-precipitate/gamma-matrix heterophase interfaces evolve temporally as the Ni-Al-Cr-Ta alloy undergoes quasi-stationary state coarsening after 1 h of aging. Tantalum is observed to partition preferentially to the gamma'-precipitate phase, and suppresses the mobility of Ni in the gamma-matrix sufficiently to cause an accumulation of Ni on the gamma-matrix side of the gamma'/gamma interface. Additionally, computational modeling, employing Thermo-Calc, Dictra and PrecipiCalc, is employed to elucidate the kinetic pathways that lead to phase decomposition in this concentrated Ni-Al-Cr-Ta alloy.
The objective of this program was to model, validate, and predict the precipitation microstructure evolution, using PrecipiCalc (QuesTek Innovations LLC) software, for 3rd generation Ni-based gas turbine disc superalloys during processing and service, with a set of logical and consistent experiments and characterizations. Furthermore, within this program, the originally research-oriented microstructure simulation tool was to be further improved and implemented to be a useful and user-friendly engineering tool. In this report, the key accomplishments achieved during the third year (2009) of the program are summarized. The activities of this year included: Further development of multistep precipitation simulation framework for gamma prime microstructure evolution during heat treatment; Calibration and validation of gamma prime microstructure modeling with supersolvus heat treated LSHR; Modeling of the microstructure evolution of the minor phases, particularly carbides, during isothermal aging, representing the long term microstructure stability during thermal exposure; and the implementation of software tools. During the research and development efforts to extend the precipitation microstructure modeling and prediction capability in this 3-year program, we identified a hurdle, related to slow gamma prime coarsening rate, with no satisfactory scientific explanation currently available. It is desirable to raise this issue to the Ni-based superalloys research community, with hope that in future there will be a mechanistic understanding and physics-based treatment to overcome the hurdle. In the mean time, an empirical correction factor was developed in this modeling effort to capture the experimental observations.
The Mars Pathfinder mission, scheduled for launch in December, 1996, will use an airbag system to safely deliver a lander to the Martian surface. The airbag landing system has undergone a comprehensive test program during its evolution from initial design phase to final qualification and acceptance testing.
Context. In high mass X-ray binaries, an accreting compact object orbits a high mass star, which loses mass through a dense and in homogeneous wind. Aims. Using the compact object as an X-ray backlight, the time variability of the absorbing column density in the wind can be exploited in order to shed light on the micro-structure of the wind and obtain unbiased stellar mass-loss rates for high mass stars. Methods. We developed a simplified representation of the stellar wind where all the matter is gathered in spherical “clumps” that are radially advected away from the star. This model enables us to explore the connections between the stochastic properties of the wind and the variability of the column density for a comprehensive set of parameters related to the orbit and to the wind micro-structure, such as the size of the clumps and their individual mass. In particular, we focus on the evolution with the orbital phase of the standard deviation of the column density and of the characteristic duration of enhanced absorption episodes. Using the porosity length, we derive analytical predictions and compare them to the standard deviations and coherence time scales that were obtained. Results. We identified the favorable systems and orbital phases to determine the wind micro-structure. The coherence time scale of the column density is shown to be the self-crossing time of a single clump in front of the compact object. We thus provide a procedure to get accurate measurements of the size and of the mass of the clumps, purely based on the observable time variability of the column density. Conclusions. The coherence time scale grants direct access to the size of the clumps, while their mass can be deduced separately from the amplitude of the variability. We further show how monitoring the variability at superior conjunctions can probe the onset of the clump-forming region above the stellar photosphere. If the high column density variations in some high mass X-ray binaries are due to unaccreted clumps which are passing by the line-of-sight, this would require high mass clumps to reproduce the observed peak-to-peak amplitude and coherence time scales. These clump properties are marginally compatible with the ones derived from radiative-hydrodynamics simulations. Alternatively, the following components could contribute to the variability of the column density: larger orbital scale structures produced by a mechanism that has yet to be identified or a dense environment in the immediate vicinity of the accretor, such as an accretion disk, an outflow, or a spherical shell surrounding the magnetosphere of the accreting neutron star.
The discovery that the asteroid Ryugu samples returned by the JAXA Hayabusa2 spacecraft are chemically and mineralogically nearly identical to CI chondrites has made us re-recognize the importance of CI chondrites in the early solar system [e.g., 1]. These CI chondritic materials have undergone strong aqueous alteration in their parent bodies, resulting in the formation of abundant Mg-Fe phyllosilicates along with other altered minerals such as carbonates, magnetite, and pyrrhotite. Initial and subsequent AO analyses of the Ryugu samples have found that they are brecciated on the mm~μm scale and that a small amount of forsterite and other primary minerals survive in some of the brecciated clasts with evidence of less degrees of aqueous alteration (“less altered clast”) [e.g., 1]. In addition, these less altered clasts contain a rare Na-bearing Mg phosphate that is still poorly characterized. Despite the analytical attempt to identify its mineral species, their identity has not been clarified yet. These rare Mg phosphates could be one of the key phases to understanding the evolution of CI chondritic bodies since a similar Na-bearing Mg phosphate has been reported from the asteroid Bennu sample returned by the NASA OSIRIS REx mission, and the importance of these materials has been suddenly highlighted. Since the initial analysis of the Ryugu sample, we have been paying attention to these Mg phosphates in CI chondrites as well as Ryugu samples, and here we report the present results on their mineralogical analysis.
Structural metallic and ceramic materials at high temperatures often suffer from creep, fatigue and oxidation, which typically involves local large inelastic strain. The large strain is usually approached by Lagrangian-description-based finite deformation theory. Here we develop an efficient, Eulerian-description-based, Incremental Realization of Inelastic Deformation (IRID) algorithm to deal with large inelastic strain with small elastic strain. We apply this algorithm to simulate high temperature oxidation with severe volume expansion using a phase-field approach. The oxidation and deformation of bond coat can lead to spallation and failure of the thermal barrier coatings (TBC) and environmental barrier coatings (EBC), which is a critical concern in design of these coatings. We simulate the growth of thermally grown oxide (TGO) in these coating systems, with phase transformations and microstructure evolution incorporated. The simulation results are compared with relevant experimental reports in the literature.
P Cygni is currently in the transition phase between core hydrogen and helium burning. The behavior of the stellar envelope in this phase is strongly affected by the intermittant dominance of hydrogen shell burning. We perform detailed stellar evolution calculations of this rapid transition phase using the most recent Livermore opacities. We find that observations and stellar evolution models agree very well if the initial main-sequence mass of P Cygni was about 60 +/- 5 solar masses. Depending on the mass-loss rate, P Cygni's current mass could be as low as 50 solar masses, which is still about a factor of 2 higher than that predicted by the radiation driven wind theory. Our calculations seem to favor the Schwarzschild criterion for convection over the Ledoux criterion in conjunction with semiconvection.
Introduction: An overarching geologic theory, GEOMARS, coherently explains many otherwise anomalous aspects of the geological history of Mars. Premises for a theory of martian geologic evolution include: (1) Mars is a water-rich terrestrial planet, (2) terrestrial planets should evolve through progressive stages of dynamical history (accretion, differentiation, tectonism) and mantle convection (magma ocean, plate tectonism, stagnant lid), and (3) the early history of Earth affords an analogue to the evolution of Mars. The theory describes the following major stages of evolution for Mars (from oldest to youngest): Stage 1 - shortly after accretion, Mars differentiates to a liquid metallic core, a mantle boundary (MBL) of high-pressure silicate mineral phases, upper mantle, magma ocean, thin komatiic crust, and convecting steam atmosphere; Stage 2- Mars cools to condense its steam atmosphere and transform its mode of mantle convection to plate tectonism; subduction of waterrich oceanic crust initiates arc volcanism and transfers water, carbonates and sulfates to the mantle; Stage 3 - the core dynamo initiates, and the associated magnetosphere leads to conditions conducive to the development of near-surface life and photosynthetic production of oxygen; Stage 4 - accretion of thickened, continental crust and subduction of hydrated oceanic crust to the mantle boundary layer and lower mantle of Mars occurs; Stage 5 - the core dynamo stops during Noachian heavy bombardment while plate tectonism continues; Stage 6 - initiation of the Tharsis superplume (approx. between 4.0 and 3.8Ga) occurs, and Stage 7 - the superlume phase (stagnant-lid regime) of martian planetary evolution with episodic phases of volcanism and water outflows continues into the present. The GEOMARS Theory is testable through a multidisciplinary approach, including utilizing GRS-based information. Based on a synthesis of published geologic, paleohydrologic, topographic, geophysical, spectral, and elemental information, we have defined geologic provinces that represent significant windows into the geological evolution of Mars, unfolding the GEOMARS Theory and forming the basis for interpreting GRS data.
Lithium (Li)-ion batteries using nickel (Ni)-rich layered oxide cathode have been pursued with interest due to high practical energy density. A fundamental understanding of the reaction pathways and structural evolution of the solid-phase synthesis of these materials is crucial for their rational design and process development for mass production. In this work, structural evolution during solid-state synthesis was traced via in situ technique, with a particular emphasis on the lithiation reaction and migration of transition metal (TM) ions. The sintering process is governed by the competitive relationship of decomposition and lithiation reactions, which can be regulated through temperature windows. Controlling the melting point of the Li sources, as well as their affinity to cathode precursors, is highly desired to maintain the layered ordering of TM ions throughout the whole synthesis process, which simplifies the manufacturing process and improves the quality of the manufactured cathode material.
The structural evolution of NiTi during the B2→B19’ martensitic phase transformation via thermal cycling is investigated using in situ four dimensional scanning transmission electron microscopy (4D-STEM). With 4D-STEM, we can directly visualize and quantify the nanoscale evolution of the martensitic structure on thermal cycling and also investigate the origin of diffuse scattering of NiTi in the pre-transitional state. Mapping of the martensite orientation and strain visualizes the progression of the transformation front and self-accommodation of the B19’ structure. Diffuse streaking and strain are measured in the pre-transitional austenite (B2) phase and demonstrate no localization or preferential directionality hinting that long-range homogeneous instability rather than nanoscale heterogeneities may be the origin of the pre-transitional anomalies in NiTi. Finally, it is revealed that NiTi does not reform the same martensite nanostructure on thermal cycling but does express similar features. This small variation is likely owing to transformation-induced dislocations.
Single crystallization remains a debated strategy for advancing Ni-rich cathode materials. While it mitigates particle cracking and improves tap density by eliminating particle boundaries, extended diffusion pathways introduce volumetric and lattice distortions, compromising electrochemical and structural stability. These challenges hinder the commercialization of high-Ni single-crystal cathodes, calling for a reassessment of their viability. Here, in this study, we report a structural design: intralattice-bonded phase single-crystal LiNi 0.92 Co 0.03 Mn 0.05 O 2 (IBP-SC92). This architecture maintains structural integrity while shortening diffusion pathways, resulting in almost zero electrochemical degradation during cycling. The robust structure and fast ion transport mitigate lattice strain, as confirmed by multiscale high-resolution diffraction and imaging techniques, preventing intragranular cracks and irreversible phase transitions. As a result, IBP-SC92 shows outstanding cycling stability, with nearly 100% capacity retention after 100 cycles in half cells and 94.5% retention after 1,000 cycles in full cells. This redefined single-crystal cathode represents a significant step towards the industrial adoption of high-energy-density materials.