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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38

Study on Kinetic Mechanism of Bastnaesite Concentrates Decomposition Using Calcium Hydroxide

The thermal decomposition of bastnaesite concentrates using calcium hydroxide was studied. Calcium hydroxide can effectively inhibit the emission of fluorine during roasting by transforming it to calcium fluoride. The decomposition rate increased with increasing reaction temperature and amount of calcium hydroxide. The decomposition kinetics were investigated. The decomposition reaction was determined to be a heterogeneous gas–solid reaction, and it followed an unreacted shrinking core model. By means of the integrated rate equation method, the reaction was proven to be kinetically first order. Different reaction models were fit to the experimental data to determine the reaction control process. The chemical reaction at the phase interface controlled the reaction rate in the temperatures ranging from 673 K to 773 K (400 °C to 500 °C) with an apparent activation energy of 82.044 kJ·mol{sup −1}. From 773 K to 973 K (500 °C to 700 °C), diffusion through the solid product’s layer became the determining step, with a lower activation energy of 15.841 kJ·mol{sup −1}.

36 MATERIALS SCIENCE↗

2023 FORCE Development Status Update

Technical and economic analysis of integrated energy systems (IES) using software models is a complex process requiring multiple commodity market decision analysis, optimal control, process modeling, and stochastic analysis. Many assumptions used in traditional energy analysis tools do not hold in future energy markets with significant storage and variable renewable energy sources (VRE), let alone with multiple commodity markets. Capturing these intricate elements for accurate techno-economic analysis of IES led to the development of the Framework for Optimization of ResourCes and Economics (FORCE) tool suite under the U.S. Department of Energy’s Integrated Energy Systems crosscutting technology program. With the aim of a full framework release in 2025, many improvements to the FORCE tool suite were developed in fiscal year 2023 (FY23). These improvements broadly fit into three focuses for development of FORCE: capability, accessibility, and reliability. Capability refers to the ability of FORCE to accurately model the technical and economic viability of various IES. Accessibility refers to ease-of-use for new and existing IES analysts to efficiently set up, analyze, and produce results using FORCE. Reliability refers to the consistency of the software, allowing consistency to analysis regardless of erstwhile changes to the software. In addition to many smaller changes, there are three major capability improvements in FORCE in FY23. In summary, FORCE developments in FY23 have moved us close to all the capability requirements for FORCE 1.0 to be delivered in FY25. Inclusion of Bayesian optimization, resilience metrics, and levelized cost analysis expand the capability, accessibility, and reliability of FORCE.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Manufacturing methods of a composite cell case for a Ni-Cd battery

Graphite epoxy material for a nickel cadmium battery cell case has been evaluated and determined to perform in the simulated environment of the battery. The basic manufacturing method requires refinement to demonstrate production feasibility. The various facets of production scale-up, i.e., process and tooling development together with material and process control, have been integrated into a comprehensive manufacturing process that assures production reproducibility and product uniformity. Test results substantiate that a battery cell case produced from graphite epoxy pre-impregnated material utilizing internal pressure bag fabrication method is feasible.

Bauer, J. L.↗

Qualitative simulation for process modeling and control

A qualitative model is developed for a first-order system with a proportional-integral controller without precise knowledge of the process or controller parameters. Simulation of the qualitative model yields all of the solutions to the system equations. In developing the qualitative model, a necessary condition for the occurrence of oscillatory behavior is identified. Initializations that cannot exhibit oscillatory behavior produce a finite set of behaviors. When the phase-space behavior of the oscillatory behavior is properly constrained, these initializations produce an infinite but comprehensible set of asymptotically stable behaviors. While the predictions include all possible behaviors of the real system, a class of spurious behaviors has been identified. When limited numerical information is included in the model, the number of predictions is significantly reduced.

Dalle Molle, D. T.↗

Activities of the Center for Space Construction

The Center for Space Construction (CSC) at the University of Colorado at Boulder is one of eight University Space Engineering Research Centers established by NASA in 1988. The mission of the center is to conduct research into space technology and to directly contribute to space engineering education. The center reports to the Department of Aerospace Engineering Sciences and resides in the College of Engineering and Applied Science. The college has a long and successful track record of cultivating multi-disciplinary research and education programs. The Center for Space Construction is prominent evidence of this record. At the inception of CSC, the center was primarily founded on the need for research on in-space construction of large space systems like space stations and interplanetary space vehicles. The scope of CSC's research has now evolved to include the design and construction of all spacecraft, large and small. Within this broadened scope, our research projects seek to impact the underlying technological basis for such spacecraft as remote sensing satellites, communication satellites, and other special purpose spacecraft, as well as the technological basis for large space platforms. The center's research focuses on three areas: spacecraft structures, spacecraft operations and control, and regolith and surface systems. In the area of spacecraft structures, our current emphasis is on concepts and modeling of deployable structures, analysis of inflatable structures, structural damage detection algorithms, and composite materials for lightweight structures. In the area of spacecraft operations and control, we are continuing our previous efforts in process control of in-orbit structural assembly. In addition, we have begun two new efforts in formal approach to spacecraft flight software systems design and adaptive attitude control systems. In the area of regolith and surface systems, we are continuing the work of characterizing the physical properties of lunar regolith, and we are at work on a project on path planning for planetary surface rovers.

Source record↗

Fuzzy Logic Controller for Low Temperature Application

The most common temperature controller used in low temperature experiments is the proportional-integral-derivative (PID) controller due to its simplicity and robustness. However, the performance of temperature regulation using the PID controller depends on initial parameter setup, which often requires operator's expert knowledge on the system. In this paper, we present a computer-assisted temperature controller based on the well known.

proportional-integral-derivative controller PID fu↗

The Impact of Prior Biosphere Models in the Inversion of Global Terrestrial CO2 Fluxes by Assimilating OCO-2 Retrievals

Atmospheric mixing ratios of carbon dioxide (CO2) are largely controlled by anthropogenic emissions and biospheric fluxes. The processes controlling terrestrial biosphere-atmosphere carbon exchange are currently not fully understood, resulting in terrestrial biospheric models having significant differences in the quantification of biospheric CO2 fluxes. Atmospheric transport models assimilating measured (in situ or space-borne) CO2 concentrations to estimate "top-down" fluxes, generally use these biospheric CO2 fluxes as a priori information. Most of the flux inversion estimates result in substantially different spatio-temporal posteriori estimates of regional and global biospheric CO2 fluxes. The Orbiting Carbon Observatory 2 (OCO-2) satellite mission dedicated to accurately measure column CO2 (XCO2) allows for an improved understanding of global biospheric CO2 fluxes. OCO-2 provides much-needed CO2 observations in data-limited regions facilitating better global and regional estimates of "top-down" CO2 fluxes through inversion model simulations. The specific objectives of our research are to: 1) conduct GEOS-Chem 4D-Var assimilation of OCO-2 observations, using several state-of-the-science biospheric CO2 flux models as a priori information, to better constrain terrestrial CO2 fluxes, and 2) quantify the impact of different biospheric model prior fluxes on OCO-2-assimilated a posteriori CO2 flux estimates. Here we present our assessment of the importance of these a priori fluxes by conducting Observing System Simulation Experiments (OSSE) using simulated OCO-2 observations with known "true" fluxes.

Biosphere↗

BETO 2021 Peer Review - Process Monitoring and Predictions of Biorefinery Performance

Online process monitoring coupled with rapid predictive tools will be essential to refineries of the future to provide real-time feedback and process control on new, renewable feeds and their accompanying processes and products. This project will provide refinery operators with tools to predict product component concentrations in minutes from online, slip stream mass spectra, allowing for rapid detection of off-specification product. We will arrive at a template for predictive tool generation through the development of a specific tool as a starting point -- co-processing of pyrolysis oils and vacuum gas oil over fluid catalytic cracking (FCC) catalysts.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Identification and control of a multizone crystal growth furnace

This paper presents an intelligent adaptive control system for the control of a solid-liquid interface of a crystal while it is growing via directional solidification inside a multizone transparent furnace. The task of the process controller is to establish a user-specified axial temperature profile and to maintain a desirable interface shape. Both single-input-single-output and multi-input-multi-output adaptive pole placement algorithms have been used to control the temperature. Also described is an intelligent measurement system to assess the shape of the crystal while it is growing. A color video imaging system observes the crystal in real time and determines the position and the shape of the interface. This information is used to evaluate the crystal growth rate, and to analyze the effects of translational velocity and temperature profiles on the shape of the interface. Creation of this knowledge base is the first step to incorporate image processing into furnace control.

Batur, C.↗

Space vehicle electrical power processing distribution and control study. Volume 1: Summary

A concept for the processing, distribution, and control of electric power for manned space vehicles and future aircraft is presented. Emphasis is placed on the requirements of the space station and space shuttle configurations. The systems involved are referred to as the processing distribution and control system (PDCS), electrical power system (EPS), and electric power generation system (EPGS).

Krausz, A.↗

Designing an Intrusion Proof Adjustable Speed Drive System Controlling a Critical Process

In this paper, an intrusion proof adjustable speed drive system controlling a critical process in an industrial control system is detailed. In such a system, should the motor speed sensor signal data be compromised and/or altered via a cyber-attack, the system can potentially be unregulated, over speed and/or malfunction thereby disrupting the critical process. The proposed active detection scheme detailed in this paper introduces a private (secret) random signal termed as "watermark" into the inverter control signal that determines the PWM gating signals of the DC-AC inverter powering the motor. The watermarking signal introduced into the PWM modulation for the DC-AC inverter is shown to propagates its unique signature, which appears in all sensors signals at the inverter output such as voltage/current/speed used to control the motor. Now employing the measured data (from sensors), two statistical variance tests are conducted to identify anomalies if any in the presence of the watermarking signal. It is shown when an intrusion occurs to manipulate the sensor data to disturb and/or destabilize the process, the proposed tests immediately display a high value indicating a compromise in sensor data. It is shown that the proposed system is capable of immediate detection of a sophisticated attacks such as record/reply attack in which the actual speed sensor is disconnected and a prerecorded speed signal from the past of the same magnitude is played back to the controller. Several types of cyber-attacks such as speed reduction/increase including vibration have been tested. Extensive simulation results verify the proposed concepts. Experimental results will be discussed in the conference presentation.

Alotaibi, Faris↗

Achieving Verifiable and High Integrity Instrumentation and Control Systems through Complexity Awareness and Constrained Design. Final Report

While most process control industries have been able to embrace digital Instrumentation and Control (I&C) technology to improve performance, reliability, maintainability, and efficiency of production, the nuclear industry has been relatively slow to adopt digital I&C for safety critical plant functions. There are a variety of reasons for this, but in general the nuclear industry takes a conservative stance that new technologies must mature before adoption. A deeper underlying reason for not fully realizing digital I&C and automation in nuclear power is associated with the complexity that can manifest in software-based systems that is different in nature from the complexity of their analog predecessors. Accordingly, this research pursued the development of innovative architectures and methods to “constrain complexity” to enhance verifiability of digital I&C devices. These constraints can positively impact the reduction of Software Common Cause Failures (SCCF) and other systematic errors. The architectural concept developed in this research effort is called SymPLe. SymPLe is specifically aimed at safety critical functions within Nuclear Power Plants and other critical infrastructure where constraining device complexity to support verifiability and safety case arguments is important. The SymPLe architecture is designed to promote “accessible verification” between OEM/utility engineers and the regulatory agencies who review and license nuclear power plant I&C systems. The major contributions of this work to the nuclear industry are: Demonstration of SymPLe as a viable approach to “complexity aware” I&C systems and Embedded Digital Devices.Comprehensive use of model-based design and engineering to produce verifiable I&C systems for the nuclear industry with clear findings on the usability of model-based engineering. Employ comprehensive use of model-based engineering, testing, and verification in an IEC 61508 workflow in support of design assurance. Gathered evidence of “difficult to find” design flaws found using model-based design and testing methods. Detailed the nature of these SCCFs including where they were introduced, the triggers, and how they were found. Gathered evidence on the synergistic use of practical formal methods and testing and how these methods can be used to significantly increase assurance of reduction and avoidance of design flaws.

Testing↗

RAM-Based parallel-output controller

Selected bit strings in serial-data link are extracted for processing. Controller is programmable interface between serial-data link and peripherals that accept parallel data. It can be used to drive displays, printers, plotters, digital-to-analog converters, and parallel-output ports.

Niswander, J. K.↗

Interaction Metrics for Feedback Control of Sound Radiation from Stiffened Panels

Interaction metrics developed for the process control industry are used to evaluate decentralized control of sound radiation from bays on an aircraft fuselage. The metrics are applied to experimentally measured frequency response data from a model of an aircraft fuselage. The purpose is to understand how coupling between multiple bays of the fuselage can destabilize or limit the performance of a decentralized active noise control system. The metrics quantitatively verify observations from a previous experiment, in which decentralized controllers performed worse than centralized controllers. The metrics do not appear to be useful for explaining control spillover which was observed in a previous experiment.

Cabell, Randolph H.↗

An Overview of Magnetic Bearing Technology for Gas Turbine Engines

The idea of the magnetic bearing and its use in exotic applications has been conceptualized for many years, over a century, in fact. Patented, passive systems using permanent magnets date back over 150 years. More recently, scientists of the 1930s began investigating active systems using electromagnets for high-speed ultracentrifuges. However, passive magnetic bearings are physically unstable and active systems only provide proper stiffness and damping through sophisticated controllers and algorithms. This is precisely why, until the last decade, magnetic bearings did not become a practical alternative to rolling element bearings. Today, magnetic bearing technology has become viable because of advances in micro-processing controllers that allow for confident and robust active control. Further advances in the following areas: rotor and stator materials and designs which maximize flux, minimize energy losses, and minimize stress limitations; wire materials and coatings for high temperature operation; high-speed micro processing for advanced controller designs and extremely robust capabilities; back-up bearing technology for providing a viable touchdown surface; and precision sensor technology; have put magnetic bearings on the forefront of advanced, lubrication free support systems. This paper will discuss a specific joint program for the advancement of gas turbine engines and how it implies the vitality of magnetic bearings, a brief comparison between magnetic bearings and other bearing technologies in both their advantages and limitations, and an examination of foreseeable solutions to historically perceived limitations to magnetic bearing.

Clark, Daniel J.↗

Control of passivation and compensation in Mg-doped GaN by defect quasi Fermi level control

A defect quasi Fermi level (dQFL) control process based on above bandgap illumination was applied to control H and V N -complexes, which are the main contributors to the passivation and self-compensation, respectively, in Mg:GaN grown via metalorganic chemical vapor deposition. Secondary ion mass spectrometry measurements confirmed that the total Mg incorporation was unaffected by the process. However, the total H concentration was reduced to similar levels obtained by post-growth thermal activation prior to any annealing treatment. Similarly, the 2.8 eV emission in the photoluminescence spectra, attributed to compensating V N and its complexes, was reduced for the dQFL-process samples. After thermal activation and Ni/Au contact deposition, Hall effect measurements revealed lower resistivities (increased mobilities and free hole concentrations) for dQFL-grown samples with Mg doping concentrations above and below 2 × 10 19 cm -3 . All these results demonstrate that the dQFL process can effectively reduce the H-passivation and self-compensation of the Mg:GaN films.

36 MATERIALS SCIENCE↗